• 한국초전도ㆍ저온공학회논문지
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• 제25권2호
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• pp.5-9
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• 2023

The effect of La_0.7Sr_0.3MnO₃ (LSMO) addition on the superconducting property of Bi_1.6Pb_0.4Sr₂Ca₂Cu₃O_10+δ ((Bi, Pb)-2223) polycrystalline samples was studied. LSMO (0.3 wt.% to 2.0 wt.%) added (Bi, Pb)-2223 samples were prepared by using a solid-state reaction method. The XRD analyses show that as the LSMO addition increases, the volume fraction of the Bi-2223 phase is gradually decreased. The critical temperature (T_c) exhibits a gradual decrease with a single transition as the LSMO amount increases up to 1.0 wt.%, but a further addition of LSMO induces an abrupt decrease of T_c with a dual transition. The analyses on the local structure of the CuO₂ plane from the X-ray absorption fine structure (EXAFS) measurements showed that for the samples with low concentration of LSMO up to 1.0 wt.%, the Cu-O bond length and the CuO₂ plane ordering do not degrade from the values of pure (Bi, Pb)-2223, while they get worsen with a further increase of LSMO addition. These results open up the possibility of LSMO as artificial pinning centers of the (Bi, Pb)-2223 system for power application.

• 콘크리트학회논문집
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• 제22권5호
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• pp.659-666
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• 2010

현행 설계기준식에 따르면 초고강도 콘크리트에서는 철근 인장이음길이보다 압축이음길이가 더 길어지는 현상이 발생된다. 압축이음은 단부 지압이 존재하므로, 인장이음보다 길 필요는 없다. 초고강도 콘크리트의 경제적 실용화를 위해 합리적인 압축이음강도의 평가가 필요하다. 이를 위해 설계강도 80, 100 MPa 콘크리트를 이용하여 횡보강근이 없는 압축이음 실험을 수행하였다. 실험 결과 압축이음강도는 콘크리트 강도의 제곱근에 비례하는 것으로 평가되었다. 지압에 의해 발현되는 이음강도는 이음길이와 무관하며 콘크리트 강도의 제곱근에 비례하는 것으로 평가되었다. 58개 실험체의 평균은 $16.5\;\sqrt{f_{ck}}$이다. 부착에 의해 발현되는 강도를 ACI 408식으로 평가한 결과 [실험값]/[이론값]의 비는 평균 0.94로, 인장이음의 부착강도와 거의 유사하였다. 따라서 인장이음강도에 대비한 압축이음강도의 향상은 단부 지압효과로 설명될 수 있다. 실험결과에서 분석된 이음길이와 콘크리트 강도의 영향 특성을 고려하여 압축이음강도 평가식과 압축이음길이 설계식을 제안하였다. 제안된 설계식은 통계적 기법에 기반을 두어, 이음부가 철근 재료강도와 동일한 수준의 신뢰성을 확보할 수 있다.

• 대한기계학회논문집A
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• 제30권4호
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• pp.402-408
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• 2006

Dissimilar friction welding were produced using 15(mm) diameter solid bar in chrome molybedenum steel(KS SCM440) to carbon steel(KS S45C) to investigate their mechanical properties. The main friction welding parameters were selected to endure good quality welds on the basis of visual examination, tensile tests, Vickers hardness surveys of the bond of area and H.A.Z and microstructure investigations. The specimens were tested as-welded and post-weld heat treated(PWHT). The tensile strength of the friction welded steel bars was increased up to 100% of the S45C base metal under the condition of all heating time. Optimal welding conditions were n=2,000(rpm), $P_1=60(MPa),\;P_2=100(MPa),\;t_1=4(s),\;t_2=5(s)$ when the total upset length is 5.4 and 5.7(mm), respectively. The peak of hardness distribution of the friction welded joints can be eliminated by PWHT. Two different kinds of materials are strongly mixed to show a well-combined structure of macro-particles without any molten material and particle growth or any defects.

• Structural Engineering and Mechanics
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• 제67권4호
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• pp.391-401
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• 2018

Locally available Stainless Steel Wire Mesh (SSWM) bonded on a concrete surface with an epoxy resin is explored as an alternative method for the torsional strengthening of Reinforced Concrete (RC) beam in the present study. An experiment is conducted to understand the behavior of RC beams strengthened with a different configuration of SSWM wrapping subjected to pure torsion. The experimental investigation comprises of testing fourteen RC beams with cross section of $150mm{\times}150mm$ and length 1300 mm. The beams are reinforced with 4-10 mm diameter longitudinal bars and 2 leg-8 mm diameter stirrups at 150 mm c/c. Two beams without SSWM strengthening are used as control specimens and twelve beams are externally strengthened by six different SSWM wrapping configurations. The torsional moment and twist at first crack and at an ultimate stage as well as torque-twist behavior of SSWM strengthened specimens are compared with control specimens. Also the failure modes of the beams are observed. The rectangular beams strengthened with corner and diagonal strip wrapping configuration exhibited better enhancement in torsional capacity compared to other wrapping configurations. The numerical simulation of SSWM strengthened RC beam under pure torsion is carried out using finite element based software ABAQUS. Results of nonlinear finite element analysis are found in good agreement with experimental results.

• 한국해양공학회지
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• 제26권1호
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• pp.64-69
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• 2012

Dissimilar friction welds were produced using 15-mm diameter solid bars of chrome molybdenum steel (KS SCM440) and carbon steel (KS SM20C) to investigate their mechanical properties. The main friction welding parameters were selected to ensure good quality welds on the basis of visual examination, tensile tests, Vickers hardness surveys of the bond area and HAZ, and macro-structure investigations. The specimens were tested as-welded and post-weld heat treated (PWHT). The tensile strength of the friction welded steel bars was increased to 100% of the SM20C base metal under the condition of a heating time of more than four seconds. Optimal welding conditions were n = 2,000 (rpm), HP = 60 (MPa), UP = 100 (MPa), HT = 5 (s),and UT = 5 (s), when the total upset length was 7.8 (mm). The hardness distribution peak of the friction welded joints could be eliminated using PWHT. The two different kinds of materials were strongly mixed to show a well-combined structure of macro-particles, with no molten material, particle growth, or defects.

• Bulletin of the Korean Chemical Society
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• 제9권5호
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• pp.303-308
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• 1988

Four crystal structures of dehydrated Ag(I) and Tl(I) exchanged zeolite A, $Ag_{12-x}Tl_x$-A, x = 2, 3, 4, and 5, have been determined by single-crystal x-ray diffraction techniques. Their structures were solved and refined in the cubic space group Pm3m at $21(1)^{\circ}C$. All crystals were ion exchanged in flowing streams of mixed $AgNO_3\;and\;TlNO_3$ aqueous solution, followed by dehydration at $350^{\circ}C$ and $2{\times}10^{-6}$ Torr for 2 days. In all of these structures, one-sixth of the sodalite units contain octahedral hexasilver clusters at their centers and eight $Ag^+$ ions are found on threefold axes, each nearly at the center of a 6-oxygen ring. The hexasilver cluster is stabilized by coordination to eight $Ag^+$ ions. The Ag-Ag distance in the cluster, ca. 2.92 ${\AA}$, is near the 2.89 ${\AA}$ bond length in silver metal. The remaining five-sixths of the sodalite units are empty of silver species. The first three $Tl^+$ ions per unit cell preferentially associate with 8-oxygen rings, and additional $Tl^+$ ions, if present, are found on threefold axes in the large cavity.

• 한국결정학회지
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• 제17권1호
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• pp.10-13
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• 2006

Ethylenediammonium chromate, $C_2H_{10}N_2{\cdot}CrO_4$ 결정구조는 a=6.667(2), b=8.845(2), c=11.827(2) ${\AA}$, 사방정계(Orthorhombic), 공간군 $P2_12_12_1$, 공간군 번호 19이며, Z=4, V=697.4(3) ${\AA}{^3},\;Dc=1.696gcm^{-3},\;{\mu}=1.594mm^{-1}$이었다. 구조분석은 중금속법으로 풀었으며, 최소 자승법으로 정밀화하였고, 최종 신뢰도 값들은 1204개의 회절반점에 대하여 $R_1=0.0254,\;R_w=0.070,\;R_{all}=0.0255$, S=1.133이었다. 두가지 이온들의 자료들은 기존 유사물질들의 자료에 상응하였으며, Ethylenediammonium 이온은 trans 구조로써 주위의 음이온과 사이에 많은 수소결합으로 연결되어 있다.

• Bulletin of the Korean Chemical Society
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• 제10권3호
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• pp.234-238
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• 1989

The crystal structure of partially $Ag^+$-exchanged zeolite A, $Ag_{3.2}Na_{8.8}$-A, vacuum dehydrated at $360^{\circ}C$ and then exposed to 0.1 torr of cesium vapor for 12 hours at $250^{\circ}C$ has been determined by single-crystal X-ray diffraction techniques in the cubic space group Pm3m (a = 12.262(2)${\AA})\;at\;21(1)^{\circ}C$. The structure was refined to the final error indexes $R_1=0.068\;and\;R_2=0.072$ by using 338 reflections for which $I_o\;>\;3{\sigma}(I_o)$ and the composition of unit cell is $Ag_{3.2}Cs_{8.8}-A.\;3\;Cs^+$ ions lie on the centers of the 8-rings at sites of D4h symmetry. Two crystallographycally different 6-ring $Cs^+$ ions were found: 1.5 $Cs^+$ ions at Cs(2) are located inside of sodalite cavity and 4.3 $Cs^+$ ions at Cs(3) are located in the large cavity. The fractional occupancies observed at Cs(2) and Cs(3) indicate that the existence of at least three types of unit cells with regard to the 6-ring $Cs^+$ ions. For example, 50% of unit cells may have two $Cs^+$ ions at Cs(2) and 4 $Cs^+$ ions at Cs(3). 30% of unit cells may have one Cs+ ion at Cs(2) and 5 $Cs^+$ ions at Cs(3). The remaining 20% would have one $Cs^+$ ion at Cs(2) and 4 $Cs^+$ ions at Cs(3). On threefold axes of the unit cell two non-equivalent Ag atom positions are found in the large cavity, each containing 0.64 and 1.92 Ag atoms, respectively. A crystallographic analysis may be interpreted to indicate that 0.64 $(Ag_5)^+$ clusters are present in each large cavity. This cluster may be viewed as a tetrasilver molecule $(Ag_4)^0$(bond length, 2.84${\AA}$) stabilized by the coordination of one $Ag^+$ ion.

• 대한화학회지
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• 제40권3호
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• pp.161-166
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• 1996

6-ethyl-5,-6-dihydrouracil($C_6H_10N_2O_2$)은 단사정계인 공간군 $P2_{1c}$으로 a=10.302(2), b=10.419(3), $c=7.095(1)\AA$, $\beta=106.6(0)^{\circ}$, Z=4, $V=729.7(3)\AA^3$, $D_c=1.29g/cm^3,\;{\lambda}(MoK\alpha)=0.71073\AA$, $\mu=0.010$cm^{-1}$, F(000)=304이며, F>4.0 $\sigma(F)$인 1070개의 관측된 회절점에 대한 R값은 0.054였다. 직접법에 의하여 구조를 풀었으며, 전행열-최소자승법에 의하여 정밀화하였고, C-H 결합길이는 $0.96\AA$에 고정하였다. Hydrouracil 고리는 불규칙한 puckered 각을 가진 envelope conformation으로 되어 있고, 고리에 붙어 있는 에틸기는 axial 방향으로 향하고 있으며, 단위격자속에는 100평면에 거의 평행인 2차원의 결합망을 이룬, 두 개의 분자간 수소결합, N(1)-H---O(7)(1+x, 0.5-y, -0.5+z)와 N(3)-H---O(7)(1+x, 0.5-y, 0.5+z)가 있으며, 이웃 분자와의 최단거리는 C(4)---O(8)(-x, -y, 1-z)의 $3.187\AA$이다.

• Steel and Composite Structures
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• 제3권2호
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• pp.75-95
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• 2003

A numerical model is presented to simulate the mechanical behaviour of composite steel and concrete columns taking into account the interaction between the hollow steel section and the concrete core. The model, based on displacement finite element methods with an Updated Lagrangian formulation, allows for geometrical and material non linearities combined with heating over all or a part of the section and column length. Comparisons of numerical calculations made using the model with 33 fire resistance tests show that the model is able to predict the fire resistance, expressed in minutes of fire exposure, of composite columns with a good accuracy.