Browse > Article
http://dx.doi.org/10.5695/JKISE.2020.53.3.87

Fast and Soft Functionalization of Carbon Nanotube with -SO3H, -COOH, -OH Groups for Catalytic Hydrolysis of Cellulose to Glucose  

Lusha, Qin (School of Materials Science and Engineering, Pusan National University)
Lee, Sungho (School of Materials Science and Engineering, Pusan National University)
Li, Oi Lun (School of Materials Science and Engineering, Pusan National University)
Publication Information
Journal of the Korean institute of surface engineering / v.53, no.3, 2020 , pp. 87-94 More about this Journal
Abstract
Herein, sulfonated carbon nanotubes (CNT) have been prepared in dilute sulfuric acid (H2SO4) via a novel sulfonation approach based on gas-liquid interfacial plasma (GLIP) at room temperature. The sulfonic acid groups and total acid groups densities of CNT after GLIP treatment in 2 M H2SO4 for 45 min can reach to 0.53 mmol/g and 3.64 mmol/g, which is higher than that of sulfonated CNT prepared under 0.5 M / 1 M H2SO4. The plasma sulfonated CNT has been applied as catalysts for the conversion of microcrystalline cellulose to glucose. The effect of hydrolysis temperature and hydrolysis time on the conversion rate and product distribution have been discussed. It demonstrates that the total conversion rate of cellulose increasing with hydrolysis temperature and hydrolysis time. Furthermore, the GLIP sulfonated CNT prepared in 2 M H2SO4 for 45 min has shown high catalytic stability of 85.73 % after three cycle use.
Keywords
Gas-liquid interfacial plasma; Soft sulfonation; Dilute sulfuric acid; Sulfonated carbon catalysts; Cellulose transformation;
Citations & Related Records
연도 인용수 순위
  • Reference
1 K. Das, D. Ray, N. R. Bandyopadhyay, S. Sengupta, Study of the Properties of Microcrystalline Cellulose Particles from Different Renewable Resources by XRD, FTIR, Nanoindentation, TGA and SEM, J. Polym. Environ., 18 (2010) 355-363.   DOI
2 S.-Y. Oh, D.-I. Yoo, Y. Shin, H.-C. Kim, H.-Y. Kim, Y.-S. Chung, W.-H. Park, J.-H. Youk, Crystalline structure analysis of cellulose treated with sodium hydroxide and carbon dioxide by means of X-ray diffraction and FTIR spectroscopy, Carbohydr. Res., 340 (2005) 2376-2391.   DOI
3 C. Li, Z. K. Zhao. Efficient Acid-Catalyzed Hydrolysis of Cellulose in Ionic Liquid, Adv. Synth. Catal. 349 (2007) 1847-1850.   DOI
4 Y. Kato, Y. Sekine, One Pot Direct Catalytic Conversion of Cellulose to Hydrocarbon by Decarbonation Using Pt/H-beta Zeolite Catalyst at Low Temperature, Catal Lett., 143 (2013) 418-423.   DOI
5 J. Li, Helena S. M. P. Soares, Jacob A. Moulijn and M. Makkee, Simultaneous hydrolysis and hydrogenation of cellobiose to sorbitol in molten salt hydrate media, Catal. Sci. Technol., 3 (2013) 1565-1572.   DOI
6 P. Wolf, C. Hammond, S. Conrad. I. Hermans, Post-synthetic preparation of Sn-, Ti- and Zr-beta: a facile route to water tolerant, highly active Lewis acidic zeolites, Dalton Trans., 43 (2014) 4514-4519.   DOI
7 J. Pang, A. Wang, M. Zheng, Y. Zhang, Y. Huang, X. Chen. T. Zhang, Catalytic conversion of cellulose to hexitols with mesoporous carbon supported Ni-based bimetallic catalysts, Green Chem., 14 (2012) 614-617.   DOI
8 A. M. Dehkhoda, A. H. West, N. Ellis, Biochar based solid acid catalyst for biodiesel production, Appl. Catal. A: Gen., l. 382 (2010) 197-204.   DOI
9 L. J. Konwar, R. Das, A. J. Thakur, E. Salminen, P. Maki-Arvela, N. Kumar, J. Mik kola, D. Deka, Biodiesel production from acid oils using sulfonated carbon catalyst derived from oil-cake waste, Journal of Mol. Catal. A: Chem., 388 (2014) 167-176.
10 M. Tao, H. Guan, X. Wang, Y. Liu, R. Louh, Fabrication of sulfonated carbon catalyst from biomass waste and its use for glycerol esterification, Fuel Process. Technol., 138 (2015) 355-360.   DOI
11 X. Mo, D. E. Lopez, K. Suwannakarn, Y. Liu, E. Lotero, J. G. Goodwin Jr, C. Lu, Activation and deactivation characteristics of sulfonated carbon catalysts, J. Catal., 254 (2008) 332-338.   DOI
12 O. Li, R. Ikura, T. Ishizaki, Hydrolysis of cellulose to glucose over carbon catalysts sulfonated via a plasma process in dilute acids, Green Chem. 19 (2017) 4774-4777.   DOI
13 H. Kobayashi, T. Komanoya, K. Hara, A. Fukuoka, Water-Tolerant Mesoporous-Carbon-Supported Ruthenium Catalysts for the Hydrolysis of Cellulose to Glucose, ChemSusChem 3 (2010) 440-443.   DOI
14 S.-Y. Chiu, C.-Y. Kao, T.-Y. Chen, Y.-B. Chang, C.-M. Kuo, C.-S. Lin, Cultivation of microalgal Chlorella for biomass and lipid production using wastewater as nutrient resource, Bioresour. Technol., 184 (2015) 179-189.   DOI
15 A. Demirbas, Biomass resource facilities and biomass conversion processing for fuels and chemicals, Energy Convers. Manag., 42 (2001) 1357-1378.   DOI
16 A. Orozco, M. Ahmad, D. Rooney, G. Walker, Dilute Acid Hydrolysis of Cellulose and Cellulosic Bio-Waste Using a Microwave Reactor System, Process. Saf. Environ., 85 (2007) 446-449.   DOI
17 D. Lai, L. Deng, J. Li, B. Liao, Q. Guo, Y. Fu, Hydrolysis of Cellulose into Glucose by Magnetic Solid Acid, ChemSusChem 4 (2011) 55-58.   DOI
18 L. Hu, L. Lin, Z. Wu, S. Zhou, S. Liu, Chemocatalytic hydrolysis of cellulose into glucose over solid acid catalysts, Appl. Catal. B: Environ., 174 (2015) 225-243.   DOI
19 S. V. de Vyver, L. Peng, J. Geboers, H. Schepers, F. Clippel, C. J. Gommes, B. Goderis, P. A. Jacobs, B. F. Sels, Sulfonated silica/carbon nanocomposites as novel catalysts for hydrolysis of cellulose to glucose, Green Chem., 12 (2010) 1560-1563.   DOI
20 R. J. Chimentao, E. Lorente, F. Gispert-Guirado, F. Medina, F. Lopez, Hydrolysis of dilute acid-pretreated cellulose under mild hydrothermal conditions, Carbohydr. Polym., 111 (2014) 116-124.   DOI
21 Z. Sun, M. Tao, Q. Zhao, H. Guang, T. Shi, X. Wang, A highly active willow-derived sulfonated carbon material with macroporous structure for production of glucose. Cellulose., 22 (2015) 675-682.   DOI
22 S. Hu, T. J. Smith, W. Lou, M. Zong, Efficient Hydrolysis of Cellulose over a Novel Sucralose-Derived Solid Acid with Cellulose-Binding and Catalytic Sites, Agric. Food Chem., 62 (2014) 1905-1911.   DOI
23 B. Zhang, J. Ren, X. Liu, Y. Guo, Y. Guo, G. Lu, Y. Wang, Novel sulfonated carbonaceous materials from p-toluenesulfonic acid/glucose as a high-performance solid-acid catalyst, Catal. Commun., 11 (2010) 629-632.   DOI
24 S. Dora, T. Bhaskar, R. Singh, D. V. Naik, D. K. Adhikari, Effective catalytic conversion of cellulose into high yields of methyl glucosides over sulfonated carbon based catalyst, Bioresour technol. 120 (2012) 318-321.   DOI
25 O. Li, L. Qin, N. Takeuchi, K. Kim, T. Ishizaki, Effect of hydrophilic/hydrophobic properties of carbon materials on plasma-sulfonation process and their catalytic activities in cellulose conversion, Catal. Today. 337 (2019) 155-161.   DOI
26 Y. Bai, L. Xiao, R. Sun, Efficient hydrolyzation of cellulose in ionic liquid by novel sulfonated biomass-based catalysts, Cellulose 21 (2014) 2327-2336.   DOI