• Title/Summary/Keyword: CaO content

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Characteristics of the Bottom Ash in Municipal Solid Waste Incineration Ash (생활 폐기물 소각재 중 바닥재의 特性)

  • 안지환;한기천;김형석
    • Resources Recycling
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    • v.10 no.4
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    • pp.48-57
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    • 2001
  • The main consistent materials and main elements of the bottom ash in municipal solid waste incineration ash according to particle size were investigated and the environmental hazards were considered by investigating the content of dioxin and heavy metals in bottom ash and the concentration of heavy metals in its leachate. The main materials of bottom ash are glasses, ceramics, scraps of iron. As the particle size increases, their percentage weight also increases and their percentage weight was over 70% in 4 mesh~25 mm particle size fraction. The main elements of bottom ash are CaO, $SiO_2$, $Fe_2$$O_3$,$ A1_2$$O_3$and the content of CaO decreases and the content of $SiO_2$increases as particle size increases. The heavy metals accumulate in small particle size fraction. The concentration of heavy metals in each leachate by domestic leaching test is almost similar. As the aging period is prolonged, pH of bottom ash lowers gradually and the leached concentration of Cu and Pb diminishes.

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Influence of Storage Atmosphere on Quality Preservation of 'Tsugaru' Apples (저장기체조성이 Tsugaru 사과의 품질유지에 미치는 영향)

  • Chung, Hun-Sik;Lee, Hyun-Dong;Kim, Sung-Youl;Lee, Hun-Chul;Jeong, Hye-Seung;Choi, Jong-Uck
    • Korean Journal of Food Science and Technology
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    • v.32 no.3
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    • pp.668-673
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    • 2000
  • The influence of storage atmosphere on ethylene production, quality attributes and storage injury of 'Tsugaru' apples was investigated. Apples were stored in 1% $O_2+1%\;CO_2,\;1%\;O_2+3%\;CO_2,\;3%\;O_2+1%\;CO_2,\;3%\;O_2+3%\;CO_2$ and air at $0^{\circ}C$ for 5 months. Ethylene production was more suppressed by 1% $O_2$ than 3% $O_2$ atmospheres regardless $CO_2$ levels. The loss of flesh firmness and the decrease of titratable acidity were not significantly different among the storage atmospheres until 3 months of storage but more retarded by 1% $O_2$ than 3% $O_2$ atmospheres thereafter. Soluble solid content was unaffected by the storage atmosphere, but the content tended to be increased until 2 months of storage and then not varied. Ethanol content increased up to a peak level followed by a gradual loss during storage in CA but increased continuously in air. In the sensory evaluation after storage for 5 months, hardness, tartness and overall acceptability of apples stored in 1% $O_2$ atmospheres were significantly higher than those stored in the others. There was no fruit injury or off-flavor production resulting from the 1% $O_2$ atmospheres. The incidence of bitter pit was reduced as storage $O_2$ level decreased. The results show that the optimum conditions of CA storage for 'Tsugaru' apples are $0^{\circ}C$ and 1% $O_2+1{\sim}3%\;CO_2$.

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Dielectric Properties of $Ba_{0.9}Ca_{0.1}(Ti_{1-x}Sn_x)O_3$ ($Ba_{0.9}Ca_{0.1}(Ti_{1-x}Sn_x)O_3$계의 유전성)

  • 윤기현;김재현;조경화;송효일
    • Journal of the Korean Ceramic Society
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    • v.23 no.1
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    • pp.7-12
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    • 1986
  • Dielectric properties of $Ba_{0.9}Ca_{0.1}(Ti_{1-x}Sn_x)O_3$ were investigated from x=0 to 0.20, and temperature range -4$0^{\circ}C$~13$0^{\circ}C$ Density and grain size decreased with increasing Sn content due to grain growth inhibitor. Dielectric constant below the Curie temperature increased with increasing Sn content and dissipation factor dec reased. These results are due to grain size effect and internal stress. Curie temperature was shifted to lower temperature with increasing ratio of total polarizability to volume resulting from substitution of $Ba^{2+}$ ion with $Ca^{2+}$ ion $Ti^{4+}$ ion with $Sn^{4+}$ ion.

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A study for use a vanadium oxide in steel manufacture (제강 공정중 산화바나듐활용 연구)

  • Choi, Young-Key
    • Journal of environmental and Sanitary engineering
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    • v.24 no.3
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    • pp.55-61
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    • 2009
  • Fe-V is used as raw material of vanadium in the steel making process. The purpose of this study, Fe-V is to replace the $VO_{4}$. So the distribution behavior of vanadium in $VO_{4}$ of the steel investigated. The distribution ratio of the vanadium where potential of the free oxygen ion will increase in slag decreased. When CaO and MgO content which is a basic oxide from CaO-$SiO_2$-FetO-MgOsatd. slag increases, S distribution ratio increases. CaO-$SiO_2$-FetO-MgOsatd. slag better than CaO-$SiO_2$-$Al_2O_3$-MgO slag is the recovery of vanadum and desulfurization.

Effect of Minor Additives on Sintering of Zircon (Zircon 소결에 미치는 첨가제의 영향)

  • Kim, Hwan
    • Journal of the Korean Ceramic Society
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    • v.15 no.1
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    • pp.3-8
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    • 1978
  • Effects on the sintering of zircon by minor additives such as $Al_2O_3$, MgO and CaO were studied at $1450^{\circ}C$~$1550^{\circ}C$ for 30 minutes. Shrinkage, compressive strength, bulk density and apparent porosity of sintered specimens were measured in relation to content of minor additives and temperature. Mineral constitutions of the sintered specimens were idenified with X-ray diffractometer. And microstructures of the sintered specimens were observed by scanning electron microscope. The results obtained were as follow. 1) Effect ofthe minor additives such as Al2O3, MgO and CaO on the sintering of zircon was related to reaction between added oxide and silica by dissociation of zircon. 2) Zircon did not dissociate at $1550^{\circ}C$, but it did slightly on the specimen added by Al2O3 5 wt% at $1550^{\circ}C$. 3) Sintering of zircon was promoted by the addition of MgO, $(Al_2O_3+CaO)$ and (MgO+CaO), then, this phenomenon was due to the formation of liquid phase.

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Effect of Limestone Powder on Hydration of $C_{3}A-CaSO_{4}$ $\cdot$ $2H_{2}O$ system ($C_3A-CaSO_4\cdot2H_2O$ 계의 수화반응에 미치는 석회석미분말의 영향)

  • Lee Jong-Kyu;Chu Yong-Sik
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.349-352
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    • 2005
  • In this work, effects of limestone powder on hydration of $C_3A-CaSO_4\cdot2H_2O$ system was discussed based on the XRD Quantitative analysis, and the possibility of Delayed Ettringite Formation was also discussed. The early hydration of $C_{3}A$ was delayed by addition of $CaCO_{3}$ powder. The delay effect was enhanced by increasing of $CaCO_{3}$ content and finer powder of $CaCO_{3}$ addition. After consumption of $CaSO_4\cdot2H_2O$, the reaction of $CaCO_{3}$ is started. Delayed Ettringite Formation would take place because monosulfoaluminate is not stable in presence of $CaCO_{3}$. In order to prevent the delayed ettringite formation in $C_3A-CaSO_4\cdot2H_2O-CaCo_3$ system, the reduction of monosulfoaluminate formation is important. Therefore, by increasing the amount of $CaCO_{3}$ addition and finer $CaCO_{3}$ powder addition, the delayed ettringite formation can be prevented.

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Characteristics and Classification of Red Brown Glass Beads Excavated in Korean Peninsula (한반도에서 출토된 적갈색 유리구슬의 특성 및 유형 분류)

  • Kim, Na-Young;Kim, Gyu-Ho
    • Journal of Conservation Science
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    • v.29 no.3
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    • pp.279-286
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    • 2013
  • It is characterized and classified as the type of red brown glass beads to compare the chemical composition and manufacturing technique on the 141 samples in 12 sites of the Three Kingdom Period analyzed until now. It can be divided into three types according to the chemical composition of stabilizers(CaO & $Al_2O_3$) and soda raw materials(MgO & $K_2O$) on the red brown glass beads except one sample. Type I of high alumina glass is identified as the most common types that is 78.6 % of the distribution ratio at analytical samples and is excavated the most from ruin sites. In contrast, type II, 13.6 % of distribution ratio at analytical samples, is about 5 % CaO and $Al_2O_3$, MgO and $K_2O$ at around 1.5 % is similar to the composition of plant ash glass. Type III is that the content of CaO is higher than $Al_2O_3$ and the content of MgO and $K_2O$ is below 1.5 %. It is the same as the composition of natron glass and its share is the lowest as 7.9 %. Of these, type III is divided into two types according to the content of MgO and $K_2O$. It is identified that manufacturing technique of type I and II is drawing and type III is casting method with microscopic investigations. Type II and III is estimated that raw materials is different because is confirmed in the majority of ruins in spite of the fact that distribution ratio is very low. So, red brown glass beads distributed in Korea Peninsula are divided into three types of glass culture.

Corrosion Behavior of Mg-Al-Zn-CaO Alloy (Mg-Al-Zn-CaO 합금의 부식 거동)

  • Moon, Jung-Hyun;Jun, Joong-Hwan;Kim, Young-Jik
    • Journal of Korea Foundry Society
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    • v.33 no.3
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    • pp.127-133
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    • 2013
  • The influences of a small amount of CaO addition on the microstructure and corrosion behavior of AZ81 casting alloy have been investigated by means of optical microscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, immersion and electrochemical tests. The added CaO led to the refinement of ${\alpha}$-Mg grains and the decrease in ${\beta}$ precipitate content by the formation of an $Al_2Ca$ phase. The AZ81-CaO alloy had a better corrosion resistance than the AZ81 alloy. The microstructural characterization on the corroded surface revealed that the enhanced corrosion resistance of the CaO-containing alloy may well be ascribed to the increased barrier effect of precipitates formed more continuously along the grain boundaries and the incorporation of Al and Ca elements into the corrosion film, by which it became more protective.

Microwave dielectric properties of $CaTiO_3-LaAIO_3$ ceramics ($CaTiO_3-LaAIO_3$계 세라믹스의 마이크로파 유전특성)

  • 여동훈;김현재;송준태
    • Electrical & Electronic Materials
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    • v.9 no.4
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    • pp.379-384
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    • 1996
  • The microwave dielectric properties of (I-x)CaTiO$_{3}$-xLaAIO$_{3}$ were investigated. The solid solution of (1-x)CaTiO$_{3}$-xLaAIO$_{3}$ had the perovskite structure in the range of all compositions. The crystal system of (1-x)CaTiO$_{3}$-xLaAIO$_{3}$ was transformed to orthorhombic(x.leq.0.4), psudo-cubic(x=0.5), and rhombohedral (x.geq.0.7) in turn, as the amount of LaAIO$_{3}$ increased. The dielectric constant and temperature coefficient of resonant frequency of solid solution were decreased with the content of LaAIO$_{3}$, whereas, the value of Q . f$_{o}$ was increased. The microwave dielectric material having Q . f$_{o}$ = 32, 500, .epsilon.$_{r}$ = 42, and .tau.$_{f}$ = 5 ppm/.deg. C was obtained from the 0.35CaTiO$_{3}$-0.65LaAIO$_{3}$ composition sintered at 1600.deg. C for 4hrs.hrs.hrs.

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Characteristics of Cement Matrix/Mortar with CaO-based Activated-sludge (CaO원 활성슬러지를 혼입한 시멘트 경화체 및 모르타르의 특성)

  • Lee, Yong-Soo;Ryu, Seong-Lyong;Shin, Kwang-Ho;Chu, Yong-Sik;Kim, Young-Yup
    • Journal of the Korea Concrete Institute
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    • v.29 no.4
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    • pp.399-406
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    • 2017
  • CaO-based by-product, which consist of CaO, $SO_3$, $Al_2O_3$ and so on, has being used to raw materials of CaO compound. When It was applied to recycling water of remicon, concrete performance can be enhanced because hydration reaction of powder material is accelerated. In this study, activated-sludge, which was putted desulfurization gypsum of CaO-based in recycling water, was manufactured to verify effect of them, and then they was investigated by characteristics of cement matrix and mortar. As a results, they indicated reduction of setting time and high soundness in cement matrix, and acceleration of hydration reaction can be verified by XRD analysis. Also, it can be maintained good workability if water content by usage of desulfurization gypsum, which used for production of activated-sludge, was adjusted. In addition, it can be verified strength development by activated-sludge although cement content by usage of desulfurization gypsum was reduced.