• Title/Summary/Keyword: C-flux

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Potassium Pentane-1,3,3,5-tetracarboxylate Draw Solute Synthesis and Application of Forward Osmosis Process (Potassium Pentane-1,3,3,5-tetracarboxylate 유도용질 합성 및 이를 이용한 정삼투 공정 응용)

  • Lee, Hye-Jin;Choi, Jin-Il;Kwon, Sei;Kim, In-Chul
    • Membrane Journal
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    • v.29 no.2
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    • pp.111-121
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    • 2019
  • An organic citrate series draw solute was synthesized using diethyl malonate for forward osmosis. The structure of the final compound potassium pentane-1,3,3,5-tetracarboxylate was confirmed by $^1H-NMR$ and $^{13}C-NMR$ analysis. Osmotic pressure, solubility, water permeability and reverse salt flux were measured for the properties of the draw solute. Forward osmosis results showed that the draw solute exhibited higher water flux than other draw solutes of trisodium citrate and tripotassium citrate. Reverse salt flux of all the organic daw solutes was much lower than that of NaCl. The osmotic pressure of the synthesized draw solute was 25% lower than that of NaCl. The solubility of the draw solute was 317 g/ 100 g water, which is 8.8 times higher than that of NaCl. A commercialized nanofiltration membrane was used for the recovery of the draw solute. The draw solute could be effectively recovered at low pressure.

Hydrolyzed PAN Hollow Fiber PVA Composite Membrane for Pervaporation Separation of Water-ethanol Mixtures (가수분해된 PAN 중공사 PVA 복합막을 이용한 물-에탄올 계의 투과증발 분리)

  • Kang, Su Yeon;Kim, So Yeon;Cheong, Seong Ihl;Seo, Chang Hee;Park, Hun Whee;Rhim, Ji Won
    • Membrane Journal
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    • v.23 no.4
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    • pp.283-289
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    • 2013
  • Poly(vinyl alcohol) (PVA) coating solution containing glutaraldehyde (GA) and maleic anhydride (MA) as crosslinking agents was coated onto hydrolyzed poly acrylonitrile (PAN) hollow fiber membranes. The permselectivities of the resulting composite membranes prepared varying the reaction temperature and the concentration of the crosslinking agents were tested for 90 wt% ethanol aqueous mixtures by the pervaporation technique at $60^{\circ}C$. In general, the flux decreased while the selectivity increased for the increases of the reaction temperature and the crosslinking concentration. In case of GA as a crosslinking, the flux $165g/m^2hr$ and the separation factor 81 were obtained at GA 11 wt% and the reaction temperature $120^{\circ}C$. And for the case of MA, the flux $174g/m^2hr$ and the separation factor 73 were obtained at MA 11 wt% and the reaction temperature $120^{\circ}C$.

The Recycling of Inorganic Industrial Waste in Cement Industry (시멘트산업에서 무기질 산업 폐·부산물의 재활용)

  • Kang, S.K.;Nam, K.U.;Seo, H.N.;Kim, N.J.;Min, K.S.;Chung, H.S.;Oh, H.K.
    • Clean Technology
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    • v.6 no.1
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    • pp.61-69
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    • 2000
  • In this study, generation process and properties of inorganic industrial waste which can be used in cement industry were investigated. The scheme of recycling to use the selected waste as raw materials, mineralizer and flux, admixture and raw materials for special cement was decided and then various experiments were carried out. The experimental results were as follows ; In the use of industrial waste as raw materials, ferrous materials could be substituted by Cu-slag, Zn-slag, electric arc furnace or convertor furnace slag etc., and a siliceous material could be substituted by sand from cast-iron industry. By-products from sugar or fertilizer industry, which has $CaF_2$ as the main component, and jarosite from Zn refinery enabled clinker phases to be formed at lower temperature by $100{\sim}150^{\circ}C$. Adding Cu slag and STS sludge in proper proportion to cement improved properties of cement. Fly ash and limestone powder as admixture had the same effect on cement. As a raw material for special cement, aluminium waste sludge could be used in making ultra early strength cement, which had the compressive strength of $300kg/cm^2$ within 2hours. And two different ashes from municipal incinerator could be raw materials of the cement which was mainly composed of $C_3S$ and $C_{11}A_7{\cdot}CaCl_2$ as clinker phases.

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Optically Controlled Silicon MESFET Modeling Considering Diffusion Process

  • Chattopadhyay, S.N.;Motoyama, N.;Rudra, A.;Sharma, A.;Sriram, S.;Overton, C.B.;Pandey, P.
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.7 no.3
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    • pp.196-208
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    • 2007
  • An analytical model is proposed for an optically controlled Metal Semiconductor Field Effect Transistor (MESFET), known as Optical Field Effect Transistor (OPFET) considering the diffusion fabrication process. The electrical parameters such as threshold voltage, drain-source current, gate capacitances and switching response have been determined for the dark and various illuminated conditions. The Photovoltaic effect due to photogenerated carriers under illumination is shown to modulate the channel cross-section, which in turn significantly changes the threshold voltage, drainsource current, the gate capacitances and the device switching speed. The threshold voltage $V_T$ is reduced under optical illumination condition, which leads the device to change the device property from enhancement mode to depletion mode depending on photon impurity flux density. The resulting I-V characteristics show that the drain-source current IDS for different gate-source voltage $V_{gs}$ is significantly increased with optical illumination for photon flux densities of ${\Phi}=10^{15}\;and\;10^{17}/cm^2s$ compared to the dark condition. Further more, the drain-source current as a function of drain-source voltage $V_{DS}$ is evaluated to find the I-V characteristics for various pinch-off voltages $V_P$ for optimization of impurity flux density $Q_{Diff}$ by diffusion process. The resulting I-V characteristics also show that the diffusion process introduces less process-induced damage compared to ion implantation, which suffers from current reduction due to a large number of defects introduced by the ion implantation process. Further the results show significant increase in gate-source capacitance $C_{gs}$ and gate-drain capacitance $C_{gd}$ for optical illuminations, where the photo-induced voltage has a significant role on gate capacitances. The switching time ${\tau}$ of the OPFET device is computed for dark and illumination conditions. The switching time ${\tau}$ is greatly reduced by optical illumination and is also a function of device active layer thickness and corresponding impurity flux density $Q_{Diff}$. Thus it is shown that the diffusion process shows great potential for improvement of optoelectronic devices in quantum efficiency and other performance areas.

Natural Emission of Nitric Oxide from Agricultural Soil of Corn-field in Eastern North Carolina

  • Kim, Deug-Soo;Paul Roelle;Viney P. Aneja
    • Journal of Korean Society for Atmospheric Environment
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    • v.11 no.E
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    • pp.31-43
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    • 1995
  • Natural emissions of NOx from soils were measured at an agricultural corn field during 3 weeks of growing season in summer (from May to June) 1995. This experiment was conducted in an effort to characterize the role of soil NOx on tropospheric ozone formation in rural atmosphere, and understand the natural NOx emission mechanism with respect to soil parameters. NO fluxes were ranged from 3.1 ng Nm$^{-2}s^{-1}$ to 259.0 ng Nm$^{-2}s^{-1}$, and average NO flux during experimental period was found to be 47.6 $\pm$ 50.6 ng Nm$^{-2}s^{-1}$ with 732 number of data. Diurnal variation of NO flux was shown clearly with daytime maximum and nighttime minimum. NO fluxes were correlated with soil temperature. Exponential soil temperature dependency of NO fluxes was found with 0.0160$^{circ}C^{-1} of k and r^2=0.508$, which agrees well to the value estimated at corn fields in eastern United States. The significant increases of NO fluxes from agricultural soil were detected after applying N fertilizers to soil. THe mechanisms attributed to this are enhanced biological nitrification and denitrification. In the view of rural ozone formation, the roles of natural NO emissions are very essential, especially in NOx - limited region such as southern United States.

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Experimental Study on the Thermal Mixing and the Critical Heat Flux in the 5${\times}$5 Rod Bundle with the Hybrid Mixing Vane (복합혼합날개를 장착한 5${\times}$5 봉다발에서 부수로 혼합 및 임계열유속 실험 연구)

  • Kang, K.H.;Shin, C.H.;Choo, Y.J.;Youn, Y.J.;Park, J.K.;Moon, S.K.;Chun, S.Y.
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2303-2308
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    • 2007
  • Experiments were performed to determine the thermal (or turbulent) diffusion coefficient (TDC) and to investigate the critical heat flux (CHF) performance in the 5${\times}$5 rod bundle with 5 unheated rods which are supported by Hybrid Mixing Vane. In this study, HFC-134a fluid was used as working fluid and the fluid temperature were measured in the important subchannels. To determine the TDC value, the measured fluid temperatures were compared with the predicted values obtained from the MATRA code. The best optimized value of ${\beta}$ was found to be 0.02 by considering prediction statistics, i.e., average and standard deviations of the differences between the experimental results and code calculations. Using the best optimized value of ${\beta}$ as 0.02, the MATRA code predicts the test results of the fluid temperature within ${\pm}$1.0 % of error. According to the experimental results on CHF of 5 non-heating guide tubes, the case with non-heating guide tube showed a little good performance in terms of CHF.

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Experimental study on characteristics of evaporation heat transfer of $CO_2$ in horizontal micro-channel tube (수평 다채널관 내 이산화탄소의 증발 열전달 특성에 관한 실험적 연구)

  • Lee, Sang-Jae;Kim, Dae-Hoon;Choi, Jun-Young;Lee, Jae-Heon;Kwon, Young-Chul
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2200-2205
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    • 2007
  • In order to investigate the variation on a heat transfer coefficient during evaporation of $CO_2$, basic experiment on the evaporation heat transfer characteristics in a horizontal micro-channel tube was performed. Hydraulic diameters of micro-channels were 0.68 and 1.46 mm. The experiment apparatus consisted of a test section, a DC power supply, a heater, a chiller, a mass flow meter, a pump and a measurement system. Experiments were conducted for various mass fluxes of 300 to 800 kg/$m^2s$, heat fluxes of 10 to 40 kW/$m^2$ and saturation temperatures of -5 to 5$^{\circ}C$. With the increase heat flux, the evaporation heat transfer coefficient increased. And the significantly change of the heat transfer coefficient was observed at any heat flux and mass flux. As the saturation temperature increased and the hydraulic diameter decreased, the heat transfer coefficient increased.

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Condensation Heat Transfer for Pure HFC Refrigerants and a Ternary Refrigerant Mixture Inside a Horizontal Tube (HFC 순수냉매 및 3성분 혼합냉매의 수평관내 응축열전달)

  • Oh, Jong-Taek;Hihara, Eiji
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.2
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    • pp.233-240
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    • 2000
  • An experimental study of condensation heat transfer was performed for pure refrigerants HFC32, HFCI25, and HFC134a, and a ternary refrigerant mixture of HFC32/125/134a (23/25/52wt%). The heat transfer coefficients were measured inside a horizontal smooth tube 5.8 mm I.D. and 8.0 m long. The refrigerant temperature at inlet was 40 $^{\circ}C$, and the mass flux was varied from 150 to 400 $kg/m^2s$. As for the pure refrigerants, the heat transfer coefficient of HFC32/125/l34a decreased as the quality decreased. In addition, the heat transfer coefficient of HFC32/l25/134a was about 20 % lower than HFC 134a at a low mass flux but showed no reduction at a high mass flux. The heat transfer coefficient of ternary refrigerant mixtures was 30% lower on the average than that of the pure refrigerant.

Analysis on Operational Current and Current Distribution between Two Coils of flux-lock Type SFCL (자속구속형 고온초전도 전류제한기의 동작전류와 각 코일의 전류분류 분석)

  • Park, Chung-Ryul;Lim, Sung-Hun;Park, Hyoung-Min;Cho, Hyo-Sang;Han, Byoung-Sung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.8
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    • pp.753-758
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    • 2005
  • A flux-lock type superconducting fault current limiter(SFCL) consists of two coils, which are wound in parallel each other through an iron core, and a high-$T_c$ Superconducting(HTSC) thin film connected in series with coil 2. If the current of the HTSC thin film exceeds its critical current by the fault accident, the resistance of the HTSC thin film generated, and thereby the fault current can be limited by the impedance of the fluk-lock type SFCL. In this paper, we investigated the dependence of both the fault current limiting characteristics and the current distribution between two coils on the operational current of the flux-lock type SFCL through the equivalent circuit analyses and short circuit tests. From the comparison of both the results, the experimental results well agreed with the analyses for equivalent circuit.

Heat Transfer Correlation during Gas-Cooling Process of Carbon Dioxide in a Horizontal Tube

  • Kang Byung-Ha;Choi Yi-Cheol;Kim Suk-Hyun
    • International Journal of Air-Conditioning and Refrigeration
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    • v.14 no.1
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    • pp.19-27
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    • 2006
  • The characteristics of heat transfer and pressure drop have been investigated experimentally during gas-cooling process of carbon dioxide. The results of this study are useful information in the design of a heat exchanger of $CO_2$ refrigerator. The test section consists of 6 series of copper tube, 4.15 and 2.18mm ID, respectively. The inlet temperature, the operating pressure, and the mass flux are varied in the range of $80{\sim}120^{\circ}C,\;{7\sim}10MPa,\;and\;400{\sim}1,900kg/m^2s$, respectively. The heat transfer coefficient of $CO_2$ is affected by temperature, inlet pressure, and mass flux of $CO_2$. At the maximum HTC, the temperature of $CO_2$ nearly accords with the psuedocritical temperature. It is found that the pressure drop is substantially affected by mass flux and inlet pressure of $CO_2$ . The results have been compared with those of previous work. The heat transfer correlation at the gas-cooling process has been also suggested which predicts within the error of 20%.