• E2M - 전기 전자와 첨단 소재
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• 제7권1호
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• pp.32-41
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• 1994

In this study, the TSC spectroscopy has been applied to investigate the influence of structural change due to a process of curing reaction on the electrical properties of epoxy composites cured with acid-anhydride. Five TSC peaks appeared in -160-250[.deg.C]: in the low temperature region below glass transition temperature(T$\_$g/), three relaxation mode peaks due to action of side chains, substitution group or terminal groups have been observed, a peak associated with T$\_$g/, appeared in 110[.deg. C] and p peak due to ionic space charges located in 150[.deg.C]. Each peak was separated into elementary peaks by the partial polarization procedure, and the distribution of activation energy and relaxation time were analized to clearify the origin of each peak. Also, overaboundantly added hardener separated a .betha. peak near 10[.deg. C] into two peaks of .betha.$\_$1/(10.deg. C) and .betha.$\_$2/(20.deg. C) according to increasement of forming field, and the separated hardener was oxidated thermally with increasing surrounding temperatures. The expansion of the free volume need in molecular motion and the reduction of the structural packing density through thermal oxidation process increased TSC between .alpha. peak and .betha. peak and decreased T$\_$g/.

• Fibers and Polymers
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• 제7권4호
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• pp.372-379
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• 2006

The surface topography, tensile properties, and thermal properties of ramie fibers were investigated as reinforcement for fully biodegradable and environmental-friendly 'green' composites. SEM micrographs of a longitudinal and cross sectional view of a single ramie fiber showed a fibrillar structure and rough surface with irregular cross-section, which is considered to provide good interfacial adhesion with polymer resin in composites. An average tensile strength, Young's modulus, and fracture strain of ramie fibers were measured to be 627 MPa, 31.8 GPa, and 2.7 %, respectively. The specific tensile properties of the ramie fiber calculated per unit density were found to be comparable to those of E-glass fibers. Ramie fibers exhibited good thermal stability after aging up to $160^{\circ}C$ with no decrease in tensile strength or Young's modulus. However, at temperatures higher than $160^{\circ}C$ the tensile strength decreased significantly and its fracture behavior was also affected. The moisture content of the ramie fiber was 9.9 %. These properties make ramie fibers suitable as reinforcement for 'green' composites. Also, the green composites can be fabricated at temperatures up to $160^{\circ}C$ without reducing the fiber properties.

• 유변학
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• 제11권1호
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• pp.9-17
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• 1999

본 연구에서는 페놀 수지/탄소섬유 복합재료가 상온에서부터 $400^{\circ}C$까지의 온도범위에서 유리 전이와 분해반응을 경험하면서 나타내는 점탄성 특징을 연구하였다. 가교 결합된 페놀메트릭스의 전형적인 유리전이에 따라 저장 탄성율(storage modulus)은 유리전이에 의하여 감소하였고 고무상태(rubbery state)에 도달함과 동시에 후경화 반응과 분해 반응 등을 포함하는 복합적인 고온반응에 의하여 증가하다가, 최대점을 보인 후 다시 감소하는 모습을 보였다. 유리전이 과정은 시간-온도 중첩원리에 따라 해석하였으나, 분해반응이 수반된 고온에서의 점탄성 특징은 저장 탄성율을 수직 및 수평 방향으로 이동시키어 마스터 커브를 완성 할 수 있었다. 이러한 실험적 결과를 토대로 아레니우스식과 Havriliak-Negami식에서 유추된 점탄성 모델을 이용하여 유리전이와 분해반응이 연속적으로 진행되는 과정을 정량적을 해석할 수 있었다. 이때의 완화시간은 유전이 과정을 통하여 감소하다가 고무상태에 이르러 최소값을 보여주고 이후로는 고온반응에 의하여 증가하는 모습을 보여주었다. 본 연구에서 제안된 점탄성 해석 방법은 반응이 수반된 열경화성 복합재료가 보여주는 점탄성 계수의 복잡한 거동을 온도와 주파수(frequency)에 따라 정확하게 묘사함으로서 이 모델링의 유용성을 증명 할 수 있었다.

• 한국해양공학회지
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• 제14권3호
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• pp.90-99
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• 2000

This study has been investigated about the influence of moisture environment properties in the unidirectional and cross laminated carbon fiber/epoxy and glass fiber/epoxy composites. As a results, it was found that the weight gain of water increased with the immersion time and the mechanical properties were decreased with the weight gain of water. And it was also shown that the mechanical properties of carbon fiber/epoxy laminates were better than those of glass fiber/epoxy laminates. And a gap of the mechanical properties between the two kinds of laminates was increasing with the immersion time in distilled water of 80$^{\circ}C $. Mechanical properties which decreased by moisture absorption in the CF and GF reinforced laminates were recovered up to some extent by drying in oven at 80$^{\circ}C $ for 10 days.

• 수산해양기술연구
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• 제44권3호
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• pp.250-256
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• 2008

Generally the side plate materials of FRP ship are composed of glass fiber and unsaturated polyester resin composites(GFRP composites). In this study, the effect of applied load and sliding speed on friction and wear characteristics of these materials were investigated at ambient temperature by pin-on-disc friction test. The cumulative wear volume, friction coefficient and wear rate of these materials for SiC abrasive paper were determined experimentally. The cumulative wear volume showed a tendency to increase nonlinearly with increase of sliding distance and was dependent on applied load and sliding speed for these composites. The friction coefficient of GFRP composites was increased as applied load increased at same sliding speed in wear test. It was verified by SEM photograph of worn surface that major failure mechanisms were microfracture, deformation of resin, cutting and cracking.

• 한국세라믹학회지
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• 제34권5호
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• pp.483-490
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• 1997

Al2O3/metal composites were fabricated by oxidation and reaction of molten Al-alloy into two types of commercial Al2O3-SiO2 fibrous insulation board. The growth rate, composition and microstructure of these materials were described. An AlZnMg(7075) alloy was selected as a parent alloy. Mixed polycrystalline fiber and glass phase fiber were used as a filler. The growth surface of an alloy was covered with and without SiO2. SiO2 powder was employed as a surface dopant to aid initial oxidation of Al-alloy. Al-alloy, SiO2, fiber block and growth inhibitor CaSiO3 were packed sequentially in a alumina crucible and oxidized in air at temperature range 90$0^{\circ}C$ to 120$0^{\circ}C$. The growth rate of composite layer was calculated by measuring the mass increasement(g) per unit surface($\textrm{cm}^2$). XRD and optical microscope were used to investigate the composition and phase of composites. The composite grown at 120$0^{\circ}C$ and with SiO2 dopant showed rapid growth rate. The growth behavior differed a little depending on the types of fiber used. The composites consist of $\alpha$-Al2O3, Al, Si and pore. The composite grown at 100$0^{\circ}C$ exhibited better microstructure compared to that grown at 120$0^{\circ}C$.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 하계학술대회 논문집
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• pp.813-816
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• 2001

In this paper, the dielectric properties of epoxy composites used for transformers are studied. The dielectric permittivity and loss of specimen are measured at the frequency range of 30[Hz]∼1[MHz] about temperature 20[$^{\circ}C$],100[$^{\circ}C$] and 140[$^{\circ}C$] respectively from a series of experiments. When the filler is added, between epoxy and silica is formed interface. Therefore, observed higher values of dielectric permittivity and loss in filled epoxy are attributed to MWS polarization effect. Also, glass transition temperature was shifted to higher temperature and value of dielectric permittivity and loss were decreased due to 2nd curing. Deformation of interfacial state is improved and value of dielectric permittivity and loss were decreased at low frequency region by the surface treatment of fillers with silane coupling agents.

• 한국세라믹학회지
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• 제44권4호
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• pp.189-193
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• 2007

Effect of additive composition on fracture toughness of in situ-toughened $SiC-Si_3N_4$ composites was investigated for five different additive compositions. The highest toughness $(6.4MPa{\cdot}m^{1/2})\;in\;SiC-Si_3N_4$ composites investigated herein was obtained when an Y-Mg-Si-Al-O-N oxynitride glass was used as a sintering additive. The improvement in fracture toughness was produced by enhanced bridging and deflection by $Si_3N_4$ grains.

• 한국진공학회지
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• 제9권3호
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• pp.279-284
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• 2000

본 연구는 옥외용 epoxy/glass fiber의 열화과정을 분석하기 위하여 FRP 적층판을 고온과 수에 노출시켰다. 열화과정은 접촉각, 표면전위감쇠, 표면저항률의 비교에 의해 평가하였다. 젖음성의 변화는 열처리 시료에서 $200^{\circ}C$까지 접촉각이 증가하였지만 수분처리 시료는 감소하였다. 표면전위감쇠 특성은 수분처리 시료에서는 감소하지만, 열처리 시료는 미 처리와 비교해서 증가하였다. 또한, 표면저항률은 접촉각의 변화와 같은 경향을 보이고 있다.

• Macromolecular Research
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• 제14권5호
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• pp.499-503
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• 2006

This report presents a new technical approach for evaluating the fiber orientation of composites using small-angle light scattering (SALS). Glass fiber (GF)/polypropylene (PP) composites with different fiber orientations were prepared by drawing compression-molded specimens. The drawn samples were remelted and then annealed at $150^{\circ}C$ in order to induce a crystalline structure on the fiber surface, and then underwent SALS analysis. The samples showed a combination of circular and streak patterns. The model calculations demonstrated that the number of nuclei on the fiber surface and the thickness of the transcrystalline layer affected the sharpness and intensity of the streak pattern. In addition, the azimuthal angle of the streak pattern was found to be dependent on the direction of the transcrystalline layer, which correlated with the fiber direction. This correlation suggests that the fiber orientation in the composites can be easily evaluated using SALS.