• Title/Summary/Keyword: Carbon Coating

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A study on the contol mechaanism of Fe deposition in gavannealed steel sheet (용융아연 합금도금강판의 Fe석출량 제어기구에 관한 연구)

  • 서정현
    • Journal of the Korean institute of surface engineering
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    • v.31 no.5
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    • pp.286-296
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    • 1998
  • Galvannealing is becomming the main stream of the coating technology applied to automobile outer and inner panels due to its low cost and easy application applied to automobile outer and inner panels due to its low cost and easy application in thick Zn coating, compared to electro galvanizing. Despite of filed up data with an experience in this field, galvannealing in thick Zn coating is getting more difficult because of the absence of Fe deposition in Zn coating. As a result, it exhibits, with different steel sheet and grain size there is a proper temperature range which is good for the tarket coating thickness of galvannealing. In case of 1,200mm wide and 0.77 mm thick extra low carbon steel with 20$mu extrm{m}$ grain size, its proper temperature range for galvannealing of one side 60g/$\textrm{m}^2$ is 470-$480^{\circ}C$.

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Adsorption of Nile Blue A from aqueous solution by different nanostructured carbon adsorbents

  • Abbasi, Shahryar;Noorizadeh, Hadi
    • Carbon letters
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    • v.23
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    • pp.30-37
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    • 2017
  • Dyes are widely used in various industries including textile, cosmetic, paper, plastics, rubber, and coating, and their discharge into waterways causes serious environmental and health problems. Four different carbon nanostructures, graphene oxide, oxidized multi-walled carbon nanotubes, activated carbon and multi-walled carbon nanotubes, were used as adsorbents for the removal of Nile Blue A (NBA) dye from aqueous solution. The four carbon nanostructures were characterized by scanning electron microscope and X-ray diffractometer. The effects of various parameters were investigated. Kinetic adsorption data were analyzed using the first-order model and the pseudo-second-order model. The regression results showed that the adsorption kinetics were more accurately represented by the pseudo-second-order model. The equilibrium data for the aqueous solutions were fitted to Langmuir and Freundlich isotherms, and the equilibrium adsorption of NBA was best described by the Langmuir isotherm model. This is the first research on the removal of dye using four carbon nanostructures adsorbents.

Effect of Refractories on Coating Material Properties in Evaporative Pattern Casting Process (소실모형주조용 도형재 특성에 미치는 충전재의 영향)

  • Choi, Hyun-Jin;Oh, Young-Kun;Jun, Ghi-Chan;Lee, Sung-Chun;Lee, Gyung-Whan
    • Journal of Korea Foundry Society
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    • v.17 no.6
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    • pp.569-576
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    • 1997
  • Coating materials for Evaporative Pattern Casting (EPC) process have been developed to investigate the effect of refractories on coating material properties. Three types of developed and one foreign coating materials were used. The former designated as A, B, C and the latter named S.K. The refractory of coating material A is spherical shape of zirconia, and the ones of B, C and S.K. is flake shape of mica. Strength, permeability at room and elevated temperature, anti-sand attachability and carbon residuary were evaluated at each coating materials. Permeability measurement device for elevated temperature was also designed. The zirconia type of coating material had excellent permeability, on the other hand the mica type had good strength and anti-sand attachability. It was found that the refractories were not broken during casting, so permeability indicated same trend at both room and elevated temperature. Based on results, coating material contained small size of mica which is designated as B has the best combination for cast iron.

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SiOC Coating on Stainless Steel Using Polyphenylcarbosilane, and Its Anti-corrosion Properties (폴리페닐카보실란을 이용한 SiOC가 코팅된 스테인리스스틸 제조 및 이의 내부식성 특징)

  • Kim, Jong-Il;Lee, Yoon-Joo;Kim, Soo-Ryong;Kim, Young-Hee;Kim, Jung-Il;Woo, Chang-Hyn;Choi, Doo-Jin
    • Korean Journal of Materials Research
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    • v.21 no.1
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    • pp.8-14
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    • 2011
  • To improve the chemical stability of metal, the ceramic coatings on metallic materials have attracted interest from many researchers due to the chemical inertness of ceramic materials. To endure strong acids, SiOC coating on metal substrate was carried out by dip coating method using 20wt% polyphenylcarbosilane solution; SiC powder was added to the solution at 10wt% and 15wt% to improve the mechanical properties and to prevent cracks of the film. Thermal oxidation as a curing step was carried out at $200^{\circ}C$ for crosslinking of the polyphenylcarbosilane, and the coating samples were pyrolysized at $800^{\circ}C$ under argon to convert the polyphenylcarbosilane to SiOC film. The thicknesses of the SiOC coating films were $2.36{\mu}m$ and $3.16{\mu}m$. The quantities of each element were measured as $SiO_{1.07}C_{6.33}$ by EPMA, and it can be confirmed that the SiOC film from polyphenylcarbosilane was formed in a manner that was carbon rich. The hardness of the SiOC film was found to be 3.2Gpa through nanoindentor measurement. No defect including cracks appeared in the SiOC film. The weight loss of the SiOC coated stainless steel was within 2% after soaking in 10% HCl solution at $80^{\circ}C$ for one week. From these results, SiOC coating shows good potential for application to protect against severe chemical corrosion of stainless steel.

INFLUENCE OF TUNGSTEN CARBIDE/CARBON COATING ON THE PRELOAD OF IMPLANT ABUTMENT SCREWS (임플랜트 지대주 나사의 텅스텐 카바이드/탄소 코팅이 전하중에 미치는 영향에 관한 연구)

  • Choi Jin-Uk;Jeong Chang-Mo;Jeon Young-Chan;Lim Jang-Seop;Jeong Hee-Chan;Eom Tae-Gwan
    • The Journal of Korean Academy of Prosthodontics
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    • v.44 no.2
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    • pp.229-242
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    • 2006
  • Statement of problem: In order to increase preload with reducing the friction coefficient, abutment screws coated with pure gold and Teflon as dry lubricant coatings have been introduced. But the reported data indicate that if screw repeated tightening and loosening cycle, an efficiency of increasing preload was decreased by screw surface wearing off. Purpose: This study was to evaluate the influence of tungsten carbide/carbon coating, which has superior hardness and frictional wear resistance, on the preload of abutment screws and the stability of coating surface after repeated closures. Material and method: The rotational values of abutment screws and the compressive forces between abutment and fixture were measured in implant systems with three different joint connections, one external butt joint and two internal cones. Moreover the stability and the alteration of coating surface were examined by comparison of the compressive force and the removable torque values during 10 consecutive trials, observation with scanning electron microscope and analyzed the elemental composition with energy dispersive x-ray spectroscopy Results and conclusion: 1. Application of coating resulted in significant increase of compressive force in all implant systems(P<.05). The increasing rate of compressive force by coating in external butt joint was gloater than those in internal cones (P<.05). 2. Coated screw showed the significant additional rotation compared to non-coated screw in all implant systems (P<.05). There were no significant differences in the increasing rate of rotation among implant systems (P>.05). 3. Removable torque values were greater with non-coated screw than that with coated screw (P<.05). 4. Coated screw showed insignificant variations in the compressive forces during 10 consecutive trials(P>.05) 5. After repeated trials, the surface layer of coated screw was maintained relatively well. However surface wearing and irregular titanium fragments were found in non-coated screw.

Fabrication of Triode Type Field Emission Device Using Carbon Nanotubes Synthesized by Thermal Chemical Vapor Deposition (열 화학 기상 증착법을 이용한 삼극관 구조의 탄소 나노 튜브 전계 방출 소자의 제조)

  • Yu W. J.;Cho Y. S.;Choi G. S.;Kim D. J.
    • Korean Journal of Materials Research
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    • v.14 no.8
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    • pp.542-546
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    • 2004
  • We report a new fabrication process for high performance triode type CNT field emitters and their superior electrical properties. The CNT-based triode-type field emitter structure was fabricated by the conventional semiconductor processes. The keys of the fabrication process are spin-on-glass coating and trim-and-leveling of the carbon nanotubes grown in trench structures by employing a chemical mechanical polishing process. They lead to strong adhesion and a uniform distance from the carbon nanotube tips to the electrode. The measured emission property of the arrays showed a remarkably uniform and high current density. The gate leakage current could be remarkably reduced by coating of thin $SiO_{2}$ insulating layer over the gate metal. The field enhancement factor(${\beta}$) and emission area(${\alpha}$) were calculated from the F-N plot. This process can be applicable to fabrication of high power CNT vacuum transistors with good electrical performance.

Properties of SBR Compound using Silica-graphite Dual Phase Filler (실리카-그라파이트 이원 충진제를 이용한 SBR 컴파운드의 성질)

  • Shin, Ji Hang;Shanmugharaj, A.M.;Lee, Pyoung Chan;Jeoung, Sun Kyung;Ryu, Sung Hun
    • Elastomers and Composites
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    • v.49 no.1
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    • pp.66-72
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    • 2014
  • Carbon coating on silica particles is done by grafting expanded graphite on the silica aggregates. Successful coating of carbon is corroborated using FT-IR, TGA, XPS and TEM. Crystalline nature of coated graphite is corroborated using XRD. Influence of carbon coated silica particles on rheometric and mechanical properties of SBR composites are investigated. Carbon coated silica particles showed significant improvement in rheometric and mechanical properties, when compared to pristine silica filled system corroborating higher polymer-filler adhesion. This fact was further supported by bound rubber content and equilibrium swelling ratios of unvulcanized and vulcanized SBR composites.

Improved Electrical Conductivity of CFRP by Conductive Nano-Particles Coating for lightning Strike Protection (낙뢰손상방지를 위한 전도성 나노입자 코팅에 의한 탄소섬유 복합재료의 전기전도도 향상 연구)

  • Ha, Min-Seok;Kwon, Oh-Yang;Choi, Heung-Soap
    • Composites Research
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    • v.23 no.1
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    • pp.31-36
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    • 2010
  • The improvement of electrical conductivity of carbon-fiber reinforced plastics (CFRP) has been investigated by silver nano-particles coating for the purpose of lightning strike protection. Silver nano-particles in colloid were sprayed on the surface of carbon fibers, which were then impregnated by epoxy resin to form a CFRP specimen. Electrical resistance was measured by contact resistance meter which utilize the principles of the AC 4-terminal method. Electrical resistance value was then converted to electrical conductivity. The coated silver nano-particles on the carbon fibers were verified by SEM and EDS. The electrical conductivity was increased by three times of the ordinary CFRP.

Comparison Study of Compact Titanium Oxide (c-TiO2) Powder Electron Transport Layer Fabrication for Carbon Electrode-based Perovskite Solar Cells (탄소전극 기반 페로브스카이트 태양전지 적용을 위한 조밀 이산화티타늄 분말 전자수송층 제작 비교 연구)

  • Woo, Chae Young;Lee, Hyung Woo
    • Journal of Powder Materials
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    • v.29 no.4
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    • pp.297-302
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    • 2022
  • This study compares the characteristics of a compact TiO2 (c-TiO2) powdery film, which is used as the electron transport layer (ETL) of perovskite solar cells, based on the manufacturing method. Additionally, its efficiency is measured by applying it to a carbon electrode solar cell. Spin-coating and spray methods are compared, and spray-based c-TiO2 exhibits superior optical properties. Furthermore, surface analysis by scanning electron microscopy (SEM) and atomic force microscopy (AFM) exhibits the excellent surface properties of spray-based TiO2. The photoelectric conversion efficiency (PCE) is 14.31% when applied to planar perovskite solar cells based on metal electrodes. Finally, carbon nanotube (CNT) film electrode-based solar cells exhibits a 76% PCE compared with that of metal electrode-based solar cells, providing the possibility of commercialization.

Carbon Fiber/Aluminum Composite Fabrication Using Wettability Control (젖음성 제어를 이용한 탄소섬유/알루미늄 복합재료 제조)

  • Lee, Yongbeom;Park, Sangjin;Han, Jun Hyun
    • Composites Research
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    • v.28 no.5
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    • pp.254-259
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    • 2015
  • Carbon fiber/aluminum (CF/Al) composites were successfully fabricated without pressure casting using wettability modification of carbon fiber. The wettability of liquid aluminum on carbon fibers was enhanced through electroless plating of copper on carbon fibers. Liquid aluminum was well infiltrated into carbon fiber bundles with Cu coating layer due to low wetting angle, and a lot of pores that existed in CF/Al composite without Cu coating on CF were greatly removed. However, a few tiny pores existed in carbon fiber bundles, which is due to not bad wettability between CF and Al but shrinkage cavity that was generated during cooling of CF/Al composite. The tiny pores could be effectively removed by a subsequent rolling.