• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 1997.10a
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• pp.145-151
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• 1997

PAG(Polyalkylene Glycol) and esters are tested with HFC-134a as a refrigeration oil. This investigation enhances the testing method by taking the compressor's environment into account. A testing environment charged with refrigerant gas more closely simulates the conditions of a compressor. The friction coetTicient of the PAG/HFC-134a system is similar to that of the mineral oil/CFC-12 system at operating conditions. Ester oils are preferable at the start & stop condition in the lubricity aspect. PAG shows good lubricity in conditions of extreme contact pressure. Consequently, this test provides reliable results on compressor lubricity of refrigeration oils with HFC-134a. It suggests a methodological way for the proper selection of refrigeration oils that may improve the durability and performance of a compressor.

• Journal of Advanced Marine Engineering and Technology
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• v.22 no.6
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• pp.871-879
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• 1998

The refrigerator consists of many components such as compressor condenser expansion valve evaporator and the cabinet which filled by urethane foam. In this paper the heat leakage of refriger-ator is measured by the new experiment method which is different from a present method, The devi-ation of the UA(overall heat transfer coefficient times area) between the simulation and experiments is about 7-8%. Using the modeling of various components of refrigeration system a performance analysos of CFC 12 and HFC 134a is performed numerically on the UA. As the results of this study according to increase the heat leakage the refrigeration load and mass flow rate of refrigerant are increased. And the increase of the mass flow rate results in the increase of the condensing and evapo-rating temperature. Therefore according to increase of the heat leakage the COP leads to increase because the increase of refrigeration capacity is larger than the increase if compressor power.

• Journal of Advanced Marine Engineering and Technology
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• v.22 no.2
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• pp.181-189
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• 1998

A general steady-state model for simulation on domastic refrigerator has been developed. The system model consists of various standard components such as evaporator compressor condenser capillary tube and cabinet. Cabinet is not system component but influence characteristic on domastic refrigerator. The purpose of this paper is to compare between characteristics of HFC 134a with CFC 12 in the domastic refrigerator and to predict the steady state cycle performance which is various specifications of cycle components under the continuous running conditions. As the results of simulation the coefficient of performance of both condenser and evaporator increases with increasing UA the increasing rate for condenser is greater than for evaporator.

• Journal of Industrial Technology
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• v.14
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• pp.141-153
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• 1994

폴리이미드 분리막에 의한 $CCl_2F_2/Air$ 혼합물의 분리특성에 관하여 온도, 압력, stage cut(${\theta}$), 주입기체 조성등의 영향을 규명하였다. 본 연구의 실험범위 내에서 이상분리인자(ideal separation factor)는 600-200이었으며, glassy polymer인 폴리이미드 분리막에 대하여 투과도가 높은 air의 투과도는 $CCl_2F_2$ (dichlorodifluoromethane, CFC-12)에 의하여 상당히 감소함을 알 수 있었다. 그러나, 폴리이미드 분리막에 대한 투과도가 낮은 $CCl_2F_2$의 투과도는 air에 의하여 투과도가 증가하였다. 또한, 수학적 모델에 의한 예측치가 실험치와 잘 일치됨을 알 수 있었다.

• Transactions of the Korean Society of Automotive Engineers
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• v.11 no.4
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• pp.196-203
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• 2003

This study was performed to design the optimal block type expansion valve through analyzing the characteristics of the block type expansion valve in automotive air conditioning system using HFC-134a. Because an alternative refrigerant (HFC-l34a) is being used instead of CFC-12 for automotive air conditioning system, newly designed air conditioning components are necessary due to changes in characteristics. The performance tests were accomplished through the test bench, that is manufactured based on the study. And then it was carried out to measure the variation of temperature and pressure at each part of the air conditioning system according to the compressor speed.

• Fire Science and Engineering
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• v.18 no.1
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• pp.7-12
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• 2004

For CFCs and Halons regulated by Montreal Protocol and their alternatives of HFC-23, HFC-125 HFC-227ea, HFC-236fa and the mixtures of inert gases of $Ar, N_2 and CO_2$, the thermodynamic properties of saturated pressure, density, enthalpy and viscosity were compared. In this study, the data from literature were expressed as a function of temperature. Thermodynamic properties of HFC compounds were similar to those of Halon-1301. Inert gas was mainly used as a mixture, but the physical properties of the inert gas does not have the favorable advantages over those of Halon-1301.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.16 no.10
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• pp.895-900
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• 2004

With the phaseout of CFC and HCFC refrigerants, refrigeration and heat pump systems must be redesigned to match and improve system performance with alternative refrigerants. A generalized flow model for predicting mass flow rate through short tube orifices is derived from a power law form of dimensionless parameters generated by Pi-theorem. The database for developing the correlation includes extensive experimental data for R12, R22, R134a, R407C, R410A, and R502 from the open literature. The correlation yields an average deviation of $0.3\%$ and a standard deviation of $6.1\%$ based on the present database. In addition, rating charts for predicting refrigerant flow rate through short tube orifices are generated for R12, R22, R134a, R407C, R410A, and R502.

• Applied Chemistry for Engineering
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• v.9 no.3
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• pp.372-376
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• 1998

Supported Pd($Pd/AlF_3$, $Pd/{\gamma}-Al_2O_3$) catalysts and solid-acid catalysts(${\gamma}-Al_2O_3$, ${\alpha}-Al_2O_3$, $AlF_3$) were used to perform dechlorination of HCFC-142b(1-chloro-1,1-difluoroethane) in the presence of excess hydrogen. In the reactions the effects of reaction temperature, the mole ratio(r) of $H_2$ to HCFC-142b and the amount of supported Pd on dechlorination of HCFC-142b into HFC-143a(1,1,1-trifluoroethane) or HFC-152a(1,1-difluoroethane) were investigated. The experimental results showed that the conversion of HCFC-142b to product gases were 60% and 92%, respectively, and the selectivity to HFC-143a in the product gases were 58% and 64% for $Pd/AlF_3$ and $Pd/{\gamma}-Al_2O_3$ catalysts, respectively. On these catalysts an optimum reaction condition was found at $200^{\circ}C$ with the space time of reactant gases as 1.05 second and the mole ratio of $H_2$ to HCFC-142b as 3. Solid-acid catalysts were also tested at the same reaction condition. The results showed that the conversions of HCFC-142b to product gases were 12%, 8% and 7%, and the selectivities to HFC-152a were 94%, 92% and 90% for ${\gamma}-Al_2O_3$, ${\alpha}-Al_2O_3$ and $AlF_3$ catalysts, respectively.

• Applied Chemistry for Engineering
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• v.16 no.3
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• pp.379-384
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• 2005

Polyurethane foams (PUFs) were prepared from polymeric 4,4'-diphenylmethane diisocyanate (PMDI), seven polyols with different functionalities and OH values, silicone surfactant, two catalysts, and three blowing agents. Chlorofluorocarbon (CFC-11), hydrochlorofluorocarbon (HCFC-141b) and hydrofluorocarbon (HFC-365mfc) were used as blowing agents. The effect of gelling and blowing catalysts on basic properties and cell structure of PUF with HCFC-141b was investigated. The cell size of the PUF decreased with an increase in the amount of catalyst from 0 to 2 pph (parts per hundred polyol). In the case of gelling type catalyst, the compressive strength increased from 11.9 to $12.66kg_f/cm^2$ with an increase in the amount catalyst from 0 to 2 pph but the density did not change significantly. The gelling time, density, and compressive strength of the PUF with three different blowing agents were measured. There was no detectable change in their properties. However, the cell structure of PUF with HCFC-141b was not uniform as in the other systems.

• Journal of Climate Change Research
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• v.3 no.2
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• pp.153-159
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• 2012

CFC-12 used in mobile air conditioning(MAC) system has been replaced by R-134a, a type of HFC refrigerant, from 1991 to 1994. R-134a has since been widely used as a refrigerant of a mobile air conditioner. However, it is one of the six main green house gases listed in Kyoto Protocol, which makes it imperative to regulate its emission and develop alternative refrigerants. In this study, the concentration of leaked R-134a was measured using VT(Variable Temperature) shed and Running loss test shed to analyze the level of air conditioner refrigerant leaked in a vehicle. According to the analysis of the concentration of R-134a leaked from a vehicle parked, annual leakage amount of R-134a was in the range of 6.46~13.28 g/yr. The figure was similar with the leakage from the mobile air conditioning system currently used. In a study using the same vehicle model, a vehicle equipped with dual evaporation system had a higher leakage rate of refrigerant than a vehicle with a single evaporation system. It appears that the added fittings and joints of the dual evaporator system led to higher leakage rate. Besides, the analysis of the change in R-134a concentration under various car speed found that more refrigerant leaked under high speed(100km/hr) and but the volume of the wind did not affect to the variation of refrigerant leakage.