• Title/Summary/Keyword: CO conversion

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Solid fuel combustion in a fluidized bed - Characteristics of a lab-scale combustor and experimental parameters (고체 연료의 유동층 연소 - 시험 연소로 특성 및 실험 인자 설정)

  • Choi, Jin-Hwan;Park, Young-Ho;Choi, Sang-Min
    • 한국연소학회:학술대회논문집
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    • 2000.12a
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    • pp.236-245
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    • 2000
  • A laboratory scale fluidized bed reactor was developed to treat the combustion characteristics of some fuels (wood, paper sludge, refuse derived fuel). The aims were to introduce the means of experiment and interpretation of the results and finally determine the particle characteristics on the pyrolysis and combustion process of the fuel. A single particle combustion process in the fluidized bed was closely observed. Understanding experimental facility characteristics and determining parameters were also carried out. The fuel combustion processes were observed by carbon conversion rate, recovery and mean carbon conversion time. They were estimated with the CO, $CO_2$ gas concentration monitored at the exit of the combustor. Fuel drying and pyrolysis process were governed by temperature distribution in the fuel particle. There was a significant overlap of the drying and devolatilization. However, transition process from devolatilization to char combustion seemed to be determined by mechanical solidity of the fuel particle after devolatilization process.

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The Development of Double Conversion Uninterruptible Power Supply Using 3-Level Converter/TNPC Inverter (3-레벨 부스트 컨버터/TNPC 인버터를 적용한 이중변환 무정전전원장치 개발)

  • Byeon, Yong Seop;Lim, Seung Beom;Choi, Kyu Hyuk;Hong, Soon Chan;Lee, Jun Young
    • Proceedings of the KIPE Conference
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    • 2014.07a
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    • pp.83-84
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    • 2014
  • This paper proposes the development of double conversion Uninterruptible Power Supply using 3-Level Converter/TNPC Inverter. The Rectifier of proposed system is operating not only 3-Level boost PFC but also battery discharger. The Inverter is converting DC voltage to AC voltage. And in terms of the efficiency, 3-Level TNPC inverter is improved compared to the origin 2-Level type. To verify the validity of proposed system, experiments were carried out.

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Studies on Synthesis of Acrylic Water Borne Polymer;Synthesis of Poly(vinyl acetate) and Poly(vinyl acetate-co-2-ethylhexyl acrylate) (Aerylic Water Borne Polymer의 합성 연구;Poly(vinyl acetate)와 poly(vinyl acetate-co-2-ethylhexyl acrylate)의 합성 연구)

  • Kim, Sang-Hern
    • Journal of the Korean Applied Science and Technology
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    • v.13 no.2
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    • pp.77-84
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    • 1996
  • Poly(vinyl acetate)와 poly(vinyl acetate-co-2-ethylhexyl acrylate)를 여러 조건에서 semicontinuous emulsion 중합으로 합성하였다. Overall conversion, emulsion 입자크기, pH, 점도 등을 합성한 두 emulsion polymer에 대해 측정하였다. Vinyl acetate monomer에 2-ethylhexyl acrylate를 도입함으로서 emulsion 입도, 점도, 중합 속도, 유리 전이 속도가 감소함을 확인하였다.

A Study on Construction and Implementation of Web education System with Chinese conversion rule set (중국어 규칙변환 웹 교육시스템 설계 및 구현에 관한 연구)

  • Lee, Ji Hyun;Lee, Eun Ryoung
    • Journal of Digital Contents Society
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    • v.17 no.4
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    • pp.227-234
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    • 2016
  • When Chinese character used in Korea, so did the characters' pronunciation, so many Korean Chinese characters today have similar pronunciation with Chinese, but since Korean and Chinese pronunciations were preserved and developed in different alphabets, the written letter of the pronunciation also differs. This study on Chinese education, has constructed and implemented an easy way to study Chinese pronunciations by creating conversion rule set between Chinese pronunciation, Chinese Hanyu latin Pinyin and Korean chinese character pronunciation consisting of an initial sound, a medial vowel, and a final consonant. This study has established web version and application version of this conversion rule set education system to enhance Chinese education.

The Estimation of Volume Conversion Factor of Rock Fill using Field Density Test (현장밀도시험을 이용한 암성토 체적환산계수 산정에 관한 연구)

  • Park, Jong-Beom;Ma, Myong-Soo
    • Journal of the Korean Geosynthetics Society
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    • v.16 no.1
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    • pp.9-17
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    • 2017
  • In this study, the field density test was conducted as a volume conversion factor for the design of the excavation soil of the blasting rock. As a result of the field density test, the average volume conversion factor of rock was 1.001, which was smaller than the volume conversion factor of weathered rock 1.1. In the case of rock filled soil, the causes of the increase and decrease of the volume of the soil are provided by various phenomena. However, the specific techniques such as investigation and test methods are insufficient. Therefore, it was confirmed that the method of field density test is very useful method.

Effect of Propene($C_3H_6$) ON NO-$NO_2$ Conversion Process in a Pulsed Corona Discharge (펄스코로나 방전에서 프로핀($C_3H_6$)이 NO-$NO_2$ 변환에 미치는 영향에 관한 연구)

  • 박광서;전배혁;전광민
    • Transactions of the Korean Society of Automotive Engineers
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    • v.8 no.5
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    • pp.67-77
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    • 2000
  • Investigated was the effect of propene(C3H6) on the NO-NO2 conversion in dry exhaust gases from lean burn engine using a pulsed corona discharge. A kinetic model was developed to characterize the plasma chemistry in simulated exhausts containing propene. The model uses ELENDIF program to solve Boltzmann equation for electron energy distribution function, and CHEMKIN-II program to solve stiff ODE(ordinary differential equation) problems for species concentrations. The corona discharge energy per pulse and the time-space averaged E/N were obtained by fitting the model to experimental data. The model calculation shows good agreement for NO and NO2 concentrations with the experimental data, and predicts the formation of byproducts such as CH2O, CH3HCO, CO AND CH3NO2 Propene enhances the NOx conversion enormously at lower energy density and the NOx conversion increases with the increase of initial propene and oxygen concentration, and temperature.

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Conversion of Glucose and Xylose to 5-Hydroxymethyl furfural, Furfural, and Levulinic Acid Using Ethanol Organosolv Pretreatment under Various Conditions

  • Ki-Seob, GWAK;Chae-Hwi, YOON;Jong-Chan, KIM;Jong-Hwa, KIM;Young-Min, CHO;In-Gyu, CHOI
    • Journal of the Korean Wood Science and Technology
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    • v.50 no.6
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    • pp.475-489
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    • 2022
  • The objective of this study was to understand the conversion characteristics of glucose and xylose using the major monosaccharide standards for lignocellulosic biomass. The acid-catalyzed organosolv pretreatment conducted using ethanol was significantly different from the acid-catalyzed process conducted in an aqueous medium. 5-hydroxymethylfurfural (5-HMF), levulinic acid and furfural were produced from glucose conversion. The maximum yield of 5-HMF was 5.5%, at 200℃, when 0.5% sulfuric acid was used. The maximum yield of levulinic acid was 21.5%, at 220℃, when 1.0% sulfuric acid was used. Furfural was produced from xylose conversion and under 0.5% sulfuric acid, furfural reached the maximum yield 48.5% at 210℃. Ethyl levulinate and methyl levulinate were also formed from the glucose standard following the esterification reaction conducted under conditions of the combined conversion method, which proceeded under both ethanol-rich and water-rich conditions.

Catalytic Removal of Nitric Oxide in Oxygen-Rich Exhaust with Methane over Metal Ion-Exchanged Zeolites (금속이온교환 제올라이트 촉매상에서 메탄을 이용한 산소과잉 배출가스중의 NO 제거)

  • 김상환;박정규
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.1
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    • pp.32-44
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    • 2002
  • Selective catalytic reduction of nitric oxide by methane in the presence of excess oxygen was investigated over copper and cobalt ion-exchanged ZSM-5 zeolites. Copper ion-exchanged ZSM-5(Cu-ZSM-5) has the limitations for commercial applications to lean-bum gasoline and diesel engines due to low thermal stability and resistance to water vapor and sulfur dioxide. But cobalt ion-exchanged ESM-5(Co-ZSM-5) is more active at high temperatures and also stable to water vapor and sulfur dioxide for catalytic reduction of nitric oxide by methane. The catalytic activity of Cu-ZSM-5 for NO reduction increases with increasing temperatures, reaches the maximum conversion of 23.0% at 350\"C. and then decreases with higher temperatures. In the meantime catalytic activities of Co-ZSM-5 show the maximum conversion of 25.8% at $500^{\circ}C$ Therefore Co-ZSM-5 catalysts have higher thermal stability at high temperatures. Catalytic activities of both zeolites were remarkably enhanced with the existence of oxygen in the exhaust. It is noted that the catalytic activity of Cu-ZSM-5 decreases with the increasing concentration of methane while the catalytic activity of Co-ZSM-5 decreases with increasing contents of methane in the exhaust. This may imply the existence of different paths of NO reduction by methane in the presence of excess oxygen fur Cu-ZSM-5 and Co-ZSM-5 catalysts. For binary metal ionexchanged ZSM-5, the primary ion-exchanged metal may be masked by secondary ion-exchanged component, which plays the important role for catalytic activities of binary metal ion-exchanged ZSM-5, Therefore CuCo-ZSM-5 catalysts show the similar volcano-shaped curves to Cu-ZSM-5 catalysts between the activity and temperature. It Is interesting that the activities of CoCu-ZSM-5 catalysts indicate almost no dependence on the concentration of methane in the exhaust.aust.

Development of Pump-Drive Turbine with Hydrostatic Bearing for Supercritical CO2 Power Cycle Application (정압 베어링을 적용한 초임계 CO2 발전용 펌프-구동 터빈 개발)

  • Lee, Donghyun;Kim, Byungock;Park, Mooryong;Yoon, Euisoo
    • Tribology and Lubricants
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    • v.36 no.3
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    • pp.153-160
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    • 2020
  • In this paper, we present a hydrostatic bearing design and rotordynamic analysis of a pump-and-drive turbine module for a 250-kW supercritical CO2 cycle application. The pump-and-drive turbine module consists of the pump and turbine wheel, assembled to a shaft supported by two hydrostatic radial and thrust bearings. The rated speed is 21,000 rpm and the rated power is 143 kW. For the bearing operation, we use high-pressure CO2 as the lubricant, which is supplied to the bearing through the orifice restrictor. We calculate the bearing stiffness and flow rate for various orifice diameters, and then select the diameter that provides the maximum bearing stiffness. We also conduct a rotordynamic analysis based on the design parameters of the pump-and-drive turbine module. The predicted Campbell diagram shows that there is no critical speed below the rated speed, owing to the high stiffness of the bearings. Furthermore, the predicted damping ratio indicates that there is no unstable mode. We conduct the operating tests for the pump and drive turbine modules within the supercritical CO2 cycle test loop. The pressurized CO2, at a temperature of 136℃, is supplied to the turbine and we monitor the shaft vibration during the test. The test results show that there is no critical speed below the rated speed, and the shaft vibration is controlled to below 3 ㎛.

Reactivity Test of Ni-based Catalysts Prepared by Various Preparation Methods for Production of Synthetic Nature Gas (합성천연가스 생산을 위한 고효율 Ni계 촉매의 제법에 따른 촉매의 반응특성 조사)

  • Jang, Seon-Ki;Park, No-Kuk;Lee, Tae-Jin;Koh, Dong-Jun;Lim, Hyo-Jun;Byun, Chang-Dae
    • Journal of Hydrogen and New Energy
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    • v.22 no.2
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    • pp.249-256
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    • 2011
  • In this study, the Ni-based catalysts for the production of synthetic natural gas were prepared by various preparation methods such as the co-precipitation, precipitation, impregnation and physical mixing methods. The ranges of the reaction conditions were the temperatures of 250~$350^{\circ}C$, $H_2$/CO mole ratio of 3.0, the pressures of 1 atm and the space velocity of 20000 $ml/g_{-cat{\cdot}}{\cdot}h$. It was found that the catalyst prepared by precipitation method had higher CO conversion than the catalyst prepared by co-precipitation method. While the catalyst prepared by precipitation method had the formation of NiO structure, the catalyst prepared by co-precipitation method had the formation of $NiAl_2O_4$ structure. It was confirmed that Ni-based catalyst prepared by the physical mixing method had the lowest CO conversion because it was deactivated by the production of $Ni_3C$ during the methanation. As a result, it was shown clearly that Ni-based catalysts prepared by impregnation method expressed the highest catalytic activity in CO methanation.