• Title/Summary/Keyword: CNT density

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Synthesis and Electrochemical Characteristics of Spherical Li4Ti5O12/CNT Composite Materials for Hybrid Capacitors

  • Yang, Joeng-Jin;Kim, Yu-Ri;Jeong, Moon-Gook;Yuk, Yong-Jae;Kim, Han-Joo;Park, Soo-Gil
    • Journal of Electrochemical Science and Technology
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    • v.6 no.2
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    • pp.59-64
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    • 2015
  • Spherical Li4Ti5O12 and Li4Ti5O12 carbon nanotube (CNT) composites were synthesized using a colloid system. The electrochemical properties of the composites were thoroughly examined to determine their applicability as hybrid capacitor anodes. The electrical conductivity of the spherical Li4Ti5O12-CNT composite was improved over that of the spherical Li4Ti5O12 composite. The synthesized composites were utilized as the anode of a hybrid capacitor, which was assembled with an activated carbon (AC) positive electrode. The CNTs attached on the spherical Li4Ti5O12 particles contributed to a 51% reduction of the equivalent series of resistance of the Li4Ti5O12-CNTs/AC hybrid capacitor compared to the Li4Ti5O12/AC hybrid capacitor. Moreover, the Li4Ti5O12-CNTs/AC hybrid capacitor showed a larger capacitance than the Li4Ti5O12/AC hybrid capacitor; specifically, the Li4Ti5O12-CNT/AC hybrid capacitor showed 1.6 times greater capacitance at 40 cycles with a 10 mA cm−2 loading current density.

A Study on the Circuit Design Methodology and Performance Evaluation for Hybrid Gate Driver (하이브리드 게이트 드라이버를 위한 회로 디자인 방법과 성능 평가에 관한 연구)

  • Cho, Geunho
    • Journal of IKEEE
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    • v.25 no.2
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    • pp.381-387
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    • 2021
  • As Head-Mounted Displays(HMDs), which are mainly used to maximize realism in games and videos, have experienced increased demand and expanded scope of use in education and training, there is growing interest in methods to enhance the performance of conventional HMDs. In this study, a methodology to utilize Carbon NanoTubes(CNTs) to improve the performance of gate drivers that send control signals to each pixel circuit of the HMD is discussed. This paper proposes a new circuit design method that replaces the transistors constituting the buffer part of the conventional gate driver with transistors incorporating CNTs and compare the performance of the suggested gate drive with that of a gate driver comprising only conventional transistors via simulations. According to the simulation results, by including CNTs in the gate driver, the output voltage can be increased by approximately 0.3V compared to the conventional gate driver high voltage(1.1V) at a speed of 12.5 GHz and the gate width also can be reduced by up to 20 times.

Electron emission stability from CNTs with various densities (탄소나노튜브 밀도의 변화에 따른 전자방출 안정성 연구)

  • Lim Sung Hoon;Yun Hyun Sik;Ryu Je Hwang;Moon Jong Hyun;Park Kyu Chang;Jang Jin;Moon Byeong Yeon
    • Journal of the Korean Vacuum Society
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    • v.14 no.4
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    • pp.258-262
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    • 2005
  • We report on the field emission properties from vertically aligned carbon nanotubes (CNTs) produced by a triode PECVD with a SiNx capping layer on metal catalyst. It is found that the CNTs density can be controlled by the capping layer thickness and decreases with increasing SiNx thickness. The CNT density of $\~$ 104/$cm^{2}$ exhibited highest electron emission characteristics, the threshold field of 1.2 V/$\mu$m and the current density of 0.17 mA/$cm^{2}$ at 3.6 V/$\mu$m. We have carried out investigation of electron emission stability under ambient gas of N2. The electron emission stability was improved with decreasing CNT density. Under $1\times$$10^{-5}$ Torr ambient pressure, the CNTs in 5 $\mu$m hole show electron emission current higher than $1\times$$10^{-4}$ A/cm2 and it's electron emission uniformity has $2\%$.

Fabrication of Triode Type Field Emission Device Using Carbon Nanotubes Synthesized by Thermal Chemical Vapor Deposition (열 화학 기상 증착법을 이용한 삼극관 구조의 탄소 나노 튜브 전계 방출 소자의 제조)

  • Yu W. J.;Cho Y. S.;Choi G. S.;Kim D. J.
    • Korean Journal of Materials Research
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    • v.14 no.8
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    • pp.542-546
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    • 2004
  • We report a new fabrication process for high performance triode type CNT field emitters and their superior electrical properties. The CNT-based triode-type field emitter structure was fabricated by the conventional semiconductor processes. The keys of the fabrication process are spin-on-glass coating and trim-and-leveling of the carbon nanotubes grown in trench structures by employing a chemical mechanical polishing process. They lead to strong adhesion and a uniform distance from the carbon nanotube tips to the electrode. The measured emission property of the arrays showed a remarkably uniform and high current density. The gate leakage current could be remarkably reduced by coating of thin $SiO_{2}$ insulating layer over the gate metal. The field enhancement factor(${\beta}$) and emission area(${\alpha}$) were calculated from the F-N plot. This process can be applicable to fabrication of high power CNT vacuum transistors with good electrical performance.

Electric Device Character and fabrication of advanced thin film including nano particles (나노입자가 내장된 기능성 박막의 제작과 전자소자 특성)

  • Ryu, Jeong-Tak;Ikuno, T;Honda, S.;Katayama, M.;Oura, K.
    • Journal of Korea Society of Industrial Information Systems
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    • v.11 no.4
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    • pp.66-71
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    • 2006
  • Carbon nanofibers have synthesized a low temperature using DC Ar plasma and Fe-Phthalocyanine, and a characteristic difference of the synthesized CNF according to the location of the substrate was investigated. The carbon nanofibers had about 100nm diameter and up to $10{\mu}m$ length. These were grown in random orientation. There are two shapes in the CNFs, screw and straight line shapes. Furthermore, we found the selective growth of nanofibers on the scratched substrates. The density of CNFs synthesized on the position (a) were higher than that synthesized on the position (b) [See the Fig. 2]. Also, the length of CNFs was different. In the shape, CNFs with screw and straight line shape were synthesized in the position (a), but. only CNFs with straight line shape were synthesized in the position (b). The difference have an important effect on the field emission characteristics.

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Simple fabrication process and characteristic of a screen-printed triode-CNT field emission arrays for the flat lamp application

  • Jung, Y.J.;Park, J.H.;Jeon, S.Y.;Park, S.J.;Alegaonkar, P.S.;Yoo, J.B.;Park, C.Y.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1214-1218
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    • 2006
  • We introduced simple fabrication process for field emission devices based on carbon nanotubes (CNTs) emitters. Instead of using the ITO material as a transparent electrode, a metal (Au) with thickness of 5-20nm was used. Moreover, the ITO patterning process was eliminated by depositing metal layer, before the CNT printing process. In addition, the thin metal layer on photo resist (PR) layer was used as UV block. We fabricated the CNT field emission arrays of triode structure with simple process. And I-V characteristics of field emission arrays were measured. The maximum current density of $254{\mu}A/cm2$ was achieved when the gate and the anode voltage was kept 150V and 3000V, respectively. The distance between anode and cathode was kept constant.

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Effect of $NH_3$ on the Synthesis of Carbon Nanotubes Using Thermal Chemical Vapor Deposition

  • Cho, Hyun-Jin;Jang, In-Goo;Yoon, So-Jung;Hong, Jin-Pyo;Lee, Nae-Sung
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1219-1224
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    • 2006
  • This study investigates the effect of $NH_3$ gas upon the growth of carbon nanotubes (CNTs) using thermal chemical vapor deposition. It is considered that the CNT synthesis occurs mainly through two steps, clustering of catalyst particles and subsequent growth of CNTs. We thus introduced $NH_3$ during either an annealing or growth step. When $NH_3$ was fed only during annealing, CNTs grew longer and more highly crystalline with diameters unchanged. An addition of $NH_3$ during growth, however, resulted in shorter CNTs with lower crystallinity while increased their diameters. Vertically aligned, highly populated CNT samples showed poor field emission characteristics, leading us to apply post-treatments onto the CNT surface. The CNTs were treated by adhesive tapes or etched back by dc plasma of $N_2$ to reduce the population density and the radius of curvatures of CNTs. We discuss the morphological changes of CNTs and their field emission properties upon surface treatments.

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Improved Surface Morphologies of Printed Carbon Nanotubes by Heat Treatment and Their Field Emission Properties

  • Lee, Hyeon-Jae;Lee, Yang-Doo;Cho, Woo-Sung;Kim, Jai-Kyeong;Lee, Yun-Hi;Hwang, Sung-Woo;Ju, Byeong-Kwon
    • Journal of Information Display
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    • v.7 no.2
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    • pp.22-25
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    • 2006
  • This paper presents heating process for obtaining standing carbon nanotube emitters to improve field-emission properties from the screen-printed multiwalled carbon nanotube (MWCNT) films. In an atmosphere with optimum combination of nitrogen and air for heat treatment of CNT films, the CNT emitters can be made to protrude from the surface. This allows for high emission current and the formation of very uniform emission sites without special surface treatment. The morphological change of the CNT film by this technique has eliminated additional processing steps, such as surface treatment which may result in secondary contamination and damage to the film. Despite its simplicity the process provides high reproducibility in emission current density which makes the films suitable for practical applications.

Study of Surface Treatments on Field Emission Properties for Triode-Type Carbon Nanotube Cathodes (3극형 탄소나노튜브 캐소드의 전계방출 특성에 미치는 표면처리에 관한 연구)

  • Lee, Ji-Eon;An, Young-Je;Lee, Je-Hyun;Chung, Won-Sub;Cho, Young-Rae
    • Korean Journal of Materials Research
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    • v.17 no.3
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    • pp.173-178
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    • 2007
  • Carbon nanotube cathodes(CNT cathodes) with a trench structure similar to gated structure of triode-type cathode were fabricated by a screen printing method using multi-walled carbon nanotubes. The effects of surface treatments on CNT cathodes were investigated for high efficiency field emission displays(FEDs). A liquid method easily removed the organic residue and protruded the CNTs. Field emission properties were measured by using a diode-type mode. The liquid method produced a turn-on field of $1.4V/{\mu}m$. The emission current density was measured about $3.1mA/cm^{2}$ at the electric field of $3V/{\mu}m$. The liquid method showed a high potential applicable to the surface treatment for triode-type FEDs.

Vacuum In-line Sealing Technology of the Screen-printed CNT-FEA

  • Kwon, Sang-Jik;Kim, Tae-Ho;Shon, Byeong-Kyoo;Cho, Euo-Sik;Lee, Jong-Duk;Uh, Hyung-Soo;Cho, Sung-Hee;Lee, Chun-Gyoo
    • Journal of Information Display
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    • v.4 no.3
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    • pp.6-11
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    • 2003
  • We have fabricated a carbon nanotube field emission display (CNT-FED) panel with a 2-inch diagonal size by using a screen printing method and vacuum in-line sealing technology. The sealing temperature of the panel was around 390$^{\circ}C$ and the vacuum level was obtained with 1.4x$10^{-5}$torr at the sealing. When the field emission properties of a fabricated and sealed CNT-FED panel were characterized and compared with those of the unsealed panel which was located in a test chamber of vacuum level similar with the sealed panel. As a result, the sealed panel showed similar I-V characteristics with unsealed one and uniform light emission with very high brightness at a current density of 243 ${\mu}A/cm^2$, obtained at the electric field of 10 V/${\mu}m$.