• Title/Summary/Keyword: Carbon Nanotube, CNT

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Modeling and Simulation of Cantilevered Carbon-Nanotube Resonator with the Attached Mass (부착 질량을 가지는 탐침 탄소-나노튜브 공진기의 모델링 및 시뮬레이션)

  • Choi, Tae Ho;Lee, Jun Ha;Kim, Tae-Eun
    • Journal of the Semiconductor & Display Technology
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    • v.11 no.2
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    • pp.81-84
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    • 2012
  • Cantilevered carbon-nanotube-resonator was investigated via classical molecular dynamics simulations. The resonator system is including the attached nanocluster. A nanocluster with a finite length was modeling by some atomic rings. The mass of the nanocluster was equally distributed on the carbon atoms, composed of the atomic rings. The effective density factor, which could be considered as the single parameter affecting the resonance frequency shift, was significantly influenced by the mass, the position, and the linear density of the attached nanocluster. The linear density of the attached nanocluster was an important parameter to analyze the vibrational behavior of the CNT-resonator, including the attached nanocluster.

Prediction of Thermo-mechanical Behavior for CNT/epoxy Composites Using Molecular Dynamics Simulation (분자동역학 시뮬레이션을 이용한 CNT/에폭시 복합재의 열기계적 거동 예측)

  • Choi, Hoi Kil;Jung, Hana;Yu, Jaesang;Shin, Eui Sup
    • Composites Research
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    • v.28 no.5
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    • pp.260-264
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    • 2015
  • In this paper, molecular dynamics (MD) simulation was carried to predict thermo-mechanical behaviors for carbon nanotube (CNT) reinforced epoxy composites and to analyze the trends. Total of six models having the volume fractions of CNT from 0 to 25% in epoxy were constructed. To predict thermal behaviors, temperature was increased constantly from 300 to 600 K, and the glass transition temperature ($T_g$) and coefficient of thermal expansion (CTE) analyzed using the relationship between temperature and specific volume. The elastic moduli that represented to the mechanical behaviors were also predicted by constant strain. Additionally, the effects of functionalization of CNT on mechanical behaviors of composite were analyzed. Models were constructed to represent CNTs functionalized by nitrogen doping and COOH groops, and interfacial behaviors and elastic moduli were analyzed. Results showed that the agglomerations of CNTs in epoxy cause by perturbations of thermo-mechanical behaviors, and the functionalization of CNTs improved the interfacial response as well as mechanical properties.

Fabrication and Evaluation of Carbon Nanotube Reinforced Al Matrix Composite by a Powder-in-sheath Rolling Method (분말시스압연법에 의한 CNT 강화 Al기 복합재료의 제조 및 평가)

  • Lee, Seong-Hee;Hong, Dongmin
    • Journal of Powder Materials
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    • v.21 no.1
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    • pp.50-54
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    • 2014
  • A powder-in-sheath rolling method was applied to a fabrication of a carbon nano tube (CNT) reinforced aluminum composite. A STS304 tube with an outer diameter of 34 mm and a wall thickness of 2 mm was used as a sheath material. A mixture of pure aluminum powders and CNTs with the volume contents of 1, 3, 5 vol was filled in the tube by tap filling and then processed to 73.5% height reduction by a rolling mill. The relative density of the CNT/Al composite fabricated by the powder-in-sheath rolling decreased slightly with increasing of CNTs content, but exhibited high value more than 98. The grain size of the aluminum matrix was largely decreased with addition of CNTs; it decreased from $24{\mu}m$ to $0.9{\mu}m$ by the addition of only 1 volCNT. The average hardness of the composites increased by approximately 3 times with the addition of CNTs, comparing to that of unreinforced pure aluminum. It is concluded that the powder-in-sheath rolling method is an effective process for fabrication of CNT reinforced Al matrix composites.

Fast and Soft Functionalization of Carbon Nanotube with -SO3H, -COOH, -OH Groups for Catalytic Hydrolysis of Cellulose to Glucose

  • Lusha, Qin;Lee, Sungho;Li, Oi Lun
    • Journal of Surface Science and Engineering
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    • v.53 no.3
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    • pp.87-94
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    • 2020
  • Herein, sulfonated carbon nanotubes (CNT) have been prepared in dilute sulfuric acid (H2SO4) via a novel sulfonation approach based on gas-liquid interfacial plasma (GLIP) at room temperature. The sulfonic acid groups and total acid groups densities of CNT after GLIP treatment in 2 M H2SO4 for 45 min can reach to 0.53 mmol/g and 3.64 mmol/g, which is higher than that of sulfonated CNT prepared under 0.5 M / 1 M H2SO4. The plasma sulfonated CNT has been applied as catalysts for the conversion of microcrystalline cellulose to glucose. The effect of hydrolysis temperature and hydrolysis time on the conversion rate and product distribution have been discussed. It demonstrates that the total conversion rate of cellulose increasing with hydrolysis temperature and hydrolysis time. Furthermore, the GLIP sulfonated CNT prepared in 2 M H2SO4 for 45 min has shown high catalytic stability of 85.73 % after three cycle use.

Carbon Nanotube (CNT) based Transparent Conductive Films for Display Applications (탄소나노튜브 기반 투명전도성 필름 및 이의 응용)

  • Lee, Geon-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.77-77
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    • 2007
  • The development of next generation displays such as flexible display is a major challenge. Most materials and processes in current flat panel display industry cannot be transferred to flexible substrates. Typically, indium tin oxide (ITO) thin films are brittle and need to be deposited at high temperature to achieve an optimal opto-electrical property, therefore ITO films cannot be used as a flexible electrode. Up to date, many alternative materials to ITO have been proposed such as conductive polymers, nanometals, solution deposited transparent conductive oxide(TCO) and carbon nanotubes(CNTs). CNT based transparent conductive films are fabricated on glass and polymer substrates. CNT thin films exhibit a sheet resistance ($R_s$) of nearby $10^3\;{\Omega}/sq$ with a transmittance of around 80% on the visible light range, which is attributed by excellent dispersion and interaction among CNTs, solvents and polymeric binders. This talk will present the current studies, opto-electrical properties, design criteria and its applications for CNT-based transparent conductive films.

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ENHANCED MICROWAVE ABSORPTION OF CNT COMPOSITES MIXING WITH Fe3O4 AND CARBONYL IRON

  • JUNG HYO PARK;JAEHO CHOI;KISU LEE;JINWOO PARK;JUNG KUN SONG;EUNKYUNG JEON
    • Archives of Metallurgy and Materials
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    • v.63 no.3
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    • pp.1513-1516
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    • 2018
  • We fabricated two different kinds of composite materials for absorbing microwave in a frequency range of 2 to 18 GHz using coaxial airline and thru-reflect-line (TRL) method. The composite materials having carbon nanotube (CNT) with carbonyl iron (CI) or iron oxide (Fe3O4) were fabricated by mixing each components. Magnetic properties were measured by SQUID equipment. Complex permittivity and complex permeability were also obtained by measuring S-parameters of the toroidal specimen dispersing CI/CNT and Fe3O4/CNT into the 50 weight percent (wt%) epoxy resin. The real permittivity was improved by mixing the CNT however, the real permeability was same as pure magnetic powders. The CI/CNT had a maximum value of real permittivity and real permeability, 11 and 1.4 at 10 GHz, respectively. The CNT composites can be adapted to the radar absorbing materials, band width 8-12 GHz.

Characteristics Analysis of Nano-composites Films Using Extruder (압출성형기를 이용한 나노복합재 필름의 특성 분석)

  • Kwon, Il-Jun;Park, Sung-Min;Yoo, Sung-Hun;Yeum, Jeong-Hyun
    • Textile Coloration and Finishing
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    • v.28 no.2
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    • pp.101-108
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    • 2016
  • Polypropylene(PP)/multiwalled carbon nanotubes(MWCNT) nanocomposites films and PP/poly(vinyl alcohol)/CNT nanocomposites films were prepared through melt mixing method by the extruder. The PP/CNT nanocomposites films, which contain CNT of a variable content, were prepared for the first time and research on a appropriate content of the CNT on the PP/CNT nanocomposites films was conducted. The effects of take-up speed of the extruder on the mechanical and chemical properties of the PP/CNT and PP/PVA/CNT nanocomposites film were studied. Field emission scanning electron microscope(FE-SEM) was used to examine the surface morphology and the DSC measurement and tensile test were conducted. It was found that the properties decreased when take-up speed was increased.

Microstructure and Mechanical Properties of CNT/Al Composite Fabricated by a Powder-in-Sheath Rolling Method utilizing Copper Tube as a Sheath (구리튜브를 피복재로 이용한 분말시스압연법에 의해 제조된 CNT/Al 복합재료의 미세조직 및 기계적 특성)

  • Lee, Seong-Hee
    • Journal of Powder Materials
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    • v.21 no.5
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    • pp.343-348
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    • 2014
  • A powder-in-sheath rolling (PSR) process utilizing a copper alloy tube was applied to a fabrication of a multi-walled carbon nanotube (CNT) reinforced aluminum matrix composite. A copper tube with an outer diameter of 30 mm and a wall thickness of 2 mm was used as a sheath material. A mixture of pure aluminum powders and CNTs with the volume contents of 1, 3, 5 vol% was filled in the tube by tap filling and then processed to 93.3% height reduction by a rolling mill. The relative density of the CNT/Al composite fabricated by the PSR decreased slightly with increasing of CNTs content, but showed high value more than 98%. The average hardness of the 5%CNT/Al composite increased more than 3 times, compared to that of unreinforced pure Al powder compaction. The hardness of the CNT/Al composites was some higher than that of the composites fabricated by PSR using SUS304 tube. Therefore, it is concluded that the type of tube affects largely on the mechanical properties of the CNT/Al composites in the PSR process.

Vibration based energy harvesting performance of magneto-electro-elastic beams reinforced with carbon nanotubes

  • Arjun Siddharth Mangalasseri;Vinyas Mahesh;Sriram Mukunda;Vishwas Mahesh;Sathiskumar A Ponnusami;Dineshkumar Harursampath;Abdelouahed Tounsi
    • Advances in nano research
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    • v.14 no.1
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    • pp.27-43
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    • 2023
  • This article investigates the energy harvesting characteristics of a magneto-electro-elastic (MEE) cantilever beam reinforced with carbon nanotubes (CNT) under transverse vibration. To this end, the well-known lumped parameter model is used to represent the coupled multiphysics problem mathematically. The proposed system consists of the MEE-CNT layer on top and an inactive substrate layer at the bottom. The substrate is considered to be made of either an isotropic or composite material. Basic laws such as Gauss's Law, Newton's Law and Faraday's Law are used to arrive at the governing equations. Surface electrodes across the beam are used to harvest the electric potential produced, together with a wound coil, for the generated magnetic potential. The influence of various distributions of the CNT and its volume fraction, substrate material, length-to-thickness ratio, and thickness ratio of substrate to MEE layer on the energy harvesting behaviour is thoroughly discussed. Further, the effect of external resistances and changes in substrate material on the response is analysed and reported. The article aims to explore smart material-based energy harvesting systems, focusing on their behaviour when reinforced with carbon nanotubes. The results of this study may lead to an improved understanding of the design and analysis of CNT-based smart structures.

Deflections, stresses and free vibration studies of FG-CNT reinforced sandwich plates resting on Pasternak elastic foundation

  • Bendenia, Noureddine;Zidour, Mohamed;Bousahla, Abdelmoumen Anis;Bourada, Fouad;Tounsi, Abdeldjebbar;Benrahou, Kouider Halim;Bedia, E.A. Adda;Mahmoud, S.R.;Tounsi, Abdelouahed
    • Computers and Concrete
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    • v.26 no.3
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    • pp.213-226
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    • 2020
  • The present study covenants with the static and free vibration behavior of nanocomposite sandwich plates reinforced by carbon nanotubes resting on Pasternak elastic foundation. Uniformly distributed (UD-CNT) and functionally graded (FG-CNT) distributions of aligned carbon nanotube are considered for two types of sandwich plates such as, the face sheet reinforced and homogeneous core and the homogeneous face sheet and reinforced core. Based on the first shear deformation theory (FSDT), the Hamilton's principle is employed to derive the mathematical models. The obtained solutions are numerically validated by comparison with some available cases in the literature. The elastic foundation model is assumed as one parameter Winkler - Pasternak foundation. A parametric study is conducted to study the effects of aspect ratios, foundation parameters, carbon nanotube volume fraction, types of reinforcement, core-to-face sheet thickness ratio and types of loads acting on the bending and free vibration analyses. It is explicitly shown that the (FG-CNT) face sheet reinforced sandwich plate has a high resistance against deflections compared to other types of reinforcement. It is also revealed that the reduction in the dimensionless natural frequency is most pronounced in core reinforced sandwich plate.