• 제목/요약/키워드: COD제거

검색결과 644건 처리시간 0.042초

Treatment of Refractory Dye Wastewater Using AOPs (고도산화공정(AOPs)을 이용한 난분해성 염색폐수 처리)

  • Kim, Jong-Oh;Lee, Kwon-Ki;Jung, Jong-Tae;Kim, Young-Noh
    • Journal of the Korean GEO-environmental Society
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    • 제7권3호
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    • pp.21-29
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    • 2006
  • The treatment performance of ozonation and three types of advanced oxidation processes (AOPs) such as $O_3/H_2O_2$, $O_3/UV$, $O_3/H_2O_2/UV$ was experimentally investigated for the treatment of refractory synthetic dye wastewater. The removal efficiency of $COD_{cr}$, color and biodegradability ($BOD_5/COD_{cr}$) were relatively evaluated in each treatment unit with simulated dye wastewater. Optimal operational conditions of pH, temperature, dosage and circulation flow rate were also investigated. All suggested processes revealed an effectiveness for the removal of color within a short operational time, moreover, $O_3/H_2O_2/UV$ process showed the highest $COD_{cr}$ removal and biodegradability enhancement among proposed oxidation process.

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Optimization and Characteristics of Removal Condition of Livestock Wastewater Using a Photocatalytic Process (광촉매공정 적용시 축산폐수의 처리특성 및 최적화)

  • Park, Jae-Hong
    • Clean Technology
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    • 제13권3호
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    • pp.222-227
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    • 2007
  • The photocatalytic degradation of livestock wastewater has been investigated over $TiO_2$ photocatalysts irradiated with a ultraviolet (UV) light. The effect of operational parameters, i.e., distance, reaction area, concentration of suspended solids(SS), and column diameter on the degradation of livestock wastewater has been performed in lab-scale. The optimal conditions for livestock wastewater were determined: distance was 3 cm (less than 7 cm), reaction area was $3.6\;m^2$, SS concentration was 40 mg/L (less than 300 mg/L) and column diameter was 5 mm (less than 10 mm). Under the optimal conditions, COD, color and coliform removal efficiencies were approximately 49%, 53% and 100%, respectively. Non-biodegradable COD removal efficiency increased with 57% using by photocatalysis process. Therefore, it is shown that photocatalysis has an effect on degradation of non-biodegradable organic matter.

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A Study on the Cause of Scale Formation in Biogas Plant with Food Wastewater (음식물류 폐수를 이용한 바이오가스 생산시설의 스케일 형성요인에 관한 연구)

  • Bae, Young-Shin;Chun, Seung-Kyu
    • Journal of Korean Society of Environmental Engineers
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    • 제35권9호
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    • pp.660-665
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    • 2013
  • To find out the major cause of scale formation in digestion facility, a componential analysis of scale and a digestion experiment for food wastewater were conducted. The analysis indicated that grease in food wastewater was closely connected to the organic component of scale. It is also indicated that grease-removed food wastewater showed 58.9% level compared to unprocessed one in crystal generation quantity in this study. The experiment provided insight that grease is one of the important causes of scale formation. Additionally, pre-removal of grease from food wastewater did not show negative effect on digestion gas production, as 68.7 L-gas/kg-COD for grease-removed food wastewater and 67.7 L-gas/kg-COD for unprocessed one.

Mixing effect on organic removal efficiency in treating low-strength wastewater using a modified anaerobic filter reactor (변형 혐기성 여상 반응조에서 교반강도가 유기물 제거효율에 미치는 영향)

  • 정병곤;이헌모
    • Journal of Environmental Science International
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    • 제5권4호
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    • pp.513-524
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    • 1996
  • Laboratory investigation was conducted to evaluat the mixing effects on organic removal efficiency to treat low-strength synthetic wastewater using modified anaerobic - filter reactor combining anaerobic filter and upflow anaerobic sludge blanket. Using the modified process the low-strength wastewater like municipal sewage could be treated with 85% T-COD removal efficiency at hydraulic retention time of 6 hours. At the constant organic loading of 0.5 kg COD/m 3-day, the organic removal efficiency and effluent COD concentration are increased as influent COD concentration increased from 125 mg/l to 500 mg/l. Mixing effects on organic removal efficiency are evident and optimum mixing speed is found as 50RPM. Placing the granular sludge and media on which slime layer was pre-formed into the reactor seemed to be very effective In achieving short start-up period. Therefore, the steady state was achived after 4 weeks and 1 week based on T-COD and S-COD, respectively.

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Estimation of Sludge Reduction and Nitrogen Removal Possibility using OSA Process (OSA 공정을 이용한 하수슬러지 감량화 및 질소제거 가능성 평가)

  • Joo, Jae-Young;Yoon, Su-Chul;Nam, Duck-Hyun;Park, Chul-Hwi
    • Journal of Korean Society of Water and Wastewater
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    • 제22권5호
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    • pp.497-503
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    • 2008
  • The Oxic-Settling-Anaerobic(OSA) process is a modified activated sludge processes for sludge reduction. It is evaluated that the sludge production in OSA process can decrease to 88% because of biomass decay and kinetic parameter($Y_H$ 0.237mgVSS/mgCOD, $b_H$ $0.195d^{-1}$) in anaerobic reactor, when compared with CAS process. However, it has problems caused by sludge reduction such as increase of nutrient loading. In case that the anoxic condition through the introduction of the intermittent aeration for the enhancement of nitrogen removal ability build up and enough rbCOD is suppled, maximum 88% of nitrogen is removed in the OSA process. If the OSA process optimizing the intermittent aeration cycle is applied to the separate sewage system with high rbCOD fraction, it can be converted to advanced process in terms of the sludge reduction and nitrogen removal, simultaneously.

Effect of High Concentration of Sulfate on Anaerobic Digestion of Propionic Acid Using an Upflow Anaerobic Sludge Blanket (상향류 혐기성 블랭킷 반응조를 이용한 프로피온산의 혐기성 처리시 고농도 황산염의 영향)

  • Lee, Chae-Young
    • Journal of the Korea Organic Resources Recycling Association
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    • 제16권3호
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    • pp.75-82
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    • 2008
  • Two UASB reactors were operated to investigate the effect of high concentration of sulfate on anaerobic digestion of propionate using an upflow anaerobic sludge blanket (UASB) reactor. An organic loading rate of $1.2kg\;COD/m^3{\cdot}d$ and a hydraulic retention time of 1.6 d were maintained during this study. In the absence of sulfate, the UASB reactor achieved about 95% removal of chemical oxygen demand whereas in the presence of $2,000\;SO_4^{2-}mg/L$, the COD removal rate decreased to 83% due probably to the inhibition of dissolved sulfide inhibition. Interactions between the methane producing bacteria (MPB) and sulfate reducing bacteria (SRB) were measured to investigate the competition between MPB and SRB. The MPB consumed average 58% of the available electron donors at $COD/SO_4^{2-}$ ratio of 1. Propionate was consumed mainly by SRB, converting sulfate into sulfide and suppressing the methane production. The specific methanogenic activity (SMA) using acetate and propionate increased as microorganism acclimated to the substrate.

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Treatment of Dairy Wastewater by the Combination of RBC and tapered Aeration (RBC와 점감포기조의 복합구성에 따른 유가공폐수 처리에 관한 연구)

  • Lee, Sang-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • 제9권6호
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    • pp.1733-1738
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    • 2008
  • The treatment efficiency of rotating biological contactors (RBCs) for the high strength of dairy wastewater was investigated. Two different systems were conducted composing of a single RBC with tapered aeration reactors for the system A and a sequential RBCs following tapered aeration reactors for the system B. Experiments using dairy wastewater were conducted for 50 days period of time, in which hydraulic rates were maintained at the constant ratios of 346L per day and variable BOD concentrations were at the range from 1,358mg/L to 829mg/L, the $COD_{cr}$, concentration of the range were from 2,384mg/L to 1,329mg/L, the range of T-N concentrations was from 66mg/L to 38mg/L, and 50% of internal recycle and 50% of sludge return were performed. Results indicated that the removal efficiencies of the system B were higher than those of the system A. The removal efficiencies of system A for the BOD, $COD_{cr}$, T-N and T-P were 97.8%, 96.7%, 87.2% and 82%, respectively. The removal efficiencies of system B for the BOD, $COD_{cr}$, T-N and T-P were as of 98.5%, 98.5%, 91.3% and 89%.

Effects of surface properties and solution ph on the pollutants removal of K-PAC (K-PAC의 오염물질 제거에 대한 용액의 pH와 표면 특성의 효과)

  • Oh, Won-Chun;Bae, Jang-Soon
    • Analytical Science and Technology
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    • 제18권5호
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    • pp.436-443
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    • 2005
  • A study of physical properties and their application using K-powdered activated carbon system followed powdered carbon dispersion was carried out at laboratory. scale. Two types of K-powdered activated carbon for the dispersion have been used in this study to investigate the catalytic removal efficiency of pollutants from the wastewater. From the surface properties obtained for carbon samples treated with aqueous solutions containing potassium salts, main investigations were subjected to isotherm shape, SEM, EDX and surface functional groups. K-powdered activated carbons were dispersed to wastewater with pH variation to investigate the removal efficiency for the color, COD, T-N and T-P. From these removal results of the piggery waste using K-powdered activated carbon, satisfactory removal performance in the region of pH 6~8 was achieved. The excellent effects for the dispersion of the K-powdered activated carbon were proved by the above mentioned properties of the material for adsorption and trapping of organics, and catalytic effects.

Sequencing batch reactor treating ship sewage and external carbon source (연속 회분식 공정을 이용한 선박오수와 외부탄소원의 혼합처리)

  • Park Sang-Ho;Choi Jeong-Hye;Ko Sung-Chul;Kim In-Soo
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 한국항해항만학회 2004년도 추계학술대회
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    • pp.147-152
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    • 2004
  • In Sequence Batch Reactor (SBR), the removal efficiencies if nutrient materials such as nitrogen and phosphate depend highly on quantity and quality of organic carbon source. Food waste thai contains abundant organic materials has been produced in ship. The applicability if anaerobically fermented if food waste (AFFW) as an external carbon source was examined in the lab-scale SBR process operated at $25^{\circ}C$. With the addition if AFFW increased, average removal efficiencies if $COD_cr$, T-N, T-P changed to $98.5\%,\;95\%,\;93\%$, respectively. Denitrification rate is 0.30g $NO_3-N/g\;VSS{\cdot}day$. In summary, it was suggested tint AFFW sould be used as an economical and effective carbon source for the biological nitrogen and phosphate removal.

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Design of Electrolysis Reactor for the Reclamation System (중수도 시스템 운전을 위한 전기분해장치의 설계)

  • Sin, Chun-Hwan;Bae, Jeong-Seok
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 한국환경과학회 2006년도 추계 학술발표회 발표논문집
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    • pp.323-327
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    • 2006
  • 전류밀도를 $1.0\;A/dm^2{\ell}$로 고정시키고, 촉매로 사용된 소금의 농도를 전체 폐수량의 약 15%로 조절하여 접촉시간을 $0\;{\sim}\;120$ 분으로 조절하여 각각의 시간에서 $COD_{Mn}$ 농도 약 70mg/L의 합성폐수를 전기분해 처리하여 접촉시간 약 30분에서 약 25 mg/L로 제거 되었으며, 60분이 지난 후부터 약 12 mg/L로 제거되는 것을 확인 할 수 있었다. 접촉시간을 1 시간으로 고정시키고, 촉매로 사용된 소금의 농도를 전체 폐수량의 약 15%로 조절하여 전류밀도를 $0\;{\sim}\;2.0\;A/dm^2{\ell}$로 조절하여 각각의 전류밀도에서 $COD_{Mn}$의 농도변화 실험결과 전류밀도 약 1.0 $A/dm^2{\ell}$에서 약 9 mg/L로 제거가 가능한 것으로 조사 되었다. 접촉시간을 1 시간, 전류밀도를 $1.0A/dm^2{\ell}$로 고정시키고 사용된 소금의 농도를 전체 폐수량의 $0\;{\sim}\;30\;%$로 조절하여 각각의 촉매 첨가율에서 $COD_{Mn}$의 농도변화를 조사결과 촉매 첨가율 30 %에서 가장 높은 처리효율을 나타내었으며, 촉매의 첨가에 의한 전기분해 효율뿐만이 아니라 직류전원공급기에 전기적 부하 또한 감소되는 것을 확인 할 수 있었다.

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