• Title/Summary/Keyword: CR 분석

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Synthesis and structural analysis of chromium(III) picolinate complexes (Cr(III)-picolinate 착물의 합성과 구조분석에 관한 연구)

  • Kim, Sung-Il;Kang, Dae-Kyung;Cha, Ki-Won
    • Analytical Science and Technology
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    • v.16 no.1
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    • pp.25-31
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    • 2003
  • Chromium(III) picolinate, a highly bioavailable compound, is known to be used for supplementing essential chromium(III) to human beings and animals. Two different methods were used to synthesize chromium(III) picolinate. The synthetic products were characterized by elemental analysis, FTI-IR, high performance liquid chromatography (HPLC) and MALDI-MS.

Removal of heavy metal by coprecipitation with barium sulfate (황산바륨의 공침현상을 이용한 중금속 이온의 제거)

  • Lim, Heon-Sung;Lee, Sueg-Geun
    • Analytical Science and Technology
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    • v.19 no.4
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    • pp.280-284
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    • 2006
  • The objective of this study is to investigate the removal of heavy metal by using the coprecipitation of barium sulfate. Several parameters governing the efficiency of the coprecipitation method were evaluated by the pH of sample solution, amount of coprecipitant, and addition of sulfide for the removal of As(V), Cd(II), Cr(III), Cr(VI), Cu(II), Hg(II) and Pb(II) metal ions ($10{\mu}g/ml$ each). The coprecipitation was about 80% - 95% only for lead at low pH but under 10% for other ions. The amount of removal was about 95% - 100% for Cd, Hg, Pb, Cu in the all pH range by the addition of sulfide with barium sulfate but As(V) and Cr(III, VI) ions were not affected by the same conditions.

High temperature oxidation of MCrAlY thermal barrier coating (MCrAlY 열차폐 코팅의 고온산화)

  • 고재황;이동복
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.219-219
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    • 2003
  • HVOF(High Velocity Oxygen Fuel)법을 사용한 MCrAlY(M=Ni, Co, Fe)계 열차폐 코팅(thermal barrier coating)은 열기관 내부의 극심한 환경 부하에 대해 구조물 표면에 열적, 화학적 장벽을 형성함으로써 구조물의 내구성을 향상시킨다 이와 동시에 열차폐 효과는 구조물의 온도상승 없이 내부 가동 온도를 높일 수 있게 함으로써 열효율을 상승시키고 연료 효율을 높여 가동비용 절감을 이룰 수 있는 동시에 고 연소를 통한 오염원의 배출을 감소시킬 수 있다. 본 연구에서는 $H_2O$$_2$=5:1 분위기 하에서 HVOF법을 사용하여 Hastelloy-X 기판위에 125$\mu\textrm{m}$의 두께로 다음 5종류의 (Ni, Co, Cr)계 MCrAlY 코팅을 용사시켰다. 준비된 (Ni, Co)-Cr-Al-(Y, Ta, Re), (Ni, Co)-Cr-Al-(Y, Re), (Ni, Co)-Cr-Al-(Y, Ta), (Ni, Co)-Cr-Al-Y, (Ni,Co)-Cr-Al-Ir 코팅시편에 대한 산화성질을 조사하기 위해 대기 중 1000, 1100, 120$0^{\circ}C$에서 50, 100, 150, 200시간 등온실험(Isothermal oxidation)을 실시하였고, XRD, SEM/EDS, EPMA를 이용하여 생성된 산화막과 코팅 시편의 조직 변화를 조사하였다. 산화온도와 산화시간이 증가할수록 산화막의 박리가 많이 발생하였으며, 분석 결과 미세하게 분포된 a-Al$_2$O$_3$ 입자, NiCr$_2$O$_4$스피넬 상, 미세한 Cr$_2$O$_3$가 관찰되었고, 코팅 조성 변화에 따라 형성되는 이들 산화물의 존재비가 달라졌으며, 산화온도가 높아질수록 산화속도가 가속화되었다.

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Estimation of Glomerular Filtration Rate using Chromium-51 EDTA (Cr-51 EDTA GFR 검사 결과의 분석 및 의의)

  • Lim, Soo-Yeon;Moon, Hyoung-Ho;Yoo, Seon-Hee;Cho, Shee-Man
    • The Korean Journal of Nuclear Medicine Technology
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    • v.13 no.1
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    • pp.98-103
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    • 2009
  • Purpose: Correct estimation of Glomerular filtration rate (GFR) is very important for an accurate clinical assessment of the kidney function. This study compares four GFR markers, a serum creatinine-based estimation using MDRD formula, Cystatin-C, Cr-51 EDTA 2 samples and 6 samples. Materials and Methods: Serum creatinine concentrations, Cystatin-C serum concentrations and Cr-51 EDTA clearance are measured in 43 patients who received or donated kidney. Results: The correlation coefficient between serum based estimated GFR (MDRD) and Cr-51 EDTA 6 samples was 0.817 (p<0.01). The correlation coefficient between Cystatin-C based GFR and EDTA 6 samples was 0.7322 (p<0.01). Regression analysis showed a statistically significant correlation between Cr-51 EDTA 2 samples and 6 samples (r=0.971, p<0.01). Mean value and ${\pm}2SD$ for the difference between Cr-51 EDTA 2 samples and 6 samples were 4.7 mL/min and ${\pm}9.3$ respectively. Conclusions: The estimation of two samples Cr-51 EDTA showed that the method can be simplified by reducing blood samples without losing its high accuracy.

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Efficient Channel Management to Maximize Spectrum Holes in Cognitive Radio Networks (CR 네트워크에서의 유휴자원 증대를 위한 효율적인 채널 관리 방법)

  • Jeong, Pil-Jung;Shin, Yo-An;Lee, Won-Cheol;Yoo, Myung-Sik
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.32 no.10B
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    • pp.621-629
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    • 2007
  • In cognitive radio (CR) network, the channels are generally classified into either the unavailable channels that are occupied by incumbent users or the available channels that are not occupied. The conventional channel classification scheme may result in poor utilization of spectrum holes since it does not take the spatial relationship between CR node and incumbent users into consideration. In this paper, we propose an efficient channel management scheme for the centralized CR network to maximize the spectrum holes by overcoming the shortcomings of conventional scheme. In addition, we mathematically analyze the effectiveness of proposed scheme. Based on the proposed channel management scheme, we also propose the rendezvous algorithm, which can establish the control channels between base station and CR node under the dynamically changing spectrum environment.

Effects of $H_2O$ Fraction of Alisma canaliculatum with Chromium on Blood Glucose Levels and Lipid Metabolism in Streptozotocin-Induced Diabetic Rats (택사 $H_2O$ 분획물과 Chromium의 투여가 Streptozotocin 유발 당뇨 흰쥐의 혈당 및 혈중 지질함량에 미치는 영향)

  • Lim, Sook-Ja;Park, Ji-Eun
    • Korean Journal of Food Science and Technology
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    • v.34 no.4
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    • pp.725-731
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    • 2002
  • Hypoglycemic effects of $H_2O$ fraction of Alisma canaliculatum (Ac) with chromium (Cr) in streptozotocin (STZ)-induced diabetic rats were investigated. Sprague-Dawley rats were divided into five groups: normal, diabetic-control, and three diabetic experimental groups. Diabetes mellitus was induced by injection of STZ (45 mg/kg) into tail vein, and $H_2O$ fraction of Ac and Cr were administrated orally to experimental rats for 14 days: Ac group (1,000 mg/kg), Cr-Ac group (Ac 1,000 mg/kg & Cr 100 mg/kg), and Cr group (100 mg/kg). Body weight losses were observed in all groups except the normal group, while the losses in experimental groups were significantly less than in diabetic-control group. The plasma glucose levels were significantly lower in Cr, Ac-Cr, and Ac groups compared to STZ-control group. Plasma cholesterol and TG levels of Ac-Cr group were significantly lower than those of diabetic-control group. Plasma HDL-cholesterol levels of three experimental groups were not significant compared to diabetic-control group, while the level of Cr group decreased more than diabetic-control group. The results suggest that there was no synergistic effect in the treatment of $H_2O$ fraction of Ac in combination with Cr, an indication that $H_2O$ fraction of Ac with Cr might possess some hypoglycemic and hypotriglyceridemic properties in STZ-induced diabetic rats.

Studies on the Development of TiAIN/CrN Multi-layered Thin Films by Unbalanced Magnetron Sputtering Process (비대칭 스퍼터링에 의한 TiAIN/CrN 나노 다층 박막의 합성 및 특성 분석에 관한 연구)

  • Kim, Gwang-Seok;Kim, Bom-Sok;Lee, Sang-Yul
    • Journal of the Korean institute of surface engineering
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    • v.38 no.6
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    • pp.207-211
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    • 2005
  • In this work a multi-layered nanostructured TiAIN/CrN superlattice coatings was synthesized using closed-field unbalanced magnetron sputtering method and the relationships between their superlattice period (1), micro-structure, hardness and elastic modulus were investigated. In addition, wear test at $500^{\circ}C$ and oxidation resistance test at $900^{\circ}C$ were performed to investigate high temperature properties of these thin films. The coatings were characterized in terms of microstructure and mechanical properties by transmission electron microscopy (TEM) and nano-indentation test. Results from TEM analysis showed that superlattice periods was inversely proportional to the jig rotation speed. The maximum hardness and elastic modulus of 37 GPa and 375 GPa were observed at superalttice period of 6.1 nm and 4.4 nm, respectively. An higher value of microhardness from TiAIN/CrN thin films than either TiAIN (30 GPa) or CrN (26 GPa) was noted while the elastic modulus was approximately an average of TiAIN and CrN films. These enhancement effects in superlattice films could be attributed to the resistance to dislocation glide across interface between the CrN and TiAIN layers. Much improved plastic deformation resistance ($H^3/E^2$) of 0.36 from TiAIN/CrN coatings was observed, compared with 0.15 and 0.16 from TiAIN and CrN, respectively. Also the wear resistance at $500^{\circ}C$ was largely increased than those of single TiAIN and CrN coatings and TiAIN/CrN coatings showed much reduced weight gain after exposure at $900^{\circ}C$ for 20 hours.