• Title/Summary/Keyword: C3H

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Fatty Acid Composition and Oxidative Properties of Anchovy Oil Extracted by Supercritical Carbon Dioxide (초임계 이산화탄소를 이용하여 추출된 멸치 오일의 지방산 조성 및 산화 특성)

  • Lee, Seung-Mi;Yun, Jun-Ho;Chun, Byung-Soo
    • Clean Technology
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    • v.17 no.3
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    • pp.266-272
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    • 2011
  • Anchovy oil was extracted using supercritical carbon dioxide ($SCO_2$) and organic solvents. Extraction was carried out at temperature range from 40 to $60^{\circ}C$, and pressure range from 15 to 25 MPa. The flow rate of $CO_2$ (22 $gmin^{-1}$) was constant entire the extraction period of 1.5 h. The fatty acid composition of anchovy oil was analyzed by gas chromatography (GC). The main fatty acids of anchovy oil were myristic acid, palmitic acid, stearic acid, palmitoleic acid, EPA (eicosapentaenoic acid), and DHA (docosahexaenoic acid). In addition, the oil obtained by $SCO_2$ extraction contained a higher percentage of polyunsaturated fatty acids especially EPA and DHA comparing to the organic solvent extracted oil. The oxidative stability of oils extracted from Anchovy by $SCO_2$ extraction was compared to those extracted by organic solvents. Results showed that the storage periods of oils obtained by $SCO_2$ extraction were longer than those of organic solvents extraction.

Capability of CO2 on Metal-Organic Frameworks-Based Porous Adsorbents and Their Challenges to Pressure Swing Adsorption Applications (금속-유기 골격계 다공성 흡착제의 이산화탄소 흡착성능과 압력순환흡착 공정 적용의 문제점)

  • Kim, Moon Hyeon;Choi, Sang Ok;Choo, Soo Tae
    • Clean Technology
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    • v.19 no.4
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    • pp.370-378
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    • 2013
  • This review has shown the capability of MOFs and ZIFs materials to adsorb $CO_2$ under typical PSA temperatures and pressures. The usual operating conditions are adsorption temperatures of $15{\sim}40^{\circ}C$ and adsorption pressures of 4~6 bar based on numerous PSA processes which are widely employed in gases industry for adsorptive separation of $CO_2$. The extent of $CO_2$ adsorption on the microporous materials depends on the metal species and organic linkers existing in the frameworks. The pore size and the surface area, and the process variables are the key parameters to be associated with the efficiency of the adsorbents, particularly adsorption pressures if other variables are comparable each other. The MOFs and ZIFs materials require high pressures greater than 15 bar to yield significant $CO_2$ uptakes. They possess a $CO_2$ adsorption capacity which is very similar to or less than that of conventional benchmark adsorbents such as zeolites and activated carbons. Consequently, those materials have been much less cost-effective for adsorptive $CO_2$ separation to date because of very high production price and the absence of commercially-proven PSA processes using such new adsorbents.

Decolorization Efficiency of Different Dyes by Extract from Spent Mushroom Substrates of Pleurotus eryngii (큰느타리(Pleurotus eryngii)의 수확 후 배지추출물을 이용한 다양한 염료의 탈색효과)

  • Lim, Seon Hwa;Kwak, A Min;Min, Gyeong Jin;Kim, Sang Su;Lee, Sang Yeop;Kang, Hee Wan
    • The Korean Journal of Mycology
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    • v.42 no.3
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    • pp.213-218
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    • 2014
  • Water extract from spent mushroom substrates (SMS) of Pleurotus eryngii was utilized in decolorization of eight synthetic dyes and wastewater from a textile factory. High laccase activity was detected in the extract of P. eryngii (SMSE). The SMSE showed that decolorization rate was 34~93% after 24 h incubation without any mediator on eight dyes including Rit-blue and Rit-red used in fiber dyeing. Dye decolorization rate more than 90% was observed on bromophenol blue and remazol brilliant blue R (RBBR). Dye in textile wastewater was decolorized at room temperature after three days by addition of P. eryngii SMSE. The results suggest that biological decolorization of dyes using the P. eryngii SMSE can be used as environmental friendly materials.

Characterization of Agarose Produced by Yeast Cell Surface Displayed-Arylsulfatase (효모 표층 Arylsulfatase에 의해 제조된 Agarose의 특성)

  • Cho, Eun-Soo;Kim, Jeong-Hwan;Kim, Yeon-Hee;Nam, Soo-Wan
    • Microbiology and Biotechnology Letters
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    • v.38 no.4
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    • pp.428-433
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    • 2010
  • Enzymatic hydrolysis of sulfate groups in agaropectin or agar simplifies the production process of high-quality or low sulfate-content agarose. This study was investigated that cell surface displayed arylsulfatase can be applied to desulfatation of agar for production of agarose. Sulfate content of agarose prepared by treatment of yeast surface-displayed arylsulfatase was decreased in a enzyme dosedependent manner. Especially, 35 unit/mL of yeast surface arylsulfatase attenuated sulfate content of agarose up to 0.2%. In the 0.6% agar(Junsei), 35 unit/mL enzyme treated at $40^{\circ}C$ for 3 h showed the lowest content of sulfate. Therefore, this result was determined to be the optimal condition to desulfatation of agar for production of agarose. In addition, the gel strength of yeast surface arylsulfatase treated agar and commercial agarose were compared. Agarose prepared by treatment of yeast surface arylsulfatase showed $559.8{\pm}0.12$ of gel strength, and it is a similar compared to the commercial agarose.

Correlation between Sandbar Development and Environmental Factors in the Nakdong River Estuary (낙동강 부정형적 사주발달과 환경인자간의 상관성 비교 연구)

  • Lee, I.C.;Yoo, C.I.;Yoon, H.S.
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.10 no.1
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    • pp.13-20
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    • 2007
  • This study was performed to provide fundamental data for long-term geomorphic predictions of estuarine sandbars in the Nakdong River. We monitored the geomorphic changes of Jinudo (Jinu Island), which is located on the far-southern side of the first western sandbar. We evaluated the temporal and spatial dynamics of the sandbar and the relationship between erosion and deposit speed with environmental factors. We found that: 1) The south side of Jinudo showed very rapid water channel closing and shoal generation. This phenomenon was more obvious during autumn (September and October) than during spring, with greater water depth reduction and variation between sides. 2) The mean deposit speed for Jinudo was approximately 0.85 mm/day. The deposit speed was 1.32 and 1.26 mm/day for the east and south sides of Jinudo, respectively. The maximum deposit and erosion speeds were 27 mm/day and 26 mm/day in July and December, respectively, on the east side of the island. 3) Mean surface deposit size was 0.18-0.26 mm. The newly deposited sandbar had a rotatively larger deposit size than the original land. 4) Correlation analysis showed that, on the southern side of the island, deposit activity prevailed in the winter due to low precipitation and a northerly wind, while erosion was dominant in the summer due to high water flow and a southerly wind. In contrast, the correlation analysis for the eastern side of the island showed that deposition is dominant when water flow is high. These results indicate that geomorphic dynamics vary among island sides.

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Physicochemical Properties of Hydroxypropylated Rice Starches (하이드록시프로필화 쌀 전분의 이화학적 특성)

  • Choi, Hyun-Wook;Koo, Hye-Jin;Kim, Chong-Tai;Hwang, Seong-Yun;Kim, Dong-Seob;Choi, Sung-Won;Hur, Nam-Youn;Baik, Moo-Yeol
    • Korean Journal of Food Science and Technology
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    • v.37 no.1
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    • pp.44-49
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    • 2005
  • Physicochemical properties of hydroxypropylated rice starches were investigated. Swelling power of hydroxypropylated rice starch increased at relatively lower temperature than native rice starch. Solubility of hydroxypropylated rice starch was lower (1.9-13.4%) than that of native rice starch (2.2-13.8%), and increased with increasing amount of propylene oxide. Pasting temperature ($66.2-70.8^{\circ}C$) and peak viscosity (2,843-3,395cp) of hydroxypropylated rice starch were lower than those of native starch ($71.6^{\circ}C,\;3,976\;cp$) and decreased with increasing amount of propylene oxide, regardless of reaction time. DSC thermal transitions of hydroxypropylated rice starches shifted toward lower temperature. Amylopectin-melting enthalpy of hydroxypropylated rice starch decreased (11.8-9.8J/g) with increasing amount of propylene oxide and was lower than that of native starch (11.9 J/g). These results indicate hydroxypropylation lowered swelling power and gelatinization temperatures of rice starch, because internal bonds of rice starch molecules were sterically weaken by substituted hydroxypropyl groups.

Effect of hydrothermal processing on ginseng extract

  • Ryu, Jebin;Lee, Hun Wook;Yoon, Junho;Seo, Bumjoon;Kwon, Dong Eui;Shin, Un-Moo;Choi, Kwang-joon;Lee, Youn-Woo
    • Journal of Ginseng Research
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    • v.41 no.4
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    • pp.572-577
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    • 2017
  • Background: Panax ginseng Meyer is cultivated because of its medicinal effects on the immune system, blood pressure, and cancer. Major ginsenosides in fresh ginseng are converted to minor ginsenosides by structural changes such as hydrolysis and dehydration. The transformed ginsenosides are generally more bioavailable and bioactive than the primary ginsenosides. Therefore, in this study, hydrothermal processing was applied to ginseng preparation to increase the yields of the transformed ginsenosides, such as 20(S)-Rg3, Rk1, and Rg5, and enhance antioxidant activities in an effective way. Methods: Ginseng extract was hydrothermally processed using batch reactors at $100-160^{\circ}C$ with differing reaction times. Quantitative analysis of the ginsenoside yields was performed using HPLC, and the antioxidant activity was qualitatively analyzed by evaluating 2,2'-azino-bis radical cation scavenging, 2,2-diphenyl-1-picrylhydrazyl radical scavenging, and phenolic antioxidants. Red ginseng and sun ginseng were prepared by conventional steaming as the control group. Results: Unlike steaming, the hydrothermal process was performed under homogeneous conditions. Chemical reaction, heat transfer, and mass transfer are generally more efficient in homogeneous reactions. Therefore, maximum yields for the hydrothermal process were 2.5-25 times higher than those for steaming, and the antioxidant activities showed 1.6-4-fold increases for the hydrothermal process. Moreover, the reaction time was decreased from 3 h to 15-35 min using hydrothermal processing. Conclusion: Therefore, hydrothermal processing offers significant improvements over the conventional steaming process. In particular, at temperatures over $140^{\circ}C$, high yields of the transformed ginsenosides and increased antioxidant activities were obtained in tens of minutes.

The Effects of Porous Resorbable Calcium Carbonate and Porous Replamineform Hydroxyapatite on the regeneration of the alveolar bone in the Periodontally involved extraction sockets in dogs. (Porous Resorbable Calcium Carbonate와 Porous Replamireform Hydroxyapatite가 성견치주질환 이환 발치와내 이식된 치근과 발치와 치조골 재생에 미치는 영향)

  • Kim, Chong-Kwan;Choi, Seong-Ho
    • Journal of Periodontal and Implant Science
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    • v.26 no.2
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    • pp.334-349
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    • 1996
  • Regeneration of the periodontal tissue destroyed by periodontal disease is one of the final goals of periodontal therapy. In the past few years, periodontists have used various alloplastic grafting materials in an attempt to regenerate bone lost from periodontal disease. These materials have used widely because they have shown to be nontoxic, biologically compatible with surrounding host tissue and chemically similar to bone. The purpose of this study was to investigate the effect of Porous Resorbable Calcium Carbonate and Porous Replamineform Hydroxyapatite on the regeneration of the alveolar bone and the healing of roots transplanted into the periodontally diseased extraction sockets of dogs. The experimental chronic periodontitis was induced by elastic ligatures on the 2nd and 3rd mandibular premolars of 2 adult dogs for 8weeks after surgically creating periodontal defect. The extracted root were split in half along the long-axis, and the extend of plaque exposure was marked on the root surfaces with burs. The roots were inserted in extraction sockets with Porous Resorbable Calcium Carbonate(PRCC) in left side and with Porous Replaminefrom Hydroxyapatite(PRH) in right side. The flaps were sutured to cover the sockets completely. The animals were sacrificed after 12 weeks of healing, and the specimens were examined histologically. The results were as follows: 1. No inflammatory reactions were observed in either groups. 2. Hoot resorption was observed in both groups while the general outline of the roots were maintained. 3. PRCC was almost completely resorbed and replaced with new bone, while R.H.A. was not resorbed & remained encased in newly-formed C-T and alveolar bone. 4. PRH was encapsulated with alveolar bone which has been deposited from apical & lateral area of the sockets, while the coronal portion of the sockets were filled with C-T. 5. In both groups, the resorbed portions of the roots were replaced with new bone. These results suggest that either PRCC or PRH may not interfere with bone formation or healing in extraction sockets, and in some degree, retard the root resorption. Because the roots maintained in anatomy, we think that graft materials prevent the root resorption.

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Breeding of Varieties of Pines Resistant to Pine Gall Midge. (Thecodiplosis japonensis Uchida et Inouye) (II) -Seasonal Variation of Needle Monoterpene Composition in Resistant Pinus thunbergii.- (솔잎혹파리 내충성(耐蟲性) 품종(品種) 육성(育成)에 관(關)한 연구(硏究) -2. 솔잎혹파리 내충성(耐蟲性) Pinus thunbergii의 침엽내(針葉內) monoterpene의 계절적변화(季節的變化))

  • Kim, C.S.;Hong, S.H.;Ryu, J.B.;Choi, C.;Kim, J.S.
    • Journal of Korean Society of Forest Science
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    • v.32 no.1
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    • pp.16-20
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    • 1976
  • Employing 7-15 resistant and 8-15 susceptible Japanese black pine (Pinus thunbergii Parl.) trees to pine gall midge (Thecodiplosis japonensis Uchida et Inouye) as samples, needle monoterpenes were analysed by GLC in January and June, and observation was made on the oviposition preference. Following results were obtained. 1. In January, the resistant trees showed higher contents of myrcene, limonene, ${\beta}$-phellandrene and terpinolene but lower contents of ${\alpha}$-and ${\beta}$-pinene and camphene compared to the susceptible trees. But in June, ${\alpha}$-pinene, camphene, limonene, ${\beta}$-phellandrene and terpinolene were higher and the content of ${\beta}$-pinene and myrcene were lower in the resistant trees than the susceptible trees. 2. The content of limonene was higher by the 6.8 percent and the content of ${\beta}$-pinene was lower by the 9.2 percent in the resistant trees than in the susceptible trees in June. 3. No preference for oviposition was found between resistant and susceptible trees. But in the resistant trees gall formation rate was quite lower than the susceptible trees. It was considered, therefore, that limonene and ${\beta}$-pinene content in the needle might be used as an indicator of the resistant Japanese black pine to the pine gall midge regardless of season.

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Hull Form Development of an AFRAMAX Tanker with a Composite Stern Frameline Concept (복합선미선형 개념에 의한 AFRAMAX형 유조선 선형의 개발)

  • Ho-Chung Kim;Chun-Ju Lee;Su-Hyung Kim
    • Journal of the Society of Naval Architects of Korea
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    • v.28 no.2
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    • pp.1-11
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    • 1991
  • A hull form for an Aframax tanker whore form parameters cover the values of $C_B{\simeq}0.8,\;L/B{\simeq}5.5\;and\;B/d{\simeq}3.5$ has been developed by applying a composite stern frameline concept and its excellent performance has been evaluated through a series of model tests at the Korea Research Institute of Ships and Ocean Engineering. The tests showed that this concept was very much promising in the cases of wide breadth and shallow draught vessels and suitably applicable to the stern frameline shape. For the comparison, a hull form developed by Japanese 'H' yard has been selected and the performances of two hull forms were evaluated by model tests and theoretical calculations. The comparison shows that Daewoo hull form requires less effective power by 10% and less delevered power by 5-6% at both full load and ballast conditions. In addition, it is suggested that Hushes method can give better correlationthan Froude method because the full scale resistance extrapolated by Froude method would be very much optimistic in case of the hull form with very low value of form factor.

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