• Title/Summary/Keyword: C-transformation

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Transformation of cis-1,2-Dichlororethylene and its Epoxide by a Butane-Grown Mixed Culture

  • Kim, Young;Lewis Semprini
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.147-152
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    • 2004
  • Aerobic cometabolism of cis-1,2-dichloroethylene (c-DCE) and c-DCE epoxide by a butane-grown mixed culture was evaluated. Transformation of c-DCE resulted in the concomitant generation of c-DCE epoxide. Chloride release studies showed nearly complete oxidative dechlorination of c-DCE (approximately 75%). Mass spectrometry confirmed tile presence of a compound with mass-to-charge-fragment ratios of 112, 83, 48, and 35. The values are in agreement with the spectra of a chemically synthesized c-DCE epoxide. Some evidences indicating the involvement of the monooxygenase in the transformation of c-DCE epoxide are: 1) $O_2$ requirement for c-DCE transformation and butane degradation; 2) butane inhibition on c-DCE transformation and vice versa; 3) the inactivation of c-DCE and c-DCE epoxide transformations by acetylene (a known monooxygenase inactivator); and 4) tire inhibition of c-DCE epoxide transformation by c-DCE.

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Diffusion-accompanied Phase Transformation of $TiSi_2$ Film Confined in Sub-micron Area

  • Kim, Yeong-Cheol
    • The Korean Journal of Ceramics
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    • v.7 no.2
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    • pp.70-73
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    • 2001
  • Phase transformation of TiSi$_2$ confined in sub-micron area of which the size is around or smaller than the grain size of C49 TiSi$_2$ phase is studied. It has been known that the C49 to C54 phase change is massive transformation that occurs abruptly starting from C54 nuclei located at triple point grain boundaries of C49 phase. When the C49 phase is confined in sub-micron area, however, the massive phase transformation is observed to be hindered due to the lack of the triple point grain boundaries of C49 phase. Heat treatment at higher temperatures starts to decompose the C49 phase, and the resulting decomposed Ti atoms diffuse to, and react with, the underneath Si material to form C54 phase that exhibits spherical interface with silicon. The newly formed C54 grains can also trigger the massive phase transformation to convert the remaining undecomposed C49 grains to C54 grains by serving as nuclei like conventional C54 nuclei located at triple point grain boundaries.

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Effect of Strengthening by Reverse Transformation of Ausformed Martensite and Marformed Martensite of Fe-31% Ni-0.2% C Alloy (Fe-31% Ni-0.2% C 합금(合金)의 오스폼드 마르텐사이트와 마르폼드 마르텐사이트의 역변태처리(逆變態處理)에 의한 강화효과(強化效果))

  • Kim, Byung Il
    • Journal of the Korean Society for Heat Treatment
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    • v.6 no.1
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    • pp.26-36
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    • 1993
  • In this study, the ausformed martensite and marformed martensite obtained from austenite with various deformation degrees in Fe-31% Ni-0.2%C alloy were transformed to revesed austenite at $510^{\circ}C$ by cyclic reverse martensite transformation. The effect of prior deformation, the rapid heating rate of reversion and number of cyclic transformation on the microstructure, mechanical properties of reversed austenite were investigated. The reverse austenite transformation is accomplised by the mechanism of shear type transformation. The structure of reversed austenite formed from ausformed martensite and marformed martensite with high deformation degrees is a fine structure of nearly equiaed grain containg a high density of dislocation tangles and was largely affected by the prior deformation applied before reversal transformation. The strength of reversed austenite is more increased with of cyclic transformation especially it is strength at the first cyclic transformation. The yield stress of revesed austenite of ausformed martensite is lower than that of marformed martensite.

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Effect of Reverse Transformation on the Mechanical Properties of High Manganease Austenitic Stainless Steel (고 Mn 오스테나이트계 스테인리스강의 기계적 성질에 미치는 역변태의 영향)

  • Kang, C.Y.;Hur, T.Y.
    • Korean Journal of Metals and Materials
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    • v.50 no.6
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    • pp.413-418
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    • 2012
  • This study was carried out to investigate the effect of reverse transformation on the mechanical properties in high manganese austenitic stainless steel. Over 95% of the austenite was transformed to deformation-induced martensite by 70% cold rolling. Reverse transformation became rapid above an annealing temperature of $550^{\circ}C$, but there was no significant transformation above $700^{\circ}C$. In addition, with an increasing annealing time at $700^{\circ}C$, reverse transformation was induced rapidly, but the transformation was almost completed at 10 min. There was a rapid decrese in strength and hardness with annealing at temperature above $550^{\circ}C$, while elongation increased rapidly above $600^{\circ}C$. At $700^{\circ}C$, hardness and strength decreased rapidly, and elongation increased steeply with an increasing reverse treatment time up to 10 min, whereas there were no significant change with a treatment time after 10 min. The reverse-transformed austenite showed an ultra-fine grain size less than $0.2{\mu}m$, which made it possible to strengthen the high manganese austenitic stainless steel.

Phase Transformation Behaviors of Ni-Ti shape memory Alloys (Ni-Ti 형상기억합금의 상변환 거동 연구)

  • Zhou B.;Oh J.O.;Yoon S.H.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.87-88
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    • 2006
  • The phase transformation behaviors of Ni-Ti shape memory alloys were investigated through a DSC(Differential Scanning Calorimetry). The annealing temperatures were applied from $600^{\circ}C,\;700^{\circ}C,\;800^{\circ}C,\;and\;900^{\circ}C$ for their effects on the phase transformation behaviors. Based on the results of DSC, phase transformation behaviors of shape memory alloys can be predicted by Liang's phase transformation model or Tanaka's phase transformation model.

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Cell transformation of bisphenol A in Syrian hamster embryo cells and mouse embryo BalB/c 3T3 cells (Syrian hamster embryo 세포와 mouse embryo BalB/c 3T3 세포에서의 bisphenol A의 세포 형질전환 연구)

  • 김종원;한의식;박미선;엄미옥;전혜승;민수진;김인숙;정해관;심웅섭
    • Environmental Mutagens and Carcinogens
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    • v.21 no.1
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    • pp.44-50
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    • 2001
  • To identify nongenotoxic carcinogen determined as negative by ICH guideline-recommended standard genotoxicity test battery; Ames test, chromosome aberration assay, mouse lymphoma $tk^{+/-}$ assay, in vivo micronucleus assay, we picked bisphenol A as a model compound. In this study, we applied in vitro BalB/c 3T3 cell transformation assay and Syrian hamster embryo (SHE) cell transfarmation assay. Bisphenol A was treated upto $769.2 ug/m{\ell}$ in BalB/c 3T3 cells and upto $125 ug/m{\ell}$ in SHE cells. bisphenol A didn't induced morphological transformation both with one stage treatment protocol and with two stage treatment protocol. But, treated far 48 hr, Bisphenol A induced morphological transformation significantly in SHE cells.

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Studies on the Factors Influencing the Transformation in Escherichia with pBR322 DNA (Escherichia coli의 pBR322 DNA 형질전환에 관여하는 인자에 관한 연구)

  • Yoo, Han-sang;Mah, Jum-sool
    • Korean Journal of Veterinary Research
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    • v.24 no.1
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    • pp.40-49
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    • 1984
  • To investigate the factors influencing the artifical transformation in Escherichia coli, E. coli C600 was transformed by pBR322 DNA with tetracycline and ampicillin resistant gene purified by CsCl-Etbr equilibrium density gradient centrifugation from E.coli HB 101. The influencing factors in the transformation such as concentration of calcium chloride, time of ice incubation, temperature and time of heat shock, time of gene expression, effects of plasmid DNA concentration and adding time were examined in these experiments. The results obtained were as follows; 1. The highest transformation frequency was observed in the treatments of 100 mM $CaCl_2$ before heat shock and the treatment of $CaCl_2$ was essential step in the process of E. coli transformation. 2. The highest transformation frequency was observed in the treatment of heat shock at $42^{\circ}C$ for 4 min. or $37^{\circ}C$ for 6 min., but the prolonged heat shock resulted a decreased transformation frequency. 3. Treatments of ice incubation at $0^{\circ}C$ for 45 min. before heat stocks or at $0^{\circ}C$ for 30min. after heat shock resulted an increased transformation frequency. 4. There was a linear relationship between DNA concentration and transformation frequency at the concentration of $8{\times}10^3$ recipient cells. The highest transformation frequency reached in carte of 7 mcg of donor DNA, but above 1 mcg of DNA concentration, transformation frequency was not remarkably increased. Addition of donor DNA just after the treatment of $CaCl_2$ was the best. 5. The best condition of gene expression at $37^{\circ}C$ were 40min. for TC-resistant gene and 100min. for AP-resistant gene. TC-resistant gene was higher in the transformation frequency and faster in the gene expression time than AP-resistant gene. In these results, the best conditions for the transformation of E. coli C 600 with pBR322 DNA were: treatment with 100mM $CaCl_2$, ice incubation at $0^{\circ}C$ for 45 min, heat shock at $42^{\circ}C$ for 4 min., 30 min. of ice incubation and incubation at $37^{\circ}C$ for 100min. for gene expression in that order.

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Study on the Martensitic Transformation Temperature and Morphology in Fe-27%Ni-0.27%C Alloy (Fe-27%Ni-0.27%C 합금의 마르텐사이트 변태온도와 형태에 관한 연구)

  • Shon, In-Jin;Kim, Hwan-Cheol;Kim, Hak-Shin
    • Journal of the Korean Society for Heat Treatment
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    • v.9 no.3
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    • pp.198-204
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    • 1996
  • This work was carried out in order to investigate the effect of grain size on martensitic transformation temperature and morphology of Fe-27%Ni-0.27%C alloy. The martensitic transformation temperature was raised with increasing the austenitizing temperature within the range from $750^{\circ}C$ to $1200^{\circ}C$, owing to the grain growth, vacancy concentration. It was observed that the larger was the austenite grain, the higher was the martensitic transformation temperature. The influence of the austenite grain size was similar to that of the austenitizing temperature. The morphology of martensite in Fe-27%Ni-0.27%C alloy changed from lath to lenticular with the variation of grain size. From the above results, it was concluded that the martensitic transformation temperature and morphology was mainly dependent upon the austenite grain size.

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Effect of Reverse Transformation on the Damping Capacity of High Manganease Austenitic Stainless Steel (고 Mn 오스테나이트계 스테인리스강의 감쇠능에 미치는 역변태의 영향)

  • Kang, C.Y.
    • Journal of Power System Engineering
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    • v.16 no.4
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    • pp.60-65
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    • 2012
  • This study was carried out to investigate the effect of reverse transformation on the damping capacity in high manganese austenitic stainless steel. ${\alpha}^{\prime}$-martensite was formed with the specific direction and surface relief by deformation. Over 95% of the austenite phase was transformed to deformation-induced ${\alpha}^{\prime}$-martensite by 70% cold rolling. Reverse transformation became rapid above an annealing temperature of $550^{\circ}C$, but there was no significant transformation above $700^{\circ}C$. In addition, with increasing annealing time at $700^{\circ}C$, reverse transformation was induced rapidly, but the transformation was almost completed at 10 min. Damping capacity was increased up to $700^{\circ}C$, and than unchanged with the increasing annealing temperature. Damping capacity increased steeply with an increasing reverse treatment time up to 10min, whereas there were no significant change with a treatment time of more than 10 min. Damping capacity increased with an increasing the reversed austenite and was strongly affected by reversed austenite.

Phase Transformation and Mechanical Properties on Sintering Temperature of $\alpha$-SiC Manufactured by Pressureless Sintering ($\beta$-SiC의 상압소결시 소결온도에 따른 상전이와 기계적 특성 변화)

  • Ju, Jin-Young;Shin, Yong-Deok
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1433-1435
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    • 2001
  • The mechanical and phase transformation of the cold isostatically pressed $\beta$-SiC ceramic were investigated as a function of the sintering temperature. The result of phase analysis revealed 6H, 4H, 3C and phase transformation between 3C and 4H showed over 2000$^{\circ}C$ and the $\beta$ ${\rightarrow}$ $\alpha$ phase transformation was in saturation at 2200$^{\circ}C$. The relative density and the mechanical properties of $\alpha$-SiC ceramic was increased with increased sintering temperature. The flexural strength showed the highest value of 230 MPa at 2200$^{\circ}C$. This reason is because crack was propagated through surface flaw. The fracture toughness showed the highest value of 4.2 $MPa{\cdot}m^{1/2}$ at 2200$^{\circ}C$.

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