• 한국유기농업학회지
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• 제22권4호
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• pp.531-547
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• 2014

This study analyzed the effect of Greenhouse of wood pellet fuel conversing from Diesel. Analyzed through a life cycle assessment of greenhouse gas emissions of carbon dioxide for the environmental assessment, In evaluation of the Ministry of the Environment, analyzed through the life cycle assessment of carbon dioxide emissions of the greenhouse gas and, In the case of economic evaluation, we analyzed the investment payback period to the total revenue generated by each of the calculated incentive based on the RHI and institutions reduction projects a reduction of costs associated with the reduction of fuel costs.

• Archives of Pharmacal Research
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• 제10권1호
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• pp.36-41
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• 1987

The conversion of xanthine dehydrogenase (type D) into xanthine oxidase (type D) was significantly increased in serum and liver of all $CCI_4$ treated rats on the necrosis and early cirrhosis stage of liver tissue. In the pretreatment of prednisolone, the ratio of type O per type O + D showed the decreasing tendency in serum, but the significant decrease in liver. In vitro, the conversion of liver xanthine oxidase from type D into type O was markedly increased by following preincubation with lysosomal fraction. The type conversion of xanthine oxidase may be caused by protelytic enzymes in lysosome.

• Carbon letters
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• 제4권4호
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• pp.185-191
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• 2003

Two types of carbon fiber based high modulus- and isotropic-pitch were exposed to isothermal oxidation in air and $CO_2$ gas and the weight change was measured by TGA apparatus. The kinetic equation was introduced $f=1-{\exp}(-at^b)$ and the constant b was obtained in the range of 1.02~1.68 for the isotropic fiber and obtained 0.91~1.93 for the high modulus fiber respectively. In considering the effect of the atmosphere for isothermal oxidation, the value of the constant b obtained in the carbon dioxide was higher than that obtained in the air. Therefore, it was found that the pitch based carbon fiber shows sigmoidal characteristic when it is oxidized in the carbon dioxide. In addition, it was also found that $k_f = 0.5$, which was reaction constant at f = 0.5, was a very useful parameter for evaluation of the oxidation reactivity of pitch based carbon fibers. According to the consideration, it is suggested that the conversion-time curves of the pitch based carbon fibers are correlated by normalized equation $f=1-{\exp}(-A{\tau}^B)$, where ${\tau}=t/t_f= 0.5$.

• 신재생에너지
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• 제5권2호
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• pp.9-14
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• 2009

Automobile Shredder Residue (ASR) is very appropriate in a gasification melting system. Gasification melting system, because of high reaction temperature over than $1,350^{\circ}C$, can reduce harmful materials. To use the gasification processes for hydrogen production, the high concentration of CO in syngas must be converted into hydrogen gas by using water gas shift reaction. In this study, the characteristics of shift reaction of the high temperature catalyst (KATALCO 71-5M) and the low temperature catalyst (KATALCO 83-3X) in the fixed - bed reactor has been determined by using simulation gas which is equal with the syngas composition of gasification melting process. The carbon monoxide composition has been decreased as the WGS reaction temperature has increased. And the occurrence quantity of the hydrogen and the carbon dioxide increased. When using the high temperature catalyst, the carbon monoxide conversion ratio ($1-CO_{out}/CO_{in}$) rose up to 95.8 from 55.6. Compared with average conversion ratio from the identical synthesis gas composition, the low temperature catalyst was better than the high temperature catalyst.

• 한국응용과학기술학회지
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• 제25권4호
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• pp.469-476
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• 2008

The synthesis of cyclic carbonate from butyl glycidyl ether (BGE) and carbon dioxide was performed in the presence of three different types of ionic liquid : quarternary ammonium salt, alkyl pyridinium salt, and alkylimidazolium salt. Ionic liquids of different alkyl groups ($C_3$, $C_4$, $C_6$ and $C_8$) and anions ($Cl^-$, $Br^-$ and $I^-$) were used for the reaction which was carried out in a batch autoclave reactor at $60{\sim}120^{\circ}C$. The catalytic activity was increased with increasing alkyl chain length in the order of $C_3$ < $C_4$ < $C_6$. But the ionic liquid with longer alkyl chain length ($C_8$) decreased the conversion of BGE because it is too bulky to form an intermediate with BGE. For the counter anion of the ionic liquid catalysts, the BGE conversion decreased in the order $Cl^-$ > $Br^-$ > $I^-$.

• 한국디지털건축인테리어학회논문집
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• 제12권2호
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• pp.67-76
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• 2012

BIM and its quantity take-off widely apply to the construction projects and LCCO2 Assessment using the BIM's quantity take-off function can be tried recently. Because BIM modeling programs such as Revit and ArchiCAD do not provide adequate library for LCCO2 Assessment, quantity take-off data should be conversed and applied to Carbon Emission Coefficient using Excel program or manual work. Therefore, the purpose of this research is 1) to propose the Unit Conversion Systems for Carbon Emission Coefficient, 2) to provide basic library sets for BIM based LCCO2 Assessment method, and 3) to apply 11 material library sets on a apartment unit plan modeling to pursue the CO2 emission evaluation of the material production in the process of LCCO2 Assessment. Research results showed CO2 emission amount of 458.64kgCO2/m2 from the apartment unit plan modeling.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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• pp.70-70
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• 2013

As the costs of carbon-footprinetd fuels grow continuously and simultaneously atmospheric carbon dioxide concentration increases, solar fuels are receiving growing attention as alternative clean energy carriers. These fuels include molecular hydrogen and hydrogen peroxide produced from water, and hydrocarbons converted from carbon dioxide. For high efficiency solar fuel production, not only light absorbers (oxide semiconductors, Si, inorganic complexes, etc) should absorb most sunlight, but also charge separation and interfacial charge transfers need to occur efficiently. With this in mind, this talk will introduce the fundamentals of solar fuel production and artificial photosynthesis, and then discuss in detail on photoelectrochemical (PEC) water splitting and CO2 conversion. This talk largely divides into two section: PEC water oxidation and PEC CO2 reduction. The former is very important for proton-coupled electron transfer to CO2. For this oxidation, a variety of oxide semiconductors have been tested including TiO2, ZnO, WO3, BiVO4, and Fe2O3. Although they are essentially capable of oxidizing water into molecular oxygen, the efficiency is very low primarily because of high overpotentials and slow kinetics. This challenge has been overcome by coupling with oxygen evolving catalysts (OECs) and/or doping donor elements. In the latter, surface-modified p-Si electrodes are fabricated to absorb visible light and catalyze the CO2 reduction. For modification, metal nanoparticles are electrodeposited on the p-Si and their PEC performance is compared.

• 수산해양기술연구
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• 제57권3호
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• pp.256-263
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• 2021

In this study, blending oils of diesel oil and butanol were used as fuel oil for diesel engine to measure combustion pressure, fuel consumption, air ratio and exhaust gas emission due to various operating conditions such as engine revolution and torque. Using these data, the results of analyzing the engine performance, combustion characteristics and exhaust emission characteristics such as NOx (nitrogen oxides), CO₂ (carbon dioxide), CO (carbon monoxide) and soot were as follows. The fuel conversion efficiency at each load was highest when driven in the engine revolution determined by a fixed pitch propeller law. Except 30% butanol blending oil, fuel conversion efficiency of the other fuel oils increased as the load increased. Compared to diesel oil, using 10% and 20% butanol blending oil as fuel oil was advantageous in terms of thermal efficiency, but it did not have a significant impact on the reduction of exhaust gas emissions. On the other hand, future research is needed on the results of the 20% butanol blending oil showing lower or similar levels of smoke concentration and carbon monoxide emission rate other than those types of diesel oil.

• Korean Chemical Engineering Research
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• 제60권4호
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• pp.478-485
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• 2022

외부사업을 통해 발행받은 인증실적을 배출권 거래제 할당 대상 업체에게 판매하고 할당 대상업체는 구매한 외부사업 인증실적을 상쇄 배출권으로 바꾸어 할당량을 확보할 수 있다. 본 방법론은 기존 기름보일러를(유종별) 사용하던 화석연료를 상대적으로 탄소 함량이 적은 프로판가스를 사용하는 보일러로 교체하였을 때 유종별 이산화탄소 배출 감축분을 인정받아 온실가스 감축을 하지 못해 배출허용량을 넘긴 대기업의 부족된 할당량으로 보충하기 위한 초기 분석으로 탄소감축 배출량과 배출권 거래 금액을 산출하였다.

• Carbon letters
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• 제15권1호
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• pp.1-14
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• 2014

Carbon nanofibers (CNFs) with diameters in the submicron and nanometer range exhibit high specific surface area, hierarchically porous structure, flexibility, and super strength which allow them to be used in the electrode materials of energy storage devices, and as hybrid-type filler in carbon fiber reinforced plastics and bone tissue scaffold. Unlike catalytic synthesis and other methods, electrospinning of various polymeric precursors followed by stabilization and carbonization has become a straightforward and convenient way to fabricate continuous CNFs. This paper is a comprehensive and brief review on the latest advances made in the development of electrospun CNFs with major focus on the promising applications accomplished by appropriately regulating the microstructural, mechanical, and electrical properties of as-spun CNFs. Additionally, the article describes the various strategies to make a variety of carbon CNFs for energy conversion and storage, catalysis, sensor, adsorption/separation, and biomedical applications. It is envisioned that electrospun CNFs will be the key materials of green science and technology through close collaborations with carbon fibers and carbon nanotubes.