• Title/Summary/Keyword: C1 reduction

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An Experimental Study on $NO_x$ Reduction Efficiency and $NH_3$ Conversion Efficiency under Various Conditions of Reductant Injection on SCR and AOC (SCR 촉매와 AOC 촉매에서 환원제 분사에 따른 $NO_x$ 저감효율과 $NH_3$ 변환효율에 관한 실험적 연구)

  • Dong, Yoon-Hee;Choi, Jung-Hwang;Cho, Yong-Seok;Lee, Seang-Wock;Lee, Seong-Ho;Oh, Sang-Ki;Park, Hyun-Dae
    • Transactions of the Korean Society of Automotive Engineers
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    • v.18 no.5
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    • pp.85-90
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    • 2010
  • As the environmental regulation of vehicle emission is strengthened, investigations for $NO_x$ and PM reduction strategies are popularly conducted. Two current available technologies for continuous $NO_x$ reduction onboard diesel vehicles are Selective Catalytic Reduction (SCR) using aqueous urea and lean $NO_x$ trap (LNT) catalysts. The experiments were conducted to investigate the $NO_x$ reduction performance of SCR system which can control the ratio of $NO/NO_2$, temperature and SV(space velocity), and the model gas was used which is similar to a diesel exhaust gas. The maximum reduction efficiency is indicated when the $NO:NO_2$ ratio is 1:1 and the SV is 30,000 $h^{-1}$ in $300^{\circ}C$. Generally, ammonia slip from SCR reactors are rooted to incomplete conversion of $NH_3$ over the SCR. In this research, slip was occurred in 6cases (except low SV and $NO:NO_2$ ratio is 1:1) after SCR. Among 6 case of slip occurrence, the maximum conversion efficiency is observed when SV is 60,000 $h^{-1}$ in $400^{\circ}C$.

Effects of Pressurereduction Rate in a Sublimation Crystal Growth Furnace on the Growth of SiC Single Crystals (승화결정성장로의 감압속도가 탄화규소 단결정 성장에 미치는 영향)

  • Kim, Jong-Pyo;Kim, Yeong-Jin;Kim, Hyeong-Jun
    • Korean Journal of Crystallography
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    • v.3 no.1
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    • pp.23-30
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    • 1992
  • a-SiC crystals were grown on the (001) plane of a-SiC seed crystals by sublimation method to find effects of pressure-reduction rate of the crystal growth furnace own the growth rate and orientstion of grown SiC crystals. Pressure-reduction rate at the initial growth stage affected the crystallinity of grown SiC crystals. In case of high pressure-reduction rate, growth rate was high and 3csic polycrystalline was grown on the seed. On the other hand, low pressure-reduction rate caused the growth rate to be slow and 6H-SiC single crystal was grown on the seed. However, even after growing SiC for 2 hours under the condition in which.

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Analysis of Thermo Environment Change by Introduction of Indoor Water Space (실내 수공간 도입에 따른 온열 환경 변화 분석)

  • Oh, Sang Mok;Oh, Se Gyu
    • KIEAE Journal
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    • v.12 no.3
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    • pp.53-60
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    • 2012
  • This research is an illustrative research to verify the thermo environmental change created after introduction of indoor pond through abridged model test and simulation analysis. Especially, temperature and comfort level are analyzed by adjusting factors like size of water space, distance length, and location. Summary of the research is as follows. First, the most effective size of water space is 7% of the indoor size, from southern side. Temperature reduction effect is about $1.6^{\circ}C$(5.5%), and for the comfort level, it is found that pmv index increases 8%. Second, based on the simulation of distance length with the sphere, it is more effective as it is close to the surface. If distance length is more than 0.5m, there is no effect on reduction of temperature and comfort level of indoor environment. Lastly, for the analysis by location of the introduced water space, simulation is undertaken by dividing the water space (14% of the indoor size) with front, side, rear and center types. Temperature reduction effect is found to be : front type ($-1.53^{\circ}C$), side type ($-0.82^{\circ}C$), rear type ($-0.44^{\circ}C$), center type ($-0.28^{\circ}C$), respectively. The indoor environment change data by introduction of water space, found in this research, is at initial phase, but it is deemed to be a basic data to refer when planning actual water space.

Cathodic Polarization Measurements on La0.9Sr0.1MnO3 Electrode for Solid Oxide Fuel Cells

  • Lee, H.Y.;Oh, S.M.
    • Applied Chemistry for Engineering
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    • v.4 no.1
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    • pp.153-161
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    • 1993
  • Cathodic oxygen reduction kinetics on $La_{0.9}Sr_{0.1}MnO_3$ electrode have been examined at $700-900^{\circ}C$ under various oxygen partial pressures. AC impedance and current interruption techniques were employed for the determination of charge transfer resistances for electrochemical oxygen reduction. The $R_{ct}$ values obtained from two different methods were very close each other for $La_{0.9}Sr_{0.1}MnO_3$ electrode. Activation energy for the electrochemical oxygen reduction was found to be 174kJ/mol under atmospheric oxygen pressure. $R_{ct}$ measurements as a function of oxygen partial pressure indicate that the rate-determining step for the electrochemical oxygen reduction on $La_{0.9}Sr_{0.1}MnO_3$ electrode is the charge transfer process.

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Characteristics of NOx Reduction and NH3 Slip in SNCR Using Pipe Nozzle for the Application of Hybrid SNCR/SCR Process (Hybrid SNCR/SCR 탈질공정에서 SNCR의 관통노즐에 의한 NOx 저감 및 NH3 Slip 특성)

  • Hyun, Ju Soo
    • Korean Chemical Engineering Research
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    • v.47 no.1
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    • pp.111-118
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    • 2009
  • A hybrid SNCR/SCR plant was designed and manufactured, and experimented on the SNCR process in the first step to investigate the optimum operation conditions of SNCR, with the equivalence ratio of the reducing agent(NSR, 0.5~5.0), reaction temperature($850{\sim}1,100^{\circ}C$), nozzle type(wall nozzle, pipe nozzle), and nozzle position as variables. In the case of wall nozzles, the NOx reduction efficiency rapidly increased to 87% at 2.5 NSR and slowed down after this. Compared to the upward spray from the pipe nozzle, wall nozzles have narrower range of applicable reaction temperature. In the case of pipe nozzles, it rapidly increased to 77% at 1.5 NSR. But the pipe nozzle downward had no NOx reduction efficiency; on the contrary, NOx increased. When the reducing agent was sprayed upward from a pipe nozzle, the NOx reduction efficiency was 50~75% in the range of 0.5~1.5 NSR, and the NOx reduction efficiency was constant without fluctuations even in the change of reaction temperature from 890 to $1,000^{\circ}C$. When 5% urea solution was sprayed upward from the pipe nozzle, 200 ppm NOx decreased to approximately 60 ppm at 1.2 NSR, and the non-reacted $NH_3$ was 50~100 ppm. In this condition, we expect over 90% NOx reduction efficiency without additional supply of $NH_3$ to SCR at the back of SNCR.

Low-temperature Reduction of N2O by H2 over Pt/SiO2 Catalysts (Pt/SiO2 촉매상에서 H2에 의한 저온 N2O 제거반응)

  • Kim, Moon Hyeon;Kim, Dae Hwan
    • Journal of Environmental Science International
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    • v.22 no.1
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    • pp.73-81
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    • 2013
  • The present work has been devoted to the catalytic reduction of $N_2O$ by $H_2$ with $Pt/SiO_2$ catalysts at very low temperatures, such as $110^{\circ}C$, and their nanoparticle sizes have been determined by using $H_2-N_2O$ titration, X-ray diffraction(XRD) and high-resolution transmission electron microscopy(HRTEM) measurements. A sample of 1.72% $Pt/SiO_2$, which had been prepared by an ion exchange method, consisted of almost atomic levels of Pt nanoparticles with 1.16 nm that are very consistent with the HRTEM measurements, while a $Pt/SiO_2$ catalyst possessing the same Pt amount via an incipient wetness technique did 13.5 nm particles as determined by the XRD measurements. These two catalysts showed a noticeable difference in the on-stream $deN_2O$ activity maintenance profiles at $110^{\circ}C$. This discrepancy was associated with the nanoparticle sizes, i.e., the $Pt/SiO_2$ catalyst with the smaller particle size was much more active for the $N_2O$ reduction. When repeated measurements of the $N_2O$ reduction with the 1.16 nm Pt catalyst at $110^{\circ}C$ were allowed, the catalyst deactivation occurred, depending somewhat on regeneration excursions.

The Mineral Carbonation Using Steelmaking Reduction Slag (제강 환원슬래그의 광물탄산화)

  • Ryu, Kyoung-Won;Choi, Sang-Hoon
    • Economic and Environmental Geology
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    • v.50 no.1
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    • pp.27-34
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    • 2017
  • Mineral carbonation for the storage of carbon dioxide is a CCS option that provides an alternative for the more widely advocated method of geological storage in underground formation. Carbonation of magnesium- or calcium-based minerals, especially the carbonation of waste materials and industrial by-products is expanding, even though total amounts of the industrial waste are too small to substantially reduce the $CO_2$ emissions. The mineral carbonation was performed with steelmaking reduction slag as starting material. The steelmaking reduction slag dissolution experiments were conducted in the $H_2SO_4$ and $NH_4NO_3$ solution with concentration range of 0.3 to 1 M at $100^{\circ}C$ and $150^{\circ}C$. The hydrothermal treatment was performed to the starting material via a modified direct aqueous carbonation process at the same leaching temperature. The initial pH of the solution was adjusted to 12 and $CO_2$ partial pressure was 1MPa for the carbonation. The carbonation rate after extracting $Ca^^{2+}$ under $NH_4NO_3$ was higher than that under $H_2SO_4$ and the carbonation rates in 1M $NH_4NO_3$ solution at $150^{\circ}C$ was dramatically enhanced about 93%. In this condition well-faceted rhombohedral calcite, and rod or flower-shaped aragonite were appeared together in products. As the concentration of $H_2SO_4$ increased, the formation of gypsum was predominant and the carbonation rate decreased sharply. Therefore it is considered that the selection of the leaching solution which does not affect the starting material is important in the carbonation reaction.

Preparation of Ultrafine C/N Controled TiCxNy Powders by Magnesium Reduction (마그네슘환원에 의한 C/N 조성제어 초미립 TiCxNy 분말 합성)

  • Lee, Dong-Won;Kim, Byoung-Kee;Yun, Jung-Yeul;Yu, Ji-Hoon;Kim, Yong-Jin
    • Journal of Powder Materials
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    • v.17 no.2
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    • pp.142-147
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    • 2010
  • The ultrafine titanium carbonitride ($TiC_xN_y$) particles below 100 nm in mean size, including various carbon and nitrogen contents (x=0.55~0.9, y=0.1~0.5), were successfully synthesized by new Mg-thermal reduction process. Nanostructured sub-stoichiometric titanium carbide ($TiC_x$) particles were initially produced by the magnesium reduction of gaseous $TiCl_4+x/2C_2Cl_4$ at $890^{\circ}C$ and post heat treatments in vacuum were performed for 2 hrs to remove residual magnesium and magnesium chloride mixed with $TiC_x$. Finally, well C/N-controled $TiC_xN_y$ phases were successfully produced by nitrification heat treatment under normal $N_2$ gas atmosphere at $1150^{\circ}C$ for 2 hrs. The values of purity, mean particle size and oxygen content of produced particles were about 99.3%, 100 nm and 0.2 wt.%, respectively.

The CO2 Reduction Potential Calculation through the Urban Park Construction

  • Lee, Eun Yeob;Kang, Myung Soo;Kim, Jong Kon
    • KIEAE Journal
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    • v.14 no.2
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    • pp.87-98
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    • 2014
  • This study is to identify quantitatively the function of carbon dioxide emissions reduction due to temperature and energy reduction according to direct carbon dioxide storage, shade provision, and evaportanspiration of urban park. According to the result of study, landscape tree indicated high carbon dioxide storage effect compare to bush, in which broadleaf tree indicated higher storage function than coniferous tree. It is believed to be the storage of carbon dioxide can be increased by increasing the composition rate of forest plants in the urban park. According to the direct estimation result of carbon dioxide storage in terms of example area, storage of carbon dioxide is estimated to be "seoul a zone" $476,818.8kg{\cdot}CO_2/m^2yr$, "anyang b zone" $186,435.7{\cdot}CO_2/m^2yr$, "daejeon c zone" $262,826{\cdot}CO_2/m^2yr$, "kwangju d zone" $231,657.8{\cdot}CO_2/m^2yr$. The carbon dioxide storage per unit area estimated to be "seoul a zone" $3.4{\cdot}CO_2/m^2yr$, "anyang b zone" $5.0{\cdot}CO_2/m^2yr$, "daejeon c zone" $2.6{\cdot}CO_2/m^2yr$, "kwangju d zone" $5.6{\cdot}CO_2/m^2yr$. The result of indirect carbon dioxide reduction effect estimated to be "seoul a zone" $291,603.4{\cdot}CO_2/m^2yr$, "anyang b zone" $165,462.4{\cdot}CO_2/m^2yr$, "daejeon c zone" $141,719.2{\cdot}CO_2/m^2yr$, "kwangju d zone" $154,803.4{\cdot}CO_2/m^2yr$. Carbon dioxide reduction potential amount through the urban park was increased to 1.6 times to 1.8 times when calculated to the indirect effect.

Synthesis of metallic copper nanoparticles and metal-metal bonding process using them

  • Kobayashi, Yoshio;Nakazawa, Hiroaki;Maeda, Takafumi;Yasuda, Yusuke;Morita, Toshiaki
    • Advances in nano research
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    • v.5 no.4
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    • pp.359-372
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    • 2017
  • Metallic copper nanoparticles were synthesised by reduction of copper ions in aqueous solution, and metal-metal bonding by using the nanoparticles was studied. A colloid solution of metallic copper nanoparticles was prepared by mixing an aqueous solution of $CuCl_2$ (0.01 M) and an aqueous solution of hydrazine (reductant) (0.2-1.0 M) in the presence of 0.0005 M of citric acid and 0.005 M of n-hexadecyltrimethylammonium bromide (stabilizers) at reduction temperature of $30-80^{\circ}C$. Copper-particle size varied (in the range of ca. 80-165 nm) with varying hydrazine concentration and reduction temperature. These dependences of particle size are explained by changes in number of metallic-copper-particle nuclei (determined by reduction rate) and changes in collision frequency of particles (based on movement of particles in accordance with temperature). The main component in the nanoparticles is metallic copper, and the metallic-copper particles are polycrystalline. Metallic-copper discs were successfully bonded by annealing at $400^{\circ}C$ and pressure of 1.2 MPa for 5 min in hydrogen gas with the help of the metalli-ccopper particles. Shear strength of the bonded copper discs was then measured. Dependences of shear strength on hydrazine concentration and reduction temperature were explained in terms of progress state of reduction, amount of impurity and particle size. Highest shear strength of 40.0 MPa was recorded for a colloid solution prepared at hydrazine concentration of 0.8 M and reduction temperature of $50^{\circ}C$.