• Fire Science and Engineering
• /
• v.18 no.1
• /
• pp.7-12
• /
• 2004

For CFCs and Halons regulated by Montreal Protocol and their alternatives of HFC-23, HFC-125 HFC-227ea, HFC-236fa and the mixtures of inert gases of $Ar, N_2 and CO_2$, the thermodynamic properties of saturated pressure, density, enthalpy and viscosity were compared. In this study, the data from literature were expressed as a function of temperature. Thermodynamic properties of HFC compounds were similar to those of Halon-1301. Inert gas was mainly used as a mixture, but the physical properties of the inert gas does not have the favorable advantages over those of Halon-1301.

• The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
• /
• v.27 no.6
• /
• pp.533-540
• /
• 1998

최근에 국내외 에너지 이용 효율성 증대 문제, CFCs등으로 인한 오존층 파괴문제, $CO_2$ 등으로 인한 지구온난화 문제, 실내공기질(IAQ)과 관련된 건물 환기량 증대요구로 인한 건물용 공조시스템(HVAC)의 설계변경 문제 등으로 인해 다양한 종류의 대체 냉방기기가 연구되어 오고 있다. 현재 미국에서는 ASHRAE Standard 62-1989에 의해 실내거주자의 필요한 IAQ와 쾌적함을 유지하기 위해 환기량을 기존의 경우보다 약 3배 이상이 되도록 권장하고 있고 또한 대다수의 미국 주 정부에서 건물설계에 관련된 조례로 ASHRAE Standard 62-1989를 적용하고 있다. 따라서 빌딩공조 설비관계자들은 늘어난 환기 요구량에 따라 잠열냉방용량이 크게 증대되므로 이를 처리하기 위한 새로운 냉방공조기기 시스템기술에 대해 관심이 증대하고 있다. 이에 따라 건조제를 x이용한 냉방 및 제습 시스템이 대체 냉방시스템 또는 기존의 냉방 시스템과 더불어 잠열부하를 처리하는 복합 시스템으로 최근에 다시 상당한 주목을 받고 있다.

• The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
• /
• v.33 no.3
• /
• pp.43-49
• /
• 2004

This article reviews R＆D of triple effect cycle developed in Japan. Most of the refrigeration and heat pump technologies are dominated by vapor compressor system. The vapor compressor system, however, is highly concerned with the environmental regulations , as most of the vapor compressor technologies are using CFCs or HCFCs which are known as ozone depleting and global warming gases. As a consequence, refrigeration technologists are trying to invent or to develop an alternative to vapor compressor refrigeration devices. Thermally driven, absorption technology is one of the possible alternatives. At the moment, absorption cycle is most promising technology The paper summarizes briefly the current research and development in advanced technologies of triple effect absorption chiller-heater in Japan.(omitted)

• Journal of Soil and Groundwater Environment
• /
• v.12 no.4
• /
• pp.60-71
• /
• 2007

Groundwater from public wells was monitored during one year with two month interval for hydrogeochemical parameters and chlorofluorocarbons (CFCs) as environmental tracers in Jeju Island. Concentrations of major cations and $SiO_2$ show variation less than 10% whereas $NO_3$ and dissolved oxygen (DO) showed larger variation though DO variation did not change oxic or suboxic condition. $NO_3$ concentration has no consistent seasonal pattern with the largest variation of 35%. Groundwater ages determined by CFCs became temporarily younger by 5 years in October for groundwater with ages of 15 to 25 years, which can be attributed to infiltrating water in rainy season. Compared to air temperature, groundwater temperature has much smaller variation with no phase difference, which can be accounted for by a two-component model consisting of infiltrating water from surface and deeper groundwater with negligible temperature variation. The relatively small variation in groundwater age and temperature indicates that groundwater recharge through fast flow-paths is much smaller compared with basal groundwater in terms of aquifer storage.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 1995.05a
• /
• pp.58-61
• /
• 1995

Instead of using CCl$_4$CCl$_2$F$_2$ gases, we used a alternative reaction gas of CFCs which we have developed, for the experiment of laser induced dry etching of laser induced dry etching of GaAs, and compared with the etch profile of a usual reation gas. Laser powers(power density) on the sample surface were varied from 100 mW(12.7 MW/$\textrm{cm}^2$) to 210mW(27 MW/$\textrm{cm}^2$) The laser beam was scanned over the sample by moving the cell with a speed raging from 8.3$\mu\textrm{m}$/sec and the gas pressure also was varied form 260 Torr to 760 Torr, High etching rates up to 136 $\mu\textrm{m}$/sec and an aspect ratio of 2.6 have been achieved by single scan of laser beam. The chemical compositions of the reaction products deposited on the etched groove were measured by Auger electron spectroscopy(AES) Etch profiles, including depth and width were observed by scanning electron microscopy(SEM)

• Journal of Korean Society for Atmospheric Environment
• /
• v.27 no.5
• /
• pp.558-568
• /
• 2011

Hazardous volatile organic compounds (HVOCs) have been increasingly getting concern in urban air chemistry due to photochemical smog as well as its toxicity or potential hazards. In this study, we investigated their concentrations and the properties in tunnel, urban roadside and residential area. As a result, among 36HVOCs measured in this study, BTEX (benzene, toluene, ethylbenzene, xylene) and dichlorodifluoromethane, 1,2,4-trimethylbenzene, trichlorofluoromethane were detected above the concentration of $1{\mu}g/m^3$ in every sampling site and the most abundant compound was toluene. The other compounds were detected at trace level or below the detection limit. In addition, we found that three CFCs (chlorofluorocarbons), such as CFC-12, CFC-11, CFC-113, were persistently detected because of the emission in the past. Toluene to benzene ratio (T/B) at tunnel and roadside were calculated to be 4.3~5.3 and at residential area 15.4, suggesting that the residential area had several emission sources other than car exhaust. The ratio of X/E (m,p-xylene to ethylbenzene) ratio was calculated to be 1.8~2.1 at tunnel, 1.7 at roadside and 1.2 at residential area, which means this ratio reflected well the relative photochemical reactivity between these compounds. Good correlation between m,p-xylene and ethylbenzene ($r^2$ > 0.85) were shown in every study sites. This indicated that correlation between $C_2$-alkylbenzenes were not severely affected by 3-way catalytic converter. In this study, it was demonstrated that the concentration of benzene was very low, compared with national air quality standard (annual average of $5{\mu}g/m^3$). Its concentration were $2.52{\mu}g/m^3$ in roadside and $1.34{\mu}g/m^3$ in residential area. We thought this was the result of persistent policy implementation including the reduction of benzene content in gasoline enforced on January 1, 2009.

• Korean Journal of Microbiology
• /
• v.51 no.2
• /
• pp.156-168
• /
• 2015

The objective of this study is to investigate the anti-Helicobacter pylori and anti-cancer activities of the live cells (LC), cell-free culture supernatants (CFCS), and bacteriocin solution (BS) obtained from Lactobacillus acidophilus BK13 and Lactobacillus paracasei BK57 strains. After incubation for 30 h in MRS broth, the concentration of lactic acid produced by L. paracasei BK57 ($155.9{\pm}10.2mM$) was higher than in MRS broth using L. acidophilus BK13 ($126.8{\pm}7.9mM$). Maximum bacteriocin activity (128 AU/ml) of BK13 strain was observed after 30 h of cultivation at $37^{\circ}C$, however its magnitude was significantly lower than that of BK57 strain (256 AU/ml). The LC of L. acidophilus BK13 and L. paracasei BK57 were able to inhibit the growth of H. pylori ATCC 43504 at different incubation times, depending on the initial inoculum of the LAB. These CFCS and BS obtained from BK13 and BK57 strains dramatically inhibited the growth, adhesive ability, and enzymatic activity of H. pylori. Meanwhile, the anti-cancer effect of the lactic acid from L. acidophilus BK13 and L. paracasei BK57 strains on AGS cells had significant differences with the control group. Therefore, these antagonistic substances-producing strains are potentially useful as new potential antimicrobial agents for the management and prevention of H. pylori infections.

• Bulletin of the Korean Chemical Society
• /
• v.35 no.5
• /
• pp.1385-1390
• /
• 2014

Hydrofluoroethers (HFEs) are developed as a suitable for the replacement of environmentally hazardous CFCs and are termed as third generation refrigerants. One of the major products of decomposition of HFEs in the atmosphere is a fluoroester. The present study relates to the OH and Cl initiated oxidation of $CF_3C(O)OCH_2CF_3$ formed from the oxidation of HFE-356mff. The latter is used as a solvent in the industry and reaches the atmosphere without any degradation. Kinetics of the titled molecule has been studied at MPWB1K/6-31+G(d,p) level of theory. Single point energy calculations have been made at G2(MP2) level of theory and barrier heights are determined. The rate constants are calculated using canonical transition state theory. Tunnelling correction are made using one-dimensional Eckart potential barrier. The rate constant calculated during the present study are compared with the experimental values determined using relative rate method and FTIR detection technique.

• Journal of The Korean Association For Science Education
• /
• v.24 no.3
• /
• pp.668-674
• /
• 2004

This study investigated Korean fifteen-year-olds' (mis)conceptions on the greenhouse effect based on the PISA results. Based on previous studies on students' ideas about the greenhouse effect, Korean students'understanding of the natural factors and human-induced factors of the greenhouse effect were analyzed. Students' misconceptions about causes of the greenhouse effect were also examined. In addition to CO2, Students mentioned CFCs, atmospheric pollution, water vapor and methane as greenhouse gases. Many students indicated that the greenhouse effect and ozone depletion have a causal relationship. Teaching implications of the misconceptions were also discussed.

• Journal of the Korean Society for Geothermal and Hydrothermal Energy
• /
• v.6 no.2
• /
• pp.15-22
• /
• 2010

The natural refrigerants have used into HVAC equipments because the CFCs and HFCs have some environmental problems like high ODP and GWP. The carbon dioxide has small effect on the environmental problem but also good thermodynamics properties. In this study, the simulation study on the performance and characteristics of a $CO_2$ gascooler and evaporator using a fin-tube and microchannel heat exchanger has been conducted. Besides, the comparison of performance with operating condition was carried out in order to apply to the $CO_2$ heat pump system. As a result, the front sizes of a gascooler and evaporator using a microchannel were decreased by 63% and 58%, respectively, compared to those using a fin-tube. The performance of the fin-tube gascooler and evaporator were more responsive to the variation of operating conditions compared to that of microchannel. The pressure drop of a fin-tube heat exchanger was higher than that of a microchannel one.