• Title/Summary/Keyword: Carbon Number

Search Result 1,419, Processing Time 0.03 seconds

A Study on the Prediction of the Cetane Number of Diesel Fuels from the Carbon Types Structural Compositions by 13C-Nuclear Magnetic Resonance Spectroscopy (13C-NMR에 의해 결정된 탄소 유형별 구조적 조성으로부터 디이젤 연료의 세탄가의 예측에 관한 연구)

  • Choi, Ju-Hwan;Chun, Yong-Jin;Choi, Ung-Su;Choi, Young-Sang;Kwon, Oh-Kwan
    • Applied Chemistry for Engineering
    • /
    • v.4 no.4
    • /
    • pp.709-714
    • /
    • 1993
  • The cetane number is a measure of ignition quality, specifically ignition delay, of diesel fuel. It is an engine measure of kinetic phenomena. The ignition quality such as kinetic behavior does correlate with the molecular structure, the carbon type structural composition. In fact, we use the group additivity rule to dissect the molecular structures and predict cetane number. In this study, the use of $^{13}C-Nuclear$ Magnetic Resonance spectroscopic measuring the molecular structure and group additivity rule at different diesel fuels, whose cetane numbers were determined on a number of standard cetane rating engines is proposed to predict cetane numbers that relate the carbon type structural composition. The effect of the molecular structures on the cetane numbers has been studied.

  • PDF

Bacterial regrowth in biofilms formed in granular activated carbon filter adsorbers and the bacterial isolation and identification (입상 활성탄 여과지에서 세균의 재성장과 생물막 형성 세균의 분리 및 동정)

  • Lee, Gyucheol;Kwon, Soonbok;Lee, Byungki;Park, Jonggeun
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.22 no.2
    • /
    • pp.205-212
    • /
    • 2008
  • This study aimed to investigate the biofilm formation, bacterial regrowth, and bacterial community structure in the granular-activated carbon (GAC) filter adsorbers (FAs) used in water treatment plants. In 2005 and 2006, raw water, settled water, GAC FA by depth, and filtered water were collected twice a year from water treatment plants (WTPs) B and S. The number of heterotrophic bacteria, including mesophilic and psychrophilic bacteria, in such collected waters was investigated along with the total number of coliforms therein. Heterotrophic bacteria were detected in most samples, mainly at the surface layers of the GAC FAs, and fewer such bacteria were found in the lower and bottom layers. An increase in the bacterial number, however, was observed in the samples from various depths of the GAC FAs in WTPs B and S compared with the surface layers. An increase in the bacterial number was also detected in the filtered water. This may indicate that there is a regrowth of the bacteria in the GAC FA. Considering, however, that heterotrophic bacteria were not found in the filtered water, it can be deduced that most bacteria are removed in the chlorination process. Coliforms were detected at the surface layer of the GAC FAs, but their regrowth was not observed. MicroLog systems were used to identify the bacteria community distribution. Eight genera and 14 species, including Pseudomonas spp., were detected in WTP B, and 8 genera and 9 species, including Aeromonas spp., in WTP S. Further studies are required to elucidate their role in the biofilms in water treatment processes.

Effect of Ginseng Saponins on the Distribution of Brain Nerve Cells in Carbon Monoxide-intoxicated Mice and Aged Mice (인삼 사포닌이 일산화탄소중독 및 노화과정에서 생쥐의 뇌신경세포 분포에 미치는 영향)

  • Shin, Jeung-Hee;Lee, Ihn-Rhan;Cho, Geum-Hee;Yun, Jae-Soon
    • YAKHAK HOEJI
    • /
    • v.36 no.3
    • /
    • pp.269-277
    • /
    • 1992
  • The effects of ginseng saponins on the distribution of nerve cells in cerebral cortex of carbon monoxide (CO)-intoxicated mice were studied in the young ($5{\sim}8$ weeks) and aged ($43{\sim}52$ weeks) mice. Mice were exposed to 5000 ppm of CO for 40 minutes (72% HbCO). After that, nerve cells in motor(area 4), somatosensory(area 3) and visual(area 17) area of cerebral cortex was observed. In young mice, the number of nerve cells in each area was significantly decreased on 1st, 7th and 14th day after CO intoxication. In aged mice, that was also decreased after CO intoxication. Especially the number of the nerve cells in motor and somatosensory area was significantly decreased on 1st and 7th day, while that in visual area was decreased only on 1st day. The number of nerve cells in young mice pretreated with ginseng saponins were significantly decreased less on 7th and 14th day than that of untreated mice. The number of nerve cells in each area of normal aged mice was larger than that of normal young mice. The results suggest that CO exposure causes local degeneration or disturbance of nerve cells and delayed neurologic sequelae, while ginseng saponins might play a role of protective action on the nerve cells which were damaged by CO.

  • PDF

Preparation of Activated Carbon Screen Using Stainless Steel Mesh and Cellulose Fiber (스테인레스 망과 섬유를 이용한 활성탄소 망의 제조)

  • Shin, Jinhwan;Kim, Taeyoung;Jeoung, Youngdo
    • Journal of the Korean GEO-environmental Society
    • /
    • v.9 no.3
    • /
    • pp.45-50
    • /
    • 2008
  • In this work, stainless steel mesh-supported activated carbons were prepared using phenolic resin and cellulose fiber. $ZnCl_2$ was used as a activation reagent in this work. $ZnCl_2$-chemical activation method has been proposed to produce highly porous activated carbons. The objectives of this work were to develop an optimal condition for manufacturing activated carbon assemblies screen from stainless steel mesh and phenolic resin. The iodine number was more increased over activation temperature of $450^{\circ}C$. Iodine number was 657 mg/g at activation temperature of $550^{\circ}C$, penolic resin concentration 20% and $ZnCl_2$ concentration 15%. Iodine number was 1359.4 mg/g when 10% cellulose added to these conditions.

  • PDF

Effect of carbonization temperature and chemical pre-treatment on the thermal change and fiber morphology of kenaf-based carbon fibers

  • Kim, Jin-Myung;Song, In-Seong;Cho, Dong-Hwan;Hong, Ik-Pyo
    • Carbon letters
    • /
    • v.12 no.3
    • /
    • pp.131-137
    • /
    • 2011
  • Kenaf fibers, cellulose-based natural fibers, were used as precursor for preparing kenafbased carbon fibers. The effects of carbonization temperature ($700^{\circ}C$ to $1100^{\circ}C$) and chemical pre-treatment (NaOH and $NH_4Cl$) at various concentrations on the thermal change, chemical composition and fiber morphology of kenaf-based carbon fibers were investigated. Remarkable weight loss and longitudinal shrinkage were found to occur during the thermal conversion from kenaf precursor to kenaf-based carbon fiber, depending on the carbonization temperature. It was noted that the alkali pre-treatment of kenaf with NaOH played a role in reducing the weight loss and the longitudinal shrinkage and also in increasing the carbon content of kenaf-based carbon fibers. The number and size of the cells and the fiber diameter were reduced with increasing carbonization temperature. Morphological observations implied that the micrometer-sized cells were combined or fused and then re-organized with the neighboring cells during the carbonization process. By the pre-treatment of kenaf with 10 and 15 wt% NaOH solutions and the subsequent carbonization process, the inner cells completely disappeared through the transverse direction of the kenaf fiber, resulting in the fiber densification. It was noticeable that the alkali pre-treatment of the kenaf fibers prior to carbonization contributed to the forming of kenaf-based carbon fibers.

Preparation of Carbon Nanotubes and Carbon Nanowires from Methane Pyrolysis over Pd/SPK Catalyst (Pd/SPK 촉매상에서 메탄의 열분해 반응으로부터 탄소 나노튜브 및 탄소 나노선의 제조)

  • Seo, Ho Joon;Kwon, Oh Yun
    • Applied Chemistry for Engineering
    • /
    • v.18 no.1
    • /
    • pp.94-97
    • /
    • 2007
  • Carbon nanotubes and nanowires were prepared by methane pyrolysis over Pd(5)/SPK catalyst by changing oxygen molar ratio in a fixed bed flow reactor under atmospheric condition and also analyzed by SEM and TEM. When the $CH_4/O_2$ molar ratio was 1, carbons were not almost deposited on the catalyst bed support, but when it was 2, carbons were deposited as much as plugging reactor. TEM and SEM images for the deposited carbons showed a number of single-walled carbon nanotubes and carbon nanowires. The growth mechanism of carbon nanotubes produced on the catalyst surface was the tip growth mode. It should be played an important role in carbon nanotubes and nanowires produced on the catalyst bed support to formate the carbon growth velocity vectors and nuclei of ring structure of carbon nanowires. SPK carrier was $N_2$ isotherm of IV type with mesopores, and excellent in the thermal stability.

Study of CO2 Absorption in Forest by Airborn LiDAR Data (LiDAR 자료를 이용한 산림 CO2 흡수량 산출 연구)

  • Go, Sin Young;Park, Jung Gi;Cho, Gi Sung
    • Journal of Korean Society for Geospatial Information Science
    • /
    • v.21 no.4
    • /
    • pp.29-35
    • /
    • 2013
  • Generally, Calculation of carbon dioxide absorption in the forest area is calculated using the information of the forest, such as tree height and DBH(Diameter of Breast Height). Tree height and DBH of these are obtained using the remote sensing data such as imagery and information of local forest survey. However, Mixed forest with a high proportion of field survey to lower the accuracy of forest information. In this study, vertical structure of the tree were identified by applying region growing method based on the slope using LiDAR data and height and number of the tree were identified by applying extracting top of the tree algorithm. Through the vertex tree extraction algorithm to identify height of tree and the number of individuals, substitute this for the DBH relation formula which is drawn from data through field surveys. In this, a quantitative calculation of carbon dioxide absorption were able to calculate the basic data. Also, carbon dioxide absorption of three type trees were calculated and average per unit area of carbon dioxide absorption were able to estimate.

Design and performance study of fabry-perot filter based on DBR for a non-dispersive infrared carbon dioxide sensor (비분산적외선 CO2 센서를 위한 DBR기반의 패브리 페로-필터 설계 및 성능 연구)

  • Do, Nam Gon;Lee, Junyeop;Jung, Dong Geon;Kong, Seong Ho;Jung, Daewoong
    • Journal of Sensor Science and Technology
    • /
    • v.30 no.4
    • /
    • pp.250-254
    • /
    • 2021
  • A highly sensitive and selective non-dispersive infrared (NDIR) carbon dioxide gas sensor requires achieving high transmittance and narrow full width at half maximum (FWHM), which depends on the interface of the optical filter for precise measurement of carbon dioxide concentration. This paper presents the design, simulation, and fabrication of a Fabry-Perot filter based on a distributed Bragg reflector (DBR) for a low-cost NDIR carbon dioxide sensor. The Fabry-Perot filter consists of upper and lower DBR pairs, which comprise multilayered stacks of alternating high- and low-index thin films, and a cavity layer for the resonance of incident light. As the number of DBR pairs inside the reflector increases, the FWHM of the transmitted light becomes narrower, but the transmittance of light decreases substantially. Therefore, it is essential to analyze the relationship between the FWHM and transmittance according to the number of DBR pairs. The DBR is made of silicon and silicon dioxide by RF magnetron sputtering on a glass wafer. After the optimal conditions based on simulation results were realized, the DBR exhibited a light transmittance of 38.5% at 4.26 ㎛ and an FWHM of 158 nm. The improved results substantiate the advantages of the low-cost and minimized process compared to expensive commercial filters.

Characterization and Construction of Chemical Vapor Deposition by using Plasma (rf 플라즈마 화학기상증착기의 제작 및 특성)

  • 김경례;김용진;현준원;이기호;노승정;최병구
    • Journal of the Korean institute of surface engineering
    • /
    • v.33 no.2
    • /
    • pp.69-76
    • /
    • 2000
  • The rf plasma chemical vapor deposition is a common method employed for diamond or amorphous carbon deposition. Diamond possesses the strongest bonding, as exemplified by a number of unique properties-extraordinary hardness, high thermal conductivity, and a high melting tempera tore. Therefore, it is very important to investigate the synthesis of semiconducting diamond and its use as semiconductor devices. An inductively coupled rf plasma CVD system for producing amorphous carbon films were developed. Uniform temperature and concentration profiles are requisites for the deposition of high quality large-area films. The system consists of rf matching network, deposition chamber, pumping lines for gas system. Gas mixtures with methane, and hydrogen have been used and Si (100) wafers used as a substrate. Amorphous carbon films were deposited with methane concentration of 1.5% at the process pressure of S torr~20 torr, and process temperature of about $750^{\circ}C$. The nucleation and growth of the amorphous carbon films have been characterized by several methods such as SEM and XRD.

  • PDF

A Study on the Determination of Carbon monoxide in the Blood by Spectrophotometry (분광광도법에 의한 혈중일산화탄소의 측정에 관한 연구)

  • 정근호
    • Journal of Environmental Health Sciences
    • /
    • v.2 no.1
    • /
    • pp.49-51
    • /
    • 1975
  • The accidents, homicides and suicides of carbon monoxide poisoning to increase in number every year are required precize, accurate, and rapid method for the determination of carbon monoxide in the blood samples. Here is the basis of this method for the determination of percentage saturation of hemoglobin by carbon monoxide which have found out to be suitable in laboratory as follows: A 0.1ml of blood is mixed with 20ml of 0.1% ammonium hydroxide, and 20mg sodium hydrosulfite is added to convert oxyhemoglobin to reduction hemoglobin. The absorbance is measured at 538nm and 578nm, the measurement was carried out within ten minutes of addition of sodium hydrosulfate.

  • PDF