• 제목/요약/키워드: Carbon Nanotube(CNT)

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감광성 탄소나노튜브 페이스트의 조성과 열처리가 전계방출 특성에 미치는 영향 (Effect of Photosensitive Carbon Nanotube Paste on Field Emission Properties)

  • 오정섭;김대준;정진우;송윤호;조영래
    • 한국재료학회지
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    • 제16권9호
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    • pp.550-556
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    • 2006
  • Photosensitive carbon nanotube (CNT) pastes are explored to develop a CNT field emitter for field emission display (FED) application. We formulated a photosensitive paste including multi-walled CNTs (MWNTs) for screen printing. The photosensitive CNT paste was synthesized by mixing of MWNTs, inorganic fillers (nano metal), organic vehicle, monomers and photo initiator. The CNT paste films were patterned by using backside exposure technique. The CNTs were strongly fixed on a cathode by formation of carbon residue during firing process. For the CNT emitters, current-voltage(I-V) characteristics and images of field emission were evaluated. The emission properties of CNT emitters are dependent on the paste composition. A turn-on electric field for the CNT field emitters is measured to be 1 V/$\mu$m. Additionally, the effect of heat treatment parameter on field emission properties was discussed. The newly formulated photosensitive CNT paste can be potentially applicable to highly reliable CNT field emitters.

Improved Electrical Conductivity of a Carbon Nanotube Mat Composite Prepared by In-Situ Polymerization and Compression Molding with Compression Pressure

  • Noh, Ye Ji;Kim, Han Sang;Kim, Seong Yun
    • Carbon letters
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    • 제13권4호
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    • pp.243-247
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    • 2012
  • A fabrication method to improve the processability of thermoplastic carbon nanotube (CNT) mat composites was investigated by using in-situ polymerizable and low viscous cyclic butylene terephthalate oligomers. The electrical conductivity of the CNT mat composites strongly depended on the compression pressure, and the trend can be explained in terms of two cases, low and high compression pressure, respectively. High CNT mat content in the CNT mat composites and the surface of the CNT mat composites with fully contacted CNTs was achieved under high compression pressure, and direct contact between four probes and the surface of the CNT mat composites with fully contacted CNTs gave resistance of $2.1{\Omega}$. In this study the maximum electrical conductivity of the CNT mat composites, obtained under a maximum applied compression pressure of 27 MPa, was 11 904 S $m^{-1}$, where the weight fraction of the CNT mat was 36.5%.

탄소나노튜브 디바이스의 전기역학적 비선형 거동 해석 (Nonlinear Analysis of Electromechanical Behavior in Carbon Nanotube Devices)

  • 김일광;이수일;강상욱
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2009년도 추계학술대회 논문집
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    • pp.467-471
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    • 2009
  • In this study a cantilevered carbon nanotube(CNT) switch was investigated with the linear and the nonlinear structural models incorporating the electrostatic force and van der Waals interactions between the CNT and ground surface. Due to the applied voltage and van der Waals interactions the CNT deforms statically and dynamically and finally pull into the surface. When the nonlinear model is considered in case of the relatively large gap between the CNT and the surface, the static pull-in voltage was increased due to the nonlinear hardening effect. Also the dynamic response was investigated with the different external dc and ac voltages. The CNT shows various dynamic behaviors and instabilities including dynamic pull-in. Based on this study, further research on the dynamic and nonlinear stability of CNT nanodevices should be requested to develop the new type of nano switches or nano-memory.

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전기장을 이용한 탄소나노튜브 카트리지 연구 (A Study on the Carbon Nanotube Cartridges Using Electric Field)

  • 최재성;곽윤근;김수현
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2005년도 춘계학술대회 논문집
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    • pp.1164-1167
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    • 2005
  • This paper is about the carbon nanotube(CNT) samples called as CNT cartridges. The CNT cartridges are useful to make it better to fabricate the nano-sized devices like nanoprobes and nanotweezers through physical attachment. To make these cartridges, we need to align CNTs and to purify them from raw material. There is a variety of methods to align 1-dimensional nanostructures like nanotubes and nanowires. In this review, we mainly focused on the methods using electric field. And we will introduce various researches in relation to the CNT cartridges and the fabrication methods using the CNT cartridges and nanomanipulation techniques.

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Brush Painting법으로 제작된 플렉시블 유기태양전지용 투명 탄소나노튜브 전극의 특성 연구

  • 조다영;김한기
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.596-596
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    • 2013
  • 본 연구에서는 Carbon nanotube 용액을 brush-painting 시스템을 이용하여 유연성 있는 PET 기판 위에 고품위의 플렉시블 투명전극을 제작하였다. CNT 박막의 두께에 따른 특성을 알아보기 위해 brushing 횟수를 증가시켜 UV/Vis Spectrometry, four-point probe 및 Hall measurement를 이용하여 전기적, 광학적특성을 알아보았다. 최적조건인 bilayer의 CNT 박막은 244 Ohm/sq.의 면 저항과 550 nm에서 68%의 투과도를 얻을 수 있었다. CNT 박막의 기계적 응력에 따른 전기적 안정성을 알아보기 위해 bending test를 진행하였다. 10,000번 구부려도 저항의 변화가 거의 없어 이 박막이 플렉시블한 소자에 적합하다는 것을 알았다. 유기태양전지의 적용 가능성을 알아보기 위해 CNT 박막을 유기태양전지의 anode 층으로 적용하여 1.6% (VOC: 0.566(V), $J_{SC}$: 7.118(mA/$cm^2$), Fill Factor: 40.49(%))의 효율을 얻어 유기태양전지 소자의 적용 가능성을 알았다. 최종적으로 실험에서 성막된 CNT 박막은 기존의 CVD공정과 같은 복잡한 공정 대신에 쉽고 간편하게 고품위의 flexible brush-painting Carbon nanotube (CNT) 투명전극을 제작 하여 플렉시블한 유기태양전지 소자의 가능성을 알아보았다.

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Carbon nanotube transparent conductive film: current status and prospect

  • Han, Chang-Soo;Oh, Sang-Keun
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.474-475
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    • 2009
  • As a substitute of ITO material, carbon nanotube (CNT) is widely studied for transparent conductive film (TCF). Current sheet resistance of CNT-TCF is about 100 ${\Omega}$/sq at 80% transmittance. But CNT-TCF performance in manufacturable level is about 500 ${\Omega}$/sq at 83% based on the Topnanosys Co's result. Therefore, critical issue in CNT-TCF research is to reduce the sheet resistance with manufacturing reliability. In this report, recent developments using CNT-TCF are introduced. Touch panel, transparent LED signboard, transparent speaker and transparent heater are representative examples. Also I describe the future issues and prospect of CNT-TCF for the flexible display.

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탄소 나노튜브 알루미늄 복합재료 저온 분사 코팅의 적층 거동 및 특성 (Deposition Behavior and Properties of Carbon Nanotube Aluminum Composite Coatings in Kinetic Spraying Process)

  • 강기철;;이창희
    • Journal of Welding and Joining
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    • 제26권5호
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    • pp.36-42
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    • 2008
  • Carbon nanotube (CNT) aluminum composite coatings were built up through kinetic spraying process. Deposition behavior of CNT aluminum composite on an aluminum 1050 alloy substrate was analyzed based on deposition mechanism of kinetic spraying. The microstructure of CNT aluminum composite coating were observed and analyzed. Also, the electrical resistivity, bond strength and micro-hardness of the CNT aluminum composite coatings were measured and compared to kinetic sprayed aluminum coatings. The CNT aluminum composite coatings have a dense structure with low porosity. Compared to kinetic sprayed aluminum coating, the CNT aluminum composite coatings present lower electrical resistivity and higher micro-hardness due to high electrical conductivity and dispersion hardening effects of CNTs.

Detection of Trace Copper Metal at Carbon Nanotube Based Electrodes Using Squarewave Anodic Stripping Voltammetry

  • Choi, Changkun;Jeong, Youngsam;Kwon, Yongchai
    • Bulletin of the Korean Chemical Society
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    • 제34권3호
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    • pp.801-809
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    • 2013
  • We investigate sensitivity and limit of detection (LOD) of trace copper (Cu) metal using pristine carbon nanotube (CNT) and acidified CNT (ACNT) electrodes. Squarewave based anodic stripping voltammetry (SWASV) is used to determine the stripped Cu concentration. Prior to performing the SWASV measurements, its optimal conditions are determined and with that, effects of potential scan rate and $Cu^{2+}$ concentration on stripping current are evaluated. The measurements indicate that (1) ACNT electrode shows better results than CNT electrode and (2) stripping is controlled by surface reaction. In the given $Cu^{2+}$ concentration range of 25-150 ppb, peak stripping current has linearity with $Cu^{2+}$ concentration. Quantitatively, sensitivity and LOD of Cu in ACNT electrode are 9.36 ${\mu}A\;{\mu}M^{-1}$ and 3 ppb, while their values are 3.99 ${\mu}A\;{\mu}M^{-1}$ and 3 ppb with CNT electrode. We evaluate the effect of three different water solutions (deionized water, tap water and river water) on stripping current and the confirm types of water don't affect the sensitivity of Cu. It turns out by optical inspection and cyclic voltammetry that superiority of ACNT electrode to CNT electrode is attributed to exfoliation of CNT bundles and improved interfacial adhesion occurring during oxidation of CNTs.

아르곤 이온에 의해 표면처리된 CNT 에미터의 전계방출 특성 (Field Emission Characteristics of Surface-treated CNT Emitter by Ar Ion Bombardment)

  • 권상직
    • 전자공학회논문지 IE
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    • 제44권2호
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    • pp.26-31
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    • 2007
  • 카본나노튜브 전계 방출 어레이(carbon nanotube field emission array, CNT FEA)를 유리기판 상에 형성시키기 위하여 CNT 페이스트를 스크린 프린팅 후 표면처리를 수행하였다. 본 실험에서는 효과적인 표면처리 방법으로서 이온 빔을 조사(expose)시키는 방법을 연구하였다. 먼저, 유리 기판상에 감광성 CNT 페이스트를 스크린 프린팅하고 UV 후면노광 및 현상공정에 의해 선택적으로 CNT 페이스트를 남겼다. 다시 고온에서 소성후 CNT들은 바인더 성분들에 의해 문히게 된다. 본 실험에서는 소성된 CNT 페이스트의 표면상에 Ar 이온빔을 가속시켜 페이스트의 바인더(binder)를 선택적으로 제거함으로써 전계방출 특성을 향상시킬 수 있었다. 표면처리를 위한 이온 빔 가속시 이온빔의 가속에너지에 따라 특성이 크게 변화되었는데, 본 연구에서는 100 V의 낮은 가속 전압에서 가장 높은 전계방출 특성을 나타내었으며 가속 전압이 너무 높으면 바인더 성분 외에도 CNT 자체가 제거됨으로써 오히려 특정이 저하됨을 알 수 있었다.

박테리아 제거를 위한 완속 모래여과에서 탄소나노튜브의 적용성 검토 (Applicability Assessment of Carbon Nanotube to Slow Sand Filtration for Bacteria Removal)

  • 안희경;박성직
    • 대한환경공학회지
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    • 제36권12호
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    • pp.873-878
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    • 2014
  • 본 연구에서는 박테리아 제거를 위한 완속모래여과에서 탄소나노튜브(Carbon Nanotube, CNT)의 적용성을 검토하기 위해서 전자현미경 분석 및 칼럼 실험을 수행하였다. CNT의 형태적 특성을 분석하기 위하여, 주사전자현미경으로 분석한 결과 CNT는 박테리아 부착이 용이한 섬유형태로 응집되어 있었다. CNT의 충진 두께, pH, 이온강도를 달리하며 칼럼 실험을 수행하였다. CNT의 충진 두께가 1 cm, 3 cm, 5 cm로 증가할수록 박테리아 제거율이 44.15%에서 99.95%로 증가하는 것으로 나타났다. 반면, pH가 5.5에서 8.5로 증가할 경우 정전기적 반발력에 의해 박테리아 제거율이 감소하는 경향을 보였다. 이온강도를 0 mM에서 50 mM로 증가하여 칼럼 실험을 수행한 경우 박테리아 제거율이 97.25%에서 70.90%로 감소하였다. 본 연구를 통해 CNT가 오염된 물에 함유되어 있는 박테리아를 처리하는 완속모래여과에 적용 가능한 것으로 나타났다.