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http://dx.doi.org/10.4313/JKEM.2019.32.3.179

Electrochemical Properties of SiOx Anodes with Conductive Agents for Li Ion Batteries  

Yun, Ji-Su (Graduate School of Energy Science and Technology, Chungnam National University)
Jang, Boyun (Separation and Conversion Materials Laboratory, Korea Institute of Energy Research)
Kim, Sung-Soo (Graduate School of Energy Science and Technology, Chungnam National University)
Kim, Hyang-Yeon (EV Components & Materials R&D Group, Korea Institute of Industrial Technology)
Publication Information
Journal of the Korean Institute of Electrical and Electronic Material Engineers / v.32, no.3, 2019 , pp. 179-186 More about this Journal
Abstract
This work investigated the effects of different conductive agents on the electrochemical properties of anodes. SiOx possesses high theoretical capacity and shows excellent cycle performance; however, the low initial coulombic efficiency and poor electrical conductivity limit its applications in real batteries. In this study, electrodes were fabricated using two different conductive agents, and the resulting physical and electrochemical properties were analyzed. SEM observations confirmed the formation of a CNT conductive network throughout the electrodes, while the electrical conductivity contributed to the electrode was confirmed by impedance measurements. Thus, the electrode fabricated with the CNT conductive agent showed greater capacity and superior cycle performance than did the electrode fabricated using the DB conductive agent.
Keywords
SiOx; Conductive agent; Carbon nanotube; Denka black; Anode materials; Li-ion battery;
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Times Cited By KSCI : 3  (Citation Analysis)
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1 J. Lee, J. Koo, B. Jang, and S. Kim, J. Power Sources, 329, 79 (2016). [DOI: https://doi.org/10.1016/j.jpowsour.2016.08.035]   DOI
2 L. F. Cui, L. Hu, J. W. Choi, and Y. Cui, ACS Nano, 4, 3671 (2010). [DOI: https://doi.org/10.1021/nn100619m]   DOI
3 J. M. Tarascon and M. Armand, Nature, 414, 359 (2001). [DOI: https://doi.org/10.1038/35104644]   DOI
4 T. D. Tran, J. H. Feikert, X. Song, and K. Kinoshita, J. Electrochem. Soc., 142, 3297 (1995). [DOI: https://doi.org/10.1149/1.2049977]   DOI
5 M. Winter, J. O. Besenhard, M. E. Spahr, and P. Novak, Adv. Mater., 10, 725 (1998). [DOI: https://doi.org/10.1002/(SICI)1521-4095(199807)10:10<725::AID-ADMA725>3.0.CO;2-Z]   DOI
6 M. Yoshio, H. Wang, K. Fukuda, T. Umeno, N. Dimov, and Z. Ogumi, J. Electrochem. Soc., 149, A1598 (2002). [DOI: https://doi.org/10.1149/1.1518988]   DOI
7 M. Mohri, N. Yanagisawa, Y. Tajima, H. Tanaka, S. Nakajima, M. Yoshida, Y. Yoshimoto, T. Suzuki, and H. Wada, J. Power Sources, 26, 545 (1989). [DOI: https://doi.org/10.1016/0378-7753(89)80176-4]   DOI
8 U. Kasavajjula, C. Wang, and A. J. Appleby, J. Power Sources, 163, 1003 (2007). [DOI: https://doi.org/10.1016/j.jpowsour.2006.09.084]   DOI
9 J. Yin, M. Wada, K. Yamamoto, Y. Kitano, S. Tanase, and T. Sakai, J. Electrochem. Soc., 153, A472 (2006). [DOI: https://doi.org/10.1149/1.2160429]   DOI
10 Z. P. Guo, J. Z. Wang, H. K. Liu, and S. X. Dou, J. Power Sources, 146, 448 (2005). [DOI: https://doi.org/10.1016/j.jpowsour.2005.03.112]   DOI
11 B. Liang, Y. Liu, and Y. Xu, J. Power Sources, 267, 469 (2014) [DOI: https://doi.org/10.1016/j.jpowsour.2014.05.096]   DOI
12 M. Green, E. Fielder, B. Scrosati, M. Wachtler, and J. S. Moreno, Electrochem. Solid-State Lett., 6, A75 (2003). [DOI: https://doi.org/10.1149/1.1563094]   DOI
13 U. Kasavajjula, C. Wang, and A. J. Appleby, J. Power Sources, 163, 1003 (2007). [DOI: https://doi.org/10.1016/j.jpowsour.2006.09.084]   DOI
14 A. Veluchamy, C. H. Doh, D. H. Kim, J. H. Lee, D. J. Lee, K. H. Ha, H. M. Shin, B. S. Jin, H. S. Kim, S. I. Moon, and C. W. Park, J. Power Sources, 188, 574 (2009). [DOI: https://doi.org/10.1016/j.jpowsour.2008.11.137]   DOI
15 Y. Liu, Z. Y. Wen, X. Y. Wang, A. Hirano, N. Imanishi, and Y. Takeda, J. Power Sources, 189, 733 (2009). [DOI: https://doi.org/10.1016/j.jpowsour.2008.08.016]   DOI
16 C. H. Doh, H. M. Shin, D. H. Kim, Y. C. Ha, B. S. Jin, H. S. Kim, S. I. Moon, and A. Veluchamy, Electrochem. Commun., 10, 233 (2008). [DOI: https://doi.org/10.1016/j.elecom.2007.11.034]   DOI
17 M. Li, Y. Zeng, Y. Ren, C. Zeng, J. Gu, and X. Feng, J. Power Sources, 288, 53 (2015). [DOI: https://doi.org/10.1016/j.jpowsour.2015.04.127]   DOI
18 M. Miyachi, H. Yamamoto, H. Kawai, T. Ohta, and M. Shirakata, J. Electrochem. Soc., 152, A2089 (2005). [DOI: https://doi.org/10.1149/1.2013210]   DOI
19 J. Yang, Y. Takeda, N. Imanishi, C. Capiglia, J. Y. Xie, and O. Yamamoto, Solid State Ionics, 152, 125 (2002). [DOI: https://doi.org/10.1016/S0167-2738(02)00362-4]   DOI
20 M. Gauthier, D. Mazouzi, D. Reyter, B. Lestriez, P. Moreau, D. Guyomard, and L. Roue, Energy Environ. Sci., 6, 2145 (2013). [DOI: https://doi.org/10.1039/C3EE41318G]   DOI
21 J. Wang, H. Zhao, J. He, and C. Wang, J. Power Sources, 196, 4811 (2011). [DOI: https://doi.org/10.1016/j.jpowsour.2011.01.053]   DOI
22 M. Yamada, A. Ueda, K. Matsumoto, and T. Ohzuku, J. Electrochem. Soc., 158, A417 (2011). [DOI: https://doi.org/10.1149/1.3551539]   DOI
23 Q. Si, K. Hanai, T. Ichikawa, M. B. Phillipps, A. Hirano, N. Imanishi, O. Yamamoto, and Y. Takeda, J. Power Sources, 196, 9774 (2011). [DOI: https://doi.org/10.1016/j.jpowsour.2011.08.005]   DOI
24 W. R. Liu, Y. C. Yen, H. C. Wu, M. Winter, and N. L. Wu, J. Appl. Electrochem., 39, 1643 (2009). [DOI: https://doi.org/10.1007/s10800-009-9854-x]   DOI
25 M. Miyachi, H. Yamamoto, and H. Kawai, J. Electrochem. Soc., 154, A376 (2007). [DOI: https://doi.org/10.1149/1.2455963]   DOI
26 X. Yang, Z. Wen, X. Xu, B. Lin, and S. Huang, J. Power Sources, 164, 880 (2007). [DOI: https://doi.org/10.1016/j.jpowsour.2006.11.010]   DOI
27 P. Novak, W. Scheifele, M. Winter, and O. Haas, J. Power Sources, 68, 267 (1997). [DOI: https://doi.org/10.1016/S0378-7753(96)02561-X]   DOI
28 C. W. Wang, K. A. Cook, and A. M. Sastry, J. Electrochem. Soc., 150, A385 (2003). [DOI: https://doi.org/10.1149/1.1543566]   DOI
29 H. Zheng, R. Yang, G. Liu, X. Song, and V. S. Battaglia, J. Phys. Chem. C, 116, 4875 (2012). [DOI: https://doi.org/10.1021/jp208428w]   DOI
30 Y. H. Chen, C. W. Wang, G. Liu, X. Y. Song, V. S. Battaglia, and A. M. Sastry, J. Electrochem. Soc., 154, A978 (2007). [DOI: https://doi.org/10.1149/1.2767839]   DOI
31 Q. Zhang, Z. Yu, P. Du, and C. Su, Recent Pat. Nanotechnol., 4, 100 (2010). [DOI: https://doi.org/10.2174/187221010791208803]   DOI
32 X. Zhang, J. Ma, and K. Chen, Nano-Micro Lett., 7, 360 (2015). [DOI: https://doi.org/10.1007/s40820-015-0051-7]   DOI
33 J. E. Lee, J. B. Koo, B. Y. Jang, and S. S. Kim, J. Korean Inst. Electr. Electron. Mater. Eng., 29, 255 (2016). [DOI: https://doi.org/10.4313/JKEM.2016.29.4.255]   DOI
34 B. Lee, J. Y. Lee, B. Jang, J. Kim, and S. S. Kim, J. Korean Inst. Electr. Electron. Mater. Eng., 32, 70 (2019). [DOI: https://doi.org/10.4313/JKEM.2019.32.1.70]   DOI
35 K. Yasuda, Y. Kashitani, S. Kizaki, K. Takeshita, T. Fujita, and S. Shimosaki, J. Power Sources, 329, 462 (2016). [DOI: https://doi.org/10.1016/j.jpowsour.2016.08.110]   DOI
36 M. Nishizawa, K. Mukai, S. Kuwabata, C. R. Martin, and H. Yoneyama, J. Electrochem. Soc., 144, 1923 (1997). [DOI: https://doi.org/10.1149/1.1837722]   DOI
37 G. Wang, Q. Zhang, Z. Yu, and M. Qu, Solid State Ionics, 179, 263 (2008). [DOI: https://doi.org/10.1016/j.ssi.2008.01.015]   DOI
38 J. Y. Lee, B. Lee, N. W. Kim, B. Jang, J. Kim, and S. S. Kim, J. Korean Inst. Electr. Electron. Mater. Eng., 32, 78 (2019). [DOI: https://doi.org/10.4313/JKEM.2019.32.1.78]   DOI
39 J. Shu, H. Li, R. Yang, Y. Shi, and X. Huang, Electrochem. Commun., 8, 51 (2006). [DOI: https://doi.org/10.1016/j.elecom.2005.08.024]   DOI