• Title/Summary/Keyword: Carbon Nanotube(CNT)

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Evaluation of power density in microbial fuel cells using expanded graphite/carbon nanotube (CNT) composite cathode and CNT anode (팽창흑연·소나노튜브 복합 음극과 탄소나노튜브 양극으로 이루어진 미생물 연료전지의 전력수율 평가)

  • Han, Sun-Kee;Lee, Chae-Young
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.4
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    • pp.503-509
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    • 2013
  • Electrochemical redox capacity of a microbial fuel cell (MFC) electrode is an important factor in the power density. This study was conducted to investigate the redox capacity of surface modified anode and cathode electrodes by measuring their conductivities. An anode electrode was modified with nitric acid and a cathode electrode was modified with heat treatment. The anode electrode modified with 20 % of the nitric acid concentration showed the highest conductivity of $6.2{\mu}S/cm/g$ and the maximum power density of $306.0mW/m^2$ when used in a MFC. The cathode electrode modified at $472^{\circ}C$ for 18 min showed the highest conductivity of $5.2{\mu}S/cm/g$ and the maximum power density of $276.20mW/m^2$ when used in a MFC. On the other hand, an MFC using both the electrodes showed the highest maximum power density of $408.2mW/m^2$. Meanwhile, a control MFC without modified electrodes generated very small voltage (0.014 mV), so the power density could not be measured.

Simulation of the Stripe type CNT Field Emitter Triod Structure (띠 모양의 에미터를 가지는 탄소나노튜브 삼전극 전계방출 디스플레이 소자의 시뮬레이션)

  • Ryu, Seong-Ryong;Lee, Tae-Dong;Kim, Yong-Gil;Byun, Chang-Woo;Park, J.W.;Ko, S.W.;Chun, H.T.;Ko, N.J.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.510-513
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    • 2002
  • 띠모양의 에미터와 에미터와 정렬된 띠모양의 케이트 구멍을 가진 탄소나노튜브(CNT) 삼극 구조에 대하여 전계방출 시뮬레이션을 수행하였다. 전자방출은 주로 가장자리에서 발생하였으며 에미터와 게이트사이의 간격이 가까워지면 급격히 증가하였다. 전자방출 특성도 상당히 우수하였다. 한쪽 가장자리만을 사용한 삼극구조의 경우에는 방출된 전자의 궤적이 좁은 띠모양으로 형성되어 방향성이 매우 우수하게 나타났다. 띠모양의 에미터 및 게이트로 이어진 삼극구조는 제작이 용이하고 조립할 때 정렬이 쉬운 장점이 있다.

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Vibration analysis of double-bonded micro sandwich cylindrical shells under multi-physical loadings

  • Yazdani, Raziye;Mohammadimehr, Mehdi;Zenkour, Ashraf M.
    • Steel and Composite Structures
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    • v.33 no.1
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    • pp.93-109
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    • 2019
  • In the present study, vibration analysis of double bonded micro sandwich cylindrical shells with saturated porous core and carbon/boron nitride nanotubes (CNT/BNNT) reinforced composite face sheets under multi-physical loadings based on Cooper-Naghdi theory is investigated. The material properties of the micro structure are assumed to be temperature dependent, and each of the micro-tubes is placed on the Pasternak elastic foundations, and mechanical, moisture, thermal, electrical, and magnetic forces are effective on the structural behavior. The distributions of porous materials in three distributions such as non-linear non-symmetric, nonlinear-symmetric, and uniform are considered. The relationship including electro-magneto-hydro-thermo-mechanical loadings based on modified couple stress theory is obtained and moreover the governing equations of motion using the energy method and the Hamilton's principle are derived. Also, Navier's type solution is also used to solve the governing equations of motion. The effects of various parameters such as material length scale parameter, temperature change, various distributions of nanotube, volume fraction of nanotubes, porosity and Skempton coefficients, and geometric parameters on the natural frequency of double bonded micro sandwich cylindrical shells are investigated. Increasing the porosity and the Skempton coefficients of the core in micro sandwich cylindrical shell lead to increase the natural frequency of the structure. Cylindrical shells and porous materials in the industry of filters and separators, heat exchangers and coolers are widely used and are generally accepted today.

Electrochemical Properties of SiOx Anodes with Conductive Agents for Li Ion Batteries (도전재 종류에 따른 리튬이차전지 음극재 SiOx의 전기화학적 특성)

  • Yun, Ji-Su;Jang, Boyun;Kim, Sung-Soo;Kim, Hyang-Yeon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.3
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    • pp.179-186
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    • 2019
  • This work investigated the effects of different conductive agents on the electrochemical properties of anodes. SiOx possesses high theoretical capacity and shows excellent cycle performance; however, the low initial coulombic efficiency and poor electrical conductivity limit its applications in real batteries. In this study, electrodes were fabricated using two different conductive agents, and the resulting physical and electrochemical properties were analyzed. SEM observations confirmed the formation of a CNT conductive network throughout the electrodes, while the electrical conductivity contributed to the electrode was confirmed by impedance measurements. Thus, the electrode fabricated with the CNT conductive agent showed greater capacity and superior cycle performance than did the electrode fabricated using the DB conductive agent.

Nonlinear bending analysis of functionally graded CNT-reinforced composite plates

  • Cho, Jin-Rae
    • Steel and Composite Structures
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    • v.42 no.1
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    • pp.23-32
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    • 2022
  • In this paper, a nonlinear numerical method to solve the large deflection problem is introduced. And the non-dimensional load-deflection behavior of functionally graded carbon nanotube-reinforced composite (FG-CNTRC) plates is parametrically investigated. The large deflection problem is formulated according to the von Kármán nonlinear theory and the (1,1,0)* hierarchical model, and it is approximated by 2-D natural element method (NEM). The shear locking phenomenon is suppressed by the selectively reduced integration method. The nonlinear matrix equations are solved by combining the incremental loading scheme and the Newton-Raphson iteration method. The proposed method is validated from the benchmark experiments, where the propose method shows an excellent agreement with the reference methods. The nonlinear behavior of FG-CNTRC plates is evaluated in terms of the non-dimensional load-deflection curve, and it is parametrically investigated with respect to the existence/non-existence and gradient pattern of CNTs, the width-to-thickness and aspect ratios of plates and the type of boundary conditions. The non-dimensional central deflection is significantly reduced when CNTs and added, and it decreases with the volume fraction of CNTs. But, it shows a uniform increase in proportion to the width-to-thickness and aspect ratios. Both the gradient pattern of CNTs and the type of boundary conditions do also show the remarkable effects.

Laser micro-drilling of CNT reinforced polymer nanocomposite: A parametric study using RSM and APSO

  • Lipsamayee Mishra;Trupti Ranjan Mahapatra;Debadutta Mishra;Akshaya Kumar Rout
    • Advances in materials Research
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    • v.13 no.1
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    • pp.1-18
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    • 2024
  • The present experimental investigation focuses on finding optimal parametric data-set of laser micro-drilling operation with minimum taper and Heat-affected zone during laser micro-drilling of Carbon Nanotube/Epoxy-based composite materials. Experiments have been conducted as per Box-Behnken design (BBD) techniques considering cutting speed, lamp current, pulse frequency and air pressure as input process parameters. Then, the relationship between control parameters and output responses is developed using second-order nonlinear regression models. The analysis of variance test has also been performed to check the adequacy of the developed mathematical model. Using the Response Surface Methodology (RSM) and an Accelerated particle swarm optimization (APSO) technique, optimum process parameters are evaluated and compared. Moreover, confirmation tests are conducted with the optimal parameter settings obtained from RSM and APSO and improvement in performance parameter is noticed in each case. The optimal process parameter setting obtained from predictive RSM based APSO techniques are speed=150 (m/s), current=22 (amp), pulse frequency (3 kHz), Air pressure (1 kg/cm2) for Taper and speed=150 (m/s), current=22 (amp), pulse frequency (3 kHz), air pressure (3 kg/cm2) for HAZ. From the confirmatory experimental result, it is observed that the APSO metaheuristic algorithm performs efficiently for optimizing the responses during laser micro-drilling process of nanocomposites both in individual and multi-objective optimization.

Development of Thin-Film Thermo-Electrochemical Cell for Harvesting Waste Thermal Energy (폐열 에너지 수집을 위한 박막형 열-전기화학전지 개발)

  • Im, Hyeongwook;Kang, Tae June;Kim, Dae Weon;Kim, Yong Hyup
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.40 no.11
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    • pp.1010-1015
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    • 2012
  • In this study, a thin-film thermo-electrochemical cell that directly converts waste thermal energy into electrical energy was fabricated. Electrical conductivity of conducting carbon fiber, which was used as flexible electrode, was increased through coating of carbon nanotube, and resistance of the CNT-coated fiber electrode was not changed even after bending test with various curvatures. Maximum output power of the thermocell was increased quadratically with the temperature difference, and showed a value of about 2.5 mW/kg at temperature difference of $3.4^{\circ}C$. As a result of discharge test for 12 hours, it is confirmed that the cell can operates continuously. And thin-film thermocell wrapped around a pipe with hot liquid flowing within was demonstrated. Internal resistance of the cell was decreased with various curvature of heat pipe, and maximum output power was increased by 30 %. Therefore, the cell can be applied to various heat source.

CNT Buckypaper-Polyurethane Composite with Enhanced Strength, Toughness and Flexible (고강도, 고강성, 그리고 유연한 탄소나노튜브 버키페이퍼-폴리우레탄 나노복합체)

  • Ha, Yu-Mi;Lim, Da-un;Kim, Yoong Ahm;Jung, Yong Chae
    • Composites Research
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    • v.29 no.4
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    • pp.161-166
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    • 2016
  • Carbon nanotube buckypaper (CNTs-BP)/thermoplastic polyurethane (PU) elastomer composites were successfully fabricated. The CNTs-BP/PU nanocomposites exhibited simultaneous improvements in both tensile modulus and strength by 1360 and 430%, respectively, as compared to pure PU. Possible reinforcing mechanisms were evidenced by SEM analyses and tensile tests. The CNTs-BP/PU nanocomposites can be potentially used as an inter-reinforcing agent in ultra-lightweight, high-strength aircraft, carbon-fiber-reinforced plastics, etc.

Electromagnetic Interference Shielding Effectiveness and Mechanical Properties of MWCNT-reinforced Polypropylene Nanocomposites (다중벽 탄소나노튜브강화 폴리프로필렌 나노복합재료의 전자파 차폐효과 및 기계적 특성)

  • Yim, Yoon-Ji;Seo, Min-Kang;Kim, Hak-Yong;Park, Soo-Jin
    • Polymer(Korea)
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    • v.36 no.4
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    • pp.494-499
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    • 2012
  • In this work, the effect of multi-walled carbon nanotube (MWCNT) on electromagnetic interference shielding effectiveness (EMI SE) and mechanical properties of MWCNT-reinforced polypropylene (PP) nanocomposites were investigated with varying MWCNT content from 1 to 10 wt%. Electric resistance was tested using a 4-point-probe electric resistivity tester. The EMI SE of the nanocomposites was evaluated by means of the reflection and adsorption methods. The mechanical properties of the nanocomposites were studied through the critical stress intensity factor ($K_{IC}$) measurement. The morphologies were observed by scanning electron microscopy (SEM). From the results, it was found that the EMI SE was enhanced with increasing MWCNT content, which played a key factor to determine the EMI SE. The $K_{IC}$ value was increased with increasing MWCNT content, whereas the value decreased above 5 wt% MWCNT content. This was probably considered that the MWCNT entangled with each other in PP due to an excess of MWCNT.

Porosity-dependent vibration investigation of functionally graded carbon nanotube-reinforced composite beam

  • Abdulmajeed M. Alsubaie;Ibrahim Alfaqih;Mohammed A. Al-Osta;Abdelouahed Tounsi;Abdelbaki Chikh;Ismail M. Mudhaffar;Saeed Tahir
    • Computers and Concrete
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    • v.32 no.1
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    • pp.75-85
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    • 2023
  • This work utilizes simplified higher-order shear deformation beam theory (HSDBT) to investigate the vibration response for functionally graded carbon nanotube-reinforced composite (CNTRC) beam. Novel to this work, single-walled carbon nanotubes (SWCNTs) are distributed and aligned in a matrix of polymer throughout the beam, resting on a viscoelastic foundation. Four un-similar patterns of reinforcement distribution functions are investigated for the CNTRC beam. Porosity is another consideration taken into account due to its significant effect on functionally graded materials (FGMs) properties. Three types of uneven porosity distributions are studied in this study. The damping coefficient and Winkler's and Pasternak's parameters are considered in investigating the viscosity effect on the foundation. Moreover, the impact of different parameters on the vibration of the CNTRC beam supported by a viscoelastic foundation is discussed. A comparison to other works is made to validate numerical results in addition to analytical discussions. The findings indicate that incorporating a damping coefficient can improve the vibration performance, especially when the spring constant factors are raised. Additionally, it has been noted that the fundamental frequency of a beam increases as the porosity coefficient increases, indicating that porosity may have a significant impact on the vibrational characteristics of beams.