• Title/Summary/Keyword: Carbon Content Analysis

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Statistical Analysis of Main Factors With Affecting the Physical Properties of Rubber Compounds (고무조성물의 물리적 성질에 영향을 미치는 주요인자에 대한 통계학적 해석)

  • Lee, Seag;Park, Nam-Cook
    • Elastomers and Composites
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    • v.32 no.1
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    • pp.20-28
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    • 1997
  • This study have Investigated the effect of various factors related to the physical properties of vulcanizated rubber compounds. rubber type, carbon black type and carbon black loading were selected as main factors and evaluation were tested by tables of orthogonal arrays with 3 factors and 3 levels. rubber types have affected cure time, tensile strength, and $T_g$ as main factor and carbon black loading have affected viscosity, scorch time, maximum torque, hardness, 300% modulus, rebound, heat build-up, $0\;&\;60^{\circ}C$ tangent delta, PICO and CUT/CHIP loss as main factor but the effects of carbon black type have affected only bound rubber content.

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Experimental evaluation of electrical conductivity of carbon fiber reinforced fly-ash based geopolymer

  • Vaidya, Saiprasad;Allouche, Erez N.
    • Smart Structures and Systems
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    • v.7 no.1
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    • pp.27-40
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    • 2011
  • Geopolymer concrete is finding a growing number of niche applications in the field of civil engineering due to its high compressive strength and strength gain rate, retainage of structural properties in elevated temperature environments, chemical stability in highly acidic conditions and environmental benefits. Combining the above mentioned characteristics with induced electrical conductivity, could enable geopolymer cement to serve as a smart and sustainable cementitious material suitable for health monitoring of civil structures. Carbon fibers were added to fresh geopolymer and OPC (ordinary Portland cement) mixes to enhance their electrical conductivities. AC-impedance spectroscopy analysis was performed on the specimens with fiber fraction ranging from 0.008 to 0.8 with respect to the weight of cementitious binder, to measure their electrical resistivity values and to determine the maximum beneficial fiber content required to attain electrical percolation. Experimental observations suggest that CFR-geopolymer cement exhibits superior performance to CFR-OPC in terms of conducting electrical current.

Evaluation of Organic Sediments Qualities for the Urban Streams in the Busan City (부산시 하천퇴적물의 유기 오염도 평가)

  • Lee, Jun-Ki;Kim, Seog-Ku;Song, Jae-Hong;Lee, Tae-Yoon
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.11
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    • pp.975-982
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    • 2009
  • The purpose of this study is to offer informations about the current conditions and basic data of stream sediments in Busan city. So we first select 14 urban streams and collect sediment samples. Then, COD, proximate analysis, volatile solid, organic carbon content and elemental analysis were conducted to determine characteristics of the sediments. Results show that COD, volatile solid, Organic carbon content, T-N of sediment are determined in the range of 1.20~75.07 mg/g, 0.19~11.54%, 0.23~34.21% and 0.76~3.46%, respectively. Analysis data of sediments were compared with USEPA sediment quality standards and ontario sediment quality guidelines. As a result, when compared with COD, volatile solid and organic carbon content values, Bosucheon and Gudeokcheon are relatively heavily contaminated than the remainder sampling sites. But when compared with T-N values, all of sites were evaluated as seriously contaminated. Finally, for the determination of the correlations between sediment COD and moisture contents, ash contents, volatile solid, total organic carbon, total nitrogen and total carbon, linear model was fitted to the data using a least-squares algorithm. As a result, Linear model was well fitted to each data with good values of the correlation coefficient (r=0.9664~0.8501).

Estimation of Ultimate Methane Yields and Biodegradability from Urban Stream Sediments Using BMP Test (BMP(Biochemical Methane Potential) test를 통한 도심하천 퇴적물의 최종메탄발생수율 및 생분해도 산정)

  • Song, Jaehong;Kim, Seogku;Lee, Junki;Koh, Taehoon;Lee, Taeyoon
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.2
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    • pp.33-42
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    • 2010
  • The main objective of this study was to offer informations about the current conditions of stream sediments and to evaluate biochemical methane potentials of stream sediments from the urban streams in Busan city using conventional BMP tests. First we select total 5 urban streams and collect sediment samples. Then, COD, proximate analysis, volatile solid, organic carbon content and elemental analysis were conducted to determine characteristics of the sediments. Results show that COD, volatile solid and organic carbon content are determined in the range of $15.20{\sim}75.07mg\;g^{-1}$, 2.34~11.54% and 1.28~34.21%, respectively. Also, several biochemical methane potential tests were performed in a laboratory. As a result, pH values of the reactors generally increased and then stabilized at 7.11~7.35. In addition, C/N ratio, ultimate methane and carbon dioxide yield (mL/g VS) and biodegradability (%) were determined to 1.05~10.27, 10.1~179.4, 10.3~34.4 and 4.0~30.1, respectively. For the determination of the correlations between ultimate methane yield and ultimate carbon dioxide yield, C/N ratio, COD, volatile solid and organic carbon content, a linear model was fitted to the data using a least-squares algorithm. As a result, except for COD ($r^2=0.7586$) and volatile solid ($r^2=0.7876$), Linear model was well fitted to each data with good values of the correlation coefficient ($r^2=0.9795{\sim}0.9858$). Finally, we propose empirical equations, which contain C/N ratio or TOC, for the prediction of ultimate methane yield for the urban streams in Busan city.

Analysis of Parameters for the Off-Site Dose Calculation Due to HTO, oBT, and Radioactive Carbon Ingestion (국내 원자력발전소 주변 삼중수소 및 $^14C$ 섭취선량 평가 경로인자 분석)

  • 이갑복;정양근;방선영;엄희문
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.361-367
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    • 2004
  • For assessment of tritium and radiocarbon ingestion dose to off site individuals, water, hydrogen, and carbon content of main farm produce of Korea were investigated to replace the existing data in K-DOSE60, the Offsite Dose Calculation Manual (ODCM) of Korea Hydro & Nuclear Power Co. Ltd, (KHNP). Main items and weighting factors of farm produce were determined with the nationwide food intake data in 2001, 2002. Main farm produce were sampled around Kori, Wolsong, Ulchin, Younggwang nuclear power sites, Content of each produce was multiplied by weighting factor and summed up to make the weighted mean group value For grains, water, hydrogen, and carbon content was not much different from the existing data currently used in K-DOSE60, but root vegetables had 3.5 times more hydrogen, and leafy vegetables and fruits had 0.7∼1.3 times more or less water, hydrogen, and carbon contents than K-DOSE60.

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Preparation and Characterization of Fe-Ni-Pt Nanocatalyst for Anion Exchange Membrane in Alkaline Electrolysis (음이온 교환막 수전해용 Fe-Ni-Pt 나노촉매 제조 및 특성)

  • JAEYOUNG LEE;HONGKI LEE
    • Journal of Hydrogen and New Energy
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    • v.34 no.5
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    • pp.421-430
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    • 2023
  • Fe-Ni-Pt nanocatalysts were loaded on carbon black powders which were synthesized by a spontaneous reduction reaction of iron (II) acetylacetonate, nickel (II) acetylacetonate and platinum (II) acetylacetonate. The morphology and the loading weight of Fe-Ni-Pt nanoparticles were characterized by transmission electron microscopy and thermogravimetric analyzer. The amount of Fe-Ni-Pt catalyst supported on the carbon black surface was about 6.42-9.28 wt%, and the higher the Fe content and the lower the Pt content, the higher the total amount of the metal catalyst supported. The Brunauer-Emmett-Teller Analysis (BET) specific surface area of carbon black itself without metal nanoparticles supported was 233.9 m2/g, and when metal nanoparticles were introduced, the specific surface area value was greatly reduced. This is because the metal nanocatalyst particles block the pore entrance of the carbon black, and thereby the catalytic activity of the metal catalysts generated inside the pores is reduced. From the I-V curves, as the content of the Pt nanocatalyst increased, the electrolytic properties of water increased, and the activity of the metal nanocatalyst was in the order of Pt > Ni > Fe.

Fabrication of fine BSCCO-2223 precursor powder by spray pyrolysis process (분무 열분해방법에 의한 미세 BSCCO-2223 전구분말의 제조)

  • 김성환;유재무;고재웅;김영국;박기호
    • Progress in Superconductivity
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    • v.5 no.1
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    • pp.65-69
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    • 2003
  • Many researches on fabrication process for BSCCO precursor powders have been developed for high J$_{c}$ BSCCO-2223 tape. Spray pyrolysis method for fabrication of precursor powder has many advantages, such as high purity, fine particle size and low carbon content of BSCCO precursor powder. Fine, spherical powders were prepared by ultrasonic spray pyrolysis from the aqueous solution of metal nitrates. BSCCO precursor powders were synthesized with various solutes concentration and heat treatment conditions. Average particle size for spray pyrolysis powders was $1.5∼3\mu\textrm{m}$. Bi-2223/Ag tape was prepared by PIT method and followed by various sintering conditions. BSCCO precursor powders were characterized by XRD, SEM, EDS, Carbon content and particle size analysis.s.

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Heat Treatment Using a Laser Beam or an Electron Beam (레이저 및 전자빔을 이용한 표면 열처리)

  • 김홍준;최우천;권영각
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.2
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    • pp.427-432
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    • 1995
  • Surface heat treatment using a laser beam or an electron beam is studied through numerical analyses and experiments. For the surface heat treatment process, a theoretical model is developed to predict the effects of laser beam power, travel speed and properties of a workpiece on the depth and width of the heat affected zone(HAZ). The shape of HAZ and the hardness of heat-treated surface are experimentally obtained using an electron beam. Three materials(SS41, S45C and S55C) are selected as workpiece materials. The hardness of HAZ is increased up to 3 times for materials of a low carbon content. The results of the numerical analysis are compared with those of experiments. The comparison shows that the numerical model predicts larger depths and widths.

Ultraviolet Photografting Reaction of Acrylamide onto Styrene-Butadiene Rubber (Styrene-Butadiene 고무의 아크릴아미드 UV 광그라프팅 반응)

  • Lee, K.I.;Ryu, S.H.
    • Elastomers and Composites
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    • v.33 no.5
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    • pp.363-369
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    • 1998
  • Photografting reaction onto styrene-butadiene rubber (SBR) as a function of monomer concentration, irradiation time and carbon black content has been studied using ultraviolet (UV). Acrylamide and benzophenone are used as monomer and photoinitiator, respectively. FT-IR ATR and static contact angle analysis using distilled water are used to measure the graft ratio of acrylamide onto SBR surface. Graft ratio of acrylamide increases with acrylamide concentration and irradiation time and contact angle tends to decrease with increasing graft ratio. It is observed that graft ratio increases with carbon black content.

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Effect of Coating Materials on Surface Layer Structures of Austenitic Stainless Steel Castings in Evaporative Pattern Process (소실모형 주조법에서 도형제가 오스테나이트 스테인레스강 주물의 표면층조직에 미치는 영향)

  • Kim, Ji-Youn;Cho, Nam-Don
    • Journal of Korea Foundry Society
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    • v.15 no.6
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    • pp.604-615
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    • 1995
  • Austenitic stainless steel castings using expandable polystylene(referred to hereafter as EPS) patterns are often affected by distinctive defects associated with incomplete decomposition of the EPS as the molds are filled with metal. The quality of the castings, with particular reference to carbon pick-up in austenitic stainless steel is further influenced to a significant extent by such factors as reduced pressure, the additive by adding $Na_2CO_3$ in coating. The steel composition and microstructure were examined at the surface layer of castings, at depths of 1mm, by taking successive layers of swarf and analysis. In experiments, the carburizing atmosphere was neutralized, showing that the coating performed efficiently by decomposing almost instantly on heating and liberating $CO_2$. The upper parts of castings obtained using EPS patterns were slightly higher in carbon pick-up than other parts. Comparing the 316L and 304 stainless steel castings, qualitative and quantative differences could be found between the carbon pick-up behaviours as influence of the carbon content and alloying elements. Carbide former such as Cr makes carbon more soluble in the steel. This must make carbon pick-up in the surface layer but at the same time richer in carbon especially in the 304 stainless steel castings.

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