• Title/Summary/Keyword: C3H

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Characteristics of Ascorbic acid Oxidase in Cucumbers (오이의 Ascorbic Acid Oxidase에 관한 연구)

  • Kim, Jung-Won;Park, Eun-Soon;Yoon, Sun
    • Journal of Nutrition and Health
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    • v.18 no.4
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    • pp.312-317
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    • 1985
  • This study was attempted to investigate the occurrence and the characteristics of ascorbic oxidase in cucumbers. Ascorbic acid oxidase was isolated from cucumbers and concentrated using ammonium sulfate precipitation. The results of this study are as follows ; 1) Ascorbic acid oxidase activity was detected in whole cucumber homogenate. 2) Highest amounts of ascorbic acid destroyed after 10 minutes' incubation of ascorbic acid oxidase with its substrate. 3) The optimum pH and temperature of this enzyme were found to be pH 6.5 and $40^{\circ}C$, respectively. 4) Ascorbic acid content in cucumber juice prepared using the cold water $(4^{\circ}C)$ was higher than that made with water at $30^{\circ}C$. 5) When orange juice ( pH 3.4 )was added, ascorbic acid destruction was completely ceased. (The ascorbic acid oxidase was inactivated at pH 3.9) Decreasing the temperature and pH are recommended to achieve maximum stability of ascorbic acid in preparing cucumber juice.

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Preparation and Investigation of Characteristics of Diamond-like Carbon Thin Films by Acetylene Plasma (아세틸렌 플라스마를 이용한 다이아몬드성 탄소 박막의 제작 및 특성)

  • Youk, Do Jin;Kang, Sung Soo;Lee, Won Jin
    • Journal of Korean Ophthalmic Optics Society
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    • v.3 no.1
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    • pp.1-8
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    • 1998
  • The a-C:H films have been grown on the glass substrate by PECVD mathod, where plasma was generated with a 60Hz line power source. The carbonization is checked from peak intensities of D($sp^3$) and G($sp^2$) peaks in Raman spectra. The hydronization and C-H bonding status in films can also be determined from FTIR results. Both the bonding strength of C-H and the ratio of $sp^3$ to $sp^2$ in bonding are found to be slightly dependent of partial pressure of $C_2H_2$. Judging from above results, we can conclude that the best value for partial pressure of $C_2H_2$ in growing process of thick films is about 15%.

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The Interaction of Gallium Bromide with Ethyl Bromide in Nitrobenzene and in 1,2,4-Trichlorobenzene (니트로벤젠溶液 및 1,2,4-트리클로로벤젠 溶液內에서의 브롬化갤륨과 브롬化에칠과의 相互作用)

  • Sang Up Choi
    • Journal of the Korean Chemical Society
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    • v.7 no.1
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    • pp.65-68
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    • 1963
  • The solubility of ethyl bromide in nitrobenzene and in 1,2,4-trichlorobenzene has been measured at $19^{\circ}$ in the presence and absence of gallium bromide. When gallium bromide does not exist in the system, the solubility of ethyl bromide in nitrobenzene is greater than in 1,2,4-trichlorobenzene, indicating the stronger interaction of ethyl bromide with nitrobenzene than with 1,2,4-trichlorobenzene. When there exists gallium bromide in the system, an unstable 1: 1 complex, C2H5Br·GaBr3, of gallium bromide with ethyl bromide is formed in the solution. The 1: 1 complex in solution dissociates into the components to a large extent according to one of the following equilibria or both: $C_2H_5Br{\cdot}GaBr_3{\rightleftarrows}C_2H_5Br+GaBr_3$C_2H_5Br{\cdot}GaBr_3{\rightleftarrows}C_2H_5Br+1}2GaBr_3$$ The stability of the 1: 1 complex of ethyl bromide with gallium bromide is compared with that of the corresponding complex of methyl bromide.

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Performance Characteristics of a Cascade Refrigeration System with Internal Heat Exchanger using Carbon Dioxide (R744) and Propane (R290) (내부 열교환기 부착 $CO_2-C_3H_8$용 캐스케이드 냉동시스템의 성능 특성)

  • Son, Chang-Hyo
    • Journal of Hydrogen and New Energy
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    • v.20 no.6
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    • pp.526-533
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    • 2009
  • In this paper, cycle performance analysis of $CO_2-C_3H_8$ (R744-R290) cascade refrigeration system with internal heat exchanger is presented to offer the basic design data for the operating parameters of the system. The operating parameters considered in this study include subcooling and superheating degree and gas cooling pressure and evaporating temperature in the propane (R290) low temperature cycle and the carbon dioxide (R744) high temperature cycle. The main results were summarized as follows : The COP of cascade refrigeration system of $CO_2-C_3H_8$ (R744-R290) increases with the increasing subcooling degree, but decreases with the increasing superheating degree. The COP of cascade refrigeration system increases with the increasing evaporating temperature, but decreases with the increasing gas cooling pressure. Therefore, superheating and subcooling degree, compressor efficiency, evaporating temperature and gas cooling pressure of $CO_2-C_3H_8$ (R744-R290) cascade refrigeration system have an effect on the COP of this system.

Effects of Practical Variations in Fasting, Stress and Chilling Regime on Post-slaughter Metabolic Rate and Meat Quality of Pork Loin (절식, 스트레스 및 냉각속도가 돼지도체의 사후 대사속도와 등심근의 육질에 미치는 영향)

  • Hwang, I.H.;Park, B.Y.;Cho, S.H.;Kim, J.H.;Lee, J.M.
    • Journal of Animal Science and Technology
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    • v.46 no.1
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    • pp.97-106
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    • 2004
  • The study was conducted to investigate the effects of practical variations in feed restriction, pre-slaughter handing and chilling regime on pork quality during ageing. A total of twenty male landraces were allocated into three treatments(i.e., pre-slaughter feeding, stress and chilling regime) in a factorial arrangement. pH, temperature, free calcium ions, WB-shear force, sarcomere length, cooking loss, drip loss and objective color were determined during rigor development and/or 1, 3, 7 d postmortem. Pre-slaughter chasing stress for approximately 15 min had no effects on pH/temperature profile and objective meat quality. There was an interaction(P < 0.05) between the fasting treatment and chi1ling regime for muscle temperature at pH 6.2. Sarcomere length indicated that the current experiment conditions did not induce muscle shortening, with 1.7 to 1.8 ${\mu}m$, in spite of a significant effect of the fasting treatment (P<0.01). Pigs fed until the morning of slaughter showed a low WB-shear force(P < 0.05) until 3 d at I "C. The treatment also resulted in a higher Hunter L* and a*(P < 0.05) at 24 h and 7 d. Fasted pigs showed a significantly(P < 0.05) reduced cooking loss. The current results indicated that feeding upon the morning of slaughter became detrimental on meat color and the negative effect on cooking loss were linearly elevated with increased ageing time. On the other hand, WB-shear force did not distinguishable after 3 d. Collectively, it appeared that feed restriction from a day before slaughter could produce more a desirable meat quality at the time of consuming. However, the limited effect of animal handling and chilling rate on meat quality is not necessarily to extend to that these do not affect pork quality, as that largely depends on experimental design.

Analytical Models for Breakdown Voltage and Specific On-Resistance of 4H-SiC Schottky Diodes (4H-SiC 쇼트키 다이오드의 해석적 항복전압과 온-저항 모델)

  • Chung, Yong-Sung
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.45 no.6
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    • pp.22-27
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    • 2008
  • Analytical models for breakdown voltage and specific on-resistance of 4H-silicon carbide Schottky diodes have been derived successfully by extracting an effective ionization coefficient $\gamma$ from ionization coefficients $\alpha$ and $\beta$ for electron and hole in 4H-SiC. The breakdown voltages extracted from our analytical model are compared with experimental results. The specific on-resistance as a function of doping concentration is also compared with the ones reported previously. Good fits with the experimental results are found for the breakdown voltage within 10% in error for the doping concentration in the range of about $10^{15}{\sim}10^{18}\;cm^{-3}$. The analytical results show good agreement with the experimental data for the specific on-resistance in the range of $3{\times}10^{15}{\sim}2{\times}10^{16}\;cm^{-3}$.

OPTICAL MICROVARIABILITY OF BLAZARS

  • GHOSH K. K.;KIM CHULHEE;RAMSEY B. D.;SOUNDARARAJAPERUMAL S.
    • Journal of The Korean Astronomical Society
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    • v.34 no.1
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    • pp.9-15
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    • 2001
  • We present the results of optical differential photometry of five blazars [PKS0219+428 (3C66A), PKS 0235+164 (AO 0235+16), H0414+019, PKS 0851+202 (OJ 287) and QSO 1807+698 (3C 371)] that were observed on 7 nights between November 05, 1997 and December 29, 1998, using the B and the V band filters. We have detected microvariations in four blazars (3C66A, AO 0235+16, H04l4+019, and OJ 287). In addition, the light curve of AO 0235+16 has displayed a mini-flare when the brightness of this source was decreasing. Night-to-night variations have also been detected in 3C66A, H04l4+019, and OJ 287. The results of our observations are discussed in the framework of accretion disk phenomena (magnetic flares or hot spots in accretion disks) and jet phenomena (plasma instabilities in jets).

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Emulsification Activity of Acinetobacter sp. 2-3A Isolated from Petroleum Oil-Contaminated Soil (유류오염 토양에서 분리한 Acinetobacter sp. 2-3A의 유화활성)

  • Lim, Ji-Hyun;Jeong, Seong-Yun
    • Journal of Environmental Science International
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    • v.18 no.11
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    • pp.1261-1270
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    • 2009
  • Fifty hydrocarbon-metabolizing microorganisms were isolated from soil samples polluted by the petroleum oils in Gamman-dong, Busan. Among them, strain 2-3A, showing strong emulsification activity, was selected by oil film-collapsing method. This bacterium was identified as Acinetobacter sp. and designated as Acinetobacter sp. 2-3A. The optimum temperature and pH on the growth of Acinetobacter sp. 2-3A were $25^{\circ}C$ and pH 7.0, respectively. The carbon and nitrogen sources for the most effective emulsification activity were 3.0% olive oil and 0.5% peptone, respectively. The 0.15% potassium phosphate was the most effective emulsification activity as a phosphate source. The optimum emulsification activity condition was $20^{\circ}C$, pH 7.0, and 2.0% NaCl. The optimum time for the best production of biosurfactant was 27 hrs. The emulsification stability was maintained at the temperature range from $4^{\circ}C$ to $100^{\circ}C$, pH range from 6.0 to 10.0, and NaCl range from 0% to 10%. For the oil resolvability of the biosurfactant, the residual oils were investigated by gas chromatography. As a result, it was verified that the biosurfactant decreased and decomposed crude oils from $_nC_{10}$ to $_nC_{32}$.

Crystal structure of 1-tert-butoxycarbonyl-4-[N-(tert-butoxycarbonyl)-N-(ethoxycarbonylmethyl)amino]-3-phenylsulfonylpyrrolidind (1-tert-butoxycarbonyl-4-[N-(tert-butoxycarbonyl)-N-(ethoxycarbonylmethyl)amino]-3-phenylsulfonylpyrrolidind의 결정구조해석)

  • 조소라;김문집
    • Korean Journal of Crystallography
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    • v.6 no.1
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    • pp.27-35
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    • 1995
  • The crystal structure of 1-tert-butoxycarbonyl-4-[N-(tert-butoxycarbonyl)-N-(ethoxycarbonylmethyl)amino]-3-phenylsulfonylpyrrolidind [C24H36O8N2S] has been from single crystal x-ray diffraction study ; C24H36O8N2S triclinic, p1, a=11.363(8)Å, b=11.589(6)Å, c=11.013(10)Å,α=95.32(6)°,β=98.64(7)°,γ=79.57(5)°,V=1406.8(18)Å3, t=293K, Z=2, CuKα(λ=1.5418Å). The molecular structure was solved by diredt method and refined by full-matrix least squares to a final R=9.78% for 3621 unique observed [F≥4σ(F)] reflections and 703 paramenters.

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Synthesis of 2(3H)-Benzofuranone Derivatives from Substituted Phenols Using Methyl 2-chloro-2-(methylthio)acetate (메틸 2-클로로-2-(메틸티오)아세트산을 이용한 치환페놀류로부터 2(3H)-벤조푸란온 유도체의 합성)

  • Choi, Hong-Dae;Kim, Mi-Heun;Shin, Sang-Hoon;Son, Byung-Wha
    • YAKHAK HOEJI
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    • v.40 no.6
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    • pp.640-645
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    • 1996
  • 5-Alkyl-2(3H)-benzofuranones(3a-e) were prepared from Friedel-Crafts reaction of 4-alkylphenols with methyl 2-chloro-2-(methylthio)acetae(1) followed by the treatment of zinc du st-acetic acid. The reaction of disubstituted phenols with 1 in the presence of stannic chloride afforded 3-methyltWa-2(3H)-benzofuranone derivatives(11a-c), which were readily converted into 2(3H)-benzofuranone derivatives(12a-c) by desulfurization with zinc dust-acetic acid.

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