• 제목/요약/키워드: COD/IL

검색결과 194건 처리시간 0.024초

득량만 표층퇴적물 중 유기물의 시.공간적 분포 및 기원 (Spatio-temporal Distribution of Organic Matters in Surface Sediments and Its Origin in Deukryang Bay, Korea)

  • 윤양호
    • 한국환경과학회지
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    • 제12권7호
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    • pp.735-744
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    • 2003
  • The field observations on a seasonal characteristic of organic matter and its origin in the surface sediment were carried out at 35 stations in Deukryang bay, southern coast of Korean Peninsula from May 1995 to February 1996. The analytical parameters were mud temperature, ignition loss(IL), chemical oxygen demand(COD), pheopigment, sulfide and water content. The origin and seasonal dynamics of organic matter in Deukryang Bay were analyzed by COD/IL, COD/sulfide ratio and principal component analysis(PCA). As a results of the mud temperature fluctuated between 2.1$^{\circ}C$ with the lowest mean 4.6$^{\circ}C$ in winter and 27.6$^{\circ}C$ with the highest mean 25.5$^{\circ}C$ in summer. The range of ignition loss(IL) was from 3.1% in autumn to 21.5% in winter. Chemical oxygen demand(COD) showed the highest mean value of 8.45 mg/g dry in spring within the range of 2.90∼18.21 mg/g dry, while it showed the lowest value of 4.33 mg/g dry in autumn within the range of 0.67∼10.37 mg/g dry. Pheopigments showed the highest mean value of 9.04 $\mu\textrm{g}$/g dry in autumn within the range of 1.36∼20.44 $\mu\textrm{g}$/g dry, while it did the lowest mean value of 2.20 $\mu\textrm{g}$/g dry in summer within the range of 0.33∼11.36 $\mu\textrm{g}$/g dry. The range of total sulfide (H$_2$S) was from no detect(ND) to 3.30 mg/g dry in spring. And water content showed the annual mean value of 43.6% within the range of 23.6∼54.9%. The source of organic matter by COD/IL and COD/sulfide ratio in Deukryang Bay had been producted by primary producer in sea water areas except the areas effected by small stream, domestic and animal wastes. And the analytical results of PCA was able to be divided into three different regions. The former was characterized by the shallow depth and authigenic organic matter from phytoplankton in northwest area and northeastern inner bay, the secondary was done by deeper depth and allochthonous one from lands in southeast area and eastern entrance of bay, and the latter was done by authigenic one from the farm of seaweeds such as, sea cabbage, sea mustard etc in western entrance of bay. But a study on the relationship between sulfide and COD concentration in the northeastern inner bay which was characterized by the water stagnation will to take much more studying including major constituents of organic matter in the future.

간이변환 수질예측모델에 의한 영일만 내부생산성 평가 (Numerical Simulation of water quality by ${\Delta}COD$ method for Inner Productivity Estimation of Yeong-Il Bay)

  • 윤한삼;류청로;이인철;김헌태
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2003년도 춘계학술대회 논문집
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    • pp.99-104
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    • 2003
  • This study investigated the yearly variation of pollutant loads outflowing from six watershed of Yeong-il Bay and compared the relationship of pollutant load and water quality, and estimated the Inner productivity of Yeong-Il Bay by using ${\Delta}COD$ method which analysis nonlinear process of water quality. As the estimated results for the pollutant loads of Yeong-Il Bay, total COD load outflowing from Hyeong-san river in flood season(summer) of 2001 year was 2275.0 kg/hr and in dry(low water) season(winter) 852.8 kg/hr, respectively. Load quantity in flood season was about 2.67 times than that in dry season. And as the calculated results of the net-flux of water for seven divisions, it showed that the net-flux of water increased for the divisions of the north coast and inner sea of Yeong-Il Bay but decreased for the south coast. On the contrary, for the cases which water quantity increase from land, the net-flux of water in estuary front of Hyeong-san river decreased but outflowing quantity of that though division of the south coast of Homi-got increased. Finally, this study compared the Inner productions for flood and dry season of Yeong-il Bay by using ${\Delta}COD$ method.

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$2004\sim2005$년 광양만의 해양수질 및 저질의 계절적 변동에 관한 연구 (A Study on the Seasonal Variation of Water Quality and Sediment Environment in Gwangyang Bay, Korea)

  • 조현서;조천래;강조해;이규형
    • 해양환경안전학회:학술대회논문집
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    • 해양환경안전학회 2006년도 춘계학술발표회
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    • pp.129-135
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    • 2006
  • 광양만 해양수질 및 저질의 계절적 변동에 관한 조사를 위해 2004년 5 월부터 2006년 2 월까지 광양만의 21개 정점을 선정하여 계절별로 관측을 실시하였다. 수질의 관측결과 폐쇄적인 내만해역의 특성을 잘 반영해 영양염류 등의 농도가 만의 내측인 묘도 서측에서 다른 곳에 비해 상대적으로 높은 농도를 보였다. 계절적 변동은 계절의 주요인자인 수온과 강우의 영향을 많이 받은 하계 (2000년 7월)에 가장 높은 농도분포를 보였으며, 동계 (2005년 1월, 2003년 2월)에는 상대적으로 낮은 농도분포를 보였다. DIP 와 TP 의 경우 춘계를 제외한 전 계절에 걸쳐 여수국가산단이 위치한 일부지점에서 높은 농도를 보였다. NIP 비의 경우 Redfield 비를 상회하는 값은 주로 표층해수에서 춘계 (2005년 5월), 동계 (2006년 2월) 에 나타났으며, 저층해수에서는 거의 모든 정점에서 Redfield 비 이하의 값을 보였다. 저질환경의 변동에서 강열감량 (IL), 화학적산소요구량 (COD) 과 산휘발성황화물 (AVS) 의 농도범위는 각각 $2.51\sim22.10%,\;2.65\sim48.41mg/g-dry,\;0.01\sim8.95mg/g-dry$를 보였다. COD 는 하계에 높은 농도를 보였고, AVS 는 추계에 높은 농도분포를 보였으며, 성진강 하구와 묘도서측해역에서 다른 지점에 비해 상대적으로 높은 값을 보였다. 저질의 경우 COD 와 IL, COD 와 AVS사이에 유의한 상관관계를 갖는 것을 확인할 수 있었으며, 상관계수는 각각 0.65 와 0.44로 나타났다.

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Treatment of Distillery Wastewater Using a Thermophilic High-Rate Hybrid Anaerobic Reactor in Industrial Scale

  • Nam, Ki-Du;Chung, In;Young, James C.;Park, Wan
    • Journal of Microbiology and Biotechnology
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    • 제9권6호
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    • pp.737-743
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    • 1999
  • A conventional thermophilic anaerobic digester was converted into a thermophilic high-rate hybrid anaerobic reactor (THAR) for treating distillery wastewater. The THAR has been operating successfully since May 1995 at a loading rate of 5.45 to $11.52{\;}kg/\textrm{m}^3/d$ (maximum of 15.02). The THAR has demonstrated a soluble Chemical Oxygen Demand (sCOD) removal efficiency of 85 to 91% and a total COD (tCOD) removal efficiency of as much as 72 to 84%. Product gas had a methane content of 59 to 68%. The tCOD removal rates were 4.31 to 5.43, 6.26 to 6.89, and 9.03 to $9.78kg{\;}tCOD/\textrm{m}^3/d$ for tapioca, com, and naked-barley wastewater, respectively. The sCOD removal rates ranged from 3.75 to 4.79,3.28 to 4.89, and 5.57 to 6.21kg $sCOD/\textrm{m}^3/d$ for tapioca, com, and naked-barley wastewater, respectively. There were unknown substances in a naked-barley distillery wastewater that were identified as being toxic for microorganisms. However, the THAR treated naked-barley wastewater continuously for 26 days, operating at an average tCOD loading of $11.08{\;}kg/\textrm{m}^3/d$without any signs of deterioration in either COD removal efficiency or gas production rate. During this period, the average removal efficiencies of tCOD and sCOD were 84% and 91%, respectively, and the gas production rate averaged 6.61 to $7.57{\;}\textrm{m}^3/\textrm{m}^3$ reactor/d which produced 0.57 to $0.69{\;}\textrm{m}^3{\;}biogas/kg{\;}tCOD_{rem}$. From tapioca and com wastewater, the reactor showed an average gas production rate of 3.18 to 3.46 and 4.91 to $5.22{\;}\textrm{m}^3/\textrm{m}^3$ reactor/d which produced 0.53 to 0.69 and 0.62 to $0.71{\;}\textrm{m}^3/kg{\;}tCOD_{rem}$, respectively.

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AN IMPULSIVE STAGE-STRUCTURED OPTIMAL CONTROL PROBLEM AND OPTIMAL HARVEST STRATEGY OF PACIFIC COD, GADUS MICROCEPHALUS, IN THE SOUTH KOREA

  • Cho, Giphil;Jeong, Yong Dam;Kim, Sangil;Jung, Il Hyo
    • East Asian mathematical journal
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    • 제34권5호
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    • pp.683-691
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    • 2018
  • We consider an optimal control problem for an impulsive stage-structured model involving ordinary differential equations with impulsive values of initial conditions in the next year. The main goal is to maximize a profit of the catch of Pacific cod in the South Korea through optimal harvest strategy as a control of adult cod. We established necessary conditions for the optimal harvest control using idea of Pontryagin's maximum principle. The optimal harvest strategy is to numerically solve the equation by using an iterative method with the Runge-Kutta method. Finally, we compare a monthly average of fishing mortality of Pacific cod from 2013 to 2017 with monthly fishing mortality for result obtained optimal harvest strategy.

Alum과 PACl을 이용한 응집처리 (Chemical Coagulation Treatment Using Alum and PACl in Complex Wastewater)

  • 성일화
    • 한국환경보건학회지
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    • 제35권1호
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    • pp.53-57
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    • 2009
  • In order to treat the complex wastewater containing organic compound and solids, pre-treatment system associated with molecular separation process were investigated. The reductions of COD and turbidity were obtained after coagulation processes using Alum (Aluminium sulfate, $Al_2(SO_4)_2{\cdot}18H_{2}O$) and PACl (poly aluminium chloride as 17% $Al_{2}O_{3}$). The results of study were as follows: using variable dosage of Alum, COD removal was highest at 4,000 mg/l, and the reduction of COD and turbidity was 42% and 92%, respectively. The optimum coagulation would be effective at pH 7.3 than pH 9.0 by the addition of alum at a concentration of 6,000 mg/l and PACl was add at 4.25% in raw complex wastewater with 2,000 mg/l alum at pH 7.3, the reduction of COD was reduced by 32%. But coagulation aid experiments indicated that PACl would be more effective in sludge separation ability than COD removal efficiency.

낙동강 본류에서 장기관측 자료를 이용한 DO, BOD, COD와 그 영향인자의 상관관계 및 TOC 분해율 (Analyses of TOC efficiency and correlation between DO, BOD, COD and influence factors using long-term observation data in the main stream of Nakdong River)

  • 강동환;소윤환;박경덕;김일규
    • 한국수자원학회:학술대회논문집
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    • 한국수자원학회 2019년도 학술발표회
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    • pp.415-415
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    • 2019
  • 본 연구에서는 낙동강 본류에서 10년(2008~2017) 동안 관측된 자료의 월별 평균 자료를 이용하여, DO, BOD, COD의 시공간 변동 및 그 영향인자들과의 상관관계를 분석하였다. 관측소별 수질은 상류에서 하류로 갈수록 나빠졌으며, BOD와 COD는 ST5에서 가장 높았다. 10개 관측소별 수질성분의 상관성을 분석한 결과, DO와 수온의 상관계수는 -0.90 이상이고, BOD와 Chl-a의 상관계수는 0.48~0.85, COD와 TOC의 상관계수는 ST5와 ST10 관측소를 제외하고 0.65 이상이었다. 모든 관측소 자료를 이용한 회귀분석 결과, 수온과 DO는 감소하는 선형함수로서 결정계수는 0.90, chl-a와 BOD는 증가하는 파워함수로서 결정계수는 0.83, TOC와 COD는 증가하는 로그함수로서 결정계수는 0.58 정도이었다. 10개 관측소별 TOC 분해율을 산정한 결과, BOD에 의한 분해율의 평균은 15.5~36.3%, COD에 의한 분해율의 평균은 57.4~89.6%의 범위로 나타났다.

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무기담채를 이용한 폐수처리

  • 차월석;권규혁;최형일;정경훈;이동병;정길록
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2003년도 생물공학의 동향(XII)
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    • pp.343-347
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    • 2003
  • 황토볼을 이용하여 폐수처리를 한 결과 다음과 같은 결과를 보였다. 흐름도 A에서는 T-P 0.5ppm이하, T-N 1.0 ppm이하, COD 10ppm 이하였으며, 흐름도 B에서는 T-P 0.3ppm이하, T-N 5.0 ppm이하, COD 15 ppm 이하의 결과를 보여 주었다. 흐름도 C에서는 T-P 0.6ppm이하, T-N 10 ppm이하, COD 15 ppm 이하였으며, 흐름도 D에서는 T-P 1 ppm, T-N 8 ppm이하, COD 20ppm 이하의 결과를 보여 주었다. BOD는 각 흐름도 A, B, C, D에서 COD보다 높은 경우에는 6 ppm, 낮은 경우에는 3 ppm 정도의 차이를 보였다. SS는 각 공정에 따라 그다지 큰 차이를 보이고 있지 않으며, 1.0 처리 용량 Ton/day으로 계산 할 경우에 5 - 20 g/day 정도를 보이고 있다. 이러한 결과치는 하수종말처리장(특별대책지역 및 잠실수중보권지역)의 2 ppm 및 폐수처리시설(농공단지, 오${\cdot}$폐수처리시설 포함)의 T-P 8 ppm, T-N 질소성분 60 ppm이내의 탄소원 COD 40 ppm 이내의 기준에 해당하는 수치의 좋은 결과로 황토볼을 이용한 폐수처리 시스템의 가능성을 보여주고 있다.

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남강 하류부에서 장기관측 자료를 이용한 유기물과 생물학적/화학적 산소요구량의 월 변동 분석 (Monthly Variation Analysis of BOD, COD and TOC using Long-term Observation Data in the Downstream of the Nam River)

  • 강동환;소윤환;박경덕;김일규;김병우
    • 한국환경과학회지
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    • 제28권6호
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    • pp.571-579
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    • 2019
  • In this study, monthly average values of BOD, COD, and TOC observed for 10 years (2008-2017) in the Nam River were estimated, and monthly variations of BOD, COD, and TOC were analyzed. Monthly average COD was always higher than monthly average BOD; monthly average TOC was high from June to September when rainfall was high. Monthly correlation coefficients between BOD and COD ranged from 0.57 to 0.94, those between BOD and TOC from 0.45 to 0.93, and those between COD and TOC from 0.75 to 0.93. The correlation coefficients were high from November to February when rainfall was low. Regression analyses for monthly average water quality data of the Nam River classified into dry season (October to April) and wet season (May to September) were conducted. Correlation coefficients were higher in the dry season than those in the wet season, and the determination coefficients of linear regression functions for BOD and COD with TOC were also higher in the dry season than those in the wet season. From this study, it can be concluded that it is appropriate to use monthly data to analyze the correlations among BOD, COD, and TOC in the stream. To analyze the relationship between TOC flowing into the stream and BOD/COD, it was found that seasonal characteristics should be considered.

한국 진해만 대구자치어 (Gadus macrocephalus) 현존량 추정을 위한 음향자원조사기법의 적용 (Application of hydro-acoustic survey technique for abundance estimation of juvenile cod (Gadus macrocephalus) in Jinhae bay, Korea)

  • 김주일;황보규;이유원;이경훈;신현옥;김정년
    • 수산해양기술연구
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    • 제49권3호
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    • pp.270-281
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    • 2013
  • Hydro-acoustic surveys with scientific echo sounder were carried out to estimate the total density and distribution of the juvenile cod in Jinhae bay, Korea. The surveys were conducted 4 times from May to June using 2 frequency method (38kHz and 120kHz) and beam trawl were used to investigate the species composition. Also the catch amounts of juvenile cod were compared with the cod density estimated by the hydro-acoustic method. It was confirmed that the juvenile cod was stayed in Jinhae bay in early June and There was the relationship between catch of juvenile cod and the estimated density by hydro-acoustic survey. The number of juvenile cod was consequently about 365,000 fish (CV 12.9%) in May and 113,000 fish (CV 9.2%) in May based on the hydro-acoustic data.