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http://dx.doi.org/10.14579/MEMBRANE_JOURNAL.2019.29.2.111

Potassium Pentane-1,3,3,5-tetracarboxylate Draw Solute Synthesis and Application of Forward Osmosis Process  

Lee, Hye-Jin (Center for Membrane, Advanced Materials Division, Korea Research Institute of Chemical Technology)
Choi, Jin-Il (Center for Small & Medium Enterprises Support, Technology Commercialization Division, Korea Research Institute of Chemical Technology)
Kwon, Sei (Center for Membrane, Advanced Materials Division, Korea Research Institute of Chemical Technology)
Kim, In-Chul (Center for Membrane, Advanced Materials Division, Korea Research Institute of Chemical Technology)
Publication Information
Membrane Journal / v.29, no.2, 2019 , pp. 111-121 More about this Journal
Abstract
An organic citrate series draw solute was synthesized using diethyl malonate for forward osmosis. The structure of the final compound potassium pentane-1,3,3,5-tetracarboxylate was confirmed by $^1H-NMR$ and $^{13}C-NMR$ analysis. Osmotic pressure, solubility, water permeability and reverse salt flux were measured for the properties of the draw solute. Forward osmosis results showed that the draw solute exhibited higher water flux than other draw solutes of trisodium citrate and tripotassium citrate. Reverse salt flux of all the organic daw solutes was much lower than that of NaCl. The osmotic pressure of the synthesized draw solute was 25% lower than that of NaCl. The solubility of the draw solute was 317 g/ 100 g water, which is 8.8 times higher than that of NaCl. A commercialized nanofiltration membrane was used for the recovery of the draw solute. The draw solute could be effectively recovered at low pressure.
Keywords
forward osmosis; draw solute; reverse salt flux; water flux; nanofiltration;
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Times Cited By KSCI : 4  (Citation Analysis)
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