• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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• pp.1046-1049
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• 2002

In this study, We fabricated Organic Electroluminescence device, in order to improve the efficiency of Blue OLED in the full-color OLED. We made two sample. Sample A is that We used TPD(N,N‘-bis(3-methylphenyl)-N,N'-diphenylbenzidine} as hole transport layer(HTL), and Butyl-PBD(2-(4-Biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole) as emitting material layer(EML) and Alq3(8-Hydroxyquinoline, aluminum} as electron transport layer(ETL). Sample B is that we used TPD(N, N'-bis(3-methylphenyl)-N,N'-diphenylbenzidine} as HTL and co-evaporated Butyl-PBD and Alq3 as EML. We investigated the characteristic of brightness and current-:voltage. The sample B that co-evaporated Butyl-PBD and Alq3 as EML improved characteristic of brightness and current-voltage than sample A. Maximum luminescence of sample B is $310cd/m^2$ and threshold voltage is 7V.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 하계학술대회 논문집
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• pp.648-651
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• 2001

We studied about luminance characteristics of blue organic electroluminecent device as thickness ratio. The device is fabricated TPD(N,N'-dyphenyl-N-N'-bis(3-methyphenyl) -1,1'-biphenyl-4,4'-diamine) as hole transport layer and Butyl -PBD(1,1,4,4-Tetraphenyl-1,3-butadiene) as emission layer and electron transport layer. Total thickness is 1000${\AA}$ as HTL and ETL, each devices has 500${\AA}$:500${\AA}$. 400${\AA}$:600${\AA}$ and 600${\AA}$:400${\AA}$ of TPD : Butyl-PBD. We obtained the maximum brightness about 175cd/㎡ 500${\AA}$: 500${\AA}$ thickness devices as HTL:ETL

• Macromolecular Research
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• 제14권3호
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• pp.343-347
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• 2006

A novel, blue light-emitting polymer, poly(phenyl-9,9-dioctyl-9',9'dihexanenitrile)fluorene (PPFC6N), containing an alkyl and cyano group in the side chain, was synthesized by Suzuki polymerization and characterized. The polymer structure was confirmed by $^1H-NMR$. The number average molecular weight and the weight average molecular weight of the obtained polymer were 9,725 and 9,943 respectively. The resulting polymer was thermally stable with a glass transition temperature ($T_g$) of $93^{\circ}C$, and was easily soluble in common organic solvents such as THF, toluene, chlorobenzene and chloroform. The HOMO and LUMO energy levels of the polymer were revealed as 5.8 and 2.88 eV by cyclic voltammetry study, respectively. The ITO/PEDOT:PSS (40 nm)/PPFC6N (80 m)/LiF (1 nm)/Al (150 nm) device fabricated from the polymer emitted a PL spectrum at 450 nm and showed a real blue emission for pure PPFC6N in the EL spectrum. When t-butyl PBD was introduced as a hole blocking layer, the device performance was largely improved and the EL spectrum was slightly shifted toward deep blue. The device with PPFC6N containing t-butyl PBD layer showed the maximum luminance of 3,200 $cd/m^2$ at 9.5 V with a turnon voltage of 7 V.

• 센서학회지
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• 제7권2호
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• pp.97-102
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• 1998

PPV(poly(p-phenylenevinylene))를 발광체로 이용한 유기 박막 EL 소자를 다양한 구조와 조건으로 제작하였으며, 그 전기-광학적 특성을 평가하였다. 제작된 EL 소자는 단층구조(ITO(indium tin oxide)PPV/Mg), 이층구조 (ITO/PVK(poly(N-vinylcarbazole))/PPV)Mg와 ITO/PPV/Polymer matrix+PBD/Mg) 그리고 삼층구조 (ITO/PVK/PPV/PS(polystyrene)+PBD(butyl-2-(4-biphenyl)-5-(4-tert-butylphenyl-1,3,4-oxadiazole))/Mg)를 가지며, 그들의 전기광학적 특성을 상호 비교하였다. 이층구조(ITO/PPV)Polymer matrix+PBD/Mg)에서는 PMMA (poly(methyl methacrylate)), PC(polycarbonate) PS 와 MCH(side chain liquid crystalline homopolymer)를 고분자 메트릭스로 사용하였으며, 특히, PS 고분자 메트 릭스를 전자수송층으로 사용하는 경우에 전자수송제인 PBD의 농도에 따른 발광휘도 특성을 구하였다. 제작된 소자의 인가전압에 따른 전류, 휘도특성을 분석한 결과 터널링효과를 나타내었고 안정된 발광특성을 가진다는 것을 알 수 있었다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 하계학술대회 논문집
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• pp.943-946
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• 2001

In this study, We have investigated degradation effects of blue organic electroluminescence devices that was consisted of TPD(N,N'-dyphenyl-N-N\`-bis(3-methyphenyl) as hole transport layer and Butyl-PBD (2- (4-Biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole)-as emission layer and electron transport layer. We have studied characteristics of brightness and current density about blue OEL that was degradated layer. Two kinds of samples that were fabricated each continuous and non-continuous method was used.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.II
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• pp.1410-1412
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• 2005

We present that the electroluminescence (EL) efficiency can be improved by doping an electron transport layer (ETL) with organic materials which can make electron current increase. The electron transport layer of aluminum tris(8 -hydroxyquinoline) (Alq3) is doped with 2-(4-Biphenylyl)-5-(4-tertbutylphenyl)- 1,3,4-oxadiazole) (butyl-PBD) to enhance the electron mobility of the ETL. The higher quantum efficiency of device having ETL using Alq3 doped with butyl-PBD can be attributed to the improved electron and hole balance.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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• pp.366-369
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• 2001

In this study, the matrix Organic Electroluminescence (OEL) device, that was consisted of R,G,B pixels. We fabricated OEL devices by side by side methode and, used organic material Alq3 as green, DCM as red and Butyl PBD as blue ETL. We investigated the characteristic of brightness and current density for matrix OEL device. As the results, each color devices has minimum about $100cd/m^{2}$ brightness and maximum luminescence was $2500cd/m^2$ in green OEL device.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 추계학술대회 논문집
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• pp.366-369
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• 2001

In this study, the matrix Organic Electroluminescence (OEL) device, that was consisted of R,G,B pixels. We fabricated OEL devices by side by side methode and, used organic material Alq3 as green, DCM as red and Butyl PBD as blue ETL. We investigated the characteristic of brightness and current density for matrix OEL device. As the results, each color devices has minimum about 100 cd/㎡ brightness and maximum luminescence was 2500cd/㎡ in green OEL device

• 전자공학회논문지D
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• 제35D권11호
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• pp.55-61
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• 1998

정공 전달 중합체인 Poly(N-vinylcarbazole) (PVK)와 전자전달 유기물 재료인 2-(4-biphenyl)-5-(t-butyl-phenyl)-1,3,4-oxadiazole (Bu-PBD)에 발광 유기물 색소 Coumurine 6, TPB, Rhodamine B를 각각 도핑한 단층박막 유기물 전기발광 소자를 제작하였다. 스핀 코팅 방법에 의한 단층 구조와 가용성 재료의 사용으로부터 소자제작이 간단하였다. 활성영역은 인듐주석산화물(ITO) 과 알루미늄 전극 사이에 놓인 단층으로 구성하고 있다. 이러한 구조에서 전자와 정공의 전하가 각 전극에서 PVK : Bu-PBD 활성층으로 주입된다. 전압을 인가한 후 발광된 빛의 색은 각각 TPB, C6, Rhodamine B의 유기물 색소에 의해 481nm, 500nm, 585nm 파장을 갖는 푸른색, 초록색 및 오렌지색을 나타내었다. PVK유기물은 다른 발광색을 갖는 유기물 색소를 분자 적으로 도핑 함으로서 주요한 중합체로서 사용될 수 있다. 그리고 전기발광색은 전체 가시광선 파장 내로 조절될 수 있다.

• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.326-326
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• 2006

The combination of living anionic and coordination polymerization techniques enabled to synthesize the polystyrene-b-polyisoprene-b-poly (butyl isocyanate) triblock polymers. Their microphase-separated structures were zig-zag structures for high ${\phi}_{PIC}$ samples, and hockey-puck structures were also observed. The phase diagram for PSt-b-PIp-b-PIC rod-coil polymers was different from that for PS-PBd-PMMA triblock polymers, and it was found that ${\phi}_{PIC}$ was the important factor to determine the microphase-separated structures.