• Corrosion Science and Technology
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• v.16 no.5
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• pp.247-256
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• 2017

The feasibility of using hydrazine for inhibiting pitting corrosion in copper sprinkler tubes was investigated by examining microscopical and structural evolution of corrosion by-products with SEM, EDS, and XRD. Hydrazine removed dissolved oxygen and reduced CuO and $Cu_2O$ as well. The stable phase was changed from CuO to $Cu_2O$ or Cu depending on hydrazine concentration. Hydrazine concentration of 500 ppm could convert all CuO corrosion by-products to $Cu_2O$. In a tightly sealed acryl tube filled with aqueous solution of 500 ppm hydrazine, octahedral $Cu_2O$ particles were formed while plate-like structures with high concentration of Cu, O, N and C were formed near a corrosion pit. The inside structure of a corrosion pit was not altered by hydrazine aqueous solution. Uniform corrosion of copper was almost completely stopped in aqueous solution of 500 ppm hydrazine. Corrosion potential of a copper plate was linearly dependent on log (hydrazine concentration). The concept of stopping pitting corrosion reaction by suppressing oxygen reduction reaction could be verified by applying this method to a reasonable number of real sprinkler systems before full-scale application.

• Corrosion Science and Technology
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• v.11 no.5
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• pp.173-178
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• 2012

To manage the wall thinning of carbon steel piping in nuclear power plants, the utility of Korea has performed thickness inspection for some quantity of pipe components during refueling outages and determined whether repair or replacement after evaluating UT (Ultrasonic Test) data. When the existing UT data evaluation methods, such as Band, Blanket, PTP (Point to Point) Methods, are applied to a certain pipe component, unnecessary re-inspecting situations may be generated even though the component does not thinned. In those cases, economical loss caused by repeated inspection and problems of maintaining the pipe integrity followed by decreasing of newly inspected components may be generated. EPRI (Electric Power Research Institute) in USA has suggested several statistical methods, TPM (Total Point Method), LSS (Least Square Slope) Method, etc. to distinguish whether multiple inspecting components have thinned or not. This paper presents the analysis results for multiple inspecting components over three times based on both NAM (Near Area of Minimum) Method developed by KEPCO-E&C and the other methods suggested by EPRI.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.184-184
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• 2012

We proposed a new measurement method of cutoff probe using the reactance spectrum of the plasma in cutoff probe system instead of transmission spectrum. The high accurate reactance spectrum of the plasma which is expected in previous circuit simulation of cutoff probe [1] was measured by using the automatic port extension method of the network analyzer. The measured reactance spectrum is good agreement with E/M wave simulation result (CST Microwave Studio). From the analysis of the measured reactance spectrum based on the circuit modeling, not only the electron density but also electron-neutral collision frequency can be simply obtained. The obtained results of electron density and e-n collision frequency were presented and discussed in wide range of experimental conditions, together with comparison result with previous methods (a previous cutoff probe using transmission spectrum and a single langmuir probe).

• Corrosion Science and Technology
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• v.10 no.4
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• pp.143-150
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• 2011

Copper electroplating has been applied to various fields such as decorative plating and through-hole plating. Technical realization of high strength copper preplating for wear-resistant tools and molds in addition to these applications is the aim of this work. Brighters and levelers, such as MPSA, Gelatin, Thiourea, PEG and JGB, were added in copper sulfate electrolyte, and the effects of these organic additives on the hardness were evaluated. All additives in this work were effective in increasing the hardness of copper electrodeposits. Thiourea increased the hardness up to 350 VHN, and was the most effective accelarator in sulfate electrolyte. It was shown from the X-ray diffraction analysis that preferred orientation changed from (200) to (111) with increasing concentration of organic additives. Crystallite size decreased with increasing concentration of additive. Hardness was increased with decreasing crystallite size, and this result is consistent with Hall-Petch relationship, and it was apparent that the hardening of copper electrodeposits results from the grain refining effect.

• Corrosion Science and Technology
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• v.11 no.1
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• pp.20-28
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• 2012

Since buried pipes contact the soil directly, corrosion by the soil could be occurred. Recently, some stainless steel pipes after 8 years burial at G area were corroded and leaked. In order to elucidate highly corroded phenomena(its rate was about 0.175 mm/y) of these pipes, the investigation for corrosion environment, soil, stray current's effect, and chemical analysis on the pipes were performed. Most of investigated sites were close to traditional water-closet and showed high moisture and thus those areas could be highly corrosive. In the investigation by two kinds of soil evaluation methods, it was revealed that the soils at G areas were highly corrosive, and moreover the contents of sulfate reducing bacteria in the soils were high. Also, open circuit potentials of many pipes showed different values and its potentials were high positive. Therefore, it was considered that corrosion of buried pipes at G area could be affected by high corrosive soil's environment and stray current corrosion.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.60 no.1
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• pp.131-137
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• 2011

This paper analyzes EM(Electromagnetic) characteristic in the high voltage connector for the hybrid electric vehicle. The connector bridges the electrical components and helps transferring electrical power and signal through it. The necessity of the high voltage and current connector development is emphasized because the hybrid electric vehicle recently uses the high voltage and current more than 500V and 80A. So far there has not been international EMC (Electromagnetic Compatibility) standards to limit the RE(Radiation Emission) from the connector for the hybrid electric vehicle. In this paper we analyzed EM characteristic of the 288V, 65A connector to check if the RE from the high voltage connector could be within the RE limit standard of vehicle. Three-dimensional modeling and simulation was conducted by using MWS(Microwave Studio) of the CST corporation, and the result was compared with the measured RE data, which showed good coincidence each other.

• Corrosion Science and Technology
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• v.19 no.1
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• pp.31-36
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• 2020

An efficient wet process approach to modifying natural graphite (NG) electrodes for Li-ion batteries is introduced in this paper. With homogeneous mixing and thermal decomposition of NG with diammonium phosphate ((NH₄)₂HPO₄), phosphorus and nitrogen were successfully incorporated into the surface layer of NG particles. Electron microscopy and X-ray photoelectron spectroscopy analyses demonstrated that the surface was well modified by this process. As a result, the treated NG electrodes exhibited much improved electrochemical performance over pristine NG at two different temperatures: 25 ℃ and 50 ℃. Excellent capacity retention of 95.6% was obtained after 100 cycles at 50 ℃. These enhanced properties were confirmed in a morphology analysis on the cross-sections of the NG electrodes after galvanostatic cycling. The improved cycle and thermal stabilities can be attributed to the surface treatment with phosphorus and nitrogen; the treatment formed a stable solid electrolyte interphase layer that performed well when undergoing Li insertion and extraction cycling.

• Corrosion Science and Technology
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• v.19 no.1
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• pp.1-7
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• 2020

Chalk River Unidentified Deposits (CRUDs) were collected from the Korean pressurized water reactor (PWR) plant (A, B, and C) where the axial offset anomaly (AOA) occurred. AOA, also known as a CRUD-induced power shift, is one of the key issues in maintaining stable PWR plant operations. CRUDs were sampled from spent nuclear fuel rods and analyzed using an electron probe micro-analyzer (EPMA). This paper describes the characteristics of boron-deposits from the CRUDs sampled from twice-burnt assemblies from the Korean PWR. The primary coolant of a PWR contains boron and lithium. It is known that boron deposition occurs in a thick CRUD layer under substantial sub-cooled nucleate boiling (SNB). The results of this study are summarized as follows. Boron was not found at the locations where the existence was confirmed in simulated CRUDs, in other words, the cladding and CRUD boundaries. Nevertheless, we clearly observed the presence of boron and confirmed that boron existed as a lump in crystalline form. In addition, the study confirmed that CRUD existed in a crystal form with a unique size of about 10 ㎛.

• Steel and Composite Structures
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• v.24 no.4
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• pp.499-512
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• 2017

This paper deals with nonlinear dynamic stability of embedded piezoelectric nano-composite separators conveying pulsating fluid. For presenting a realistic model, the material properties of structure are assumed viscoelastic based on Kelvin-Voigt model. The separator is reinforced with single-walled carbon nanotubes (SWCNTs) which the equivalent material properties are obtained by mixture rule. The separator is surrounded by elastic medium modeled by nonlinear orthotropic visco Pasternak foundation. The separator is subjected to 3D electric and 2D magnetic fields. For mathematical modeling of structure, three theories of classical shell theory (CST), first order shear deformation theory (FSDT) and sinusoidal shear deformation theory (SSDT) are applied. The differential quadrature method (DQM) in conjunction with Bolotin method is employed for calculating the dynamic instability region (DIR). The detailed parametric study is conducted, focusing on the combined effects of the external voltage, magnetic field, visco-Pasternak foundation, structural damping and volume percent of SWCNTs on the dynamic instability of structure. The numerical results are validated with other published works as well as comparing results obtained by three theories. Numerical results indicate that the magnetic and electric fields as well as SWCNTs as reinforcer are very important in dynamic instability analysis of structure.

• Corrosion Science and Technology
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• v.16 no.2
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• pp.64-68
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• 2017

The interactions between corrosion pits on stainless steel under loading conditions are studied by using a cellular automata model coupled with finite element method at a mesoscopic scale. The cellular automata model focuses on a metal/film/electrolyte system, including anodic dissolution, passivation, diffusion of hydrogen ions and salt film hydrolysis. The Chopard block algorithm is used to improve the diffusion simulation efficiency. The finite element method is used to calculate the stress concentration on the pit surface during pit growth, and the effect of local stress and strain on anodic current is obtained by using the Gutman model, which is used as the boundary conditions of the cellular automata model. The transient current characteristics of the interactions between corrosion pits under different simulation factors including the breakdown of the passive film at the pit mouth and the diffusion of hydrogen ions are analyzed. The analysis of the pit stability product shows that the simulation results are close to the experimental conclusions.