• Title/Summary/Keyword: C-based surface layer

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Some Consideration on Structure of Carbon fibers during Hot Stretching (고온 연신 열처리 탄소섬유의 구조 고찰)

  • Kim, Hong-Su
    • Korean Journal of Materials Research
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    • v.9 no.1
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    • pp.30-34
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    • 1999
  • A polyacrylonitrile(PAN)-based carbon fiber tow was heat-treated by directly passing electric current through the tow. The effects of the stretching stress applied during high temperature heat-treatment of PAN-based carbon fibers were investigated by measuring the electric resistance changes taking place during the internal resistance heating. The structure parameters characterizing the stacks of carbon layer, such as interlayer spacing, sizes and orientation of the carbon fibers heat-treated with hot-stretching were evaluated as a function of surface temperature of tow during heat treatment in the range of $1000~2400^{\circ}C$. Though the layer extent in the fiber axis direction depends strongly on the electric resistance, the changes in a crystallite parameter is independent of the longitudinal strain.

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Influence of Heat Diffusing Temperature for a (Sr.Ca)$TiO_3$-based Ceramics on Voltage-Current Properties ((Sr.Ca)$TiO_3$계 세라믹의 전압-전류 특성에 미치는 열확산 온도의 영향)

  • 강재훈;박용필;장경욱;오재한;최운식
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.697-700
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    • 2001
  • In this paper, the structural and electrical properties of the Sr$_{1-x}$ Ca$_{x}$TiO$_3$ (0$\leq$x$\leq$0.2) (0$\leq$r$\leq$0.2)-based grain boundary layer ceramics were investigated by X-ray, SEM and V-I system. Increasing the Ca content, the average grain size and the lattice constant were decreased. The relative density of all specimens was >96%. The 2nd phase formed by thermal diffusing from the surface lead to a very excellent electrical properties, that is, $\varepsilon$$_{r}$>50000, tan$\delta$<0.05, $\Delta$C< $\pm$ 10%.\pm$ 10%.%.

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Study on the Dielectric and Voltage-Current Properties of $(Sr{\cdot}Ca)TiO_3$-based Ceramics ($(Sr{\cdot}Ca)TiO_3$계 세라믹의 유전 및 V-I 특성에 관한 연구)

  • Kang, Jae-Hun;Choi, Woon-Shik;Kim, Tae-Wan;Song, Min-Jong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.09a
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    • pp.72-75
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    • 2001
  • In this paper, the $Sr_{1-x}Ca_{x}TiO_{3}(0{\leq}x{\leq}0.2)$ 2)-based grain boundary layer ceramics were fabricated to measured dielectric properties and voltage-current properties. The sintering temperature and time were $1420\sim1520^{\circ}C$, 4hours, in $N_{2}$ gas, respectively. The structural and the dielectric properties were investigated by SEM, X-ray, HP4194A and K6517. The 2nd phase formed by thermal diffusion from the surface lead to a very high apparent dielectric constant, $\varepsilon_r$ > 50000. X-ray diffraction patterns exhibited cubic structure for all specimens. Increasing content of Ca, the peak intensity were decreased.ﱇﶖ⨀ਆᘍ܀㘱㔮㠹㬅K䍄乍

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A 20-GHz Miniaturized Ring Hybrid Circuit Using TFMS on Low-Resistivity Silicon

  • Lee Sang-No;Lee Joon-Ik;Yook Jong-Gwan;Kim Yong-Jun
    • KIEE International Transactions on Electrophysics and Applications
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    • v.5C no.2
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    • pp.76-80
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    • 2005
  • In this paper, a miniaturized ring hybrid circuit is characterized based on a thin film microstrip (TFMS) on low-resistivity silicon. In order to obtain low-loss characteristics, a polyimide layer with 50 $\mu$m thickness is spin-coated onto the silicon to be used for the substrate. First, propagation characteristics of TFMS lines consisting of the ring hybrid circuit are presented. Then, a ring hybrid circuit based on TFMS is featured by employing the triple concentric circle approach for miniaturization. Triple concentric circle lines with $\lambda$$_{g}$/4 or 3$\lambda$$_{g}$/4 line lengths are implemented on the surface of the polyimide by circularly meandering to reduce the circuit size of the designed ring hybrid. Good agreement between measured and simulated results is obtained.

Pt-AlGaN/GaN HEMT-based hydrogen gas sensors with and without SiNx post-passivation

  • Vuong, Tuan Anh;Kim, Hyungtak
    • Journal of IKEEE
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    • v.23 no.3
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    • pp.1033-1037
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    • 2019
  • GaN-based sensors have been widely investigated thanks to its potential in detecting the presence of hydrogen. In this study, we fabricated hydrogen gas sensors with AlGaN/GaN heterojunction and investigated how the sensing performance to be affected by SiN surface passivation. The gas sensor employed a high electron mobility transistors (HEMTs) with 30 nm platinum catalyst as a gate to detect the hydrogen presence. SiN layer was deposited by inductively-coupled chemical vapor deposition as post-passivation. The sensors with SiN passivation exhibited hydrogen sensing characteristics with various gas flow rates and concentrations of hydrogen in inert background gas at $200^{\circ}C$ similar to the ones without passivation. Aside from quick response time for both sensors, there are differences in sensitivity and recovery time because of the existence of the passivation layer. The results also confirmed the dependence of sensing performance on gas flow rate and gas concentration.

Evaluation of Design Temperature for Asphalt Concrete in South Korea (남한의 아스팔트 콘크리트 설계온도 추정에 관한 연구)

  • Lee, Kwang Ho;Kim, Soo Il
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.12 no.2
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    • pp.77-85
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    • 1992
  • Layer material properties of asphalt concrete changes with climatic conditions. Pavement design and analysis should be performed in the representative climatic condition that gives standard physical properties of pavement layer materials. In this study, an evaluation procedure of pavement design temperature is proposed and programed based on damage effect analysis using fatigue failure criterion. Three regions, Seoul, Daegeon, and Pusan, are chosen to obtain the representative climatic data of South Korea. Domestic pavement design temperature is developed by applying the proposed algorithm to 6 domestic pavement section models with the respective regional climatic data. Asphalt concrete pavement failure criterion is also proposed for the condition of developed domestic pavement design temperature. The design temperature for the region of South Korea is estimated as $l7^{\circ}C$, which is converted to $23.6^{\circ}C$ for the AC surface layer temperature. It is found that the procedure to determine design properties of AC surface layer material at $20^{\circ}C$ gives overestimated results of AC moduli for the domestic pavement system. From the comparison study, it is also found that the estimated pavement design temperature is similar to the result of SHELL Design Chart.

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Self-Limiting Growth of ZnO Thin Films and Substrate-Temperature Effects on Film Properties (자기제한적 표면반응에 의한 ZnO 박막성장 및 기판온도에 따른 박막특성)

  • Lee, D.H.;Kwon, S.R.;Lee, S.K.;Noh, S.J.
    • Journal of the Korean Vacuum Society
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    • v.18 no.4
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    • pp.296-301
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    • 2009
  • An inductively coupled plasma assisted atomic layer deposition(ICP-ALD) system has been constructed for the deposition of ZnO thin films, and various experiments of ZnO thin films on p-type Si(100) substrates have been carried out to find the self-limiting reaction conditions for the ICP-ALD system under non-plasma circumstances. Diethyl zinc[$Zn(C_2H_5)_2$, DEZn] was used as the zinc precursor, $H_2O$ as the oxidant, and Ar as the carrier and purge gas. At the substrate temperature of $150^{\circ}C$, atomic layer deposition conditions based on self-limiting surface reaction were successfully obtained by series of experiments through the variation of exposure times for DEZn, $H_2O$, and Ar. ZnO deposition was repeated at different substrate temperatures of $90{\sim}210^{\circ}C$. As a result, the thermal process window(ALD window) for ZnO thin films was observed to be $110{\sim}190^{\circ}C$ and the average growth rate was measured to be constant of 0.29 nm/cycle. Properties of the film's microstructure and composition(Zn, O, etc.) were also studied. As the substrate temperature increases, the crystallinity was improved and ZnO(002) peak became dominant. The films deposited at all temperatures were high purity, and the films deposited at high temperatures had the composition ratio between Zn and O closer to one of a stable hexagonal wurtzite structure.

Microstructure and Corrosion Characteristics of Al-Si Diffusion Coated Ni Base Super alloy (Al-Si확산코팅에 따른 Ni기 초합금의 미세조직과 부식특성)

  • 안종천;김택수;윤동주;이경구
    • Journal of the Korean institute of surface engineering
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    • v.32 no.2
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    • pp.100-108
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    • 1999
  • The microstructure and corrosion properties of Al-Si diffusion coated PWA1426 alloy have been investigated. Experimental variables are included temperatures of heat-treatment and coating thickness. The microstructure of coated layer and corrosion properties were analysed by SEM, EDS and hot corrosion test. Two major processes have been found to contribute to microstructural changes in the coating. These are, firstly, the transformation of the NiAl to other $Ni_2Al_3$-based phase and secondly, the precipitation of Cr containing phases. Specimens heat treated at $1080^{\circ}C$ showed superior corrosion resistance to heat treated at $880^{\circ}C$. These increase in life was attributed to the transformation of NiAl and increased coating thickness of PWA1426 alloy.

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Electrochemical Characteristics of Setaria viridis-Based Carbon Anode Materials Prepared by Thermal Treatment for Lithium-Ion Secondary Batteries (열처리에 의해 제조된 강아지풀 기반 리튬 이온 이차전지용 탄소 음극재의 전기화학적 특성)

  • Dong Ki Kim;Chaehun Lim;Seongjae Myeong;Naeun Ha;Chung Gi Min;Young-Seak Lee
    • Applied Chemistry for Engineering
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    • v.35 no.2
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    • pp.140-147
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    • 2024
  • In order to increase the utilization of biomass, an electrochemical performance was considered after manufacturing a carbon anode material (SV-C) for a Setaria viridis-based lithium ion secondary battery through a heat treatment process. When the heat treatment temperature of the Setaria viridis is as low as 750 ℃, the capacitance (1003.3 mAh/g, at 0.1 C) is high due to the negative (-) charge of oxygen present on the surface attracting lithium, along with the low crystallinity and high specific surface area (126 m2/g), but the capacity retention rate is believed to be as low as 61.0% (at 500 cycles and 1 C). In addition, it was confirmed that when the heat treatment temperature increased to 1150 ℃, the carbon layer was condensed to be excellent in arrangement, and the structural defects were reduced, resulting in a significant reduction in the specific surface area (32 m2/g) of the pores. Furthermore, when the surface defects of the anode material are reduced and the crystallinity is increased, the capacity retention rate is as high as 89.7% (at 500 cycles and 1 C), but the degree of defects is small, the active point is reduced, and the specific capacity is considered to be very low at 471.7 mAh/g. In the scope of this study, it was found that in the case of the Setaria viridis-based carbon anode material manufactured according to the heat treatment temperature, the surface oxygen content and crystallinity have higher reliability on the electrochemical properties of the anode material than the specific surface area.

Biological Studies On Arkshell Culture I. Distribution Of Drifting Larvae Of Te Arkshell, Anadara broughtonii Schrenck (피조개의 양식에 관한 생물학적 연구 I.부유유생의 분포)

  • Yoo, Sung Kyoo;Park, Kyung Yang;Yoo, Myung Sook
    • 한국해양학회지
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    • v.12 no.2
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    • pp.75-81
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    • 1977
  • Distribution of drifting larvae of Anadara broughtnoii SCHRENCK was studied based on the planktonic sampling which has been collected in fifteen sampling areas of southern coast of Korea and Ulsan Bay during summer season from 1973 to 1977. Vertical and horizontal occurrence was analyzed related to the environmental factors such as surface water temperature, current velocity and depth of water column. High density of the larvae was observed in the Chinhae Bay which included the sampling areas Rampo, Sockcheon, Majeon, Changpo, Dangdong, Bedun, Changchoa, and Wonmun. Maximum occurrence of the farvae was accompanied with the highest water temperature of the summer season, and it was usually August when the water temperature was over 27$^{\circ}C$. In August, 1975, the highest density of the farvae was observed, when the mean surface water temperature was the highest compared to those of other years. The first appearence of the drifting larvae was also related to the surface water temperature. Each year the larae begin to appear from the late July and the ready-to-fall larvae appear in abundance from the mid-August. Vertical distribution patterns of the larvae are closely related to the depth of the water column as well as to the current velocity. In shallow water the larvae tend to aggregate in the bottom layer, while they are diffused to some extent in deep water. In shallow water column ( 8m) more or less 75% of the total larvae individuals was observed in the lower 4m layer and in deep water column ( 16m) only 45% of those was found in the lower 4m layer. In the water of lower velocity a large fraction of the larvae population is distributed in the lower depth layer.

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