• Journal of Korean Society for Atmospheric Environment
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• v.15 no.3
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• pp.249-255
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• 1999

We sdudied effect of additives on catalytic activity in thermal catalytic de-NOx process which was composed of thermal reduction, catalytic reduction and catalytic oxidation stage. Pd-Pt/${\gamma}$-$Al_2O_3$ catalysts with the addition of transition metals(Co, Cu, Fe, Ni, W, Zn, Zr) and rare earth metals(Ce, Sr) were prepared by the conventional washcoating method. Those catalysts were characterized by CO pulse chemisorption, ICP, $N_2$ adsorption, SEM and XRD. The effect of catalyst additives on NOx removal for diesel emission was studied in thermal catalytic de-NOx process at reduction temperature(350~50$0^{\circ}C$), space velocity(5,000~20,000 $hr^{-1}$) and the engine load(0~120kW). The concentraton of CO, $CO_2$, NO and $NO_2$ in the exhaust gas increased with the engine load. On the other hand the concentration of $O_2$ decreased. The de-NOx activityof all prepared catalysts increased with respect to high CO and low $O_2$ level in the thermal reduction stage of the process. Insertion of Ce to Pt-Pd/${\gamma}$-$Al_2O_3$ catalyst showed the best activity of all the catalysts under these experimental conditions. De-NOx catalysts are effective to remove CO in addition to NOx in the catalytic reduction stage.

• Journal of ILASS-Korea
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• v.21 no.3
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• pp.130-136
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• 2016

NOx and PM are important air pollutants as vehicle management policy aspect. Medium-duty truck is the main source of the pollutants although the vehicle market share is only 3.5%. National emission portion of NOx and PM form the mobile sourece are 14% and 16% respectively. In this study it was investigated that characteristics of air pollutants emission on medium duty truck equipped with EGR and SCR system. Vehicle's test reflected driving cycle on the chassis dynamometer, and applied test cycle was WHVC(World Harmonized Vehicle Cycle) mode. The test cycle include three segments, represent urban, rural and motorway driving. Based on the test results NOx, PM, HC were less emitted form SCR vehicle than EGR vehicle. And CO was less emitted form EGR vehicle than SCR vehicle due to CO oxidation reaction on DPF surface. And most air pollutants reduced as average vehicle speed increased. Pollutants were less emitted on motorway section than urban and rural sections. But highly NOx emission on motorway section was verified according to increased EGR ratio on fast vehicle speed. HC and CO additional emission was identified as 68%, 58% respectively during SCR vehicle's cold engine start emission test. NOx additional emission was detected by 24% on SCR vehicle's condition of engine cold start while not detected on vehicle equipped with EGR. SCR vehicle's additional NOx emission was derived from low reaction temperature during engine cold start condition. medium-duty truck emission characteristics were investigated in this study and expected to used to improve air pollutants management policy of medium-duty truck equipped with SCR & EGR.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.40 no.8
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• pp.503-510
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• 2016

Incinerators generally emit pollutants such as NOx and CO during the combustion process. In this paper, pollutant emissions and temperature distributions were studied in a simulated incinerator with a reversed (relative to the flue gas flow) secondary air injection system. The experiments were performed by using a lab-scale furnace in order to evaluate the effects of the injection location, direction and flow rate of secondary air jets. The emission of NOx was lower in the case of reversed secondary air injection than in the case of cross injection, due to the recirculation and mixing of the exhaust gas. In the reversed air injection cases, thermal NOx emissions decreased as secondary air ratio increased from 30 to 60 and slightly increased at secondary air ratios higher than 60. In most cases, CO emissions were not detected except for a few reversed secondary air injection cases, in which cases CO concentrations below 2ppm were observed.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.33 no.7
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• pp.70-75
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• 2005

In this study, experimental investigations were conducted on NOx emission characteristics with fuel swirl flow in swirl combustor. Many types of vanes, which altered air and fuel swirl angles, were employed to verify the mixing processes. For strong air swirl, fuel counter-swirl resulted in relatively large turbulent intensity, high energy to the high frequency region and narrow width of high temperature region compared with co-swirl condition. These effects of fuel counter-swirl resulted in low NOx emission characteristics at strong air swirl condition. And NOx reduction mechanism was also discussed.

• Proceedings of the KSME Conference
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• 2000.04b
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• pp.398-403
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• 2000

Experimental study on the porous ceramic burner for oil burning has been performed. Temperature profile of the combustor and CO and NOx emission have been obtained for with and without porous ceramic plate. It is found that very uniform and high temperature region with porous ceramic plate can be realized due to high radiation emission from the plate and also obtained lower CO and soot particulate emission, when compared to the conventional burner. When this burning method is applied to conventional boiler of small heating capacity, it is found that near 6 and 7 percent increase in thermal efficiency could be obtained without a proper calibration for optimization.

• 한국연소학회:학술대회논문집
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• 2012.11a
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• pp.149-152
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• 2012

The laboratory experiments have been conducted to investigate the effects of air preheated temperature on the emission characteristics by a model gas turbine burner with a hybrid/dual swirl jet flames configuration. The concentration of NOx and CO emissions, and flue gas temperature at combustor exit were measured with varying the equivalence ratio for different air preheated temperatures of 300, 400, 500K at atmospheric pressure. It was overall shown that the NOx and CO emissions, and flue gas temperature were decreased according to the decreasing of equivalence ratio due to the effects of lean premixed combustion regardless of the air preheated temperature. Experimental results of a lean premixed flames configuration indicated that the NOx emission was increased with higher inlet air temperature and air flow rate, which is attributed to the increasing of flue gas temperature and heat release related to the thermal NOx mechanism. But the CO emission was shown the opposite tendency, that is, the CO emission was decreased with increasing of inlet air temperature and flow rate.

• Journal of the Korean Society for Marine Environment & Energy
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• v.7 no.4
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• pp.174-179
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• 2004

Domestic marine diesel engine makers reduce the NOx emission mostly by applying low NOx fuel nozzle and injection timing retard. However, it is necessary to develop high efficient technology (EGR, DWI and SCR, etc.) to reduce NOx emission in order to prepare for the further reinforcement of the NOx emission limit. Also, in the near future, IMO will restrict additively THC, PM and CO with NOx. Therefore, domestic engine makers have to prepare for it and the relevant government ministries should give a sufficient support to these technology research and establish or amend the relevant law, which should include the excursion riverboat.

• 한국연소학회:학술대회논문집
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• 2000.12a
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• pp.140-147
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• 2000

Using lobed burner, flame visualization and measurements of NOx and CO concentration in the combustor exit were carried out to evaluate the relation between the lobed structure in a burner and pollutant emission characteristics. The flame stability is enhanced by the lobed burner compared to conventional circular one. The correlation on fuel discharge velocity for flame blowout should be included on a variable related to the wall effect of the burner, because the flame blowout is observed at the burner having large perimeter. The burner having lobed structure in fuel discharge side compared to conventional burner reduces by 5% NOx emission due to lower flame intensity through flame elongation. Meanwhile the burner having lobed structure in air discharge side and both fuel and air discharge side increase the NOx emission.

• 한국연소학회:학술대회논문집
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• 2013.06a
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• pp.111-112
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• 2013

An experimental study of a dual swirl burner was conducted to analyze NOx emission in the lean conditions. The dual swirl burner is composed of a combination of swirling jet premixed(main section) and diffusion flames(pilot section). It was operated with a co-swirling configuration and overall equivalence ratios between 0.6 and 0.8. The purpose of this study is to analyze experimentally the characterization of flame temperature and NOx concentration in reacting zone and to supply the useful experimental data for numerical simulations. The measurements of temperature and NOx concentration were captured using a thin digitally-compensated thermocouple and a sampling quartz probe with quenching effect of sudden expansion, and were measured by the NOx analyzer of chemiluminescence method. We could analyse the NOx emission characteristics comparing the temperature distributions in the lean equivalence ratios.

• 한국연소학회:학술대회논문집
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• 2005.10a
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• pp.314-319
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• 2005

In this study, the combustion characteristics were investigated with the variation of design factors on multiple slit gas burner. The design factors consist of slit height, width, spacing, and inner length. The combustion characteristics were made analysis of the CO emission and NOx emission by using CO analyzer and NOx analyzer. The lower perimeter to area and the narrow spacing extends the lift-flame limit. The CO emission increases with the increasing perimeter to area ratio at the same condition. The NOx emission is found to be less significant with the port perimeter to area ratio. The flame interference might highly depend on the spacing and port perimeter to area ratio, and it also affects the burner performance.