• Title/Summary/Keyword: C3H

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A Study for Oxidation Reaction of Alcohols with Cr (Ⅵ)-Isoquinoline Compound (Ⅰ) (Cr (Ⅵ)-Isoquinoline 화합물에 의한 알코올들의 산화반응에 관한 연구 (Ⅰ))

  • Yang, Jeong Seong;Park, Yeong Jo;Baek, Hyeong Cheol
    • Journal of the Korean Chemical Society
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    • v.34 no.6
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    • pp.534-538
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    • 1990
  • Chromium(Ⅵ) compound, [$C_9H_7$NH]$_2Cr_2O_7$ has been prepared by the reaction of isoquinoline with chromium trioxide under the presence of water. [$C_9H_7$NH]$_2Cr_2O_7$ is nonhydroscopic and dissolved in water very well. Structure of [$C_9H_7$NH]$_2Cr_2O_7$ is identified by FTIR spectra and elemental analysis data. The ability of [$C_9H_7$NH]$_2Cr_2O_7$ for the oxidation of alcohols were examined in methylene chloride. [$C_9H_7$NH]$_2Cr_2O_7$ was found as efficient oxidizing agent for the conversion of allyl, primary and secondary alcohols to the corresponding aldehydes or ketones.

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Properites of Inorganic Hybrid Silica Materials according to the XRD patterns (XRD 패턴에 따른 유무기복합 화합물의 특성)

  • 오데레사;고유신;김경식
    • Proceedings of the IEEK Conference
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    • 2003.07b
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    • pp.995-998
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    • 2003
  • This paper reports the correlation between dielectric constant and degree of amorphism of the hybrid type Si-O-C thin films. Si-O-C thin films were deposited by high density plasma chemical vapor deposition using bistrimethyl- silylmethane(BTMSM, $H_{9}$C$_3$-Si-C $H_2$-Si-C$_3$ $H_{9}$) and oxygen precursors with various flow rate ratio. As-deposited film and annealed films at 40$0^{\circ}C$ were analyzed by XRD. The Si-O-C thin films were amorphous from XRD patterns. For quantitative analysis, the diffraction pattern of the samples was transformed to radial distribution function by Fourier analysis, and then compared with each other. The degree of amorphism of annealed films was higher than that of as-deposited ones. The dielectric constant varied in accordance with flow rate ratio of precursors. The lowest dielectric constant was obtained from the as-deposited film which has the highest degree of amorphism after annealing.

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Synthese von Duttonite VO(OH)$_2$ (두토니트의 합성)

  • Rohak Bak
    • Journal of the Korean Chemical Society
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    • v.17 no.6
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    • pp.424-427
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    • 1973
  • Durch hydrothermale Behandlung wurde das Mineral Duttonit von einem rosafarbenen 4-wertigenvanadin Aquoxid($VO_2{\cdot}H_2O$) synthesiert und davon wurden Einkristallu gezuchtet. Das monokline hydroxid kristallisiert in der Raumgruppe $C_2/c$. Es befinden sich vier formeleinheiten in der Einheitszelle. Die Abmessungen der Elementarzelle betragen; a = 8.78 ${\AA}$; b = 3.94 ${\AA}$; c = 5.95 ${\AA}$; ${\beta}=90^{\circ}$41'.

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Lipid Specificity for Membrane Oxidation Catalyzed by Cytochrome c : An EPR Study

  • 민동필;한상화
    • Bulletin of the Korean Chemical Society
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    • v.17 no.3
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    • pp.279-284
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    • 1996
  • Decay of the spin label attached to cytochrome c or to stearic acid has been measured by electron paramagnetic resonance (EPR) spectroscopy to monitor membrane oxidation induced by cytochrome c-membrane interaction. Binding of cytochrome c sequestered the acidic phospholipids and membrane oxidation was efficient in the order linoleic oleic>stearic acid for a fatty acid chain in the acidic phospholipids. The spin label on cyt c was destroyed at pH 7 whereas that on stearic acid embedded in the membrane was destroyed at pH 4, presumably due to different modes of cyt c-membrane interaction depending on pH. Interestingly, cyt c also interacts with phosphatidylethanolamine, an electrically neutral phospholipid, to cause rapid membrane oxidation. Both EPR and fluorescence measurements indicated that electrostatic interaction is at least partially responsible for the process.

Properties of Crude $\beta$-amylase from Korean ginseng, Panax ginseng C. A. Meyer (고려인삼(Panax Ginseng C. A. Meyer) 중의 조(組) $\beta$-amylase의 분리와 그 성질)

  • Kim, Byung-Mook
    • Korean Journal of Food Science and Technology
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    • v.17 no.4
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    • pp.240-244
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    • 1985
  • Curde $\beta$-amylase was prepared by frationation of the water extracts from Korean ginseng, Panax Ginseng C.A. Meyer, with 0.2-0.6 saturation of ammonium sulfate. The enzyme showed the typical properties of $\beta$-amylase, producing only maltase from starch. The enzyme preparation also showed no maltase activity. The enzyme was stable at the pH 5-9 and at the temperature below $40^{\circ}C$. The enzyme showed the optimum pH at 5.0 and the optimum temperature at $35^{\circ}C$. Its activities had proportional relations with substrate concentration below 12 mg%, showing Km V slues of 4.76 mg%. The enzyme was inhibited by $Ag^{+}$, $Hg^{++}$, $Cd^{++}$, $Cu^{++}$,$ Al^{3+}$, and $Fe^{3+}$.

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Synthesis of $Ni_2Y$ magnetic particles by coprecipitation method (공침법에 의한 $Ni_2Y$ 자성 분말의 합성)

  • 김한근;사공건
    • Electrical & Electronic Materials
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    • v.9 no.9
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    • pp.906-910
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    • 1996
  • Ferroxplana N $i_{2}$Y(B $a_{2}$N $i_{2}$F $e_{12}$ $O_{22}$ ) magnetic particles, which is one of the hexagonal ferrite were synthesized by a coprecipitation method. The coprecipitates were prepared by adding aqueous solution of BaC $I_{2}$ - 2 $H_{2}$O, NiC $I_{2}$ - 6 $H_{2}$O and FeC $I_{3}$ - 6 $H_{2}$O(of which the mole ratio is $Ba^{+2}$ : N $i^{+2}$ : F $e^{3+}$= 1 : 1 : 6) to a mixture of NaOH and N $a_{2}$C $O_{3}$. The shape of Ferroxplana N $i_{2}$Y magnetic particles obtained at 1, 100(.deg. C) was hexagonal plate-like, average particle size and aspect ratio were 2(.mu.m) and 7, respectively.y.

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Studies on the Utilization of Phenolic Substance by Yeast (효모에 의한 phenol 성 물질의 자화에 관한 연구)

  • 김상달;서정훈
    • Microbiology and Biotechnology Letters
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    • v.6 no.4
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    • pp.155-159
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    • 1978
  • Phenol utilizing yeast No. 558 isolated from soil sewage sediment was able to use substantial amount of phenol as the sole carbon source, and the biomass productivity by this organism was very excellent. This organism could grow well in 1000 ppm of phenol concentration, the maxim-um specific growth rate obtainable at pH 5.0, 3$0^{\circ}C$ was 0.27/hr., and the biomass yield coefficient Y vs. consumed phenol was 3.2. Maximum production rate of biomass was observed at 35$^{\circ}C$, pH 3.5 to pH 4.5, and the addition of the 0.005~0. 01% yeast extract was the most effective. Addition of HgCl$_2$ and phenyl hydrazine, inhibitors of oxide-reductase, in the phenol containing cultural liquid caused this organism no-growth at the concentration of 10$^{-5}$ M, 10$^{-3}$ M respectively. This organism could utilize not only phenol but catechol, resorcinol and benzidine.

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Self-Heating Effects in β-Ga2O3/4H-SiC MESFETs (β-Ga2O3/4H-SiC MESFETs에서의 Self-Heating)

  • Kim, Min-Yeong;Seo, Hyun-Su;Seo, Ji-Woo;Jung, Seung-Woo;Lee, Hee-Jae;Byun, Dong-Wook;Shin, Myeong-Cheol;Schweitz, Michael A.;Koo, Sang-Mo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.1
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    • pp.86-92
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    • 2022
  • Despite otherwise advantageous properties, the performance and reliability of devices manufactured in β-Ga2O3 on semi-insulating Ga2O3 substrates may degrade because of poorly mitigated self-heating, which results from the low thermal conductivity of Ga2O3 substrates. In this work, we investigate and compare self-heating and device performance of β-Ga2O3 MESFETs on substrates of semi-insulating Ga2O3 and 4H-SiC. Electron mobility in β-Ga2O3 is negatively affected by increasing lattice temperature, which consequently also negatively influences device conductance. The superior thermal conductivity of 4H-SiC substrates resulted in reduced β-Ga2O3 lattice temperatures and, thus, mitigates MESFET drain current degradation. This, in turn, allows practically reduced device dimensions without deteriorating the performance and improved device reliability.

The Development of a Biofilter to Reduce Atmospheric Methane Emissions from MSW Landfills

  • Park, Soyoung;K.W. Brown;J.C. Thomas
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.73-76
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    • 2002
  • Biofilter performance to reduce C $H_4$ emissions from MSW landfills was tested under a variety of environmental and design conditions. The optimum soil moisture content for C $H_4$ oxidation in a loamy sand was 13% by weight. The addition of N $O_3$-N did not affect the C $H_4$ oxidation rate. Soil depths of 30cm and 60cm were equally efficient in C $H_4$ oxidation. When the C $H_4$ loading rate was decreased, the percentage of C $H_4$ oxidized increased. The maximum C $H_4$ oxidation rate was 27.2 mol $m^{-2}$ $d^{-1}$ under optimum conditions (loamy sand soil, 13% moisture content, 30cm soil depth, and an loading rate of 32.8 mol $m^{-2}$ $d^{-1}$). Based on the above results, the installation of a properly sized and managed biofilter above a landfill cover should be capable of achieving a major reduction in atmospheric methane emissions from MSW landfills built with RCRA covers.

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Zinc-induced Apoptosis in C6 glial Cells via Generation of Hydrogen Peroxide($H_2O_2$) (신경교세포주 C6 glial에서 Zinc의 Hydrogen Peroxide($H_2O_2$) 생성을 통한 세포고사)

  • 이지현;김명선;소흥섭;김남송;조광호;이향주;이기남;박길래
    • Toxicological Research
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    • v.16 no.3
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    • pp.179-185
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    • 2000
  • Zinc is known to generate reactive oxygen species (ROS) including superoxide anion and hydrogen peroxide ($H_2O_2$), which eventually contribute to cytotoxicity in a variety of cell types. Here in, we demonstrated that zinc decreased the viability of C6 glial cells in a time and dose-dependent manner, which was revealed as apoptosis characterized by ladder-pattern fragmentation of genomic DNA. chromatin condensation and DNA fragmentation in Hoechst dye staining. Zinc-induced apoptosis of C6 glial cells was prevented by the addition of catalase and antioxidants including reduced glutathione (GSH), N-acetyl-L-cysteine (NAC) and pyrrolidinedithiocarbamate (PDTC). Wefurther confirmed that zinc decreased intrac-ellular levels of GSH and generated $H_2O_2$in C6 glial cells. Moreover, antioxidants also decreased the generation of zinc-induced $H_2O_2$ in C6 glial cells. These data indicated that zinc-induced the apoptotic death of C6 glial cells via generation of reactive oxygen species such as $H_2O_2$.

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