• Title/Summary/Keyword: Carbon Nano-tube

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Mechanical and Electrical Properties of Low-Cement Mortar Using a Large Amount of Industrial By-Products (산업부산물을 다량활용한 저시멘트 모르타르의 역학적·전기적 특성)

  • Kim, Young-Min;Im, Geon-Woo;Lim, Chang-Min;Lee, Gun-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.43-44
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    • 2023
  • This study evaluated the mechanical and electrical properties of low-cement mortar using a large amount of industrial by-products to reduce carbon emissions from the cement industry. As types of industrial by-products, blast furnace slag and fly ash, which are representative materials, were used, and ultra-high fly ash was mixed and evaluated to solve the problem of initial strength loss. In addition, in order to evaluate the electrical properties, 1% of MWCNT was incorporated relative to the powder mass. As experimental items, the compressive strength was measured on the 1st, 3rd, 7th and 28th days of age, and the rate of change in electrical resistance was measured on the 28th day of age. As a result of the experiment, the initial strength of the test specimen mixed with blast furnace slag and fly ash was significantly lower than that of 100% cement, and the specimen mixed with blast furnace slag showed strength equal to that of cement at 28 days of age. As an electrical characteristic, the electrical resistance was reduced when the load was loaded, and this reason is judged to be the effect of improving the conductivity as the connection between CNTs is narrowed by the compressive load.

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Effect of Fucoidan on Angiogenesis and Gene Expression in Human Umbilical Vein Endothelial Cells (후코이단이 혈관 내피세포의 신생혈관 생성 효과 및 관련 유전자의 발현에 미치는 영향)

  • Park, Ho;Kim, Beom-Su
    • Korean Journal of Clinical Laboratory Science
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    • v.49 no.4
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    • pp.323-328
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    • 2017
  • Angiogenesis is a process including members of the angiogenic factors. In particular, fibroblast growth factor 2 (FGF2) is considered the most potent angiogenic factor because it promotes cell proliferation and tube formation. A recent study reported that fucoidan derived from marine plant potentiated FGF-2 induced tube formation in human endothelial cells. On the other hand, the molecular mechanisms involved in the angiogenic activity of fucoidan and FGF2 are unknown. In this study, a fucoidan treatment promoted angiogenesis induced by FGF2. The effects of fucoidan on FGF2-induced angiogenesis were confirmed by a proliferation assay using a CellTiter96 Aqueous One solution after a treatment with fucoidan and FGF2. The tube formation and wound healing assay for the angiogenic activity were also confirmed. Reverse transcription PCR showed a change in the mRNA of vascular endothelial growth factor-A (VEGF-A), intercellular adhesion molecule-1 (ICAM-1), matrix metallopeptidase9 (MMP9), and the signal transducer and activator of transcription3 (STAT3). In summary, the Fucoidan/FGF2 treatment induced an increase in cell proliferation, improved the tube formation and wound healing activity, and altered the STAT3, VEGF-A, ICAM-1, and MMP9 mRNA expression levels. Further research will be needed to provide a scientific explanation in terms of cell-signaling and confirm the present findings.

Dust Explosion Characteristics of Multi-Walled Carbon Nano Tube (다중벽 탄소나노튜브의 분진폭발 특성)

  • Han, In Soo;Lee, Keun Won;Choi, Yi Rac
    • Korean Chemical Engineering Research
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    • v.55 no.1
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    • pp.40-47
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    • 2017
  • Dust explosion hazards are always present when combustible dusts are manufactured or handled in the process. However, industries is experiencing difficulty in establishing chemical accident prevention measures because of insufficiency of information on dust explosion characteristics of combustible dust handled in industry. In this study, we investigated experimentally dust explosion characteristics of two kinds of multi-walled carbon nano tubes (MWCNT) different in particle size distribution and examined classification of dust explosion hazardous area for MWCNT manufacturing or handling process by applying the NFPA 499 code. As a result, $P_{max}$, $K_{st}$, LEL, MIE and MIT of MWCNT 1 having $124.2{\mu}m$ median diameter are obtained 6.3 bar, $56bar{\cdot}m/s$, $125g/m^3$, over 1000 mJ, and over $650^{\circ}C$. $P_{max}$, $K_{st}$, LEL, MIE and MIT of MWCNT 2 having $293.5{\mu}m$ median diameter are 6.2 bar, $42bar{\cdot}m/s$, $100g/m^3$, over 1000 mJ, and over $650^{\circ}C$, respectively. MWCNT 1, 2 are not categorized as combustible dust listed in the NFPA 499 Code for classification of dust explosion hazardous area because explosion severity and ignition sensitivity of MWCNT 1, 2 are below 0.35 and 0.01, respectively.

The study on the quality characteristics factor of medium-sized orbit scroll (중형 선회 스크롤의 품질 특성 인자에 대한 연구)

  • Kim, Jae-Gi;Lim, Jeng-Taek;Kang, Soon-Kook;Park, Jong-Soon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.9
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    • pp.718-723
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    • 2016
  • The use of the scroll compressor in the air conditioning of medium-sized vehicles has increased because of its low torque fluctuation, high energy efficiency and low noise. In addition, the main components of the compressor have been changed from steel to aluminum to reduce its weight, following studies on the constituent materials. The processing precision of the fixed scroll and orbiting involute scroll wrap of the scroll compressor must be below $10{\mu}m$. To ensure this, the surface roughness and contour tolerance are measured. To improve the hardness of the orbiting scrolls using aluminum subjected to anodizing treatment and as the base material, we used a sealing treatment and measured the resulting characteristics. The aluminum materials were made of an Al-Mg-Cu based alloy including small amounts of Ni, Fe, and Zn. The surface roughness was less than $3{\mu}m$ and the processing accuracy was within $10{\mu}m$. Also, the hardness of the nanodiamonds with CNTs used in the sealing treatment was more than 450. This was found to improve the hardness of the material by 50% or more compared to the water sealing treatment and there was little difference between the use of carbon nanotubes and nanodiamonds as sealing materials.

Understanding Interfacial Charge Transfer Nonlinearly Boosted by Localized States Coupling in Organic Transistors (Carbon Nano Tube 및 산화그래핀을 첨가한 폴리우레아 복합재 제조 및 그 화학적 특성 분석)

  • Kim, Hyeongtae;Lee, Jihyun;An, Woo-Jin;Park, Jun Hong
    • Journal of Adhesion and Interface
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    • v.22 no.4
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    • pp.136-143
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    • 2021
  • Polyurea has been investigated as a polymer matrix for composite materials because of its high mechanical strength. Although polyurea has a similar chemical structure to polyurethane, it has much higher strength and durability. In this study, the fabrication of polyurea composites reinforced with carbon nanotube (CNT) and graphene oxide (GO) is demonstrated to enhance the tensile strength of the glass fibers composite. Using FTIR and Raman spectroscopies, the chemical structures of polyurea, CNT, and GO are investigated. As a result, spectroscopy analysis reveals that the chemical structure of CNT, GO, and polyurea is maintained during the fabrication of the composite structure. Scanning electron microscopy reveals the uniform distribution of CNT and GO across the polyurea matrix. The reinforcement of 1 wt% CNT in polyurea enhances the tensile strength of CNT/polyurea composites. In contrast, the reinforcement of GO in polyurea induces the degradation of the tensile strength of GO/polyurea composites.

Development of CNT Coating Process using Argon Atmospheric Plasma (아르곤 상압플라즈마를 이용한 CNT 코팅 공정 기술 개발)

  • Kim, Kyoung-Bo;Lee, Jongpil;Kim, Moojin
    • Journal of Industrial Convergence
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    • v.20 no.10
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    • pp.33-38
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    • 2022
  • In this paper, a simple method of forming a solution-based carbon nanotube (CNT) for use as a conductive material for electronic devices was studied. The CNT thin film coating was performed on the glass by applying the spin coating method and the argon atmospheric pressure plasma process. In order to observe changes in electrical and physical properties according to the number of coatings, samples formed in the same manner from times 1 to 5 were prepared, and surface shape, reflectance, transmittance, absorbance, and sheet resistance were measured for each sample. As the number of coatings increased, the transmittance decreased, and the reflectance and absorptivity increased in the entire measurement wavelength range. Also, as the wavelength decreases, the transmittance decreases, and the reflectance and absorption increase. In the case of electrical properties, it was confirmed that the conductivity was significantly improved when the second coating was applied. In conclusion, in order to replace CNT with a transparent electrode, it is necessary to consider the number of coatings in consideration of reflectivity and electrical conductivity together, and it can be seen that 2 times is optimal.

Development of Nanomodified Snow-Melting Concrete Using Low-Temperature Phase-Change Material Impregnated Lightweight Aggregate (저온 상변화 물질 함침 경량골재를 이용한 나노 개질 융설 콘크리트 개발)

  • Kyoung, Joo-Hyun;Kim, Sean-Mi;Hu, Jong-Wan
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.42 no.6
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    • pp.787-792
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    • 2022
  • In winter, the excessive use of deicing salt deteriorates concrete pavement durability. To reduce the amount of deicing salt used, phase-change materials (PCMs) potentially offer an alternative way to melt snow through their latent heat storage characteristics. In this research, thermal energy storage concrete was developed by using PCM-impregnated expanded clay as 50 % replacement to normal aggregate by volume. In addition, to improve the thermal efficiency of PCM lightweight aggregate (PCM-LWA)-incorporated concrete, multi-walled carbon nanotubes (MWCNTs) were incorporated in proportions of 0.10 %, 0.15 %, and 0.20 % by binder weight. Compressive strength testing and programmed thermal cycling were performed to evaluate the mechanical and thermal responses of the PCM-LWA concrete. Results showed a significant strength reduction of 54 % due to the PCM-LWA; however, the thermal performance of the PCM-LWA concrete was greatly improved with the addition of MWCNTs. Thermal test results showed that 0.10 % MWCNT-incorporated concrete had high thermal fatigue resistance as well as uniform heat flow, whereas specimens with 0.15 % and 0.20 % MWCNT content had a reduced thermal response due to supercooling when the ambient temperature was varied between -5℃ and 10℃.

Self-aligned Graphene Passivation Method by Poly-4vinylphenol/Poly(melamine-co-formaldehy de) for Flexible and Wearable Electronics

  • Park, Hyeong-Yeol;Lee, In-Yeol;Park, Jin-Hong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.473-473
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    • 2013
  • 전자종이, 입을 수 있는 디스플레이, 플렉서블 터치 스크린, 투과성 면 등과 같은 차세대 플렉서블 투명 전자소자는 기계적으로 유연하고 광학적으로 투명하며 무게가 가벼운 특성을 지녀야 할 것으로 예상된다. 현재까지는Indium tin oxide (ITO), zinc tin oxide (ZTO), carbon nano tube (CNT)와 polyimide 계열의 물질들이flexible, wearable, and transparent electronics (FWTEs) 소자의 electrode, active channel, dielectric layers로 제안되어 활발히 연구되었다. 최근에는 높은 이동도(~200,000 cm2/Vs) 및 유연성(fracture strain of 30%), 투명도 (97.5% for monolayer)와 같은 특성을 갖는 그래핀에 대한 연구가 활발히 진행되고 있다. 그러나 그래핀을 차세대 플렉서블 투명 전자소자 구현에 적용하기 위해서는 플렉서블하고 투명한 절연체의 확보 및 그래핀의 진성(intrinsic) 특성 유지 등과 같은 문제점들을 해결해야 한다. 따라서, 본 연구팀에서는 그래핀 기반 플렉서블 투명 전자소자의 게이트 절연층으로 적합한 poly-4-vinylphenol/poly (melamineco-formaldehyde) (PVP/PMF) 물질을 제시하고 이에 대한 전기적 재료적 분석을 수행하였다. 특히 다양한 PVP와 PMF의 비율 및 가열(annealing 혹은 curing) 온도에서 형성된 PVP/PMF 층의 화학 및 전기적 특성을 FT-IR, I-V, 그리고 C-V 측정을 통해 확인하였다. PVP/PMF는 유기절연 물질의 하나로서 높은 유연성과 투명도를 갖고 있을 뿐만 아니라 그래핀에 적용 시 그래핀의 진성 특성을 확보할 수 있다. 이는 PVP/PMF에 존재하는 hydroxyl (-OH) 그룹과 그래핀 상에서 정공(hole)을 공급하는 것으로 알려져 있는 -OH 그룹들간의 cross-linking 메커니즘에 의한 것으로 예상된다. 마지막으로 최적화된 PVP/PMF (낮은 hysteresis 전압)를 게이트 절연층에 적용하여 polyethylene terephthalate (PET) 기판 및 연구원의 손가락 위에 95.8%의 투명도 및 0에 가까운 Dirac point를 갖는 그래핀 기반 플렉서블 투명 전자소자를 성공적으로 집적하였다.

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Development and prospect of Smart EMW Absorber for Protection of Electronic Circuits and Devices with Heat Radiating Function (전자회로 및 부품 보호용 방열기능형 스마트 전파 흡수체의 개발과 전망)

  • Kim, Dong Il;Park, Soo Hoon;Joo, Yang Ick
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.19 no.5
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    • pp.1040-1046
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    • 2015
  • With the rapid progress of electronics and radio communication technology, human enjoys greater freedom in information communication. However, EMW (Electro-Magnetic Wave) environments have become more complicate and difficult to control. Thus, international organizations, such as the American National Standard Institution (ANSI), Federal Communications Commission (FCC), the Comite Internationale Special des Perturbations Radio Electrique (CISPR), etc, have provided standard for controlling the EM wave environments and for the countermeasure of the electromagnetic compatibility (EMC). In this paper, the status of EMW absorbers and the goal of smart EMW absorber in the future were described. Furthermore, design method of the smart EM wave absorber with heat radiating function was suggested. The designed smart EM wave absorber has the absorption ability of more than 20 dB from 2 GHz to 2.45 GHz band, the optimum aperture (hole) size, the adjacent hole space, and the thickness of which were 6 mm, 9 mm, and 6.5 mm, respectively. Thus, it is respected that these results can be applied as various EMC devices in electronic, communication, and controlling systems.

Experimental Study on Internal Temperature Change Induced by Heating Element Attached to Tunnel Lining Surface (터널 라이닝 표면에 부착된 발열체로 인한 내부 온도 변화의 실험적 연구)

  • Jin, Hyunwoo;Hwang, Youngcheol
    • Journal of the Korean GEO-environmental Society
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    • v.18 no.11
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    • pp.35-40
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    • 2017
  • The rearside of concrete lining of tunnels constructed in cold region might experience on freezing due to the low temperature. This causes damage of concrete lining resulting in adverse affect on the durability as well as integrity of tunnel structure by causing damage to the concrete lining. In order to prevent the rearside of tunnel lining from freeing, the temperature change inside the concrete lining was measured by attaching a heating element to the tunnel lining surface and generating heat for a certain period of time. A special freezing chamber was developed to conduct the experiments considering in-situ environment. The carbone nanotube (CNT) was used as a heating element in this study. The temperature distribution of the concrete lining was measured by applying the heat to the heating element. The effect of the outside temperature and heating duration were analyzed.