• Title/Summary/Keyword: CLEAN

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Health Effect Assessment on Cleanup Workers of an Oil Spill in Yeosu (여수 유류유출사고 방제작업자의 건강영향평가)

  • Kim, Geunbae;Kang, Tack Shin;Yoon, Mira;Jo, Hyejung;Joo, Youngkyung;Yu, Seung Do;Lee, Bo Eun
    • Journal of Environmental Health Sciences
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    • v.42 no.6
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    • pp.385-395
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    • 2016
  • Objectives: The aim of this study was to assess exposure to VOCs and PAHs and the health effects on volunteers who participated in an oil spill cleanup in Yeosu. Methods: Atmospheric VOCs were evaluated in the vicinity of the accident site and questionnaire surveys were conducted to identify personal characteristics and acute health symptoms of clean-up workers seven days after the accident. The levels of metabolites of VOCs (t,t-MA, HA, PGA, MA, MHA) and PAHs (2-NAP, 1-OHP, 2-HF, 1-HPH), oxidative stress markers (TABARS, 8-OHdG) in the urine of workers were analyzed. Their correlation was determined by multiple regression analysis with SAS ver. 9.4. Results: Although the concentration of atmospheric VOCs in the residential areas were low at the time of survey, the levels of VOCs and PAHs metabolites in clean-up workers were higher than those in the control group after clean-up activities. The levels of urinary VOC and PAH metabolites were significantly increased after clean-up compared to those measured before participation. The thiobarbituric acid reactive substance (TBARS) concentrations were also increased and showed significant correlations with those of metabolites of benzene. Conclusion: This study shows that oil spill clean-up activities affect exposure to VOCs and PAHs and the health of clean-up workers. The results suggest the need for check-ups of participants in oil spill cleaning work.

Determination of Phthalates Compounds in the Ambient Atmosphere (II) - Evaluation of Experimental Artifacts and Sample Clean-up Procedures - (환경대기 중 프탈레이트 화합물의 농도 측정 (II) - 실험재료 전처리 및 시료정제과정 평가 -)

  • Park, Young-Hwa;Hwang, Yoon-Jung;Seo, Young-Kyo;Baek, Sung-Ok
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.5
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    • pp.455-460
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    • 2010
  • This study was carried out to find out any inherent problems occurring in the sampling and analytical procedures, and to suggest the relevant solutions to the problems. In addition, an optimal condition of clean-up process was developed, which was based on a method using silica glass column. As a result of experiments to test any artificial contamination of blank samples such as glassware and collection media, artifacts of DBP and DEHP appeared to be detected in various kinds of laboratory tools and apparatuses used in the sampling and analytical works. Therefore, it is necessary to investigate a degree of contamination before laboratory works by conducting a prior check any possible contaminations in all experimental tools and apparatus. It is also necessary to devise a method to avoid a tool, if possible, or to use a substitute of phthalate free. If the use of any plastic tool to cause contamination is inevitable, it should be properly corrected with a blank level, as is equally treated as the sample. The clean-up process demonstrated in this study can give us a significant benefit in terms of the quantity and quality of a target compound by GC/MS analysis.

Design Standard of Activated Carbon Vessel for the Intermittent Emission Sources of Volatile Organic Compounds (휘발성 유기화합물의 간헐적 배출원에 대한 활성탄 흡착 시스템 설계기준)

  • Lee, Si-Hyun;Lim, Jeong-Whan;Rhim, Young-Jun;Kim, Sang-Do;Woo, Kwang-Je;Son, Mi-Sook;Park, Hee-Jae;Seo, Man-Cheol;Ryu, Seung-Kon
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.2
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    • pp.250-260
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    • 2007
  • It was investigated that the emission characteristics of volatile organic compounds (VOCs) from small and medium companies located on industrial complexes in Metropolitan area. The emission characteristics are intermittent sources in which VOCs emissions are highly depends on the working condition. Optimized ventilation system to improve air quality in working area for the three typical companies were installed. Adsorption characteristics of major VOCs such as MEK, IPA, and toluene emitted front the companies were investigated for design of the activated carbon vessel as a VOCs control facility in each company. Concentration of total hydrocarbon and gas amounts needed to ventilation were also used as a design parameter. Mixed adsorbent to improve adsorption characteristics of problematic solvents like IPA and the design guideline of the activated carbon vessel have been suggested.

Sulfuric Acid Decomposition on CuFeAlOx Catalysts (CuFeAlOx 촉매상에서의 황산분해 반응)

  • Jeon, Dong-Kun;Lee, Kwan-Young;Gong, Gyeong-Taek;Yoo, Kye-Sang;Kim, Hong-Gon;Jung, Kwang-Deog;Lee, Byung-Gwon;Kim, Chang-Soo
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.1
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    • pp.71-76
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    • 2008
  • CuFeOx/$Al_2O_3$ catalysts are developed for the use in sulfuric acid decomposition which is a subcycle in thermochemical iodine-sulfur cycle to split water into hydrogen and oxygen. Both Cu and Fe components are co-precipitated with Al component to enhance distribution of active components. Developed catalysts are improved in the capability of sulfuric acid decomposition and endurance under highly acidic environment compared to commercial catalysts such as Pt/$Al_2O_3$ and $2CuO{\cdot}Cr_2O_3$. Developed CuFeAlOx catalysts exhibited higher sulfuric acid decomposition ability than $2CuO{\cdot}Cr_2O_3$ and longer endurance trends than Pt/$Al_2O_3$ maintaining comparable performance, respectively.

Photocatalytic Systems of Pt Nanoparticles and Molecular Co Complexes for NADH Regeneration and Enzyme-coupled CO2 Conversion

  • Kim, Ellen;Jeon, Minkyung;Kim, Soojin;Yadav, Paras Nath;Jeong, Kwang-Duk;Kim, Jinheung
    • Rapid Communication in Photoscience
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    • v.2 no.2
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    • pp.42-45
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    • 2013
  • Natural photosynthesis utilizes solar energy to convert carbon dioxide and water to energy-rich carbohydrates. Substantial use of sunlight to meet world energy demands requires energy storage in useful fuels via chemical bonds because sunlight is intermittent. Artificial photosynthesis research focuses the fundamental natural process to design solar energy conversion systems. Nicotinamide adenine dinucleotide ($NAD^+$) and $NADP^+$ are ubiquitous as electron transporters in biological systems. Enzymatic, chemical, and electrochemical methods have been reported for NADH regeneration. As photochemical systems, visible light-driven catalytic activity of NADH regeneration was carried out using platinum nanoparticles, molecular rhodium and cobalt complexes in the presence of triethanolamine as a sacrificial electron donor. Pt nanoparticles showed photochemical NADH regeneration activity without additional visible light collector molecules, demonstrating that both photoactivating and catalytic activities exist together in Pt nanoparticles. The NADH regeneration of the Pt nanoparticle system was not interfered with the reduction of $O_2$. Molecular cobalt complexes containing dimethylglyoxime ligands also transfer their hydrides to $NAD^+$ with photoactivation of eosin Y in the presence of TEOA. In this photocatalytic reaction, the $NAD^+$ reduction process competed with a proton reduction.