• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.17 no.6
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• pp.652-660
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• 2004

The cis-hex-3-ene-1,5-diynyl-bridged diiron compound 3, [(η$^{5}$ - $C_{5}$ M $e_{5}$ ) Fe(dppe)］$_2$($\mu$-C≡C-CH=CH-C≡C), have been prepared and characterized by cyclic voltammetry(CV), and electronic spectroscopy (UV-VIS and near-IR, NMR). From the results, compound 3 show two well resolved, single-electron, reversible oxidation waves by CV, and comproportionation constant(Kc) calculated from the CV data for compound 3. The Mixed-valence (MV) radical cation 3$^{+}$ show strong absorptions in the near IR, 1586 nm, and this band is more readily assigned as MV $\pi$-$\pi$ band of delocalized complex (Robin-Day Mixed-valence Class III), and the $H_{ab}$ , effective coupling parameter are most consistent with electronic delocalization.

• The Bulletin of The Korean Astronomical Society
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• v.44 no.2
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• pp.55.1-55.1
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• 2019

We investigate broadband emission properties of the pulsar wind nebula (PWN) 3C 58 using a spectral energy distribution (SED) model. We attempt to match simultaneously the broadband SED and spatial variations and emission about 3C 58 in X-ray band. We further the model to explain a possible far-IR feature of which a hint is recently suggested in 3C 58: a small bump at ~10^11 GHz in the PLANCK and Herschel band. While external dust emission may easily explain the observed bump, it may be internal emission of PWNe implying an another additional population of particles. Although significance for the bump in 3C 58 is not higher than other PWNe, here we explore possible origins of the IR bump using the emission model and find that a population of electrons with GeV energies can explain the bump. If it is produced in the PWN, it may provide new insights into particle acceleration and flows in PWNe.

• Bulletin of the Korean Chemical Society
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• v.29 no.7
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• pp.1353-1358
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• 2008

Benzyl arylether dendrimers with zinc porphyrin core and terminal vinyl groups have been synthesized and their photophysical properties and the influence of dendritic environments were investigated. Free base porphyrin-cored benzyl arylether dendrimers 1a-1c and 3a-3c, and their zinc derivatives 2a-2c and 4a-4c have been prepared. Absorption spectra are similar for all porphyrin-cored benzyl arylether dendrimers, except that absorption intensity at 280 nm increases in the higher generation of dendrimer. Fluorescence spectra are similar with two bands for all free base porphyrin dendrimers 1a-1c and 3a-3c, although fluorescence intensity ratio of shorter wavelength emission band to longer wavelength band varies with the generation of dendrimer. Emission efficiencies of 1a-1c and 3a-3c are lower than that of TTP. Emission efficiencies of 2a-2c and 4a-4c are higher than that of ZnTTP. Absorption and emission properties of 1a-1c, 2a-2c, 3a-3c, and 4a-4c were affected negligibly with dendritic environments.

• Korean Journal of Soil Science and Fertilizer
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• v.45 no.2
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• pp.127-134
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• 2012

Microwave remote sensing can help monitor the land surface water cycle, crop growth and soil moisture. A ground-based polarimetric scatterometer has an advantage for continuous crop using multi-polarization and multi-frequencies and various incident angles have been used extensively in a frequency range expanding from L-band to Ka-band. In this study, we analyzed the relationships between L-, C- and X-band signatures and soil moisture content over the whole soybean growth period. Polarimetric backscatter data at L-, C- and X-bands were acquired every 10 minutes. L-band backscattering coefficients were higher than those observed using C- or X-band over the period. Backscattering coefficients for all frequencies and polarizations increased until Day Of Year (DOY) 271 and then decreased until harvesting stage (DOY 294). Time serious of soil moisture content was not a corresponding with backscattering over the whole growth stage, although it increased relatively until early August (R2, DOY 224). We conducted the relationship between the backscattering coefficients of each band and soil moisture content. Backscattering coefficients for all frequencies were not correlated with soil moisture content when considered over the entire stage ($r{\leq}0.50$). However, we found that L-band HH polarization was correlated with soil moisture content (r=0.90) when Leaf Area Index (LAI)<2. Retrieval equations were developed for estimating soil moisture content using L-band HH polarization. Relation between L-HH and soil moisture shows exponential pattern and highly related with soil moisture content ($R^2=0.92$). Results from this study show that backscattering coefficients of radar scatterometer appear effective to estimate soil moisture content.

• Publications of The Korean Astronomical Society
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• v.12 no.1
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• pp.85-98
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• 1997

The A-X (0-0) band of CS, which appears in high dispersion IUE spectra of comets Halley (1982i) and Wilson (19861), has been investigated in detail. We developed models, which include fluorescence and collisional processes We found that in order to account for the observed emission band precisely, IUE tracking errors should be included in line shape calculations it has been found that rotational excitation by electrons is a dominant process in determining populations of rotational ground states. We derived an electron density of $2.0\times10^4/cm^3$ at several thousand kilometers from the comet Wilson's nucleus by examining collisional influence on the CS band structure. We presented a band model for the 0-0 band of $C^{34}S$ and discussed the detectability of $^{34}S$ spectroscopically.

• Proceedings of the Korea Electromagnetic Engineering Society Conference
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• 2005.11a
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• pp.259-264
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• 2005

In this paper, a novel compact microstrip-fed antenna with band-rejection characteristic for wideband applications is proposed. By cutting an L-shaped notch on the radiation patch, the wideband property for the proposed antenna is achieved. In addition, a C-shaped slot is introduced to obtain the band rejection operation of the antenna. The antenna, with very small size of $15.5\times21 mm^2$ including the ground plane, operates over 3.08 to 10.97 GHz and has the rejection band of 5.03 to 5.91 GHz for $S_{11}$ < -10 dB.

• Journal of the Korean Institute of Navigation
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• v.15 no.1
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• pp.1-9
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• 1991

The coaxial sample holder with 20mm in diameter and the adaptor from type N connector-to-20mm${\phi}$ coaxial tube are designed and manufactured which have been used for designing and measuring the fabricated microwave absorber. In addition, the measure in method of material constants of the microwave absorbers is described, which is focused on minimizing the error due to the sample's shapes, the fitting conditions, etc. After describing the design method of a single-layed microwave absorber, the microwave absorbers for X-band, C-band and S-band RADARs are designed and fabricated, respectively, which are composed of ferrite, carborn, and binder and have good performance. Futhermore, we develop the high performance microwave absorber in extremely wide-band type for RADAR, which is composed of different material and its mixing ratio and which could cover nearly from 4 to 10 GHz.

• Proceedings of the KSRS Conference
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• 2009.03a
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• pp.202-206
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• 2009

본 논문에서는 X-band GB-SAR 시스템을 이용하여 지상을 모니터링 하였으며, 대기 중의 습도와 거리의 영향을 받는 대기보정 상수를 산출하였다. 시스템에서 X-band 안테나는 중심주파수 9.65 GHz, 밴드 폭 600 MHz이며, 신호의 증폭과 다편파 측정 및 분석을 위해 각각 마이크로파 앰프와 마이크로파 스위치를 이용하였다. Azimuth step과 length는 5 cm와 5 m로 최대 관측 거리는 약 200 m 이다. phase 분석에 쓰인 산란체는 총 5개의 trihedral corner reflector로서, 시스템으로부터의 거리를 각각 다르게 설정하였다. 실험은 3일간 연속적으로 수행되었으며, 실험간 상대습도는 최소 50 %에서 최대 90 %까지로 약 40 %의 변화를 보였다. 고정된 상태의 reflector는 마치 이동한 것과 같은 현상을 보였는데 이는 마이크로화의 전파과정에서 발생하는 거리와 습도에 따른 지연효과라고 판단하였으며, 이를 배제하기 위하여 대기보정식을 산출하였다. 산출과정에서 temporal coherence가 0.98 이하인 reflector의 신호는 제외하였는데 이 경우 시스템 및 reflector의 안정성에 문제가 있다고 판단하였기 때문이다. 산출된 대기보정식은 C-band 안테나를 사용한 실험과 비교하여 보았다.

• Proceedings of the IEEK Conference
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• 2003.11c
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• pp.37-40
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• 2003

The 1.63㎓, 2.33㎓ dual-band PLL frequency synthesizer has been developed for applications to the miniature repeater. The miniature dual-band repeater will be used at shopping mall, basements and underground parking lots. The in-loop 1.63㎓, 2.33㎓ dual-band PLL frequency synthesizer has been developed by designing Si BJT VCO and PLL loop circuits with Colpitts. The prototype of 1.63㎓, 2.33㎓ dual-band PLL frequency synthesizer of size 19${\times}$19${\times}$8(mm) has shown operating frequencies of 1.63㎓, 2.33㎓ ranges, RF output of 1dBm(PCS), 1dBm(IMT-2000), phase noise of -100 dBc/Hz(PCS), -95dBc/Hz(IMT-2000) at 10KHz offset, harmonics suppression of -24dB c(PCS), -15dBc(IMT-2000).

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2007.11a
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• pp.413-414
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• 2007