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http://dx.doi.org/10.5012/bkcs.2008.29.7.1353

Porphyrin-Cored Arylether Dendrimers with Vinyl Groups in the Periphery  

Lim, So-Yeon (Department of Chemistry, Sunchon National University)
Choi, Dae-Ock (Department of Chemistry, Sunchon National University)
Shin, Eun-Ju (Department of Chemistry, Sunchon National University)
Publication Information
Bulletin of the Korean Chemical Society / v.29, no.7, 2008 , pp. 1353-1358 More about this Journal
Abstract
Benzyl arylether dendrimers with zinc porphyrin core and terminal vinyl groups have been synthesized and their photophysical properties and the influence of dendritic environments were investigated. Free base porphyrin-cored benzyl arylether dendrimers 1a-1c and 3a-3c, and their zinc derivatives 2a-2c and 4a-4c have been prepared. Absorption spectra are similar for all porphyrin-cored benzyl arylether dendrimers, except that absorption intensity at 280 nm increases in the higher generation of dendrimer. Fluorescence spectra are similar with two bands for all free base porphyrin dendrimers 1a-1c and 3a-3c, although fluorescence intensity ratio of shorter wavelength emission band to longer wavelength band varies with the generation of dendrimer. Emission efficiencies of 1a-1c and 3a-3c are lower than that of TTP. Emission efficiencies of 2a-2c and 4a-4c are higher than that of ZnTTP. Absorption and emission properties of 1a-1c, 2a-2c, 3a-3c, and 4a-4c were affected negligibly with dendritic environments.
Keywords
Arylether dendrimer; Porphyrin; Absorption spectra; Fluorescence spectra
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Times Cited By KSCI : 4  (Citation Analysis)
Times Cited By Web Of Science : 3  (Related Records In Web of Science)
Times Cited By SCOPUS : 2
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