• The Korean Journal of Ceramics
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• 제5권2호
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• pp.131-136
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• 1999

Yttria stabilized zirconia(YSZ) films were deposited on porous NiO substrates and quartz plates by the thermal CVD using $ZrCl_4, YCl_3$ as precursors, and $O_2$ as a reactive gas at atmospheric pressure. The evaporation temperature of $ZrCl_4$ was varied from $250^{\circ}C$ to $550^{\circ}C$ while the temperatures of $YCl_3$ and the substrate were varied from $1000^{\circ}C$ to $1030^{\circ}C$. As the evaporation temperature of $ZrCl_4$ increased, the deposition rate of $ZrO_2$ decreased, contrary to our expectation. As a result of the decreased deposition rate of $ZrO_2$, the yttria content increase. The high evaporation temperature of $ZrCl_4$ makes the well-faceted crystal while the low evaporation temperature leads to the cauliflower-shaped structure. The dependence of the evaporation temperature on the growth rate and the morphological evolution was interpreted by the charged cluster model.

• 한국응용과학기술학회지
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• 제28권1호
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• pp.85-94
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• 2011

Expanded graphites were used as anode materials of high power Li-ion secondary battery. The expanded graphite was prepared by mixing the graphite with $HClO_4$ as a intercalation agents and $KMnO_4$ as a oxidizing agents. The physical and electrochemical properties of prepared expanded graphites through the variation of process variables such as contents of intercalation agent and oxidizing agent, and heat treatment temperature were analyzed for determination of optimal conditions as the anode of high power Li-ion secondary battery. After examing the electrochemical properties of expanded graphites at the different preparing conditions, the optimal conditions of expanded graphite were selected as 8 wt.% of oxidizing agent, 400 g of intercalation agent for 20 g of natural graphite, and heat treatment at $1000^{\circ}C$. The sample showed the improved charge/discharge characteristics such as 432 mAh/g of initial reversible capacity, 88% of discharge rate capability at 10 C-rate, and 24 mAh/g of charge capacity at 10 C-rate. However, the expanded graphite had the problems of potential plateaus like natural graphite and lower initial efficiency than the natural graphite.

• 한국분말재료학회지
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• 제28권6호
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• pp.470-477
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• 2021

Energy storage systems should address issues such as power fluctuations and rapid charge-discharge; to meet this requirement, CoFe₂O₄ (CFO) spinel nanoparticles with a suitable electrical conductivity and various redox states are synthesized and used as electrode materials for supercapacitors. In particular, CFO electrodes combined with carbon nanofibers (CNFs) can provide long-term cycling stability by fabricating binder-free three-dimensional electrodes. In this study, CFO-decorated CNFs are prepared by electrospinning and a low-cost hydrothermal method. The effects of heat treatment, such as the activation of CNFs (ACNFs) and calcination of CFO-decorated CNFs (C-CFO/ACNFs), are investigated. The C-CFO/ACNF electrode exhibits a high specific capacitance of 142.9 F/g at a scan rate of 5 mV/s and superior rate capability of 77.6% capacitance retention at a high scan rate of 500 mV/s. This electrode also achieves the lowest charge transfer resistance of 0.0063 Ω and excellent cycling stability (93.5% retention after 5,000 cycles) because of the improved ion conductivity by pathway formation and structural stability. The results of our work are expected to open a new route for manufacturing hybrid capacitor electrodes containing the C-CFO/ACNF electrode that can be easily prepared with a low-cost and simple process with enhanced electrochemical performance.

• 전기화학회지
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• 제2권3호
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• pp.123-129
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• 1999

리튬이온전지용 $LiCoO_2$ 전극의 super s black 도전재료의 함량에 따른 초기 충방전 특성을 1 mol/l $LiPF_6/EC+DEC(1:3\;by\;w/w)$의 전해액에서 리튬기준전극에 대하여 4.3 V에서 2.0 V의 전위 구간에 대하여 C/4 및 C/2율로 충방전하여 측정하였다. 최초의 충전과정에서 high impedance충전 특성을 보였으며, super s black도전재료를 $3\%w/w$ 사용한 경우, $0.5 mA/cm^2$ 전류밀도의 충전에서 high impedance의 해소에 따라 $3.82\;{\Omega}\;{\cdot}\;g-LiCoCo_2$의 저항 감소를 나타내었으며, $0.728\;{\Omega}{\cdot}g-LiCoCo_2$의 전극저항과 비교하여 약 7배 높은 값을 나타내었다. 제2차 충전에의 high impedance해소는 약 $63\;{\Omega}{\cdot}g-LiCoCo_2$으로서 전극저항의 $12\%$ 정도이며, 제1차 충전의 high impedance해소에 비하여 $1.7\%$의 수준으로 감소하였다. 제1차 충전 및 방전 비용량은 C/4방전율에서 각각 160-161 및 $153\~155mAh/g-LiCoO_2$으로, 쿨롱효율은 $95.4\~96.4\%$였으며, 비가역 비용량은 약 6 mAh/g-$LiCoO_2$였다. 충전종료 지점에서 측정한 비저항은 도전재료 함량 $2\~7\%w/w$범위에서 낮은 값을 나타내어 비가역 비용량 특성의 변화와 일치하였다. 도전재료의 함량 증가에 따라 용량밀도가 감소하였으며, C/4율 방전에서 super s black함량 $2\%w/w$와 $2.9\%w/w$의 도전재료를 사용한 전극의 용량밀도는 각각 447mAh/ml 및 431 mAh/ml였다

• 전자공학회논문지
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• 제54권4호
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• pp.99-107
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• 2017

본 논문은 기존의 리튬 배터리(lithium battery) 등가모델의 정확도 개선을 위한 배터리 모델 계수 보정기법을 제안한다. 전기자동차 등 다양한 산업분야에 사용되는 리튬 배터리의 배터리 셀간 잔존용량(SOC, state of charge) 동일하게 유지하여 배터리 수명의 단축을 최소화하기 위해 BMS(battery management system)가 연구 개발 되었지만, 배터리 셀 전압 기반의 셀 밸런싱(cell balancing) 동작으로 내부저항 및 커패시터에 따른 SOC 변화를 따라가지 못한다. 배터리 내부저항 및 커패시터에 따른 배터리 SOC 추정을 위해 다양한 배터리 등가모델이 연구되었지만, 모든 배터리에 동일하게 적용하는 것은 한계가 있으며 특히 과도상태의 배터리 상태 추정이 어렵다. 기존의 배터리 전기적 등가모델 연구는 1종의 배터리를 대상으로 5~10% 오차율로 충 방전 동적특성을 모사하며 서로 다른 전기적 특성을 갖는 실제 배터리에 적용이 부적합하다. 따라서 본 논문에서는 모델 및 용량이 다른 실제 배터리 운용환경에 적합하며 오차율 5%이하의 동적특성 모사가 가능한 배터리 모델 계수 보정 알고리즘을 제안한다. 제안하는 배터리 모델 계수 보정법 검증을 위해 3.7 V 정격전압, 280 mAh, 1600 mAh 용량의 리튬 배터리를 사용하였으며, 리튬 배터리의 전기적 등가 모델로 2단 RC Tank 모델을 사용하였다. 또한 0.25C, 0.5C, 0.75C, 1C 4가지 C-rate를 사용하여 배터리 충 방전 실험 및 모델검증을 진행하였으며 제안하는 배터리 모델 계수 보정 알고리즘을 통해 구현한 두 종류의 배터리 모델의 배터리 충 방전 특성 및 과도상태 특성의 오차율은 최대 2.13%이다.

• 디지털융복합연구
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• 제19권5호
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• pp.135-144
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• 2021

국내택배는 전자상거래 활성화에 힘입어 매년 높은 성장률을 보이는 반면, 택배단가는 계속 떨어지고 있다. 낮은 택배단가로 택배사에 수익성 악화는 물론 소비자에게는 서비스 저하, 종사자에게는 과로 및 사고 등을 초래하여 택배요금 정상화를 위한 개선이 필요하다. 이 연구에서는 합리적인 요금체계 모델과 요금을 계산하는 시스템적인 접근방법을 제시하였다. 연구 방법은 화물의 부피와 무게로 부피중량(Voulumatirc Weight) 및 운임톤(Revenue Ton)을 반영하여 청구중량(Chargeable Weight)를 계산하고 택배원가을 토대로 새로운 택배요금 모델을 제시하였다. 또한 현장에서도 쉽고 편하고 합리적으로 요금을 결정할 수 있는 요금결정지원시스템을 개발하였다. 실증에서는 실제 거래되는 택배를 샘플링하여 요금차이를 검토한 결과, 부피보다는 중량에 의존하여 요금이 결정되고 있었으며 개인택배의 경우 63.5%, B2C택배의 경우 40%가 부적합으로 확인되었다. 택배현장에서 나타나는 부작용과 문제점을 해소하기 위한 대안으로 택배가격 개선방안 연구가 절실함에 이 연구가 활용될 수 있을 것이다.

• 한국수소및신에너지학회논문집
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• 제17권1호
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• pp.31-38
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• 2006

There are two types of metal hydride electrodes as a negative electrode in a Ni-MH battery, $AB_2$ Zr-based Laves phases and $AB_5$ LM(La-rich mischmetal)-based alloys. The $AB_5$ alloy electrodes have characteristic properties such as a large discharge capacity per volume, easiness in activation, long cycle life and a low cost of alloy. However they have a relatively small discharge capacity per weight. The $AB_2$alloy electrodes have a much higher discharge capacity per weight than $AB_5$ alloy electrodes, however they have some disadvantages of poor activation behavior and cycle life. Therefore, in order to improve the discharge capacity of the $AB_5$ alloy electrode the Zr, Ti and V which are the alloying elements of the $AB_2$ alloys were added to the $LaNi_{3.6}Ai_{0.4}Co_{0.7}Mn_{0.3}$ alloy which was chosen as a $AB_5$ alloy with a high capacity. The addition of Zr, Ti and V to $LaNi_{3.6}Ai_{0.4}Co_{0.7}Mn_{0.3}$ alloy improved the activation to be completed in two cycles. The discharge capacities of Zr 0.02, Ti 0.02 and V 0.1 alloys in $LaNi_{3.6}Ai_{0.4}Co_{0.7}Mn_{0.3}M_y$ (M = Zr, Ti, V) were respectively 346, 348 and 366 mAh/g alloy. The alloy electrodes, Zr 0.02, Ti 0.05 and V 0.1 in $LaNi_{3.6}Ai_{0.4}Co_{0.7}Mn_{0.3}M_y$ (M = Zr, Ti, V), have shown good cycle property after 200 cycles. The rate capability of the $LaNi_{3.6}Ai_{0.4}Co_{0.7}Mn_{0.3}M_y$ (M = Zr, Ti, V) alloy electrodes were very good until 0.6 C rate and the alloys, Zr 0.02, Ti 0.05 and V 0.1, have shown the best result as 92 % at 2.4 C rate. The charge retention property of the $LaNi_{3.6}Ai_{0.4}Co_{0.7}Mn_{0.3}M_y$ (M = Zr, Ti, V) alloys was not good and the alloys with M content from 0.02 to 0.05 showed better charge retention properties.

• KIEE International Transactions on Electrophysics and Applications
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• 제4C권1호
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• pp.21-25
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• 2004

From the gradual increasing state of charge (GISOC) observations, electrochemical behavior of multi-walled carbon nanotube│(lM LiP $F_{6}$ , EC,DEC,DME 3:5:5 volume ratio)│lithium cells was evaluated using the galvanostatic charge-discharge process. A MWCNT delivers a specific charge capacity of 1,300 mAh/g in a Li cell when cycled up to an end voltage of 0 V (vs. Li/L $i^{＋}$ )at a constant current rate every 10 hours. However, in the present study, the specific discharge capacity obtained is 338 mAh/g, thus amounting to a coulombic efficiency of only 26％. Further, when the MWCNT│Li cells were tested using the GISOC method, two distinguishable linear-fit ranges were observed due to the intercalation/deintercalation of lithium, which were found to have II $E_1$, IIC $s_1$ and II $E_2$of 27.3％, 372 mAh/g, and 25.5％, respectively. Q $c_1$, could be calculated from the data of IIE and IICs of each range by the modified equation "II $C_{sum}$= $\Sigma$( $Q_{C}$- $Q_{D}$)=(II $E_{1}$$^{-1}$ ) $Q_{Dl}$ ＋(II $E_2$$^{-1}$ -1) ( $Q_{D2}$- $Q_{Dl}$ ) ＋ IIC $s_1$= $Q_{Cl}$ - $Q_{Dl}$ ". Results of the GISOC method could be converted to the results of galvanostatic charge-discharge process, irrespective of the state of charge of the cell or battery.ery.y.y.

• Korean Chemical Engineering Research
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• 제57권4호
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• pp.547-552
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• 2019

Electrochemical properties of $LiMn_{0.8}Fe_{0.2}PO_4$ cathode were investigated with gel polymer electrolyte (GPE). To access fast and efficient transport of ions and electrons during the charge/discharge process, a pure and well-crystallized $LiMn_{0.8}Fe_{0.2}PO_4$ cathode material was directly synthesized via spray-pyrolysis method. For high operation voltage, polyacrylonitrile (PAN)-based gel polymer electrolyte was then prepared by electrospinning process. The gel polymer electrolyte showed high ionic conductivity of $2.9{\times}10^{-3}S\;cm^{-1}$ at $25^{\circ}C$ and good electrochemical stability. $Li/GEP/LiMn_{0.8}Fe_{0.2}PO_4$ cell delivered a discharge capacity of $159mAh\;g^{-1}$ at 0.1 C rate that was close to the theoretical value ($170mAh\;g^{-1}$). The cell allows stable cycle performance (99.3% capacity retention) with discharge capacity of $133.5mAh\;g^{-1}$ for over 300 cycles at 1 C rate and exhibits high rate-capability. PAN-based gel polymer is a suitable electrolyte for application in $LiMn_{0.8}Fe_{0.2}PO_4/Li$ batteries with perspective in high energy density and safety.

• 한국항공운항학회지
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• 제6권1호
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• pp.147-163
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• 1998

The purpose of this research is to look for the best description of calculating the reasonable Landing Fee. Landing Fee is consisted one of major revenues for maintaining an airport. Traditional Landing Fee Rate has been charged based on the weight factor; Maximum take-off weight, Maximum landing weight, or Maximum authorized weight. To achieve a better reliable value of Landing Fee Rate, The elements of Noise and Peak-Time have to be considered as well as the aircraft weight. This research designs the algorithms for calculating Landing Fee Rate and also Landing Fee, based on the aircraft weight. The Network is also applied to above. That is, CGI(Common Gate Interface) is constructed to interface the terminal of calculating Landing Fee Rate, and the terminal of collecting and transmitting the data such as the Weight. The computer language on the CGI was made by C++ and PERL. The main point of this research is to integrate the airport and Information System and to construct the database which is based on the different perspective of calculating Landing Fee Rate. However, the result of the most efficient and reliable will be computed based on above. This research will broaden the range of application up to the each case of airports.