• 제목/요약/키워드: CZ method

검색결과 65건 처리시간 0.032초

조화용융성조성을 가진 $LiNbO_3$ 단결성의 미소결함 (Micro-defects in $LiNbO_3$ single crystals with congruent melting composition)

  • 김현기;권달회;이선우;심광보;오근호
    • 한국결정성장학회지
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    • 제9권3호
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    • pp.267-272
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    • 1999
  • Czochralski법으로 성장시킨 조화용융조성(48.6 mol%$LiNbO_3$)의 undoped 및 MgO-doped $LiNbO_3$ 단결정 내의 미소결함을 광학현미경 및 주사/투과 전자현미경을 이용하여 정밀분석하였다. Dopant 첨가 및 성장된 부위(g)에 따른 분역구조의 변화와 결함밀도를 측정함으로써 결함양상을 분석하고 최적 결정성장조건과의 상관관계를 고찰하였다. 강자성 분역벽 주변의 높은 결함밀도는 이 근처가 응력이 집중된 영역임을 반영하고, 특히 한쪽 방향의 분역벽에만 결함이 밀집된 결함구조를 가지고 있음을 확인하였다.

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결정질 실리콘 태양전지에 적용될 Light-induced plating을 이용한 Ni/Cu 전극에 관한 연구 (The Research of Ni/Cu Contact Using Light-induced Plating for Cryatalline Silicom Solar Cells)

  • 김민정;이수홍
    • 한국태양에너지학회:학술대회논문집
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    • 한국태양에너지학회 2009년도 추계학술발표대회 논문집
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    • pp.350-355
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    • 2009
  • The crysralline silicon solar cell where the solar cell market grows rapidly is occupying of about 85% or more high efficiency and low cost endeavors many crystalline solar cells. The fabricaion process of high efficiency crystalline silicon solar cells necessitate complicated fabrication processes and Ti/Pd/AG contact, This metal contacts have only been used in limited areas in spite of their good srability and low contact resistance because of expensive materials and process. Commercial solar cells with screen-printed solar cells formed by using Ag paste suffer from loe fill factor and high contact resistance and low aspect ratio. Ni and Cu metal contacts have been formed by using electroless plating and light-induced electro plating techniques to replace the Ti/Pd/Ag and screen-printed Ag contacts. Copper and Silver can be plated by electro & light-induced plating method. Light-induced plating makes use the photovoltaic effect of solar cell to deposit the metal on the front contact. The cell is immersed into the electrolytic plating bath and irradiated at the front side by light source, which leads to a current density in the front side grid. Electroless plated Ni/ Electro&light-induced plated Cu/ Light-induced plated Ag contact solar cells result in an energy conversion efficiency of 16.446 % on 0.2~0.6${\Omega}$ cm, $20{\times}20mm^2$, CZ(Czochralski) wafer.

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결정질 실리콘 태양전지의 광학적 손실 감소를 위한 표면구조 개선에 관한 연구 (Investigation of the surface structure improvement to reduce the optical losses of crystalline silicon solar cells)

  • 이은주;이수홍
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2006년도 춘계학술대회
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    • pp.183-186
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    • 2006
  • Reduction of optical losses in crystalline silicon solar cells by surface modification is one of the most important issues of silicon photovoltaics. Porous Si layers on the front surface of textured Si substrates have been investigated with the aim of improving the optical losses of the solar cells, because an anti-reflection coating and a surface passivation can be obtained simultaneously in one process. We have demonstrated the feasibility of a very efficient porous Si AR layer, prepared by a simple, cost effective, electrochemical etching method. Silicon p-type CZ (100) oriented wafers were textured by anisotropic etching in sodium carbonate solution. Then, the porous Si layer were formed by electrochemical etching in HF solutions. After that, the properties of porous Si in terms of morphology, structure and reflectance are summarized. The surface morphology of porous Si layers were investigated using SEM. The formation of a porous Si layer about $0.1{\mu}m$ thick on the textured silicon wafer result in an effective reflectance coefficient $R_{eff}$ lower than 5% in the wavelength region from 400 to 1000nm. Such a surface modification allows improving the Si solar cell characteristics.

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경남지역에서 발생한 가금티푸스의 역학적 특성 및 진단방법에 대한 비교 시험 (Epidemiological characteristics on fowl typhoid outbreak in Kyongnam province and comparison of diagnostic methods for identification of salmonella gallinarum)

  • 최유정;김도경;김용환
    • 한국동물위생학회지
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    • 제23권4호
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    • pp.349-360
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    • 2000
  • An epidemiological survey was conducted to investigate fowl typhoid outbreaks in Kyungnam province of Korea. The causative agent, salmonella gallinarum was isolated from 68 chicken samples of tentatively diagnosed fowl typhoid cases occurred during the period from January 1996 to September 1999. Comparative studies were also carried out to evaluate the diagnostic methods for detection of S gallinam The results obtained were as follows; 1. Of the 68 cases of tentatively diagnosed fowl typhoid, 56 (82%) cases were determined as fowl typhoid by biochemical test and pathological findings. The other 12 (18%) cases were determined as paratyphoid. 2. Fowl typhoid outbreaks occur continuously all seasons in the year, however the incidence was remarkably increased from May to September. 3. The frequency of incidence of fowl typhoid in terms of regional distribution was relatively high in egg-laying hens facilities, and the mode of transmission is likely to be either egg-to-egg or lateral transfer by wild birds or rats. 4. All of 18 isolates from 56 cases were identified as S gallinarum by biochemical and serological test. 5. Antimicrobial drug susceptibility test against 18 isolates showed that the isolates were highly susceptible to ASH, CZ, CF and GM (above 90%), whereas those strains were 100% resistant to EM, NA and PC. 6. S gallinarum rfbS gene was targeted to be amplified by PCR for comparative detection of S gallinarum in the experimentally infected chickens. The amplified 720bp DNA fragment, which is specific in D serogroup strains of S enterica subspecies was confirmed by agarose gel electrophoresis. 7. A comparison made between fecal culture and PCR-method revealed that later-method was relatively higher in detection rate than that of former method for S gallinarum. 8. Comparison of currently applied methods, rapid serum agglutination test (RST) and microplate agglutination test (MAT), with experimentally infected chickens were made to evaluate sensitivity of detection by neutralizing antibody titration. Both methods detected neutralizing antibodies from the challenged chickens of 5 day post infection. However, positive reactions were determined after 7 and 9 days post infection by MAT and RST, respectively.

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결정질 실리콘 태양전지의 저가 고 효율화를 위한 Ni/Cu/Ag 전극 태양전지 (The Research of Ni/Cu/Ag Contact Solar Cells for Low Cost & High Efficiency in Crystalline Solar Cells)

  • 조경연;이지훈;이수홍
    • 한국태양에너지학회:학술대회논문집
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    • 한국태양에너지학회 2009년도 춘계학술발표대회 논문집
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    • pp.214-219
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    • 2009
  • In high-efficiency crystalline silicon solar cells, If high-efficiency solar cells are to be commercialized. It is need to develop superior contact formation method and material that can be inexpensive and simple without degradation of the solar cells ability. For reason of plated metallic contact is not only high metallic purity but also inexpensive manufacture. It is available to apply mass production. Especially, Nickel, Copper and Silver are applied widely in various electronic manufactures as easily formation is available by plating. The metallic contact system of silicon solar cell must have several properties, such as low contact resistance, easy application and good adhesion. Ni is shown to be a suitable barrier to Cu diffusion as well as desirable contact metal to silicon. Nickel monosilicide(NiSi) has been suggested as a suitable silicide due to its lower resistivity, lower sintering temperature and lower layer stress than $TiSi_2$. Copper and Silver can be plated by electro & light-induced plating method. Light-induced plating makes use the photovoltaic effect of solar cell to deposite the metal on the front contact. The cell is immersed into the electrolytic plating bath and irradiated at the front side by light source, which leads to a current density in the front side grid. Electroless plated Ni/ Electro&light-induced plated Cu/ Light-induced plated Ag contact solar cells result in an energy conversion efficiency of 14.68 % on $0.2{\sim}0.6{\Omega}{\cdot}cm,\;20{\times}20mm^2$, CZ(Czochralski) wafer.

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UV 경화 수지의 화학적 기계적 경화특성 분석 (Analysis of Chemical and Mechanical Properties of UV Curing Resin)

  • 장용수;김정근;고선호;곽이구
    • 한국기계가공학회지
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    • 제19권6호
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    • pp.88-95
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    • 2020
  • Currently, Fiber-Reinforced Plastic (FRP) composite materials are used in many industrial fields, owing to their superior stiffness and specific strength compared to metals. However, there are issues with FRP inefficiency, due to low productivity of such materials, environmental problems they pose and long curing times needed. Trying to address these issues, research was conducted towards the development of a FRP composite material with excellent properties and short production time, introducing a curing method using a UV lamp. Four types of composite materials were prepared, cured with catalyst or UV (CZ: Catalyst + ZNT 6345, CR: Catalyst + RF 1001 MV, UVZ: Photoinitiator + ZNT 6345, and UVR: Photoinitiator + RF 1001 MV). Examination of the chemical and mechanical properties of these composites showed that UV-cured materials performed better than the catalyst-cured ones. These results indicate that the production process of FRP composite materials can be simplified by using a UV lamp for curing, resulting in composite materials with the same quality, but reduced production time by about 70% compared to currently used practices. This advancement will contribute greatly to the composite material industry.

생산성 증대를 위한 대구경 잉곳 연속 성장 초크랄스키 공정 최적 속도 연구 (A Study of Optimum Growth Rate on Large Scale Ingot CCz (Continuous Czochralski) Growth Process for Increasing a Productivity)

  • 이유리;노지원;정재학
    • Korean Chemical Engineering Research
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    • 제54권6호
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    • pp.775-780
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    • 2016
  • 최근 태양전지 산업에서는 효율과 더불어서 생산성을 높이고 원가를 절감할 수 있는 설계가 요구되고 있다. 생산성의 향상을 위하여 반응기의 크기를 키우면 기존의 8 inch 잉곳에서 12 inch 잉곳으로 생산이 가능하다. 또한 연속공정법을 사용하여 생산성 증대를 극대화 시킬 수 있다. 본 연구에서는 12인치 잉곳이 최적 컨디션의 수율향상을 위한 소비전력 감소와 생산성 향상에 관한 시뮬레이션을 진행하였다. 인출속도 별 계면 형상과 폰-미제스 스트레스, 온도구배, 소비전력을 비교하여 최적의 인출속도를 찾았다. 그 결과, 생산성 향상과 에너지를 절감할 수 있는 최적 공정 파라미터를 도출할 수 있었다. 이러한 연구는 실제 태양전지 산업에서 생산성 향상에 기여할 수 있을 것으로 기대 된다.

남해안 어류양식장에서 분리된 Escherichia coli에 대한 항균제 감수성 (Antimicrobial Susceptibility of Escherichia coli Isolated from Fish Farms on the Southern Coast of Korea)

  • 손광태;오은경;박큰바위;권지영;이희정;이태식;김지회
    • 한국수산과학회지
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    • 제42권4호
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    • pp.322-328
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    • 2009
  • Three-hundred and sixteen Escherichia coli strains from seawater, and a variety of farmed fishes, including oliver flounder (Paralichthys olivaceus), black rock fish (Sebastes schlegeli), red sea bream (Pagrus major) and sea bass (Lateolabrax japonicus) between May to October in 2004, were tested by agar dilution method to determine their susceptibility patterns to 17 antimicrobial agents. Overall, 92.1% of Escherichia coli isolates from samples showed antimicrobial resistance to at least one antimicrobial agent and the multiple resistance was seen in 173 isolates (54.7%). The resistance of E. coli isolates to tetracycline (74.1%) was highest, followed by cephalothin (69.9%), doxycycline (66.5%), streptomycin (47.2%), ampicillin (46.2%), cefazolin (31.6%), enrofloxacin (31.0%). norfloxacin (28.2%). The most frequent resistance pattern was TE-D-CF-CIP-ENO-NOR-AM-S-C-SXT-AmC-CZ (14.7%), followed by CF (6.2%), TE (5.1%), TE-CF (4.5%) in 177 isolates from fishes and TE-D-CF (7.2%) followed by TE-D-CF-S (5.8%), CF and TE-D-S (3.6%) in 139 isolates from seawater.

대기압 플라즈마를 이용한 P타입 태양전지 웨이퍼 도핑 연구 (Study of P-type Wafer Doping for Solar Cell Using Atmospheric Pressure Plasma)

  • 윤명수;조태훈;박종인;김상훈;김인태;최은하;조광섭;권기청
    • Current Photovoltaic Research
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    • 제2권3호
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    • pp.120-123
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    • 2014
  • Thermal doping method using furnace is generally used for solar-cell wafer doping. It takes a lot of time and high cost and use toxic gas. Generally selective emitter doping using laser, but laser is very high equipment and induce the wafer's structure damage. In this study, we apply atmospheric pressure plasma for solar-cell wafer doping. We fabricated that the atmospheric pressure plasma jet injected Ar gas is inputted a low frequency (1 kHz ~ 100 kHz). We used shallow doping wafers existing PSG (Phosphorus Silicate Glass) on the shallow doping CZ P-type wafer (120 ohm/square). SIMS (Secondary Ion Mass Spectroscopy) are used for measuring wafer doping depth and concentration of phosphorus. We check that wafer's surface is not changed after plasma doping and atmospheric pressure doping width is broaden by increase of plasma treatment time and current.

새로운 무게센서에 의한 $Bi_{12}GeO_{20}$ 단결정 육성연구(II) (The Crystal Growth of $Bi_{12}GeO_{20}$ Single Crystal by the CZ Technique with New Weighing Sensor (II))

  • 장영남;배인국
    • 한국결정학회지
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    • 제9권1호
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    • pp.30-38
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    • 1998
  • 주파수 무게센서를 장착한 자동직경제어 방식에 의해 Bi12GeO20 단결정을 쵸크랄스키법으로 육성하였다. 회전속도에 따른 계면모양의 변화를 관찰하기 위해, 회전속도를 변화시키면서 육성한 결과, 23-21rpm에서 평평한 계면이 형성되었다. Bi2O3의 휘발에 의한 화학 양론적 조성으로부터 이탈에 따른 Bi4Ge3O12의 생성과 이로 인한 색 변화를 관찰하기 위해, Bi2O3의 함량을 0.1-1mol% 보충한 결과, 0.3mol% 증발 보상을 하였을 때, 내포물이 적은 연한 갈색의 광학용 단결정을 육성할 수 있었다. 이러한 성장조건 하에서 직경 25mm x 길이 70mm 인 거의 일정한 직경을 갖는 단결정이 육성되었고 결함밀도는 103개/cm2를 나타내었다. XRD및 TEM에 의해 단결정의 우선 성장방향을 측정한 결과<110>이었다.

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