• Title/Summary/Keyword: CaO content

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Mineralogical Characteristic and Occurrence of Tremolite and Actinolite in the Dong-A mine, Korea (동아광산 일대 투각섬석과 양기석의 산출상태 및 광물학적 특성 연구)

  • Kim, Seong Ho;Kim, Jeong Jin
    • Journal of the Mineralogical Society of Korea
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    • v.28 no.4
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    • pp.333-341
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    • 2015
  • As results of X-ray diffraction analysis, samples of asbestos and soil were composed maily of dolomite ($CaMg(Co_3)_2$, tremolite ($Ca_2Mg_5Si_{18}O_{22}(OH)_2$), actinolite ($Ca(Mg,\;Fe)_6Si_8O_{22}(OH)_2$), talc ($Mg_3Si_4O_{10}(OH)_2$), calcite ($CaCO_3$) and small amounts of quartz ($SiO_2$) and clay minerals. The average size of asbestos fibers was about $100{\mu}m$ and maximum of some asbestos was $250.0{\mu}m$ in length. The aspect ratio of asbestos fiber were over 3 : 1 and inclined extinction in the range of $8.0-19.5^{\circ}$. Single isolated fragments of asbestos are probably fiber and acicula form in crystal edge along the cleavage plane. Tremolite that composed main asbestos mineral in rock and soil around Dong-a mine is higher content of Fe than actinolite asbestos.

Luminescence of $Eu^{3+}-doped\;GdCa_4B_3O_{10}$ phosphor under UV and VUV irradiation

  • Oh, Jae-Suk;Kwak, Chung-Heop;Jung, Ha-Kyun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1355-1359
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    • 2006
  • Due to its efficient red emission, $Eu^{3+}$ ion has been doped in various host materials. $GdCa_4B_3O_{10}:Eu^{3+}$ phosphor for red emission has been prepared by solid state reaction. Photoluminescence properties for the phosphor under UV and VUV excitation were investigated. The $GdCa_4B_3O_{10}:Eu^{3+}$ phosphor under both excitation conditions shows typical red emission spectrum centered at 611 nm with several weak peaks due to energy transfer from $^5D_O\;to\;^7F_J(J=1,2,3,4)$ of $Eu^{3+}$ ion. On the other hand, the activator content exhibiting the concentration quenching under UV and VUV irradiation is 10 mole% and 2.5 mole%, respectively.

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Hydrothermal Reactivity of Various Classified Fly Ashes by Electrostatic Precipitator (전기집진장치로부터 단별채취한 플라이 애쉬의 수열반응성)

  • ;Estuo Sakai;Masaki Daimon
    • Journal of the Korean Ceramic Society
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    • v.37 no.8
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    • pp.811-816
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    • 2000
  • This paper discussed hydrothermal reactivity of Ca(OH)2 and classified bituminous fly ashes which were collected at an electrostatic precipitator in coal fired power plant at 181$^{\circ}C$. The major products of hydrothermal reaction were tobermorite and hydrogrossularite because bituminous fly ashes contained Al2O3 content greater than 20 wt%. As increasing amount of Al2O3 content greater than 20 wt%. As increasing amount of Al2O3 in glass phases, formation of hydrogrossularite increased. Formation rate of crystalline tobermorite increased with content of finer particles, higher glass content and more Al2O3 in glass phases. There was a positive correlation between residue on 45${\mu}{\textrm}{m}$ sieve and hydrothermal reactivity of fly ash up to 3 hours. The hydrothermal reactivity of fly ash at 181$^{\circ}C$ for 12 hours was more affected by fineness than by glass content of fly ash.

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Geochemical and Physical Properties of the Jangseong and Imported Chinese Coals (장성탄광 석탄과 수입 중국 석탄의 지구화학적 및 물리적 특성)

  • Chon, Hyo Taek;Kim, Myeong Kyun
    • Economic and Environmental Geology
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    • v.28 no.4
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    • pp.381-388
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    • 1995
  • The petrographic, geochemical, and physical properties of the Jangseong and Chinese coals were investigated. The most common mineral matters of Jangseong coal are kaolinite, muscovite, sericite, illite, quartz and pyrophyllite. Mineral matters in Chinese coal are mainly composed of quartz, calcite, dolomite and kaolinite. Jangseong coal ash has higher content of $Al_2O_3$, $K_2O$, $TiO_2$, As, Rb and V, and lower content of CaO, MgO, $Na_2O$, $Fe_2O_3$ and $P_2O_5$ than those of Chinese coal ash. The liquid limit and the plasticity index of Jangseong coal were compared with those of Chinese coal. The result shows that the briquetting ability of Jangseong coal is a little bit better than that of Chinese coal. The briquetting ability is found to be principally dependent on the type and the content of mineral matter in coal, especially clay mineral.

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Genetic Environments of the High-purity Limestone in the Upper Zone of the Daegi Formation at the Jeongseon-Samcheok Area (정선-삼척 일대 대기층 상부 고품위 석회석의 생성환경)

  • Kim, Chang Seong;Choi, Seon-Gyu;Kim, Gyu-Bo;Kang, Jeonggeuk;Kim, Kyeong Bae;Kim, Hagsoo;Lee, Jeongsang;Ryu, In-Chang
    • Economic and Environmental Geology
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    • v.50 no.4
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    • pp.287-302
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    • 2017
  • The carbonate rocks of the Daegi Formation are composed of the limestone at the upper and lower zones, and the dolomite at the middle zone, in which the upper zone has higher CaO content than others. The colors of carbonate rock in the Daegi Formation can be divided into five types; white, light brown, light gray, gray, and dark gray. The white to light gray colored rocks correspond to the high purity limestone with 53.15 ~ 55.64 wt. % CaO, and the light brown colored rocks contain 20.71 ~ 21.67 wt. % MgO. The bleaching of carbonate rocks are not related to CaO composition of the rocks, as light gray rocks tend to be higher in CaO content than those of the white rocks at the lower zone. The pelitic components are also occasionally increased in white limestone than light grey one. $Al_2O_3$ is one of the most difficult content to remove during hydrothermal processes, so the interpretation that the limestone is purified together with hydrothemral bleaching, has little merit. The wide range (over 16 ‰) of ${\delta}^{18}O_{SMOW}$, smaller variation (within 2 ‰) of ${\delta}^{13}C_{PDB}$ are apparent in both the upper and lower zones, which indicate the Daegi Formation had been affected overall by hydrothermal fluids. The K-Ar isotopic age of hydrothermal alteration in the GMI limestone mine is $85.1{\pm}1.7Ma$. Gradual change from grey through light grey to white limestone is accompaned by lower oxygen stable isotope values, which is major evidence that the hydrothermal effect is the main process of the bleaching. Although the Daegi Formation has suffered from hydrothermal activity and increase in whiteness, there is no clear evidence demonstrating the relationship between bleaching and high purity of limestone. The purification of limestone has nothing to do with the hydrothermal activity in this area. Instead, it should be considered that the change of sedimentary environment related to see-level fluctuation which can prevent deposition of pelitic components especially $Al_2O_3$ contrbuted to the formation of the high purity limestone in the upper zone of the Daegi Formation. Considering the evidences such as increase in CaO content of limestone by depth, gradual change from calcite to dolomite at the lower zones, and occurring the high purity limestone at the upper zone, the interpretation of sequence stratigraphic aspect to the formation of the high purity Daegi limestone appears to be more suitable than that of hydrothermal alteration origin.

A Study on Electrochemical Characteristics of LiCoO2/LiNi1/3Mn1/3Co1/3O2 Mixed Cathode for Li Secondary Battery (리튬2차전지용 LiCoO2/LiNi1/3Mn1/3Co1/3O2계 복합정극의 전기화학적 특성 연구)

  • Kim Hyun-Soo;Kim Sung-Il;Eom Seung-Wook;Kim Woo-Seong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.1
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    • pp.64-70
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    • 2006
  • In this study, the $LiCoO_2/LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ mixed cathode electrodes were prepared and their electrochemical performances were measured in a high cut-off voltage. As the content of $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ increased in a mixed cathode, the reversible specific capacity and cycleability of the electrode enhanced, but the rate capability was deteriorated. On the contrary the rate capability of the cathode enhanced, but the reversible specific capacity and cycleability were deteriorated, increasing the content of $LiCoO_2$ in the mixed cathode. The cell of $LiCoO_2/LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ ($50:50 wt\%$) mixed cathode delivered a discharge capacity of ca. 168 mAh/g at a 0.2 C rate. The capacity of the cell decreased with the current rate and a useful capacity of ca. 152 mAh/g was obtained at a 2.0 C rate. However, the cell showed very stable cycleability: the discharge capacity of the cell after 20th charge/discharge cycling maintains ca. 163 mAh/g.

Changes in Nutrients Uptake and Dry Matter Yield of Orchardgrass ( Dactylis glomerata L. ) and Alfalfa ( medicago sativa L. ) by Gypsum Application. (석고시용이 Orchargrass ( Dactylis glomerata L. ) 와 Alfalfa ( Medicago sativa L. )의 양분흡수 및 목초수량에 미치는 영향)

  • 윤순강;송기웅;김재규
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.10 no.3
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    • pp.141-146
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    • 1990
  • Changes in dry matter yield, crude components, nutrients uptake($P_2O_5$, $K_2O$, CaO, MgO) and sulphur containing amino acid(cysteine, methionine) of orchardgrass(Dacty1is glomerata. L) and alfalfa(A4edicago sativa. L) by gypsum application(as sulphur source, 0, 2. 5, 10, 20kg SIlOa) were investigated to understand the effect of sulphur on herbage production in pasture, which was established in 1987 as means of hand broadcasting. The effect of gypsum on dry matter yield at different cutting times during growing seasons has not been found both in orchardgrass and in alfalfa, but in respect to annual total dry matter yield there were increment in herbage yield (P<0.05) of alfalfa at 5, 10, 20kg SIlOa in 1989 and the amounts of sulphur taken up in herbage slightly increased according to the rates of gypsum application. Maximum apparent recovery of sulphur was 7.55% at 2kg SIlOa in orchardgrass and was 17.8% at 5kg S/lOa in alfalfa. There were no any great differences in the content of crude components of both species and this trend was similar with the mineral contents of orchardgrass. But in alfalfa, the amounts of $K_2O$, CaO, and $P_2O_5$ taken up were increased by gypsum application and the increment in the amounts of minerals taken up in herbage at 20kg SIlOa were 14.9 of $K_2O$, 9.1 of CaO, and 2.5kgIlOa of $P_2O_5$ as compared to those of at untreated plot. Cysteine and methionine were not influenced by gypsum applicaton not only in orchardgrass but also cysteine in alfalfa, however, the content of methionine in alfalfa was slightly increased at 2, 5, lOkg SIlOa and at 20kg SIlOa was reverse.

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A Study on Synthesis of Mayenite by Using Recycled Aluminium Resource for Application in Insulating Material (알루미늄 재활용 소재를 이용한 내화재용 Mayenite 합성 연구)

  • Im, Byoungyong;Kang, Yubin;Joo, Soyeong;Kim, Dae-Guen
    • Resources Recycling
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    • v.29 no.6
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    • pp.65-72
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    • 2020
  • Black dross is a dark gray dross generated during the aluminum recycling process that uses flux, and contains NaCl, KCl, Al2O3, MgO, etc. Black dross is separated into soluble substances (NaCl, KCl) and insoluble substances (Al2O4, MgO) through the dissolution process. Soluble materials can be reused as salt flux, and Al2O3 and MgO can be upcycled to various ceramic materials through the synthesis process. In this study, Mayenite was synthesized using Al2O3 and MgO recovered from black dross, and the synthesis was performed according to the mixing ratio and reaction temperature. It was confirmed that when Mayenite was synthesized using black dross (spinel) and CaCO3, precursors were changed to Mg0.4Al2.4O4 and CaO at 700 ℃, and to Ca12Al14O33 (Mayenite) after 800 ℃. In the mixing conditions experiment, it was confirmed that the Mayenite XRD peak increased with increase of the CaCO3 content, and the Mg0.4Al2.4O4 XRD peak decreased. As a result of the BET analysis of the synthesized powder, the surface area decreased as the fine particles were grown and agglomerated in the process of generating mayenite.

Growth Stimulation of Mulberry Trees in Unsterilized Soil under Field Conditions with VA Mycorrhizal Inoculation (VA내생균근이 뽕나무의 생장에 미치는 영향)

  • 김중채;최연홍;문재유;김주읍
    • Journal of Sericultural and Entomological Science
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    • v.26 no.2
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    • pp.7-10
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    • 1984
  • Mulberry Seedlings germinated and grown under green house conditions were inoculated with Glomus mosseae, Mosse and Trappe (a Kind of Vesicular arbuscular mycorrhizae) prior to outplanting into unsterilized soil. They were grown on phosphate deficient soil for 6 months after planting. Shoot length, stem diameter and leaf yield of the inoculated plants were found to be significantly greater than uninoculated ones. It was observed in foliar mineral content that the levels of N, P$_2$O$\sub$5/, CaO of the inoculated plants were higher but the level of MgO of the inoculated plants was lower than the uninoculated ones. In the mineral content of roots, it was observed that the level of P$_2$O$\sub$5/ was higher but the level of N was lower significantly in the inoculated plants than the uninoculated ones.

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Characteristic Comparison of the Composition Classification on Potash Glass Beads Excavated in Korea (한국 포타쉬 유리구슬의 조성 분류에 따른 특성 비교)

  • KIM, Na-Young;KIM, Gyu-Ho
    • Journal of Conservation Science
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    • v.31 no.3
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    • pp.255-265
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    • 2015
  • In this study, the potash glass beads of 281 samples in 30 sites analyzed until now were classified according to the chemical composition. And the color, size, manufacturing technique and distribution period were compared. Korea potash glass beads are divided into 3 types depending on the stabilizer content. I, II type is the CaO and $Al_2O_3$ content of less than 5%. Relatively, I type has a high CaO and II type has a high $Al_2O_3$. In contrast, III type comprises more than CaO 5%. I, II type is the saltpetre, III type is estimated using plant ash as row material of flux. A review of the properties by type, I type is cobalt blue, copper blue and purple beads. The outer diameter is sized to the range 1.4~7.4mm. Also it was produced by the drawing technique. It was used continuously from BC 1C until around AD 6C. On the other hand, II type is outer diameter of 1.9~3.6mm and a copper blue beads. manufacturing technique is the same as the I type. This seems to have been in use since around AD 1C to 4C. Finally, III type is brown, colorless, amber beads and an outer diameter of about 10mm. It was formed by winding technique and appeared in the tombs of Goryeo and Joseon Dynasty. As a result, 3 types of potash glass beads distributed in Korea is likely to flowing through the various trade routes from different provenances.