• Composites Research
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• 제12권3호
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• pp.75-83
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• 1999

Carbon/Phenolic 및 silica/phenolic 내열 복합재료의 강화재의 종류와 적층방향에 따른 비열, 열확산 계수, 열전도도를 분석하였다. Carbon/Phenolic 및 silica/phenolic 복합재료의 비열은 시차 주사 열량법을 이용하여 측정하였으며, 열확산계수는 레이저 섬광법을 이용하여 laminar와 평행방향과 laminar와 직교방향으로 측정하였다. Carbon/Phenolic 및 silica/phenolic 복합재료의 열확산계수는 온도가 증가함에 따라 감소하였다. Carbon/Phenolic 및 silica/phenolic 복합재료의 열전도도를 밀도, 열확산계수 및 비열을 이용하여 계산하였다. 열전도도는 온도가 증가함에 따라 증가하였으며, carbon/Phenolic의 경우 laminar와 평행방향의 열전도도가 laminar와 직교방향의 열전도도보다 2배 높은 이방성을 나타내었으며 이는 carbon 섬유의 열전도도 이방성 때문으로 해석되었다. 이차원 섬유강화 복합재료의 열전도도를 기지와 강화재의 열전도도와 부피분율을 이용하여 해석하였다. Carbon/Phenolic 및 silica/phenolic 복합재료의 열전도도를 적층방향에 따라 강화재와 기지의 열전도도를 이용하여 해석하여 carbon 섬유와 silica 섬유의 열전도도를 계산하였다. 계산된 섬유의 열전도도와 기지의 열전도도로부터 섬유의 부피분율에 따른 복합재료의 상온열전도도를 예측할 수 있었다.

• Fibers and Polymers
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• 제5권1호
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• pp.31-38
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• 2004

In the present paper, a variety of fiber reinforcements, for instance, stabilized OXI-PAN fibers, quasi-carbon fibers, commercial carbon fibers, and their woven fabric forms, have been utilized to fabricate pseudo-unidirectional (pseudo-UD) and 2-directional (2D) phenolic matrix composites using a compression molding method. Prior to fabricating quasi-carbon fiber/phenolic (QC/P) composites, stabilized OXI-PAN fibers and fabrics were heat-treated under low temperature carbonization processes to prepare quasi-carbon fibers and fabrics. The thermal conductivity and thermal expansion/contraction behavior of QC/P composites have been investigated and compared with those of carbon fiber/phenolic (C/P) and stabilized fiber/phenolic composites. Also, the chemical compositions of the fibers used have been characterized. The results suggest that use of proper quasi-carbonization process may control effectively not only the chemical compositions of resulting quasi-carbon fibers but also the thermal conductivity and thermal expansion behavior of quasi-carbon fibers/phenolic composites in the intermediate range between stabilized PAN fiber- and carbon fiber-reinforced phenolic composites.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2002년도 추계학술발표대회 논문집
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• pp.29-32
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• 2002

The mechanical and thermal properties of spun carbon fabric/continuous carbon fabric interplay hybrid composite materials have been studied. The properties of the hybrid composites are compared with those of the continuous carbon fabric/phenolic composites and spun carbon fabric /phenolic composites. Through hybridization, tensile strength and flexural strength of hybrid composites were increased by about 17%, and 10%, respectively compared with spun carbon composites. The thermal conductivity of the hybrid composite is lower approximately 4~6% along the direction parallel to the laminar plane than that of the continuous carbon/phenolic composite.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 1999년도 추계학술발표대회 논문집
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• pp.160-163
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• 1999

The mechanical properties and failure behaviour of carbon/phenolic composites were inverstigated by tension and compression. Carbon/phenolic composites were fabricated by infiltration of matrix into 8 harness satin woven fabric of PAN-based carbon fibers. The tensile and compressive tests were performed at 25℃ under air atmosphere and, at 400℃ and 700℃ under N₂ atmosphere. The tensile strengths of carbon/phenolic composites in with-laminar/0° warp direction were about 10 times higher than those in with-laminar/45° warp direction, which was analyzed due to a change of fracture mode from fiber pull-out by shear to tensile fracture of fibers. The fracture of carbon/phenolic composites in with-laminar/45° direction was analyzed due to delamination by buckling. Tensile and compressive strength of carbon/phenolic composites decreased to about 50% at 400℃, and to about 10% at 700℃ compared to that at room temperature. The main reason for the decrease of tensile or compressive strength with increasing temperature was analyzed due to a reduction of bond strength between fibers and matrix resulting from thermal degradation of phenolic resin.

• Carbon letters
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• 제17권1호
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• pp.33-38
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• 2016

In the present study, exfoliated graphite nanoplatelets (xGnP) with different particle sizes were coated onto polyacrylonitrile-based carbon fibers by a direct coating method. The flexural properties, interlaminar shear strength, and the morphology of the xGnP-coated carbon fiber/phenolic matrix composites were investigated in terms of their longitudinal flexural strength and modulus, interlaminar shear strength, and by optical and scanning electron microscopic observations. The results were compared with a phenolic matrix composite counterpart prepared without xGnP. The flexural properties and interlaminar shear strength of the xGnP-coated carbon fiber/phenolic matrix composites were found to be higher than those of the uncoated composite. The flexural and interlaminar shear strengths were affected by the particle size of the xGnP, while the particle size had no significant effect on the flexural modulus. It seems that the interfacial contacts between the xGnP-coated carbon fibers and the phenolic matrix play a role in enhancing the flexural strength as well as the interlaminar shear strength of the composites.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2002년도 추계학술발표대회 논문집
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• pp.48-51
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• 2002

This paper predicted the thermal conductivity of spun carbon/phenolic composites by the thermal resistance method. This method uses the analogy between the diffusion of heat and electrical charge. To verify the theoretical predictions, the thermal conductivity of spun carbon/phenolic composites was examined experimentally. The reported thermal conductivities of graphite/epoxy composite of a eight harness satin laminate was used of the comparison with the prediction values of the model and it was noticed that a good agreement has been found.

• Macromolecular Research
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• 제13권3호
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• pp.194-205
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• 2005

The network structure of Ni-coated carbon black (NCB) composites filled with phenolic resin was investigated by means of using scanning electron microscopy, viscosity, interfacial tension, shrinkability, Flory-Huggins interaction parameters, and swelling index. The electrical properties of the composites have been characterized by measurement of the specific conductivity as a function of temperature. Additionally, the variation of conductivity with temperature for the composites has been reported and analyzed in terms of the dilution volume fraction, relative volume expansion, and barrier heights energy. The thermal stability of phenolic-NCB composites has been also studied by means of the voltage cycle processes. The experimental data of EMI wave shielding were analyzed and compared with theoretical calculations. The mechanical properties such as tensile strength, tensile modulus, hardness and elongation at break (EB) of NCB-phenolic resin composites were also investigated.

• Carbon letters
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• 제1권2호
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• pp.60-63
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• 2000

In this work, the carbon fibers-reinforced carbon matrix composites made with different carbon char yields of phenolic resin matrix have been characterized by mechanical flexural tests for acoustic emission properties. The composites had been fabricated in the form of two-dimensional polyacrylonitrile based carbon fibers during the carbonization process. It was found that the composites made with the carbon char yield-rich of resin matrix result in better mechanical interfacial properties, i.e., the interlaminar shear strength (ILSS) of the composites. The data obtained from the acoustic emission monitored appeared to show that the composites made with carbon char yield-rich were also more ductile. From the acoustic emission results, the primary composite failure was largely depended on the debonding at interfaces between fibers and matrix. The interlaminar shear strengths of the composites were correlated with the acoustic emission results.

• Composites Research
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• 제16권3호
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• pp.49-57
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• 2003

본 연구에서는 항공기 구조재로 활용되고 있는 카본/에폭시 복합재료와 기체 외부 열차단용 소재로 추천되고 있는 실리카/페놀 및 카본/페놀 복합재료 2종에 대하여 고온 환경하에서 인장시험을 행하였다. 고온용 스트레인게이지를 응용하여 각각의 복합재료에 대한 온도변화에 따른 인장강도, 탄성계수, 프와송비 같은 기계적 물성치를 도출하였으며, 복합재료 방향성에 따른 기계적 물성 및 인장 거동을 강화재 종류별로 비교 고찰하였다. 본 연구결과를 통하여 획득된 기초자료들은 항공기 구조재 및 열차단용 내열재료를 이용한 복합 구조재의 설계 및 해석에 응용되었다.

• 접착 및 계면
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• 제11권4호
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• pp.149-154
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• 2010

단일 탄소섬유/페놀수지 및 탄소나노튜브-페놀수지 복합재료의 계면적 특성을 젖음성과 함께 전기저항 측정 및 미세역학시험법을 사용하여 평가하였다. 순수 페놀수지 및 탄소나노튜브-페놀수지 복합재료의 Broutman시편을 사용한 압축강도는 인장강도와 비교하였다. 탄소나노튜브-페놀수지 복합재료의 접촉저항은 2점 및 4점법에 의한 경사형 시편을 사용하여 측정하였다. 동적접촉각에 의한 표면에너지와 젖음성은 Wilhelmy 플레이트 법으로 측정하였다. 표면에서 탄소나노튜브가 불균일한 미세구조로 형성되므로, 동적접촉각은 90도 이상의 소수성을 나타내었다. 탄소나노튜브-페놀수지 복합재료는 보다 나은 응력전달 효과에 기인하여 순수 페놀수지보다 더 큰 겉보기 강성도를 보여주었다. 단일 탄소섬유와 탄소나노튜브-페놀수지 복합재료간의 접착일, $W_a$은 탄소나노튜브 첨가로 인한 점도 증가 때문에, 순수 페놀수지 보다 더 크게 나타났다. 이는 마이크로 풀 아웃 시험에서 단일 탄소섬유의 미세파손 형태와 일치함을 보여 주었다.