• Title/Summary/Keyword: COD(chemical oxygen demand)

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Anaerobic Treatment of Landfill Leachate Using a Upflow Anaerobic Sludge Blanket Reactor (UASB 반응조를 이용한 매립지 침출수의 혐기성 처리)

  • Lee, Chae-Young
    • Journal of the Korea Organic Resources Recycling Association
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    • v.14 no.4
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    • pp.151-160
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    • 2006
  • Anaerobic treatment of landfill leachate was studied to investigate the behaviors of pollutant and the characteristics of microorganism for 10 months. The upflow anaerobic sludge blanket (UASB) reactor achieved about 90% chemical oxygen demand (COD) removal at organic loading rates(OLR) up to $20kgCOD/m^3.d$. At higher OLR ($8-20kgCOD/m^3.d$), the propionate concentration increased, indicating that converting propionate to acetate was the rate-limiting step. Nevertheless, increase in the precipitate inside and on the surface of granules as well as on the wall of the reactor resulted in operational problems. The main inorganic precipitate in the granule was calcium compound. Although specific methanogenic activity (SMA) was not affected seriously in this study, metals had to be removed prior to anaerobic treatment so as to be free from the excessive inorganic accumulation that resulted in operational problems.

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A Study on the Comparison and Analysis of COD Results and Experimental Methods (COD 측정분석 방법에 관한 연구)

  • 박선구;신찬기;류재근
    • Journal of environmental and Sanitary engineering
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    • v.12 no.3
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    • pp.19-29
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    • 1997
  • The Chemical Oxygen Demand(COD) by potassium permanganate and potassium dichromate is used as a measure of the organic matter content of a sample. Newly proposed $K_{2}Cr_{2}O_{7}$ analysis method to be list at Korean Official Method was made from analysis and comparison of the experimental process on Japanese Industrial Standard(JIS), American Open Reflux and Closed Reflux Methods. New $K_{2}Cr_{2}O_{7}$ method had better the qualitative and reproducible COD results than another methods as a result of the tested four times repeatedly by using Lakes water Plant wastewater. The COD data ratio by $KMnO_{4}$ and $K_{2}Cr_{2}O_{7}$ methods was 2-3, 3, 2-17 and 3-4 times respectively when its data had compared with the lakes water and treated water of domestic and experimental wastewater, and raw wastewater which is generated at the manufacturing process of 6 steps and treated wastewater of chemistry source. Its ratio indicated to 2-4 and 2-3 times respectively on raw wastewater and plant wastewater of Chemistry, rubber and plastic, fiber, metal molding source. Oxidation ratio of benzene and ethyl benzene by $KMnO_{4}$ method was nearly zero, but the oxidation ratio by $K$_{2}Cr_{2}O_{7}$ method was 50%, 70% respectively. Also, Oxidation ratio of phenol by $KMnO_{4}$ and $K_{2}Cr_{2}O_{7}$ methods was 80%, 100% respectively, and trichloroethylene and tetrachloroethylene were not nearly oxidizd by $KMnO_{4}$ and $K_{2}Cr_{2}O_{7}$ methods. As the above contents, oxidation ratio and COD results by $KMnO_{4}$ and $K_{2}Cr_{2}O_{7}$ were different from various from various compounds and samples respectively.

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Performance Evaluation of ABR and ASBR for Anaerobic Methane Fermentation (ABR과 ASBR 형태에 따른 혐기성 메탄 발효 운전 성능 평가)

  • Lee, Chae-Young;Lee, Se-Wook
    • Journal of the Korea Organic Resources Recycling Association
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    • v.19 no.2
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    • pp.49-54
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    • 2011
  • This study was conducted to evaluate the performance of methane fermentation from effluent of hydrogen fermentation reactor in anaerobic baffled reactor (ABR) and anaerobic sequencing batch reactor (ASBR). Two reactors were operated at organic loading rate of $1.0kg\;COD/m^3{\cdot}d$ and hydraulic retention time (HRT) of 20 day. Methane production rates of ABR and ASBR for start-up periods were 0.04 L/L/d and 0.19 L/L/d, respectively, whereas maximum methane production rates of ABR and ASBR were 0.25 L/L/d and 0.31 L/L/d, respectively. Removal rates of chemical oxygen demand (COD) in ABR and ASBR for start-up periods were 89% and 92%, respectively. After startup periods, removal rates of COD and volatile solids (VS) in ABR and ASBR were maintained over 90%. The specific methanogenic activity (SMA) increased as microorganism acclimated to the substrate.

Comparison of Bacterial Numbers and Treatment Efficiencies in Bioreactors of Various Advanced Wastewater Treatment Processes (다양한 고도폐수처리공정에서의 생물반응조 세균수와 처리효율과의 비교)

  • Sung, Gi Moon;Cho, Yeon-Je;Kim, Sung Kyun;Park, Eun Won;Yu, Ki Hwan;Lee, Sang-Hyeon;Lee, Dong-Geun;Park, Seong Joo
    • Journal of Korean Society on Water Environment
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    • v.25 no.2
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    • pp.329-334
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    • 2009
  • Bacterial numbers, such as endospore-formers, and treatment efficiencies were investigated for Rotating Activated Bacillus Contactors (RABC) and other advanced wastewater treatment processes including anaerobic-anoxic-oxic (A2O), sequencing batch reactor (SBR) and biological aerated filter (BAF). Endospore-forming bacterial numbers in the RABC showed 129-fold higher levels than those of the existing advanced systems. RABC process demonstrated the highest bacterial numbers in its bioreactors (paired t-test, p<0.01). RBC biofilms and aeration tanks of the RABC system showed 131- and 476-fold higher than other existing advanced processes, respectively. Mean treatment efficiencies of the existing systems were 83.5% for chemical oxygen demand (COD), 59.1% for total nitrogen (TN) and 76.8% for total phosphorus (TP). However, RABC process removed 96.9% for COD, 96.9% for TN and 91.9% for TP for highly concentrated food wastewater (COD>1,500 mg/L, TN>150 mg/L, TP>50 mg/L). Treatment efficiency was significantly reduced when the numbers of Bacillus genus in the bioreactors decreased below $10^6CFU/mL$. The automated RABC (A-RABC), in which dissolved oxygen concentrations are automatically controlled, showed higher treatment efficiencies compared to the RABC process. The RABC system maintained sufficient bacterial numbers for the effective treatment of highly concentrated food wastewater. Moreover, final effluent was in agreement to water quality standards.

Effect of Environmental Factors on the Growth, Glycogen and Hemoglobin Content of Cultured Arkshell, Scapharca broughtonii (서식환경에 따른 피조개 Scapharca broughtonii의 성장과 글리코겐 및 헤모글로빈량의 변화)

  • PARK Mi Seon;LIM Hyun Jeong;KIM Pyoung Joong
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.31 no.2
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    • pp.176-185
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    • 1998
  • For the sustainable production of cultured arkshell Scapharca broughtonii and pre-estimation of the harvest of it, we investigated the relationship between the habitat environmental factors and the physiological conditions of the arkshell in the two experiment sites near the Chinhae Bay, Korea. For the analysis of habitat environmental factors such as temperature, salinity, dissolved oxygen, DIP (dissolved inorganic phosphate), DIN (dissolved inorganic nitrogen), suspended solids and chlorophyll a of bottom water and T-S (total sulfide) and COD (chemical oxygen demand) of surface sediment were measured, To determine physiolosical condition of cultured arkshell, shell length, fatness, glycogen, hemoglobin content and gametogenesis were examined. Water temperature were higher in Woongchon than in Songdo in 1992, and were Higher in Songdo in 1993. Salinity were higher in Songdo than in Woongchon except from January to May in 1992. COD, suspended solids and chlorophyll a content were higher in Songdo than in Woongchon, while the contents of sediment sulfide, DO, DIP and DIN were higher in Woongchon. Based on the environmental assessment, significant factors affecting the growth and physiological condition of arkshell were quantity of food and total sulfide content in the bottom sediment.

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Studies on the Marine Environmental Improvement and Environmental Perception of the Inhabitants around the Sun-So Coast (선소 해역 부근의 해양 환경 개선 사업 고찰 및 주민들의 환경 인식 조사에 대한 연구)

  • Shim, Wang-Geun;Park, Se-Ra;Kim, Sang-Chai
    • Hwankyungkyoyuk
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    • v.22 no.1
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    • pp.12-30
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    • 2009
  • The relationship between marine environmental improvement and environmental perception of the inhabitants was investigated. For this purpose, the seawater and bottom materials were analysed. Apart from this, the questionnaire surveys were also conducted around the Sun-so coastal area. In order to examine the improvement in the marine environment, 12 monitoring sites, which are located around Sun-so coast and can be divided into two parts such as inland (GW1-GW6) and outland (GW7-GW12) sea, were chosen. All the collected samples were analyzed to find out the quality of seawater (temperature, pH, salinity, dissolved oxygen: DO, chemical oxygen demand: COD and suspend solid: SS), nutrients (total nitrogen: TN and phosphate: $PO_4-P$) and bottom materials (COD, volatile solids: VS) as per the standard analytical procedures. In addition, the questionnaire mainly focused on the following three factors: 1) social economy, 2) dependent environmental awareness and 3) independent environmental awareness related with the environmental education. The monitoring studies indicated that the marine environment of the Sun-so coast showed various trends for analyzing parameter. No significant temporal changes in temperature, pH and salinity were observed. However, the other parameters showed decreasing (COD, SS, TN, $PO_4-P$ and VS) and increasing (DO) trends according to the quality of seawater and bottom materials. The questionnaire survey clearly showed that most of the residents in Sun-so recognized the improvement of marine environment as compared with the situation experienced in the past. The dredging project which is closely related with economic and living conditions of the local residents led to alter the environmental perceptions and attitudes. The survey also indicated that the inhabitants perceived the necessity of the environmental education (87% of respondents) and preferred regular schooling (55% of respondents) as effective and practical education methods.

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Distribution characteristics of chemical oxygen demand and Escherichia coli based on pollutant sources at Gwangyang Bay of South Sea in Korea (남해 광양만에서 오염원에 따른 화학적 산소요구량과 대장균의 해역별 분포특성)

  • Baek, SeungHo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.5
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    • pp.3279-3285
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    • 2014
  • This study aimed to understand seasonal and geographical characteristic of chlorophyll-${\alpha}$ (chl-${\alpha}$), COD (chemical oxygen demand) and Escherichia coli at Gwangyang Bay during the period from February 2010 to November 2012. The bay is divided into three different zones based on the pollutant levels and geographical characteristics. During the study periods, water temperature, salinity, Chl. ${\alpha}$, and chemical oxygen demand (COD) varied in the range of $4.68-28.63^{\circ}C$, 1.94-33.84 psu, 0.31-35.10 ${\mu}gL^{-1}$, and 0.70-13.35 $mgL^{-1}$, respectively. Total chl-a concentration were high at the zone I, which can be characterized as a semi-enclosed eutrophic area, and it were low at the zone III, which is influenced by low nutrients of surface warm water current from offshore of the bay. The high concentration of COD was observed at inner bay during the four seasons and the water quality level was kept to be bad condition during spring season at the zone II, which is influenced by Seomjin River water. The highest colony form of E. coli was recorded to be 3550 $cfuL^{-1}$ during summer at station 1 (zone I), whereas it was relatively kept low level during all seasons at the zone III. As a result, the E. coli was correlated with water temperature (r=0.31 p<0.05) and salinity (r=-0.55 p<0.05), implying that those parameters have play an important crucial role in proliferation of E. coli. Consequently, our results indicated that the E. coli can be significantly promoted within pollutant sources including the high nutrients supplied by rive discharge during spring and summer rainy seasons in semi-enclosed area of Gwangyang Bay.

Nanofiltration of Dyeing Wastewater Using Polyamide Ro-Membranes after the Pretreatment with Chemical Coagulants

  • Hwang Jeong-Eun;Jegal Jonggeon;Mo Joonghwan;Kim Jaephil
    • Korean Membrane Journal
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    • v.7 no.1
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    • pp.58-66
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    • 2005
  • Nanofiltration (NF) of a dyeing wastewater was carried out using polyamide NF-membranes. Before applying the wastewater to the membrane process, it was pretreated with various chemical coagulants such as alum, ferric chloride and HOC-100A. In order to see the effect of the pretreatment of the wastewater using chemical coagulants on the membrane separation process, the optimum conditions for the coagulation and sedimentation process using the chemical coagulants were sought. By the pretreatment, despite the different coagulants used, the chemical oxygen demand (COD) and UV-absorbance of the wastewater were lowered by more than $70\%$. The pretreated wastewater was then applied to the membrane process. The effect of the coagulants used for the pretreatment on the membrane fouling was studied. From this study, it was found that the HOC-100A was the best out of the coagulants used far the removal of the materials that could cause membrane fouling.

Population Dynamics of Zacco platypus in Gap-Stream and Its Relation with Water Quality

  • Shin, Young-Eun; Choi, Ji-Woon;An, Kwang-Guk
    • Korean Journal of Ecology and Environment
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    • v.42 no.4
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    • pp.422-431
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    • 2009
  • This study was to provide basic data for aquatic ecosystem research using fishes. Field sampling was carried out at five selected sites of Gap Stream, and fish samples, especially for a selection of sentinel species were collected three times in June, September, and October 2007. We analyzed total length distribution of Zacco platypus in relation with the season and the sampling sites, and then compared with total body weight, condition factor (K), and age distribution of the fish. The fish population data were compared with physico-chemical water quality, obtained from the Ministry of Environment, Korea. Water quality analysis showed a significant nutrient enrichment, based on total nitrogen (TN) and total phosphorus (TP), and organic matter pollution, based on biological oxygen demand (BOD) and chemical oxygen demand (COD) in the Site 5, which is directly influenced by wastewater disposal plant (WDP). Population analysis of the sentinel species showed that the total number of individuals, age distribution, and the population size-structure were influenced by the effluents from the WDP, and that reproductive failure of young-age population were evident in Site 5. According to the relation analysis of total weight to K, the disturbed population was mainly attributed to combined effects of habitat modifications and chemical degradations. Regression analysis of K values against water quality parameters showed significant (p<0.05) positive relations with nutrient and organic matter contents. Our data suggest that the population structure using a sentinel fish species reflected the ambient water quality in the stream and that diagnosis of aquatic ecosystem health using Z. platypus population may be practical for water resource and ecosystem conservations.

Comparison of Water Quality between Forested and Agricultural Subcatchments in Daegwallyong Area (대관령 지역의 산림 소유역과 농경지 소유역의 수질 비교)

  • Shin Young-Kyu
    • Journal of the Korean Geographical Society
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    • v.39 no.4
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    • pp.544-561
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    • 2004
  • Weekly monitoring of discharge and water quality in forested and agricultural subcatchments were performed to understand the difference of water quality caused by land uses in Doegwollyong area. Correlations between water quality variables including discharge were analyzed for the same purpose. There was little variation of water Quality in forested subcatchment. On the other hand, the range of water quality variation in agricultural subcatchment was wide due to soil loss and the application of chemical fertilizers and livestock manure. Dissolved oxygen(DO) had strong negative correlation with discharge in both subcatchments. Total nitrogen(T-N) and potassium ion(K$^{+}$) had stronger positive correlation with discharge in forested subacatchment than in agricultural one. On the other hand, total suspended sediments(TSS), total phosphorus(T-P), and chemical oxygen demand(COD) had stronger correlation with discharge in agricultural subcatchment than in forested one. As water pollution of the Doam Lake, especially the increase of T-P is serious, soil conservation is very important to improve water quality. In particular, the loss of soil and nutrients from late June till early July were more serious than any other seasons, therefore it is necessary to apply environmentally sustainable methods of cultivation.n.