• 제목/요약/키워드: CD73

검색결과 214건 처리시간 0.027초

기판후면 온도 모니터링 및 Fluxmeter를 이용한 CIGS 박막 제조와 고효율 태양전지로의 응용연구

  • 김은도;조성진
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.668-668
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    • 2013
  • CIGS 박막태양전지는 다른 박막태양전지에 비해 높은 에너지 변환효율을 보이고 있으며, 광범위한 기술 응용분야를 가지고 있다. CIGS를 광흡수층으로 하는 태양전지의 구조는 5개의 단위박막(배면전극, 광흡수층, 버퍼층, 앞면 투명전극, 반사방지막)을 순차적으로 형성시켜 만든다. 단위박막별로 다양한 종류의 재료와 조성, 또한 제조방법에서는 갖가지 물리적, 화학적 박막 제조방법이 사용된다. 현재 광흡수층인 CIGS층의 경우 동시증발법과 스퍼터링법이 높은 효율을 보이고 있다. 본 연구에서는 CIGS층을 3-stage process를 적용한 동시증발법을 사용하였고, Fluxmeter와 기판후면 온도 모니터링을 이용하여 제조하였으며, 버퍼층은 moving 스퍼터링 법으로 ZnS를 증착하였고, 투명전극층은 PLD (Pulsed Laser Deposition)를 이용하여 제조하였다. 가장 높은 광변환효율을 보인 Al/ZnO/CdS/Mo/SLG박막시료는 유효면적 0.45 $cm^2$에 광변환효율 15.71%, Jsc: 33.64 mA/$cm^2$, Voc: 0.64 V, FF: 73.18%를 얻을 수 있었으며, CdS를 ZnS로 대체한 Al/ZnO/ZnS/Mo/SLG 박막시료는 유효면적 0.45 $cm^2$에 광변환효율 12.13%, Jsc: 33.22 mA/$cm^2$, Voc: 0.60 V, FF: 62.85%를 얻을 수 있었다.

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폐슬러지를 이용한 흡착·부상 공정에 의한 중금속 제거 (Removal of heavy metals using waste sludge by biosorptive flotation)

  • 이창한;안갑환
    • 한국환경과학회지
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    • 제14권7호
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    • pp.691-697
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    • 2005
  • Waste sludge may be used to recovery wastewater contaminated with heavy metals. The waste sludge is an inexpensive readily available source of biomass for biosorption with metal-bearing wastewater. The biosorption of heavy metals such as Pb(II), Cu(II), Cr(II), and Cd(II) onto waste sludge was investigated in batch ex­periments and waste sludge loaded heavy metals was separated by dissolved air flotation. The biosorption equi­bria of heavy metals could be described by Langmuir and Freundich isotherms. The adsorption capacity for waste sludge was in the sequence of Pb(II)>Cr(II)>Cu(II)>Cd(II). The system attained equilibrium about 20 min. The Langmuir and Freundlich adsorption model effectively described the biosorption equilibrium of Cu(II) and Cr(II) ions on waste sludge. Maximum adsorption capacity of Cu(II) and Cr(II) were 196.08 and 158.73 mg/g, respectively. Solid-liquid separation efficiencies were kept above $95\%$ on waste sludge loaded heavy metals, and were decreased with pH increasing.

Blue Organic Light-Emitting Diodes Based on Triphenylene Derivatives

  • Kim, Seul Ong;Jang, Heung Soo;Lee, Seok Jae;Kim, Young Kwan;Yoon, Seung Soo
    • Bulletin of the Korean Chemical Society
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    • 제34권8호
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    • pp.2267-2270
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    • 2013
  • A series of blue fluorescent emitters based on triphenylene derivatives were synthesized via the Diels-Alder reaction in moderate yields. The electronic absorption and emission characteristics of the new functional materials were affected by the nature of the substituent on the triphenylene nucleus. Multilayered OLEDs were fabricated with a device structure of: ITO/NPB (50 nm)/EML (30 nm)/Bphen (30 nm)/Liq (2.0 nm)/Al (100 nm). All devices showed efficient blue emissions. Among those, a device using 1 gives the best performances with a high brightness (978 cd $m^{-2}$ at 8.0 V) and high efficiencies (a luminous efficiency of 0.80 cd/A, a power efficiency of 0.34 lm/W and an external quantum efficiency of 0.73% at 20 $mA/cm^2$). The peak wavelength of the electroluminescence was 455 nm with CIEx,y coordinates of (0.17, 0.14) at 8.0 V.

공동주택 이중관 공법의 현안 분석 및 개선 연구 (A Study on the Status and Improvement of Double Pipe System in Apartment Buildings)

  • 김명석;김영일;정광섭
    • 설비공학논문집
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    • 제25권1호
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    • pp.37-42
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    • 2013
  • Double pipe system in which PB pipe is inserted in CD pipe buried in the concrete slab is widely used for cold and hot water supplies in apartment housings. The system, however becomes complicated and the overlaying pipes in the concrete slab weaken the compressive strength of the slab. Also, insufficient insulation increases energy loss. In this work, the problems of the double pipe system are studied and plans A, B, and C are suggested for improvement. In terms of compressive strength of the concrete slab, plan A(total pipe length 73 m) was the weakest and plan B(2 m) was the strongest. Energy loss of plan A was the largest with 558.9 W and plan B was the lowest with 220.7 W. However, considering the combined effect of strength and heat loss, plan C becomes the best choice, which retains the advantage of the double pipe system.

Sex differences in QEEG in adolescents with conduct disorder and psychopathic traits

  • Calzada-Reyes, Ana;Alvarez-Amador, Alfredo;Galan-Garcia, Lidice;Valdes-Sosa, Mitchell
    • Annals of Clinical Neurophysiology
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    • 제21권1호
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    • pp.16-29
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    • 2019
  • Background: Sex influences is important to understand behavioral manifestations in a large number of neuropsychiatric disorders. We found electrophysiological differences specifically related to the influence of sex on psychopathic traits. Methods: The resting electroencephalography (EEG) activity and low-resolution brain electromagnetic tomography (LORETA) for the EEG spectral bands were evaluated in 38 teenagers with conduct disorder (CD). The 25 male and 13 female subjects had psychopathic traits as diagnosed using the Antisocial Process Screening Device. All of the included adolescents were assessed using the Diagnostic and Statistical Manual of Mental Disorders, Fourth Edition, Text Revision (DSM-IV-TR) criteria. The visually inspected EEG characteristics and the use of frequency-domain quantitative analysis techniques are described. Results: Quantitative EEG (QEEG) analysis showed that the slow-wave activities in the right frontal and left central regions were higher and the alpha-band powers in the left central and bitemporal regions were lower in the male than the female psychopathic traits group. The current source density showed increases in paralimbic areas at 2.73 Hz and decreases in the frontoparietal area at 9.37 Hz in male psychopathics relative to female psychopathics. Conclusions: These findings indicate that QEEG analysis and techniques of source localization can reveal sex differences in brain electrical activity between teenagers with CD and psychopathic traits that are not obvious in visual inspections.

목란근피(牧丹根皮)의 Paeonol 및 무기성분(無機成分) 함량(含量) (Contents of Paeonol and Inorganic Components in Herbaceous Root-Bark of Paeonia moutan SIMS)

  • 정상환;서동환;박노권;김기재;최부술
    • 한국약용작물학회지
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    • 제2권3호
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    • pp.227-233
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    • 1994
  • 1990년 10월부터 1991년 5월까지 국내시판 생약중 목단근피에 대하여 생약으로서의 안전성과 유효성 및 품질 관리상의 기초자료를 연고자 생약근중에 존재하는 Paeonol 및 회분과 무기성분 함량을 조사분석한 결과를 요약하면 다음과 같다. 1. 한국산 시판 목단근피중의 Paeonol 함량은 평균 0.65% 였다. 2. 회분함량은 평균 3.53%로 대한 약전규격 6.0%이하였으며 산불용성 회분은 0.77%로 기준치 1.0% 이하였다. 3. 시판 목단근피중의 총질소 평균 함량은 1.03%, 인산은 0.55%, 가리는 0.82%, 칼슘 함량은 1.50% 이었다. 4. 시판 목단근피중의 MgO는 0.21%, Fe는 325.83ppm, Cr은 1.82ppm, Cu는 3.73ppm, Zn은 18.93ppm, Mn은 21.27ppm 이었으며 인체의 잔류량 때문에 문제시 되고 었는 Hg는 각지방 별로 수집된 생약에는 검출되지 않았다. 5. 목단근피 생약중의 평균 Cd 함량은 0.25ppm였으며 Pb함량은 3.09ppm이었고 특히 생약 중 잔류량 문제로 심각한 Cd 및 Pb 함량으로 보아 국내산 시판용 목단근피로써는 큰 문제가 없을 것으로 판단되었다. 6. 국내산 목단근피는 재배기술 및 가공조제 방법에 따라 유효성분 및 무기성분들에 많은 차이가 있을 것으로 생각되어 향후 더 많은 연구검토가 요청 된다고 하겠다.

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가정용 소형 퇴비화용기에 의한 부엌쓰레기의 분산식 퇴비화;V. 현장조건에서 퇴비화 (Decentralized Composting of Garbage by a Small Composter for a Dwelling House;V. Field experiment)

  • 서정윤;주우홍
    • 한국환경농학회지
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    • 제15권2호
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    • pp.179-187
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    • 1996
  • 실험실에서 주택용 소형 퇴비화용기로 사용 가능성이 확인된 이중 벽으로 만든 퇴비화용기를 단독주택의 가족이 4인인 한 가정에 설치하여 적용 가능성을 실험하였다. 그 결과를 요약하면 다음과 같다 : 1) 계절별 실험한 결과 퇴비 내에서 상승한 최고온도는 봄철 $31^{\circ}C$, 여름철 $36^{\circ}C$, 겨울철 $50^{\circ}C$였다. 2) 60일 후 생산된 퇴비의 pH는 겨울철 7.94, 봄철 8.21 그리고 여름철 8.29였다. 퇴비화기간의 경과에 따라 퇴비중 유기물함량은 감소 그리고 회분 함량은 증가하였음에도 불구하고 퇴비 중 각종 무기성분 및 중금속은 축적되지 않았다. 60일 후 회분함량은 겨울철 73.8%, 봄철 55.8% 그리고 여름철 57.0%였다. 질소함량은 0.2-5.8%의 범위였으며 겨울철에 가장 높았고 그리고 여름철에 가장 낮았다. 특히 높은 수분과 Cd의 함량은 퇴비화 가능한 가정쓰레기의 퇴비화에 문제점으로 지적되었다. 60일 후 계절 평균 약 58.5%의 무게가 감소하였다. 퇴비화과정 중 무기성분들의 함량범위는 3 계절 $P_2O_5\;1.50{\sim}4.41%$, $K_2O\;0.02{\sim}1.31%$, CaO $0.13{\sim}1.68%$, MgO $0.05{\sim}1.22%$였다. 또한 중금속성분들의 함량은 Zn $13{\sim}89mg/kg$, Cu $4{\sim}62mg/kg$, Cd $1{\sim}21mg/kg$, Pb $N.D.{\sim}97mg/kg$, Cr $N.D.{\sim}37mg/kg$, Hg $N.D.{\sim}1,38mg/kg$의 범위였다.

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우리나라 다류의 중금속 함량 및 안전성 평가 (Trace Metal Contents in Tea Products and Their Safety Evaluations)

  • 정소영;김정수;김은정;박성국;김미혜;홍무기;김명철;이종옥
    • 한국식품과학회지
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    • 제35권5호
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    • pp.812-817
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    • 2003
  • 본 연구는 우리나라 식품공전의 다류제품 중 중금속 함량을 파악하여 우리나라 및 외국의 모니터링, 기준과 비교함으로써 안전성을 평가하고자 하였다. 총 200건의 다류제품에 대하여 ICP, AAS 및 Mercury analyzer를 이용하여 측정한 납 등 중금속 평균함량은 Hg: 0.003 mg/kg, Pb: 0.03 mg/kg, Cd: 0.007 mg/kg, As: 0.006 mg/kg, Cu: 2.73 mg/kg, Mn: 66.91 mg/kg, Zn: 4.54 mg/kg, A1: 85.53 mg/kg으로 외국에서 보고된 결과와 유사하거나 낮은 수준이었다. 또한 우리나라 국민이 다류를 통해 섭취하는 납, 카드뮴, 수은 등 유해중금속의 섭취량은 FAO/WHO에서 설정한 PTWI의 $0.1{\sim}0.2%$ 이하로 매우 낮았다.

전주 일광산 주변의 환경 오염에 관한 연구 -겨울철 중금속오염을 중심으로- (Environmental Contamination of the Abandoned Chonju Il Mine in the Chonbuk Area)

  • 조규성;정덕호
    • 한국환경과학회지
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    • 제7권5호
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    • pp.623-631
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    • 1998
  • Pyrite contained in wasted ore dumps induces a strong acid environment when it contacts oxygenated rainfall. Present research was designed to evaluate the pollution of an area that is supposedly contaminated by pyrite of ore wasted dumps form in Chonju Il Mine. Measured are the pH and selected heavy metal elements in the supposedly polluted hydrologic system. The samples include three types : those collected from the stream waters; those from the stream sediments; and those from the rice field soil scattered over the area. The dispersion path of the pollution source was also traced. The pH of the hydrologic system ranged from 3.44 to 5.46, which clearly indicates that the area is on the acid environment. The pH tends to rise as the distance from the minehead increases. The content of heavy metal elements dissolved in the stream water varies as follows; Mn=69.73~1.99ppm, Cd=0.02~0.03ppm, Zn=0.77~1.18ppm, Cu=0.04~0.13ppm, Pb=0.22~0.32ppm. The stream water in this state may induce serious heavy metal pollution to the agricultural land and the water for human life especially in the villages down the stream. The content of heavy metal elements dissolved in the stream sediment varies as follows; Mn=245.0~4685.0ppm, Cd=10.0~15.0ppm, Zn=105.0~210.0ppm, Cu=65.0~155.0ppm, Pb=90.0~150.0ppm. The content of heavy metal elements dissolved in the rice field soil varies as follows; Mn=185.0~260.0ppm, Cd=10.0~15.0ppm, Zn=135.0~180.0ppm, Cu=65.0~90.0ppm, Pb=100.0~130.0ppm. The pollution index in the stream sediment and the rice field sell is 1.36~2.03, which shows that pollution had already begun all over the area where the samples were collected.

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Expression of Hypoxia-inducible Factor Prolyl Hydroxylase 3 HIFPH3 in Human Non-small Cell Lung Cancer (NSCLC) and Its Correlation with Prognosis

  • Chu, Xiao;Zhu, Cheng-Chu;Liu, Hui;Wang, Jiao-Chen
    • Asian Pacific Journal of Cancer Prevention
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    • 제15권14호
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    • pp.5819-5823
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    • 2014
  • Purpose: To investigate the expression of hypoxia-inducible factor prolyl hydroxylase 3 (HIFPH3) in non-small cell lung cancer (NSCLC) and explore the correlation of HIFPH3 expression with lymph node metastasis and microvessel density (MVD). Materials and Methods: A total of 73 cases of NSCLC specimens, 24 cases of para-cancerous tissues, and 20 normal pulmonary tissues were collected for HIFPH3 and CD31 immunohistochmical (IHC) study. Microvessel density (MVD) of the NSCLC tissues was also determined based on the expression of CD31. Results: The expression of HIFPH3 in carcinoma tissue was statistically higher than para-cancerous and normal pulmonary tissues (${\chi}^2=48.806$, p<0.05). Compared withthe negative lymph node metastasis group, the lymph node metastasis group showed significantly higher HIFPH3 expression (${\chi}^2=6.300$, p<0.05). The strong HIFPH3+group displayed a significantly higher MVD than weak HIFPH3+ and HIFPH3- groups (p<0.05). No differences in positive HIFPH3 expression were noted regarding the tumor diameter, age, smoking status, gender of NSCLC patients, tumor size, histopathology, or differentiation. Conclusions: HIFPH3 expression in human NSCLC lesions is significantly higher than that in para-cancerous and normal lung tissues and is positively associated with lymph node metastasis and MVD.