• 제목/요약/키워드: By-product Feed

검색결과 400건 처리시간 0.033초

머신 러닝과 데이터 전처리를 활용한 증류탑 온도 예측 (Prediction of Distillation Column Temperature Using Machine Learning and Data Preprocessing)

  • 이예찬;최영렬;조형태;김정환
    • Korean Chemical Engineering Research
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    • 제59권2호
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    • pp.191-199
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    • 2021
  • 화학 공정의 주요 설비 중 하나인 증류탑은 물질들의 끓는점 차이를 이용하여 혼합물에서 원하는 생산물을 분리하는 설비이며 증류 공정은 많은 에너지가 소비되기 때문에 최적화 및 운전 예측이 필요하다. 본 연구의 대상 공정은 공급처에 따라 원료의 조성이 일정하지 않아 정상 상태로 운전이 어려워 효율적인 운전이 어렵다. 이를 해결하기 위해 데이터 기반 예측 모델을 이용하여 운전 조건을 예측 할 수 있다. 하지만 미가공 공정 데이터에는 이상치 및 노이즈가 포함되어 있어 예측 성능을 향상시키기 위해 데이터 전처리가 필요하다. 본 연구에서는 인공 신경망 모델인 Long short-term memory (LSTM)과 Random forest (RF)를 사용하여 모델을 최적화한 후, 데이터 전처리 방법으로 Low-pass filter와 One-class support vector machine을 사용하여 데이터 전처리 방법 및 범위에 따른 예측 성능을 비교하였다. 각 모델의 예측 성능과 데이터 전처리의 영향은 R2과 RMSE를 사용하여 비교하였다. 본 연구의 결과, 전처리를 통해 LSTM의 경우 R2은 0.791에서 0.977으로 RMSE는 0.132에서 0.029로 각각 23.5%, 78.0% 향상되었고, RF의 경우 R2은 0.767에서 0.938으로 RMSE는 0.140에서 0.050으로 각각 22.3%, 64.3% 향상되었다.

DETERMINATION OF MOISTURE AND NITROGEN ON UNDRIED FORAGES BY NEAR INFRARED REFLECTANCE SPECTROSCOPY(NIRS)

  • Cozzolino, D.;Labandera, M.;Inia La Estanzuela
    • 한국근적외분광분석학회:학술대회논문집
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    • 한국근적외분광분석학회 2001년도 NIR-2001
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    • pp.1620-1620
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    • 2001
  • Forages, both grazed and conserved, provide the basis of ruminant production systems throughout the world. More than 90 per cent of the feed energy consumed by herbivorous animals world - wide were provided by forages. With such world - wide dependence on forages, the economic and nutritional necessity of been able to characterize them in a meaningful way is vital. The characterization of forages for productive animals is becoming important for several reasons. Relative to conventional laboratory procedures, Near Infrared Reflectance Spectroscopy (NIRS) offers advantages of simplicity, speed, reduced chemical waste, and more cost-effective prediction of product functionality. NIR spectroscopy represents a radical departure from conventional analytical methods, in that entire sample of forage is characterized in terms of its absorption properties in the near infrared region, rather than separate subsamples being treated with various chemicals to isolate specific components. This forces the analyst to abandon his/her traditional narrow focus on the sample (one analyte at a time) and to take a broader view of the relationship between components within the sample and between the sample and the population from which it comes. forage is usually analysed by NIRS in dry and ground presentation. Initial success of NIRS analysis of coarse forages suggest a need to better understand the potential for analysis of minimally processed samples. Preparation costs and possible compositional alterations could be reduced by samples presented to the instrument in undried and unground conditions. NIRS has gained widespread acceptance for the analysis of forage quality constituents on dry material, however little attention has been given to the use of NIRS for chemical determinations on undried and unground forages. Relatively few works reported the use of NIRS to determine quality parameters on undried materials, most of them on both grass and corn silage. Only two works have been found on the determination of quality parameters on fresh forages. The objectives of this paper were (1) to evaluate the use of NIRS for determination of nitrogen and moisture on undried and unground forage samples and (2) to explore two mathematical treatments and two NIR regions to predict chemical parameters on fresh forage. Four hundred forage samples (n: 400) were analysed in a NIRS 6500 instrument (NIR Systems, PA, USA) in reflectance mode. Two mathematical treatments were applied: 1,4,4,1 and 2,5,5,2. Predictive equations were developed using modified partial least squares (MPLS) with internal cross - validation. Coefficient of determination in calibration (${R^2}_{CAL}$) and standard error in cross-validation (SECV) for moisture were 0.92 (12.4) and 0.92 (12.4) for 1,4,4,1 and 2,5,5,2 respectively, on g $kg^{-1}$ dry weight. For crude protein NIRS calibration statistics yield a (${R^2}_{CAL}$) and (SECV) of 0.85 (19.8) and 0.85 (19.6) for 1,4,4,1 and 2,5,5,2 respectively, on a dry weight. It was concluded that NIRS is a suitable method to predict moisture and nitrogen on fresh forage without samples preparation.

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Inhibitory Activity of Garlic Fermented by Pediococcus pentosaceus KACC 91419 against Antibiotic-resistant Pathogens

  • Ham, Jun-Sang;Lee, Seung-Gyu;Kim, Min-Kyung;Oh, Mi-Hwa;Jeong, Seok-Geun;Kim, Dong-Hun;Lee, Se-Hyung;Chae, Jong-Pyo;Lee, Ji-Yoon;Kang, Dae-Kyung
    • Asian-Australasian Journal of Animal Sciences
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    • 제23권9호
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    • pp.1236-1243
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    • 2010
  • The aim of this study was to screen lactic acid bacteria for the fermentation of garlic and to assess the increase in inhibitory activity of garlic fermented against antibiotic-resistant pathogens for use as an animal feed supplement. We screened 45 strains of lactobacillus for the fermentation of garlic. Of these strains, 23 showed similar growth rates with or without allicin. Cultures of the 23 strains were mixed with an equivalent amount of garlic juice and incubated overnight at $37^{\circ}C$. The three strains with the lowest pH values were Lactobacillus paracasei KCTC 3169, L5 strain, and L. reuteri SW. Garlic juice fermented by the L5 strain more strongly inhibited antibiotic-resistant pathogenic bacteria than L. paracasei KCTC 3169, L. reuteri SW, or garlic juice itself. By examining carbohydrate utilization, morphologic properties and 16S rRNA gene sequences, we identified the L5 strain as Pediococcus pentosaceus and deposited it in the name of P. pentosaceus KACC 91419 into the Korea Agricultural Culture Collection. To identify the antimicrobial compound from the garlic filtrate fermented by P. pentosaceus KACC 91419, we fractionated P. pentosaceus KACC 91419 culture on a C18 column and checked the antimicrobial activity of fractions A6 to A10. Only fraction A9 showed inhibitory activity on Staphylococcus aureus. Comparing the mass spectra of the fractions with and without antimicrobial activity, we observed a single dominant product ion (m/z 157.99) from the fraction showing antimicrobial activity. Its molecular mass (157.99) was 2 atomic mass units less than that of allicin (162.02). This suggests that allicin might be converted to its derivative, which has antimicrobial activity, during fermentation by P. pentosaceus KACC 91419.

Effects of High Dietary Levels of Selenium-Enriched Yeast and Sodium Selenite on Macro and Micro Mineral Metabolism in Grower-Finisher Swine

  • Kim, Y.Y.;Mahan, D.C.
    • Asian-Australasian Journal of Animal Sciences
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    • 제14권2호
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    • pp.243-249
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    • 2001
  • Thirty six barrows with an initial body weight of 28 kg were used to determine the effect of two dietary Se sources and a wide range of Se levels encompassing 0.3, 1.0, 3.0, 5.0, 7.0, and 10.0 mg/kg Se. The organic Se form was a Se-enriched yeast product, whereas the inorganic Se source was sodium selenite. The experiment was a $2{\times}6$ RCB design conducted in three replicates. Each barrow was placed in an individual metabolism crate and provided their dietary treatment and water on an ad libitum basis for a minimum 2 wk period, whereupon feed intake was adjusted to a constant intake within replicate at approximately 90% of intake for a 4 d adjustment period. Urine and feces were subsequently collected for a 7 d period and analyzed for Se and minerals. The results demonstrated that urinary Se was approximately 25% higher when pigs were fed sodium selenite (p<0.01), whereas fecal Se was lower by 25% (p<0.01). Se retention tended to be higher when organic Se was provided (p>0.15). Urinary Se increased as dietary Se level increased for both Se sources but increased more and at a high rate when sodium selenite was fed resulting in an interaction response (p<0.01). Fecal Se increased linearly as the dietary level of both Se sources increased, but the fecal Se from organic Se increased at a faster rate resulting in an interaction response (p<0.01). Se retention increased linearly (p<0.01) as dietary Se increased for both Se sources. The apparent digestibility of Se increased by Se level when pigs were fed sodium selenite, but not when the organic Se source was provided resulting in an interaction response (p<0.05). Retention of consumed Ca, Zn increased when pigs were fed organic Se (p<0.05) whereas P and Na retention were higher when the inorganic Se was provided. Mineral retention was not affected by dietary Se level except P. These results suggest that Se excretion by urine was the main route of excretion when pigs were fed sodium selenite but the fecal route when Se-enriched yeast was provided. The excretion of Fe, Zn, Mn, and Cu via urine and feces was not affected by high dietary Se level or dietary Se sources.

셰이빙 스크랩으로부터 콜라겐 펩타이드계 공중합체 합성과 특성 (Synthesis and Characterization of Collagen Peptide Based Copolymer from Shaving Scrap)

  • 박민석;신수범;김호수;김민수;김하선;장재혁;이진규;이동국
    • 공업화학
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    • 제33권6호
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    • pp.581-587
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    • 2022
  • 피혁 산업은 매년 여러 유형의 유해한 피혁 폐기물을 발생시킨다. 그중에서, 셰이빙 스크랩은 크롬이 함유되어 있어 재활용하기 어렵다. 최근에 셰이빙 스크랩을 이용한 흡착제, 충전제 및 가금류 사료와 같은 다양한 부가가치 제품생산에 활용될 수 있는 많은 연구 결과들이 발표되었다. 본 연구에서는 셰이빙 스크랩으로부터 콜라겐 펩타이드를 추출하고, 이들의 물성을 개선하여 새로운 소재로 사용될 수 있는 방법을 연구하였다. 먼저, 수산화나트륨을 이용하여 셰이빙 스크랩에 포함된 크롬을 제거하였다. 그리고 가수분해물을 제조하여 농축 및 저온 결정화를 통해 정제하였다. 정제된 콜라겐 펩타이드 농축물을 스프레이 드라이어를 이용하여 분말로 제조하였다. 추출 및 정제된 콜라겐 펩타이드와 methacrylic anhyride (MAA)를 반응시켜 이중결합을 도입하였으며, 1H 핵자기공명분광법으로 확인하였다. 다음으로, 개질화 콜라겐 펩타이드에 2-ethylhexyl acrylate (2-EHA)와 레독스 중합하여 공중합체를 만들었으며, 적외선 분광분석으로 그라프트 여부를 정성적으로 확인하였다. 결론적으로, 본 연구를 통하여 피혁 폐기물인 셰이빙 스크랩으로부터 콜라겐 펩타이드를 추출한 후 일정한 처리를 통하여 새로운 친환경 재료로 전환할 수 있음을 확인하였다.

Sialic Acid를 지표성분으로 하는 유청가수분해단백분말의 기능성식품 개발연구 - II. 효소분리 용매정제로 고농도 Sialic Acid가 함유된 유청가수분해단백분말(23%)의 랫드를 이용한 90일 반복경구투여 독성시험 평가 연구 - (Development and Research on a Functional Hydrolyzed Whey Protein Powder Product with Sialic Acid as a Marker Compound - II. Repeated 90-day Oral Administration Toxicity Test using Rats Administered Whey Protein Powder containing Highly Concentrated Sialic Acid (23%) produced by Enzyme Separation and Solvent Enrichment Method -)

  • 노혜지;조향현;김희경;고홍범
    • Journal of Dairy Science and Biotechnology
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    • 제34권2호
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    • pp.117-135
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    • 2016
  • 본 시험은 sialic acid가 23%를 함유하도록 제조한 유청가수분해단백분말제제(whey protein of hydrolysis)의 기능성 식품원료로 개발을 위한 동물안전성을 평가에 연구목표를 두었다. 시험물질은 sialic acid 23%(v/v)와 원료인 GMP(glycomacropeptide)가수분해 단백질이 87%(v/v)로 구성되어 있었다(시험명: 23%-GNANA). 시험물질의 독성 유무는 한국식품의약안전청(KFDA, 2014)과 OECD(2008)의 의약품 등의 독성시험 기준에 따라 실시하였다. 평가방법으로서, 시험물질의 투여용량을 0, 1,250, 2,500 및 5,000 mg/kg/day하여 SPF Sprague-Dawley 계열 암수 랫드에 90일 동안 반복경구투여하였을 때 나타나는 독성 여부를 평가하였다. 평가항목으로서는 사망률, 일반증상관찰, 체중 변화, 사료섭취량 측정, 안검사, 요검사, 혈액학적 및 혈액생화학적 검사, 부검 시 장기의 중량 측정, 부검 시 육안적 및 조직병리학적 검사 등을 평가하였다. 결과로서, 시험물질로 인한 일반증상 및 사망동물은 발생하지 않았다. 또한, 안과학적 검사, 요검사 그리고 혈액학적 및 혈액이화학적 이상 여부와 부검 시 육안적 검사 및 조직병리학적 검사에서 대조군 대비 특이한 변화는 관찰되지 않았다(P<0.05). 이외의 평가 항목에서, 암컷은 사료섭취량과 증체율이 다소 감소하였고, 그리고 수컷에서는 요의 SG와 PRO 및 고환 무게가 다소 증가하는 경향을 보였지만, 시험물질-유래 경미한 변화(non-adverse effect)가 고용량군(5,000 mg/kg/day)만 확인되었다. Weight-based classification(독성 강도에 따른 분류)를 적용한 최종 독성평가 결과는 다음과 같다. 수컷의 경우, NOEL(No Observed Effect Level)은 5,000 mg/kg/day 그리고 암컷의 경우는 NOAEL(No Observed Adverse Effect Level)은 5,000 mg/kg/day로 최종 확인되었다. 따라서, 암수 모두에서 시험물질의 NOAEL은 투여최대용량인 5,000 mg/kg/day로 확인되었다. 결론적으로, 시험물질인 유청가수분해단백분말제제는 건강기능식품의 특성상 임상허용용량인 1,000 mg/kg/day의 5배 수준에서 안전함을 확인되었다.

조피볼락(Sebastes schligeli)에 있어 사료내 단백질 사료원으로서의 어분대체품 (Fish Meal Analog as a Dietary Protein Source in Koran Rockfish, Sebastes schlegeli)

  • 김강웅;배승철
    • 한국양식학회지
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    • 제10권2호
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    • pp.143-151
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    • 1997
  • 본 연구는 조피볼락 사료에 있어서 어분대체품을 결정하고, 상품어분대체품과 유인물질의 첨가 효과를 통하여 조피볼락용 어분대체품개발을 위한 기초자료도 사용하고자 수행되었다. 실험사료는 조단백질 52%로, 가용성 에너지 16.8 KJ/g으로 설계되었고, 주단백질원으로 북양어분, 어분대체품 및 상품어분대체품을 사용하였다. 사료의 성분조성은 다음과 같이 요약된다 : 사료1, 100%FM (control) ; 사료2, 60%FM : 40% CFMA ; 사료3, 60%FM : 40% CFMA+ATT ; 사료 4, 80%FM : 20% FMA ; 사료5, 80% FM: 20%FMA+ATT : 사료 6, ; 사료6, 60%FM : 40%FMA+ATT; 사료7, 40%FM : 60% FMA+ATT. 어분대체품은 혈분(BM), 오징어간분(SLP), 육골분(MBM), 수지박(LM), 가금부산물(PBP), 우모분(FM), 필수아미노산(Met, Lys, Ile) 등을 적절히 배합하여 제작 사용하였다. 성장률, 사료효율, 일간성장률 및 단백질효율에 있어서 사료 1은 사료 4, 사료 5 및 사료 6에 비해 유의적인 차이가 없었지만(P>0.05), 나머지 실험구들은 대조구에 비해 유의적으로 낮게 나타났다(P<0.05). 특히, 상품어분대체품(CFMA)인 사료 2와 사료 3은 실험사료로 제작된 동일한 수준의 사료 6과 비교하여 성장률, 사료효율, 단백질효율에서 유의적으로 낮은 경향을 보였다. 0.5% 유인물질을 첨가한 사료 3과 5는 사료 2와 4에 비해 유의적인 차이는 보이지 않았으며(P>0.05), 간중량지수, hemoglobin 및 비만도에 있어서는 유의적인 차이가 나타났다(P<0.05). 따라서, 조피볼락에 있어서 어분대체품(FMA)으로 어분단백질을 40%정도 대체 가능함을 알 수 있었다.

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산 가수분해시 가열방법과 시간 및 추출조건에 따른 대두가공 부산물의 이소플라본 함량 변화 (Analysis of Isoflavone Contents of Soybean By-products with Acid Hydrolysis Method)

  • 한진숙;홍희도;김성란
    • 한국식품영양과학회지
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    • 제35권10호
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    • pp.1420-1426
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    • 2006
  • 여러 유도체 형태로 존재하는 대두 isoflavone을 산 가수 분해 방법 및 시간을 달리하면서 isoflavone 배당체의 aglycone으로의 전환율 및 aglycone의 분해여부를 실험하였다. 산 가수분해시 가열처리 조건을 $105^{\circ}C$ 항온기, $95^{\circ}C$ 수욕조, $120^{\circ}C$ heating block 및 hot plate로 달리한 결과 환류냉각장치를 이용하고 heating block에서 가수분해시키는 방법이 가장 적절한 가수분해 방법인 것으로 나타났다. 가수분해 시간 동안 aglycone의 안정성을 검토한 결과 적정 가수분해 시간인 60분 동안에는 genistein, daidzein 및 glycitein 모두 큰 함량변화가 없었다. 가수분해하는 시료의 양과 산의 비율은 시료 $10\sim30mg$당 1 N HCl 용액 1 mL의 비율이 적정하였다. 이상의 결과로부터 정량법은 0.5 g의 대두 시료에 1 N HCl용액 15 mL를 첨가하고 $120^{\circ}C$의 heating block에서 60분간 가수분해시킨 후 methanol로 50 mL로 정용하고 HPLC로 분석하도록 확립하였다. 이에 따라 대두 가공부산물의 iosflavone을 분석한 결과 착유 및 착유 후 hexane 제거를 위한 열처리 공정에서 isoflavone의 손실은 적은 것으로 나타났다.

Influence of Quaternary Benzophenantridine and Protopine Alkaloids on Growth Performance, Dietary Energy, Carcass Traits, Visceral Mass, and Rumen Health in Finishing Ewes under Conditions of Severe Temperature-humidity Index

  • Estrada-Angulo, A.;Aguilar-Hernandez, A.;Osuna-Perez, M.;Nunez-Benitez, V.H.;Castro-Perez, B.I.;Silva-Hidalgo, G.;Contreras-Perez, G.;Barreras, A.;Plascencia, A.;Zinn, R.A.
    • Asian-Australasian Journal of Animal Sciences
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    • 제29권5호
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    • pp.652-658
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    • 2016
  • Twenty $Pelibuey{\times}Katahdin$ ewes ($35{\pm}2.3kg$) were used to determine the effects of the consumption of standardized plant extract containing a mixture of quaternary benzophenanthridine alkaloids and protopine alkaloids (QBA+PA) on growth performance, dietary energetics, visceral mass, and ruminal epithelial health in heat-stressed ewes fed with a high-energy corn-based diet. The basal diet (13.9% crude protein and 2.09 Mcal of net energy [NE] of maintenance/kg of dry matter) contained 49.7% starch and 15.3% neutral detergent fiber. Source of QBA+PA was Sangrovit RS (SANG) which contains 3 g of quaternary benzophenathridine and protopine alkaloids per kg of product. Treatments consisted of a daily consumption of 0 or 0.5 g SANG/ewe. Ewes were grouped by weight and assigned to 10 pens (5 pens/treatment), with two ewes per pen. The experimental period lasted 70 days. The mean temperature humidity index during the course of this experiment was $81.7{\pm}1.0$ (severe heat stress). There were no treatment effects on water intake. Dry matter intake was not affected (p = 0.70) by treatments, but the group fed SANG had a numerically (11.2%) higher gain in comparison to the control group, SANG improved gain efficiency (8.3%, p = 0.04), dietary NE (5.2%, p<0.01) and the observed-to-expected NE (5.9%, p<0.01). Supplemental SANG did not affect ($p{\geq}0.12$) carcass characteristics, chemical composition of shoulder, and organ weights (g/kg empty body weight) of stomach complex, intestines, and heart/lung. Supplemental SANG decreased liver weight (10.3%, p = 0.02) and increased visceral fat (16.9%, p = 0.02). Rumen epithelium of ewes fed SANG had lower scores for cellular dropsical degeneration (2.08 vs 2.34, p = 0.02), parakeratosis (1.30 vs 1.82, p = 0.03) and neutrophil infiltration (2.08 vs 2.86, p = 0.05) than controls. It is concluded that SANG supplementation helped ameliorate the negative effects of severe heat on growth performance of feedlot ewes fed high-energy corn-based diets. Improvement in energetic efficiency may have been mediated, in part, by anti-inflammatory effects of supplemental SANG and corresponding enhancement of nutrient uptake.

Energy and Ileal Digestible Amino Acid Concentrations for Growing Pigs and Performance of Weanling Pigs Fed Fermented or Conventional Soybean Meal

  • Wang, Y.;Lu, W.Q.;Li, D.F.;Liu, X.T.;Wang, H.L.;Niu, S.;Piao, X.S.
    • Asian-Australasian Journal of Animal Sciences
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    • 제27권5호
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    • pp.706-716
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    • 2014
  • A new strategy of co-inoculating Bacillus subtilis MA139 with Streptococcus thermophilus and Saccharomyces cerevisiae was used to produce fermented soybean meal (FSBM). Three experiments were conducted to determine the concentration of digestible energy (DE) and metabolizable energy (ME) (Exp. 1), apparent ileal digestibility (AID) and standardized ileal digestibility (SID) of amino acids (AA) (Exp. 2), and feeding value (Exp. 3) of FSBM produced by this new strategy (NFSB) compared with soybean meal (SBM) and conventionally available FSBM (Suprotein). In Exp. 1, twenty-four barrows (initial body weight [BW] of $32.2{\pm}1.7kg$) were randomly allotted to 1 of 4 diets with 6 replicates per diet. A corn basal diet and 3 diets based on a mixture of corn and 1 of 3 soybean products listed above were formulated and the DE and ME contents were determined by the difference method. The results showed that there were no differences in DE and ME between SBM and either FSBM product (p>0.05). In Exp. 2, eight barrows (initial BW of $26.8{\pm}1.5kg$) were fitted with ileal T-cannulaes and used in a replicated $4{\times}4$ Latin square design. Three corn-starch-based diets were formulated using each of the 3 soybean products as the sole source of AA. A nitrogen-free diet was also formulated to measure endogenous losses of AA. The results showed that the SID of all AA except arginine and histidine was similar for NFSB and SBM (p>0.05), but Suprotein had greater (p<0.05) SID of most AA except lysine, aspartate, glycine and proline than NFSB. In Exp. 3, a total of 144 piglets (initial BW of $8.8{\pm}1.2$ kg) were blocked by weight and fed 1 of 4 diets including a control diet with 24% SBM as well as diets containing 6% and 12% NFSB or 12% Suprotein added at the expense of SBM. During d 15 to 28, replacing SBM with 6% NFSB significantly improved average daily gain (ADG) and average daily feed intake (ADFI) (p<0.05) for nursery piglets. During the overall experiment, ADG of piglets fed diets containing 6% NFSB was significantly greater (p<0.05) than that of piglets fed SBM. In conclusion, fermentation with the new strategy did not affect the energy content or the AID and the SID of AA in SBM. However, inclusion of 6% NFSB in diets fed to nursery piglets improved performance after weaning likely as a result of better nutritional status and reduced immunological challenge.