• Title/Summary/Keyword: C-S-H phase

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Aluminizing and Corrosion of Carbon Steels in N2/0.5%H2S Gas at 650-850℃

  • Abro, Muhammad Ali;Lee, Dong Bok
    • Journal of Surface Science and Engineering
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    • v.48 no.3
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    • pp.110-114
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    • 2015
  • The effect of hot-dip aluminizing on the corrosion of the low carbon steel was studied at $650-850^{\circ}C$ for 20-50 h in $N_2/0.5%\;H_2S$ gas. The aluminized steel consisted primarily of the Al topcoat and the underlying Al-Fe alloy layer. Aluminizing drastically improved the corrosion resistance by forming the ${\alpha}-Al_2O_3$ surface scale. Without aluminizing, the steel formed nonadherent, fragile, thick scales, which consisted of FeS as the major phase and iron oxides such as FeO, $Fe_3O_4$ and $Fe_2O_3$ as minor ones.

Kinetic Behavior of Escherichia coli on Various Cheeses under Constant and Dynamic Temperature

  • Kim, K.;Lee, H.;Gwak, E.;Yoon, Y.
    • Asian-Australasian Journal of Animal Sciences
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    • v.27 no.7
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    • pp.1013-1018
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    • 2014
  • In this study, we developed kinetic models to predict the growth of pathogenic Escherichia coli on cheeses during storage at constant and changing temperatures. A five-strain mixture of pathogenic E. coli was inoculated onto natural cheeses (Brie and Camembert) and processed cheeses (sliced Mozzarella and sliced Cheddar) at 3 to 4 log CFU/g. The inoculated cheeses were stored at 4, 10, 15, 25, and $30^{\circ}C$ for 1 to 320 h, with a different storage time being used for each temperature. Total bacteria and E. coli cells were enumerated on tryptic soy agar and MacConkey sorbitol agar, respectively. E. coli growth data were fitted to the Baranyi model to calculate the maximum specific growth rate (${\mu}_{max}$; log CFU/g/h), lag phase duration (LPD; h), lower asymptote (log CFU/g), and upper asymptote (log CFU/g). The kinetic parameters were then analyzed as a function of storage temperature, using the square root model, polynomial equation, and linear equation. A dynamic model was also developed for varying temperature. The model performance was evaluated against observed data, and the root mean square error (RMSE) was calculated. At $4^{\circ}C$, E. coli cell growth was not observed on any cheese. However, E. coli growth was observed at $10{\circ}C$ to $30^{\circ}C$C with a ${\mu}_{max}$ of 0.01 to 1.03 log CFU/g/h, depending on the cheese. The ${\mu}_{max}$ values increased as temperature increased, while LPD values decreased, and ${\mu}_{max}$ and LPD values were different among the four types of cheese. The developed models showed adequate performance (RMSE = 0.176-0.337), indicating that these models should be useful for describing the growth kinetics of E. coli on various cheeses.

Control Method of the Three-phase VSI for 200KVA UPS (200KVA급 UPS용 3상 전압형 인버터의 제어기법)

  • Yu, B.W.;Lee, S.H.;Choi, J.H.;Choi, C.H.
    • Proceedings of the KIEE Conference
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    • 1997.07f
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    • pp.2259-2261
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    • 1997
  • In this paper, control scheme of the three phase VSI(Voltage Source Inverter) for 200KVA UPS is described. The proposed controller is designed to robust against parameter variations, disturbances and load change using PI controller. The switching pattern is determined to Ramp Comparison Method. The inverter provides pure sinusoidal output voltage with very low THD (Total Harmonic Distortion). Finally, the performance of the proposed inverter is shown by experimental result.

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Dynamic Characteristic Analysis of Multi-bridge PWM Inverter SSSC (다중브리지 PWM 인버터로 구성된 SSSC의 동특성 분석)

  • Bae B.Y.;Park S.H.;Ha Y.C.;Kim H.J.;Han B.M.;Kim H.W.
    • Proceedings of the KIPE Conference
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    • 2001.07a
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    • pp.685-688
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    • 2001
  • This paper proposes an SSSC based on multi-bridge inverters. The dynamic characteristic of the proposed SSSC was analyzed by EMTP simulation and a scaled handware model, assuming that the SSSC is inserted in the transmission line of the one-machine-infinite-bus power system. The proposed SSSC has 6 multi-bridge inverters per phase, which generates 13 pulses for each half period of power frequency. The proposed SSSC generates a quasi-simusoidal output voltage by 90 degree phase shift to the line current The proposed SSSC does not require the coupling transformer for voltage injection, and has a flexibility in operation voltage by increasing the number of series connection.

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Study on the Solid Phase Extraction of Hg(II)-SBDTR Chelate with C18 Disks and Its Application to the Determination of Mercury in Tobacco and Tobacco Additive

  • Yang, Guan-Gyu;Xia, Zhen-Yuang;Wu, Yu-Ping;Sun, Han-Dong;Yin, Jia-Yuan
    • Bulletin of the Korean Chemical Society
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    • v.25 no.4
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    • pp.549-552
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    • 2004
  • A sensitive, selective and rapid method has been developed for the determination of mercury based on the rapid reaction of mercury(II) with p-sulfobenzylidenethiorhodanine (SBDTR) and the solid phase extraction of the colored chelate with $C_{18}$ disks. In the presence of pH 3.5 sodium acetate-acetic acid buffer solution and Emulsifier-OP medium, SBDTR reacts with mercury(II) to form a red chelate of a molar ratio 1 : 2 (mercury to SBDTR). This chelate was prconcentrated by solid phase extraction with $C_{18}$ disks. An enrichment factor of 50 was achieved. The molar absorptivity of the chelate is $1.28{\times}10^5 L{\cdot}mol^{-1}{\cdot}cm^{-1}$ at 545 nm in measured solution. Beer's law is obeyed in the range of 0.01-3 ${\mu}$g/mL. The relative standard deviation for eleven replicates sample of 0.01 ${\mu}$g/mL is 1.65%. This method was applied to the determination of mercury in tobacco and tobacco additive with good results.

Optimizing analytical method in Health Functional Food code with adjustable chromatographic parameters: A case study of vitamin C (건강기능식품공전 시험법의 크로마토그래프법 조건의 조정 및 비타민C에 대한 적용성 평가 연구)

  • Junghoon Shin;Yooseong Jeong;Yong Seok Choi;Sang Beom Han;Dong-Kyu Lee
    • Analytical Science and Technology
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    • v.37 no.3
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    • pp.143-154
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    • 2024
  • In this study, we improved the vitamin C test method and reviewed data on the adjustable range of chromatography conditions for quantification. First, we adjusted the mobile phase conditions such as solvent composition, salt concentration, pH and column temperature and in particular, it was confirmed through an improved test method that the peak derived from the buffer solution could be clearly separated from the target component, vitamin C by adjusting the pH. The retention time of vitamin C was partially changed by adjusting the column diameter, length and particle size but the number of theoretical plates indicated similar values and did not affect the separation and quantitative analysis of the target component. The flow rate according to the column specifications was derived from the equation proposed by the U.S. FDA (Food and Drug administration) and the Korean MFDS (Ministry of Food and Drug Safety), and evaluation of the applicability to vitamin complexes showed high selectivity for vitamin C even with altered stationary phase conditions and flow rates. In conclusion, vitamin C can be optimally separated and detected by changing the chromatographic method conditions and it was confirmed that the mobile and stationary phase conditions of liquid chromatography can be slightly adjusted in case the assay method uses an isocratic elution.

The Magnetic Properties of Rapidly Quenched Yttrium-Palladium-Borocarbides Ribbon

  • Kim, K.S;Yu, S.C;Moon, Y.M;Baek, J, S;Lim, W.Y
    • Journal of Magnetics
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    • v.1 no.1
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    • pp.42-45
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    • 1996
  • We have studied the superconductivity of rapidly quenched $YPd_2B_2C$ ribbons. The superconductivity in bulk $YPd_2B_2C$ is completely suppressed by annealing as-cast ingots at hihger temperature, suggesting that the superconducting phase is metastable. The rapidly quenched sample, in the as-quenched state, shows the superconducting transition temperature of about 21 K. Form our magnetic data, the value for the upper critical field $H_c2$ (0) is estimated to be 10 T. The critical current density and the expected specific heat discontinuity $({\Delta}C/{\gamma}{T_c})$ were obtained to be about$10^8A/m^2$ at 10 Oe and 1.55, respectively.

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Design of a 10Gbps CMOS Clock and Data Recovery Circuit (10Gbps CMOS 클록/데이터 복원회로 설계)

  • Cha, C.H.;Shim, H.C.;Jeon, S.H.;Yu, C.G.
    • Proceedings of the KIEE Conference
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    • 2007.10a
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    • pp.197-198
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    • 2007
  • In this paper, a 10Gbps Clock and Data Recovery circuit is designed in $0.18{\mu}m$ CMOS Technology. The circuit incorporates a multiphase LC oscillator, a quarter-rate Bang-Bang phase detector, a Charge Pump and a second order loop filter. The simulation results show that the designed circuit has a peak-to-peak clock jitter of 4.1ps and a peak-to-peak recovered data jitter of 8ps while consuming about 44mW from a 1.8V supply.

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