• 상하수도학회지
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• 제13권1호
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• pp.72-80
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• 1999

Separation of VOCs(Volatile Organic Compounds) in Water Using Activated Carbon is known to be effective. Activated Carbon has been and will be employed in many water treatment plants. Simplified plug flow homogeneous surface diffusion model(PFHSDM) has been used to predict adsorption of organic matter. Finite Element Method(FEM) was used to analyze the model. Out of water quality control substances, benzene, toluene and tetrachloroethylene were used in the small column test. Film diffusion coefficients and surface diffusion coefficients were obtained from the column test, and were compared with the modeling results. Mc Cune, Williamson, William and Kataoka model, were compared with film diffusion coefficients obtained in the test. McCune model was fitted best for those VOCs used in this experiment. Film diffusion coefficients of VOCs obtained were benzene 0.265 cm/min, toluene 0.348 cm/min and tetrachloroethylene 0.298 cm/min. Surface diffusion coefficients of VOCs obtained were benzene $6.36{\times}10^{-8}cm^2/min$, toluene $3.20{\times}10-8cm2/min$, and tetrachloruethylene $4.94{\times}10^{-8}cm^2/min$.

• 소성∙가공
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• 제22권8호
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• pp.463-469
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• 2013

In the previous work, a new forging process design, which included incremental upsetting, diffusion bonding and cogging, was suggested as a method to manufacture 1.9wt%C ultrahigh carbon workrolls. The previous study showed that incremental upsetting and diffusion bonding are effective in closing voids and healing of the closed void. In addition, compression tests of the 1.9wt%C ultrahigh carbon steel revealed that new microvoids form within the blocky cementite at temperatures of less than $900^{\circ}C$ and that local melting can occur at temperatures over $1120^{\circ}C$. Thus, the forging temperature should be controlled between 900 and $1120^{\circ}C$. Based on these results, incremental upsetting and diffusion bonding were used to check whether they are effective in closing and healing voids in a 1.9wt%C ultrahigh carbon steel. The incremental upsetting and diffusion bonding were performed using sub-sized specimens of 1.9wt%C ultrahigh carbon steel. The specimen was deformed only in the radial direction during the incremental upsetting until the reduction ratio reached about 45~50%. After deformation the specimens were kept at $1100^{\circ}C$ for the 1 hour in order to obtain a high bonding strength for the closed void. Finally, microstructural observations and tensile tests were conducted to investigate void closure behavior and bonding strength.

• Carbon letters
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• 제16권1호
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• pp.1-10
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• 2015

In recent years, flame synthesis has absorbed a great deal of attention as a combustion method for the production of metal oxide nanoparticles, carbon nanotubes, and other related carbon nanostructures, over the existing conventional methods. Flame synthesis is an energy-efficient, scalable, cost-effective, rapid and continuous process, where flame provides the necessary chemical species for the nucleation of carbon structures (feed stock or precursor) and the energy for the production of carbon nanostructures. The production yield can be optimized by altering various parameters such as fuel profile, equivalence ratio, catalyst chemistry and structure, burner configuration and residence time. In the present report, diffusion and premixed flame synthesis methods are reviewed to develop a better understanding of factors affecting the morphology, positioning, purity, uniformity and scalability for the development of carbon nanotubes along with their correlated carbonaceous derivative nanostructures.

• 한국염색가공학회지
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• 제12권1호
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• pp.52-60
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• 2000

In the prior studies, we reported that the dye uptakes of C. I. Disperse Violet 1 on polyester fiber in hexane and cyclohexane were higher than those in the other solvents, as the number of carbon atoms of alkanes decreased, the dye uptake increased, and the logarithmic plot of the dye uptakes vs. the solubilities of the dye showed that the dye uptakes are inversely proportional to the solubilities. In this study, for Interpretation of dyeing behavior of C. I. Disperse Violet 1 on polyester in alkanes, the thremodynamic parameters of dyeing, such as standard affnity, heat of dyeing(enthalpy change), entropy change, diffusion coefficient, and activation energy of diffusion, were obtained from isotherms and dyeing rates at different temperature. As the number of carbon atoms of alkanes increased, the standard affinity decreased, but the heat of dyeing(enthalpy change) and the entropy change showed larger negative values. These results mean that as the number of carbon atoms of alkanes increases, the dye uptake decreases, but both the fraction of the dye molecules dyed at relatively highly aligned or compact region of polyester fiber and the regularity of dye aggregates in the fiber become increased. As the number of carbon atoms of alkanes increased, the diffusion coefficient decreased, but the activation energy of diffusion increased. In the alkane of larger number of carbon atoms, because the solubility of the dye is higher, the desorption rate of the dye is faster and the diffusion coefficient is smaller than those in the smaller alkanes. But the energy required to separate the dye molecules from the alkane molecules is much higher because the interaction between the alkane molecule and the dye molecule become strong with the number of carbon atoms.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 추계학술대회 초록집
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• pp.76.1-76.1
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• 2010

Recently, many efforts to solve the durability problem of PEM fuel cell are carried on constantly. However, despite this attention, durability researches of gas diffusion layer (GDL) are not much reported yet. Generally, GDL of PEM fuel cell experiences three external attacks, which are dissolution of water, erosion of gas flow, corrosion of electric potential. In this study, among these degradation factors, carbon corrosion of electric potential was focused and investigated with accelerated carbon corrosion test. Through the test, it is confirmed that carbon corrosion occurred at GDL, and corroded GDL decreased a performance of operating fuel cell. The property changes of GDL were measured with various methods such as air permeability meter, pore distribution analyzer, thermo gravimetric analyzer, and tensile stress test to discover the effects of carbon corrosion. Carbon corrosion caused not only loss of weight and thickness, but also degradation of mechanical strength of GDL. In addition, to analysis the reason of GDL property changes, a surface and a cross section of GDL were observed with scanning electron microscope. After 100 hours test, the GDL showed serious damage in center of layer.

• Asian Journal of Atmospheric Environment
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• 제10권1호
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• pp.1-12
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• 2016

Numerous researchers have proposed that surface area is a more appropriate indicator than mass for evaluating pulmonary inflammatory responses caused by exposure to fine and ultrafine particles. In this study, measurements of surface area concentrations of aerosols were conducted in Yokohama, Japan, using the diffusion charging method. $PM_{2.5}$ mass concentration and black carbon concentration in $PM_{2.5}$ were also measured. The 24-hour continuous measurement campaigns were conducted 39 times from March to November, 2014. The surface area concentration was more closely correlated with the black carbon concentration than with the $PM_{2.5}$ mass concentration. It is considered that the abundance of black carbon particles significantly affects the surface area concentration of $PM_{2.5}$. The strength of the correlation between the surface area and black carbon concentrations varied considerably among the measurement campaigns. A relatively weaker afternoon correlation was observed compared with the other time zones (morning, evening, and night). We consider that these phenomena are due to the transportation/formation of the particles other than black carbon that affects surface area concentration and/or the variation of the surface condition of the black carbon particles.

• 한국연소학회지
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• 제8권2호
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• pp.50-55
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• 2003

Synthesis of carbon nanofibers on a metal substrate by an ethylene fueled inverse diffusion flame was observed. Stainless steel plates were used for the catalytic metal substrate. The effects of radial distance and residence time of the substrate were investigated. The role of hydrocarbon composition in the fuel was also viewed. Nanofibers with a diameter range of 30-70nm were found on the substrate. The carbon nanofibers were formed and grown in the region from 4 to 5.5mm from the central axis of a flame outside of the visible flame front in the radial direction. The minimum residence time required for the formation of carbon nanofibers were about 20 seconds, and over 60 seconds were required for the full-scale growth. The characteristic time of the formation of carbon nanofibers was much shorter than that of the substrate temperature growth. In this study, the variation in hydrocarbon composition had no significant effect on the formation and growth of the carbon nanofibers.

• 소성∙가공
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• 제22권5호
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• pp.269-274
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• 2013

Experiments and numerical simulations of the incremental upsetting test were carried out to investigate void closure behavior and mechanical characteristic of a 1.5wt%C ultra-high carbon steel. The experimental results showed that the voids become quickly smaller as the reduction ratio increases. The simulation results confirmed this behavior and indicated that the voids were completely closed at a reduction ratio of about 40~45% during incremental upsetting. After the completion of the incremental upsetting tests, the process of diffusion bonding was employed to heal the closed voids in the deformed specimens. To check the appropriate temperature for diffusion bonding, deformed specimens were kept at 800, 900, 1000 and $1100^{\circ}C$ for an hour. In order to investigate the effect of holding time for diffusion bonding at $1100^{\circ}C$, specimens were kept at 10, 20, 30, 40, 50 and 60minutes in the furnace. A distinction between closed and healed voids was clearly established using microstructural observations. In addition, subsequent tensile tests demonstrated that complete healing of a closed void was achieved for diffusion bonding temperatures in the range $900{\sim}1100^{\circ}C$ with a holding time larger than 1 hour.

• 한국결정성장학회지
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• 제18권1호
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• pp.15-21
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• 2008

탄화규소(SiC)는 산화저항성, 내식성, 고온 강도 및 열전도 특성 등의 기계적 특성이 매우 우수한 재료로 알려져 있지만, 강한 공유결합성으로 인하여 그 소결이 매우 어려운 재료이다. 본 연구에서는 치밀한 탄화규소 소결체를 제조하기 위하여 카본 및 보론을 소결 첨가제로하여 열간 가압 소결법을 적용하여 탄화규소 소결체를 제작하여 그 특성을 평가하였다. 카본의 첨가는 탄화규소의 소결을 촉진하는 역할을 하여 비정상 입성장을 억제하기 때문에 미세하고 균일한 미세구조를 형성하였기 때문에 탄화규소 소결체의 기계적 특성을 향상시키는 것을 확인 할 수 있었다. 또한 차본의 첨가는 소결 중 보론의 첨가에 의해 발생하는 탄화규소의 6H 구조에서 4H 구조로의 상전이를 억제함을 알 수 있었다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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• pp.224-224
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• 2012

For decades, carbon fiber has expanded their application fields from reinforced composites to energy storage and transfer technologies such as electrodes for super-capacitors and lithium ion batteries and gas diffusion layers for proton exchange membrane fuel cell. Especially in fuel cell, water repellency of gas diffusion layer has become very important property for preventing flooding which is induced by condensed water could damage the fuel cell performance. In this work, we fabricated superhydrophobic network of carbon fiber with high aspect ratio hair-like nanostructure by preferential oxygen plasma etching. Superhydrophobic carbon fiber surfaces were achieved by hydrophobic material coating with a siloxane-based hydrocarbon film, which increased the water contact angle from $147^{\circ}$ to $163^{\circ}$ and decreased the contact angle hysteresis from $71^{\circ}$ to below $5^{\circ}$, sufficient to cause droplet roll-off from the surface in millimeter scale water droplet deposition test. Also, we have explored that the condensation behavior (nucleation and growth) of water droplet on the superhydrophobic carbon fiber were significantly retarded due to the high-aspect-ratio nanostructures under super-saturated vapor conditions. It is implied that superhydrophobic carbon fiber can provide a passage for vapor or gas flow in wet environments such as a gas diffusion layer requiring the effective water removal in the operation of proton exchange membrane fuel cell. Moreover, such nanostructuring of carbon-based materials can be extended to carbon fiber, carbon black or carbon films for applications as a cathode in lithium batteries or carbon fiber composites.