• Title/Summary/Keyword: CO Poisoning

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Operation Characteristics of 5 kW Class Proton-Exchange-Membrane Fuel Cell(PEMFC) Stack (5 kW급 고분자 전해질 연료전지 스택의 운전 특성)

  • Kim, Jae-Dong;Lee, Jung-Woon;Park, Dal-Ryung
    • Journal of the Korean Institute of Gas
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    • v.11 no.1 s.34
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    • pp.51-54
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    • 2007
  • 78-cell proton exchange membrane fuel cell(PEMFC) stack with an effective electrode area of $295cm^{2}$ were investigated its operational characteristics and effects of CO poisoning. When power output, 5.4 kW, was released at current density of $325mA/cm^{2}$ for 6 hours, stablility of each cell was showed the small deviation of 2.3%. Carbon monoxide is a conventional contaminant in the fuel obtained from reforming processes with an important influence on the performance of the PEMFC. The studies of continuous injection of CO presented (5-20 ppm) with the time gave information about poisoning and recovery processes of the stack.

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Experimental Study on the Preferential Oxidation Reactor Performance Using a Water Cooling Heat Removal for Polymer Electrolyte Membrane Fuel Cell (수냉식 방열을 이용한 연료전지용 PROX 반응기의 성능에 관한 실험적 연구)

  • KIM, JINSAN;JO, TAEHYUN;KOO, BONCHAN;LEE, DOHYUNG
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.5
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    • pp.503-509
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    • 2016
  • Fuel cell is a device for producing electricity by using the hydrogen produced by the fuel processor. At this time, CO is also created by the fuel processor. The resulting CO enters the stack where is produce electricity and leads to the adsorption of anode catalyst, finally the CO poisoning occurs. Stack which occurred CO poisoning has a reduction in performance and shelf life are gradually fall because they do not respond to hydrogen. In this paper, experiments that using a PROX reactor to prevent CO poisoning were carried out for removing the CO concentration to less than 10ppm range available in the fuel cell. Furthermore experiments by the PROX reaction was designed and manufactured with a water-cooling heat exchange reactor to maintain a suitable temperature control due to the strong exothermic reaction.

Association between Smoking and Delayed Neuropsychological Sequelae in Acute Carbon Monoxide Poisoning (급성 일산화탄소 중독 환자들에서 흡연과 지연성 신경정신과학적 후유증 발생의 상관관계)

  • Kim, Hak Myeon;Choi, Sung Woo;Nah, Sang Un;Choi, Hyo Jeong;Lim, Hoon;Kim, Gi Woon;Han, Sang Soo;Lee, Young Hwan
    • Journal of The Korean Society of Clinical Toxicology
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    • v.16 no.2
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    • pp.102-107
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    • 2018
  • Purpose: This study examined the association between smoking and delayed neuropsychological sequelae (DNS) in acute carbon monoxide (CO) poisoning. Methods: Patients admitted to the medical center emergency department from March 2016 to March 2017 because of CO poisoning were examined retrospectively. The patients were divided into two groups: DNS and Non-DNS group. Multiple factors were analyzed to explain DNS, which was assessed by motor disturbances, cognitive impairment, dysphagia, Parkinson-like syndromes, epilepsy, and emotional lability in CO poisoning. Results: A total of 120 patients were included. The factors related to DNS were smoking (pack-years) (p=0.002) and initial carbon monoxide-hemoglobin level (p=0.015). On the other hand, after multivariate logistic regression analysis, smoking (Odds ratio 1.07; 95% CI, 1.02-1.13; p=0.004) was the only factor associated with DNS. Conclusion: Smoking is a very reliable factor for predicting the occurrence of DNS. A history of smoking in patients who suffer from CO intoxication is important. If a patient smokes, treatment should be started actively and as soon as possible.

A Method to Prevent CO Poisoning from Instantaneous Water Heaters (순간 가스온수기의 CO 중독사고 예방에 관한 연구)

  • Ahan, Jeong-Jin;Yeo, Chang-Hoon;Jo, Young-Do
    • Journal of the Korean Institute of Gas
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    • v.15 no.3
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    • pp.26-30
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    • 2011
  • Instantaneous water heater being not properly installed and not adequately maintained may produce fatal accidents due to carbon monoxide poisoning and suffocation. Insufficient supply of air into the gas appliance for complete burning of the fuel or blocking the outlet of the combustion gas could be a cause to increase carbon monoxide concentration in the exhaust gas of the gas appliance. In this work, the experiments are done with a collected instantaneous water heater using in domestic and the concentration of oxygen near the gas appliance and carbon monoxide in exhaust gas are observed to investigate the risk of instantaneous water heater. The concentration of oxygen near the gas appliance is reduced until 17.7% for the ratio of the ventilation area and floor area being 3.5%. If the outlet of combustion gas is blocked, the carbon monoxide concentration is steeply increasing more than 4,000ppm. Therefore, periodic checking the outlet of combustion gas is more important than vent area to reduce the risk of carbon monoxide poisoning.

Unintentional Pharmaceutical Poisoning in the Emergency Department (응급실로 내원한 비의도적 의약품 중독)

  • Jo, Hyo Rim;Lee, Choung Ah;Park, Ju Ok;Hwang, Bo Na
    • Journal of The Korean Society of Clinical Toxicology
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    • v.16 no.2
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    • pp.116-123
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    • 2018
  • Purpose: The social environment of easy access to medicines and arbitrary personal decisions leading to overdose aggravate unintentional medicine poisoning. This study aimed to investigate the characteristics of patients who visited emergency departments with unintentional medicine poisoning and reasons for poisoning based on age group. Methods: We retrospectively collected patients who experienced unintentional medicine poisoning based on data from the national injury surveillance system between 2013 and 2016. Subjects were classified into three groups based on age (0-14 years, 15-64 years, and ${\geq}65\;years$). We identified sex, insurance, time of poisoning, place, alcohol co-ingestion, hospitalization, death, and reason for poisoning in each age group. Results: A total of 27,472 patients visited an emergency department with poisoning during the study period; 1,958 patients who experienced unintentional poisoning were enrolled in this study. Respiratory medicine was the most frequent medicine in those younger than 15 years of age, and sedatives and antipsychotic drugs were the most common in patients older than 15 years of age. In total, 35.1% of patients older than 65 years were hospitalized. The most common reasons for poisoning were careless storage of medicine in those younger than 15 years of age and overdose due to arbitrary decisions in those older than 15 years of age. Conclusion: Unintentional medicine poisoning has distinct characteristics based on age group, and strategies to prevent poisoning should be approached differently based on age.

Study of performance of a stack in the presence of CO and air (연료전지의 CO 피독 및 회복에 관한 연구)

  • Kim, Hee-Su;Kim, Dong-Chan;Han, Ji-Hee;Lee, Ho-Jun
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.180-183
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    • 2007
  • CO in the reformed gas for proton exchange membrane fuel cell(PEMFC) has a strong tendency to adsorb on the surface of the catalyst and thus to block the sites that hydrogen needs for reactions. Even part per million levels of CO can cause serious poisoning. This CO poisoning can overcome to bleed trace amounts of air into the anode. In this study, we indicated the alteration of stack performance in various CO concentration and then bled a small amount of air. The performance of stack was reduced by increasing CO amount, and recovered by air bleeding. But the air-bleeding have an impact on performance of anode should be further explored.

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A Study on Hydrogen Impurity Effect in Anode of Proton Exchange Membrane Fuel Cell on Various Concentration of CO and H2S (고분자전해질 연료전지 연료극의 일산화탄소 및 황화수소 농도에 따른 불순물영향에 관한 연구)

  • LEE, EUN-KYUNG;BAEK, JAE-HOON;LEE, JUNG-WOON;LEE, SEUNG-KUK;LEE, YEON-JAE
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.6
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    • pp.670-676
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    • 2016
  • Hydrogen town in Republic of Korea was established in 2013. Hydrogen as a byproduct produced by various processes of factories is used in hydrogen town facilities. As cell performance is affected by contaminations in fuel gas, various standards about impurities of fuel have been determined by many countries. This study shows performance degradation of single cell with impurities concentrations. Traces of carbon monoxide (CO) and hydrogen sulfide ($H_2S$)can cause considerable cell performance losses. For comparing the performances by poisoning of CO, acceleration test, I-V curve, constant current are performed. Both the CO and $H_2S$ poisoning rate are a function of their concentration. With the higher concentrations the higher poisoning rates are observed. And, it was confirmed that, oxidation behavior and side reaction generation are not affected. Under the lower $H_2S$ concentration condition, the poisoning rate is much higher than that of CO because of its different adsorption intensity. It can be possible that the result of this study can be used for enacting regulation as a baseline data.

An Epidemiological Study on the Incidence of CO poisoning in Korea (일산화탄소중독(一酸化炭素中毒)의 발생실태(發生實態)에 대(對)한 역학적고찰(疫學的考察))

  • Lee, K.H.;Choi, Y.O.;Kim, C.H.;Yun, D.R.
    • Journal of Preventive Medicine and Public Health
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    • v.4 no.1
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    • pp.95-105
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    • 1971
  • Carbon monoxide poisoning is one of the most serious health hazards in Korea. Although the incidence rate has been assumed to be the highest in the world, there has been no avaiable reports as far as the annual & nation-wide incidence are concered. Authors analyzed the incidence reports from 1965 to 1970 filed by the National Police & also made incidence survey on Seoul area in 1968 & 1969. The results of these surveys informed us that the official police reports are very much underevaluated. The stochastic estimations of the generel incidence were made based on the informations which were obtained through incidence survey made in Seoul area. The findings obtained are as follows; 1. The annual incidence of CO poisoning tends to increase since 1965. 2. The incidence is higher in the urban area & the incidence in Seoul is the highest in the world. 3. The frequency of incidence is the highest in the December. 4. The main causes of poisoning are the gas leakage from 'ondol' floor & the leaking of gas from kitchen to room through the connecting door. 5. The incidence survey made in Seoul area revealed that the official police reports are underevaluated around one-eighth of actual incidence. 6. The health hazards induced by CO poisoning is greater than those caused by 19 Class I & Class II communicable diseases.

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Electrochemical Performance and Cr Tolerance in a La1-xBaxCo0.9Fe0.1O3-δ (x = 0.3, 0.4 and 0.5) Cathode for Solid Oxide Fuel Cells

  • Choe, Yeong-Ju;Hwang, Hae-Jin
    • Journal of the Korean Ceramic Society
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    • v.52 no.5
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    • pp.308-314
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    • 2015
  • The electrochemical performance and Cr poisoning behavior of $La_{1-x}Ba_xCo_{0.9}Fe_{0.1}O_{3-{\delta}}$ (LBCF, x = 0.3, 0.4, 0.5) and $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_{3-{\delta}}$ (LSCF) cathodes were investigated for solid oxide fuel cells (SOFCs). The polarization resistance of the LBCF/GDC/LBCF symmetrical cell was found to decrease with increasing Ba content (x value). This phenomenon might be associated with the high oxygen vacancy concentration in the LBCF sample, with x = 0.5. In addition, there was no chromium poisoning in the LBCF cathode. On the other hand, the polarization resistance of the LSCF cathode was found to significantly increase after exposure to gaseous chromium species; it appears that this result stemmed from the formation of $SrCrO_4$ phase. Therefore, it can be expected that LBCF can be a durable potential cathode material for intermediate-temperature solid oxide fuel cells (IT-SOFC).

An Epidemiological Study on the Neurological Sequelae of Acute Carbon Monoxide Poisoning (급성일산화탄소중독(急性一酸化炭素中毒)의 신경학적(神經學的) 후유증(後遺症)에 관(關)한 역학적(疫學的) 연구(硏究))

  • Park, Byung-Joo;Cho, Soo-Hun;Ahn, Yoon-Ok;Shin, Young-Soo;Yun, Dork-Ro
    • Journal of Preventive Medicine and Public Health
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    • v.17 no.1
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    • pp.5-24
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    • 1984
  • There has been an immense need for elaborate studies on the complications and the neuological sequelae generated by acute carbon monoxide (CO) poisoning which is highly prevalent in Korea due to widespread adoption of the anthracite coal briquette as domestic fuel for heating and for cooking. For this epidemiological study, a total of 444 subjects who received hospital emergency care for acute CO poisoning during the period of March 1982 to February 1983 were randomly selected from the emergency patients's lists of 13 general hospitals in Seoul area. Informations on the neurological sequelae were elucidated by means of home visiting with prearranged questionnaire consisting questions and concise neurological examination. The findings obtained were summarized as follows; 1. The complications were found in 18% of the surveyed and acute decubitus was comprised 67.5% of the complications. 2. The total cumulative incidence of the neurological sequelae was 41.2 per 100 patients and the absolute incidence rate regardless of the duration after poisoning was 40.8%. 3. The incidence of the neurological sequelae was higher in the older age than in the younger and also higher in female than in male. Twice higher incidence was observed in the admitted patients than in the non-admitted patients and the incidence became higher in proportion to the duration of CO exposure, coma and admission. The poorer the consciousness level of patients found, at emergency room and at discharge, the higher the incidence. The incidence of the neurological sequelae by emergency care was higher in hyperbaric oxygen therapy group(51.9%) than in 100% $O_2$ group(38.0%) 4. A total of five variables significantly associated with the occurrence of the neurological sequelae were selected by the stepwise discriminant analysis. The variables were following course of emergency care, age, consciousness level at discharge, admission duration, and consciousness level at emergency room in their sequence of discriminant power. Eight variables were selected as those associated with the degree of the neurological sequelae through the stepwise multiple regression analysis. Of these variables, the acute decubitus alone explained 21.1% of the total variation ana all the eight variables could explain 36.5% of the same. The remaining seven variables listed in the order of their relative importance were: age, consciousness level at discharge, admission duration, coma duration and consciousness level at emergency room. 5. It was postulated that unexpectedly high incidence of the neurological sequelae of the CO poisoning in this epidemiological study was mainly due to the inadequate emergency care and the lack of efficient and sophisticated treatment measure. In the effort to minimize the incidence of grave neurological sequelae of acute CO poisoning, new guidelines for the emergency care and treatment should be pursued with efficient ways.

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