• Title/Summary/Keyword: CZT

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The Effects of Sodium Doping on the Electrical Properties of the Cu2ZnSn(S,Se)4 (CZTSSe) Solar Cells (용액법을 이용한 나트륨 도핑에 따른 Cu2ZnSnSe4 (CZTSSe) 박막의 합성 및 특성 평가)

  • Shim, Hongjae;Kim, Jihun;Gang, MyungGil;Kim, Jinhyeok
    • Korean Journal of Materials Research
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    • v.28 no.10
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    • pp.564-569
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    • 2018
  • $Cu_2ZnSn(S,Se)_4$ (CZTSSe) films were prepared on Mo coated soda lime glass substrates by sulfo-selenization of sputtered stacked Zn-Sn-Cu(CZT) precursor films. The precursor was dried in a capped state with aqueous NaOH solution. The CZT precursor films were sulfo-selenized in the S + Se vapor atmosphere. Sodium was doped during the sulfo-selenization treatment. The effect of sodium doping on the structural and electrical properties of the CZTSSe thin films were studied using FE-SEM(field-emission scanning electron microscopy), XRD(X-ray diffraction), XRF(X-ray fluorescence spectroscopy), dark current, SIMS(secondary ion mass spectrometry), conversion efficiency. The XRD, XRF, FE-SEM, Dark current, SIMS and cell efficiency results indicated that the properties of sulfo-selenized CZTSSe thin films were strongly related to the sodium doping. Further detailed analysis and discussion for effect of sodium doping on the properties CZTSSe thin films will be discussed.

Comparison of Environmental Radiation Survey Analysis Results in a High Dose Rate Environment Using CZT, NaI(Tl), and LaBr3(Ce) Detectors

  • Sungyeop Joung;Wanook Ji;Eunjung Lee;Young-Yong Ji;Yoomi Choi
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.21 no.4
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    • pp.543-558
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    • 2023
  • Currently, Japan is undertaking a nationwide project to measure and map radioactive contamination around Fukushima, as part of the efforts to restore normalcy following the nuclear accident. The Japan Atomic Energy Agency (JAEA) manages the Fukushima Environmental Safety Center, located approximately 20 km north of the Fukushima Daiichi nuclear power plant in Minamisōma City, Fukushima Prefecture. In collaboration with the JAEA, this study involved conducting comparison experiments and analyses with radiation detectors in high radiation environments, a challenging task in Korean environments. Environmental radiation surveys were conducted using three types of detectors: CZT, NaI(Tl), and LaBr3(Ce), across two contaminated areas. Dose rate values were converted using dose rate conversion factors for each detector type, and dose rate maps were subsequently created and compared. The detectors yielded similar results, demonstrating their feasibility and reliability in high radiation environments. The findings of this study are expected to be a crucial reference for enhancing the verification and supplementation of procedures and methods in future radiation measurements and mobile surveys in high-radiation environments, using these three types of radiation instruments.

CdZnTe Detector for Computed Tomography based on Weighting Potential (가중 퍼텐셜에 기초한 CT용 CdZnTe 소자 설계)

  • Lim, Hyunjong;Park, Chansun;Kim, Jungsu;Kim, Jungmin;Choi, Jonghak;Kim, KiHyun
    • Journal of radiological science and technology
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    • v.39 no.1
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    • pp.35-42
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    • 2016
  • Room-temperature operating CdZnTe(CZT) material is an innovative radiation detector which could reduce the patient dose to one-tenth level of conventional CT (Computed Tomography) and mammography system. The pixel and pixel pitch in the imaging device determine the conversion efficiency of incident X-or gamma-ray and the cross-talk of signal, that is, image quality of detector system. The weighting potential is the virtual potential determined by the position and geometry of electrode. The weighting potential obtained by computer-based simulation in solving Poisson equation with proper boundaries condition. The pixel was optimized by considering the CIE (charge induced efficiency) and the signal cross-talk in CT detector system. The pixel pitch was 1-mm and the detector thickness was 2-mm in the simulation. The optimized pixel size and inter-pixel distance for maximizing the CIE and minimizing the signal cross-talk is about $750{\mu}m$ and $125{\mu}m$, respectively.

Digital Beamforming in the Frequency Domain (주파수 영역 빔 형성에 관한 연구)

  • 박성범
    • Proceedings of the Acoustical Society of Korea Conference
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    • 1996.06a
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    • pp.13-17
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    • 1996
  • 다수의 신호를 동시에 사용하는 경우에 나타나는 광대역 신호나 센서의 수와 형성하고자 하는 빔의 수가 많은 경우를 다루기 위해서는 주파수 영역 기법이 필요하다. FFT를 사용하는 낮은 샘플링 주파수에서도 시간 영역에서의 보간 방법보다 빠르게 정확한 시간 지연을 줄 수 있어 코히어런트 신호처리가 가능하다. 또한 특정 센서가 불량인 경우 보정이 상대적으로 용이하다는 장점을 가진다. 여러 가지 주파수 영역 빔형성 기법 중 계산량과 저장 용량면으로 효율적인 방법은 CZT와 FIR interpolation 방법이다. 또한, 공액 빔을 형성할 경우에는 Goertzel의 알고리듬을 이용하는 방법도 효율적이다.

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Transform Domain Adaptive Filtering with a Chirp Discrete Cosine Transform LMS (CDCTLMS를 이용한 변환평면 적응 필터링)

  • Jeon, Chang-Ik;Yeo, Song-Phil;Chun, Kwang-Seok;Lee, Jin;Kim, Sung-Hwan
    • The Journal of the Acoustical Society of Korea
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    • v.19 no.8
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    • pp.54-62
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    • 2000
  • Adaptive filtering method is one of signal processing area which is frequently used in the case of statistical characteristic change in time-varing situation. The performance of adaptive filter is usually evaluated with complexity of its structure, convergence speed and misadjustment. The structure of adaptive filter must be simple and its speed of adaptation must be fast for real-time implementation. In this paper, we propose chirp discrete cosine transform (CDCT), which has the characteristics of CZT (chrip z-transform) and DCT (discrete cosine transform), and then CDCTLMS (chirp discrete cosine transform LMS) using the above mentioned algorithm for the improvement of its speed of adaptation. Using loaming curve, we prove that the proposed method is superior to the conventional US (normalized LMS) algorithm and DCTLMS (discrete cosine transform LMS) algorithm. Also, we show the real application for the ultrasonic signal processing.

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The structure and the surface composition of semiconductor CdZnTe films by EBE (EBE로 증착된 반도체 CdZnTe 박막의 결정구조와 표면조성)

  • 박국상;김선옥;이기암
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.5 no.1
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    • pp.25-36
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    • 1995
  • We have investigated the structure and the conductivity of the $Cd_{1-y}Zn_{y}$ Te films evaporated on the glass substrates (Corning 7059) by Electron Beam Evaporator (EBE) in pressure of approximately $1 {\times} 10^{-6}$ torr.The structure temperatures were held at both room temperature and $300^{\circ}C$, and the samples have annealed for an hour at $300^{\circ}C$ The survace com-position of the as-prepared films were slightly different from those of CdZn Te source material.Cd losses on the CdZnTe surface was measured about 4% of atomic ratio at room temperature substrate, whereas Zn atomic ratio was nearly constant, relatively. The strure is observed to be polycrystalline whose phase is mainly cubic phase. Thermal expansion coefficient was $6.30 {\times} 10^{-5}/^{\circ}C$ which was calculated from the variation of lattice parameter by X-ray powder pat-terns measured at $400^{\circ}C$.Diffraction peaks were slightly increased by annealing for an hour at $300^{\circ}C $, but they werey highly affected by substrate temperature during evaporation.

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High-Performance Compton SPECT Using Both Photoelectric and Compton Scattering Events

  • Lee, Taewoong;Kim, Younghak;Lee, Wonho
    • Journal of the Korean Physical Society
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    • v.73 no.9
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    • pp.1393-1398
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    • 2018
  • In conventional single-photon emission computed tomography (SPECT), only the photoelectric events in the detectors are used for image reconstruction. However, if the $^{131}I$ isotope, which emits high-energy radiations (364, 637, and 723 keV), is used in nuclear medicine, both photoelectric and Compton scattering events can be used for image reconstruction. The purpose of our work is to perform simulations for Compton SPECT by using the Geant4 application for tomographic emission (GATE). The performance of Compton SPECT is evaluated and compared with that of conventional SPECT. The Compton SPECT unit has an area of $12cm{\times}12cm$ with four gantry heads. Each head is composed of a 2-cm tungsten collimator and a $40{\times}40$ array of CdZnTe (CZT) crystals with a $3{\times}3mm^2$ area and a 6-mm thickness. Compton SPECT can use not only the photoelectric effect but also the Compton scattering effect for image reconstruction. The correct sequential order of the interactions used for image reconstruction is determined using the angular resolution measurement (ARM) method and the energies deposited in each detector. In all the results of simulations using spherical volume sources of various diameters, the reconstructed images of Compton SPECT show higher signal-to-noise ratios (SNRs) without degradation of the image resolution when compared to those of conventional SPECT because the effective count for image reconstruction is higher. For a Derenzo-like phantom, the reconstructed images for different modalities are compared by visual inspection and by using their projected histograms in the X-direction of the reconstructed images.

Effect of sulfur addition on Cu2ZnSnSe4 thin film by Pulsed Laser Deposition (PLD를 이용한 CZTS의 박막의 S 첨가의 영향)

  • Jang, Yun-Jung;Amal, M. Ikhlasul;Alfaruqy, M. Hilmy;Kim, Kyoo Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.86.1-86.1
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    • 2010
  • Cu2ZnSnSe4는 CIS 태양전지의 In 대체 물질계로 주목을 받고 있는 저가형 태양전지 재료로 장차 차세대 태양전지 재료로 응용이 기대되고 있다. 그러나 에너지 밴드갭이 0.9~1.1eV로 다소 낮아 태양전지 광흡수층 재료로 사용하기 위해서는 wide band gab화 처리가 필요하다. 본 연구에서는 CZTSe에 S를 첨가하여 에너지 밴드갭을 확장하고자 하며, S의 첨가가 CZTSe 박막의 특성에 미치는 영향에 대하여 조사하였다. 실험의 편의성을 도모하고자 펄스레이저 법을 사용하여 증착하였다. 박막 조성 제어에는 Cu, Zn, Sn, Se, S 분말을 볼밀로 분쇄, 혼합하여 균질 혼합상 프리커서를 제조하고 이를 Cold Isostatic Press(CIP) 성형하여 Source target을 사용하였다. Pulsed YAG-Laser를 사용하여 soda lime glass상에 증착하고 조성, 구조, 조직을 관찰하고 에너지 밴드갭, 광흡수계수, 면저항, 전하밀도 등 특성을 조사하였다.

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The electrical and optical properties of Cd$_{0.96}$Ze$_{0.04}$Te thin films (Cd$_{0.96}$Ze$_{0.04}$Te 박막의 전기 광학적 특성)

  • 김선옥;현준원
    • Journal of the Korean institute of surface engineering
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    • v.31 no.6
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    • pp.389-392
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    • 1998
  • We have investigated the crystal properties of the Cd0.96Zn0.04Te(CZT) films evaporated on the Si(100) substrates by Elecctron Beam Evaporator(EBE) techique. The compositions of the As-preared films were different about 4% of atomic ratio, The films stucture was observad to be polycrystalline in cubic phase. Diffraction peaks were notable at the substrate temperature of $300^{\circ}C$. The reflectance measurements yield $E_1$=3.25~3.29 eV $E_1$+${\Delta}_1$=3.76~3.83 eV and $E_2$=5.08 eV,showing that the films wear in cubic phase. For the film evaporated at the substrate temperature of $150^{\circ}C$, the peaks of photocurrent are at 720nm and 980nm.

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Gamma-ray Detectors for Nuclear Medical Imaging Instruments (핵의학 영상기기의 감마선 검출기)

  • Cho, Gyu-Seong
    • Nuclear Medicine and Molecular Imaging
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    • v.42 no.2
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    • pp.88-97
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    • 2008
  • In this review paper, basic configurations of gamma detectors in SPECT and PET systems were reviewed together with key performance parameters of the imaging system, such as the detection efficiency, the spatial resolution, the contrast resolution, and the data acquisition time for quick understanding of the system-component relationship and future design of advanced systems. Also key elements of SPECT and PET detectors, such as collimators, gamma detectors were discussed in conjunction with their current and future trend. Especially development trend of new scintillation crystals, innovative silicon-based photo-sensors and futuristic room-temperature semiconductor detectors were reviewed for researchers who are interested in the development of future nuclear medical imaging instruments.