• Title/Summary/Keyword: Buffering layer

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Introduction of a Buffering Layer for the Interfacial Stability of LSGM-Based SOFCs (LSGM계 고체산화물 연료전지의 계면안정성을 위한 완층층의 도입)

  • Kim, Kwang-Nyeon;Moon, Jooho;Son, Ji-Won;Kim, Joosun;Lee, Hae-Weon;Lee, Jong-Ho;Kim, Byung-Kook
    • Journal of the Korean Ceramic Society
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    • v.42 no.9 s.280
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    • pp.637-644
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    • 2005
  • In order to find a proper buffering material which can prohibit an unwanted interfacial reaction between anode and electrolyte of LSGM-based SOFC, we examined a gadolinium doped ceria and scandium doped zirconia as a candidate. For this examination, we investigated the microstructural and phase stability of the interface under different buffering layer conditions. According to the investigation, ceria based material induced a serious La diffusion out of the LSGM electrolyte resulted in the formation of very resistive $LaSrGa_3O_7$ phase at the interface. On the other hand zirconia based material was directly reacted with LSGM electrolyte and thus produced very resistive reaction products such as $La_2Zr_2O_7,\;Sr_2ZrO_4,\;LaSrGaO_4\;and\;LaSrGa_3O_7$. From this study we found that an improper buffering material induced the higher internal cell resistance rather than an interfacial stability.

Effect of Complexing/Buffering Agents on Morphological Properties of CuInSe2 Layers Prepared by Single-Bath Electrodeposition

  • Lee, Hana;Lee, Wonjoo;Seo, Kyungwon;Lee, Doh-Kwon;Kim, Honggon
    • Current Photovoltaic Research
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    • v.1 no.1
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    • pp.44-51
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    • 2013
  • For preparing a device-quality $CuInSe_2$ (CISe) light-absorbing layer by single-bath electrodeposition for a superstrate-type CISe cell, morphological properties of the CISe layers were investigated by varying concentrations of sulfamic acid and potassium biphthalate, complexing/buffering agents. CISe films were grown on an $In_2Se_3$ film by applying a constant voltage of -0.5V versus Ag/AgCl for 90 min in a solution with precursors of $CuCl_2$, $InCl_3$, and $SeO_2$, and a KCl electrolyte. A dense and smooth layer of CISe could be obtained with a solution containing both sulfamic acid and potassium biphthalate in a narrow concentration range of combination. A CISe layer prepared on the $In_2Se_3$ film with proper concentrations of complexing/buffering agents exhibited thickness of $1.6{\sim}1.8{\mu}m$ with few undesirable secondary phases. On the other hand, when the bath solution did not contain either sulfamic acid or potassium biphthalate, a CISe film appeared to contain undesirable flake-shape $Cu_{2-x}Se$ phases or sparse pores in the upper part of film.

Link-layer Assisted Seamless Media Streaming over Mobile IP-enabled Wireless LAN (Mobile IP 지원 무선 랜 상에서 링크 계층의 지원을 통한 연속적인 미디어 스트리밍)

  • Lee, Chul-Ho;Lee, Dong-Wook;Kim, Jong-Won
    • Journal of KIISE:Computing Practices and Letters
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    • v.15 no.9
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    • pp.626-636
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    • 2009
  • In Mobile IP-enabled wireless LAN (WLAN), packet flows are corrupted due to the handoff of a mobile node (MN) at the link and network layers, which results in burst packet losses and can cause temporary buffer underflow in a streaming client at the MN. This transient behavior hurts time-sensitive streaming media applications severely. Among many suggestions to address this handoff problem, few studies are concerned with empirical issues regarding the practical validation of handoff options on the time-sensitive streaming media applications. In this paper, targeting seamless streaming over Mobile IP-enabled WLAN, we introduce a seamless media streaming framework that estimates accurate pre-buffering level to compensate the handoff latency. In addition, we propose a link-layer (L2) assisted seamless media streaming system as a preliminary version of this framework. The proposed system is designed to reduce the handoff latency and to overcome the playback disruption from an implementation viewpoint. A packet buffering and forwarding mechanism with L2 trigger is implemented to reduce the handoff latency and to eliminate burst packet losses generated during the handoff. A pre-buffering adjustment is also performed to compensate the handoff latency. The experimental results show that the proposed approach eliminates packet losses during the handoff and thus verify the feasibility of seamless media streaming over Mobile IP-enabled WLAN.

A Proxy-Based Fast Handover Scheme in Mobile WiMAX Networks (Mobile WiMAX에서 Proxy 기반의 고속 핸드오버 방안)

  • Lee, Hwa-Sub;Kim, Bok-Ki;Min, Sang-Won
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.8 no.4
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    • pp.65-72
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    • 2009
  • In this paper, we propose a proxy-based fast handover scheme to improve a performance in the mobile WiMAX network using PMIPv6 for supporting the network-layer mobility. In our proposed scheme, we define three link-layer messages and one network-layer message to reduce the handover latency, and propose a buffering mechanism to minimize packet loss and solve out-of-sequence problem. A performance evaluation indicates that the proposed scheme works more efficiently than PMIPv6 in terms of the handover latency and packet loss.

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Effect of Acid Deposition on the Acidification of Surface Water II : Column and the Field Studies (산성강하물이 지표수의 산성화에 미치는 영향 II: 컬럼연구 및 현장조사)

  • 김영관;우경식
    • Journal of Korea Soil Environment Society
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    • v.2 no.1
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    • pp.35-44
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    • 1997
  • A column study using artificial acid rain was conducted to evaluate the buffering capacities in soil layer and host rock. In an effort to compare the effect of composition of host root two valleys of which compositions of host rock are different were chosen within the study area and the pHs of the water flowing in the valleys were measured from May, 1996 to October, 1996. The pHs of the artificial acid rain prepared by adding appropriate amounts of both sulfuric and nitric acids to distilled water were 3, 4, and 5, and the column effluents were analyzed for major cations and anions. The cation exchange capacities(CECs) of A Horizon and the B Horizon were 9.68 and 6.16 meq/100g, respectively, Compared to the B Horizon, the pH in the column effluent of A Horizon with larger CEC was higher. The sums of $Ca^{2+}$, $Mg^{2+}$, $Na^{+}$in the column effluents gradually decreased, indicating the loss of CEC by acid rain. The field study showed that pHs of the surface water in the valleys increased as the water flows downwards. The magnitude of this buffering capacity was greater for the valley in which smectite in addition to kaolinite and illite was a weathered product of host rocks. This also indicates that host rock as well as soil layer retains the buffering capacity.

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Calretinin-Immunoreactive Amacrine Cells and Ganglion Cells in the Greater Horseshoe Bat, Rhinolophus ferrumequinum (한국관박쥐망막에서 칼레티닌 면역반응성의 무축삭세포 및 신경절 세포에서의 관찰)

  • Jeon, Young-Ki;Jeon, Chang-Jin
    • Journal of Korean Ophthalmic Optics Society
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    • v.12 no.4
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    • pp.133-139
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    • 2007
  • Although the physiological roles of calretinin have not been established, it may simply work as a calcium buffer or may actively work in calcium-mediated signal transduction. Calretinin plays a little role in the transport and physiological buffering of calcium in the adult photoreceptor cells, bipolar cells and horizontal cells of the human retina. We identified the calretinin-immunoreactive neurons in the inner nuclear cell layer and ganglion cell layer and the distribution pattern of the labeled neurons in the retina of a bat, Rhinolophus ferrumequinum, in this study. We observed the existence of calretinin-immunoreactive AII amacrine cell in the inner nuclear layer and ganglion cells in the ganglion cell layer of bat retina through this study. This observation must be significant along with our previous studies as we need to study for more understanding about the unsolved issue of a bat vision and the unique behavioral aspects of bat flight maneuverability.

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Factors affecting the chloride threshold level for steel corrosion in concrete

  • Moon, Han-Young;Ann, Ki-Yong;Kim, Hong-Sam
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.205-208
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    • 2005
  • The present study surveys the concrete properties-concerned factors influencing the chloride threshold level for steel corrosion in concrete, altogether with supporting experimental works, in particular, chloride binding capacity, buffering capacity, condition of steel-concrete interface and cement replacement. It concluded that the order of the dominance on CTL is such that chloride binding < buffering capacity of cement matrix < physical condition of steel-concrete interface. This is attributed to the fact that calcium hydroxide does not form a continuous layer on the steel surface and that bound chlorides are released at the stage of corrosion initiation.

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Single-phase Gallium Nitride on Sapphire with buffering AlN layer by Laser-induced CVD

  • Hwang Jin-Soo;Lee Sun-Sook;Chong Paul-Joe
    • Bulletin of the Korean Chemical Society
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    • v.15 no.1
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    • pp.28-33
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    • 1994
  • The laser-assisted chemical vapor deposition (LCVD) is described, by which the growth of single-phase GaN epitaxy is achieved at lower temperatures. Trimethylgallium (TMG) and ammonia are used as source gases to deposit the epitaxial films of GaN under the irradiation of ArF excimer laser (193 nm). The as-grown deposits are obtained on c-face sapphire surface near 700$^{\circ}$C, which is substantially reduced, relative to the temperatures in conventional thermolytic processes. To overcome the lattice mismatch between c-face sapphire and GaN ad-layer, aluminum nitride(AlN) is predeposited as buffer layer prior to the deposition of GaN. The gas phase interaction is monitored by means of quadrupole mass analyzer (QMA). The stoichiometric deposition is ascertained by X-ray photoelectron spectroscopy (XPS). The GaN deposits thus obtained are characterized by X-ray diffractometer (XRD), scanning electron microscopy (SEM) and van der Pauw method.

Effect of Fiber Content, Yarn Size and Construction of Knit Fabrics on the Buffering Capacity against Water Vapor (편성물의 섬유의 종류, 실의 굵기 및 니트타입에 따른 투습완충능력)

  • Yoo, Hwa-Sook;Hu, Yoon-Sook;Kim, Eun-Ae
    • Journal of the Korean Society of Clothing and Textiles
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    • v.20 no.1
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    • pp.228-238
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    • 1996
  • The purpose of this study was to evaluate the effect of chacteristics of knit fabrics on the microclimate of the skin simulating system. To determine the effect of characteristics of knit fabrics, vapor state of sweat pulse was simulated in the closed system. Different contents of fibers such as cotton, wool and polyester with different yarn size and knit types were chosen for specimens. The changes of humidity and temperature of air layer in the simulated systems were measured. Buffering indices, $K_d$ and $\beta_r$, were determined by considering $\alpha_p, \DeltaP_{max}, t_{max}, and tan\beta$. Physical properties of knit fabrics such as thickness, porosity, air resistance and moisture vapor transport were measured. Results showed that vapor pressure of wool was lower than cotton or polyester This was attributed to the hydrophilicity of wool which absorbed moisture rather quickly and retained in the knit fabric. The time to decrease vapor pressure was faster for polyester than cotton or wool. As a result, $K_d$ was in the order of wool> polye, item> cotton. $\beta_r$ of wool was rower than cotton or polyester due to its lowers porosity and slower desorption rate. For the yarn size, $K_d$ was in the order of 80's> 60's> 30's; thinner and lighter yarn showed better water vapor transport property. For knit type, buffering capacity of single jersey was better than interlock knit fabric. Statistical analysis showed that the air permeability was the most influential factor far the water vapor transport properties.

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Distribution of Calcium Hydroxide at the ITZ between Steel and Concrete

  • Ann Ki-Yong;Kim Hong-Sam;Kim Yang-Bae;Moon Han-Young
    • Journal of the Korea Concrete Institute
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    • v.17 no.3 s.87
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    • pp.481-485
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    • 2005
  • The present study examines the distribution of calcium hydroxide, unhydrated cement grain and porosity at the steel-concrete interface. The formation of calcium hydroxide has been confirmed by microscopic analysis using BSE images containing the ITZ between the steel and concrete. It was found that calcium hydroxide does not form a layer on the steel surface, different from the hypothesis that has been available in investigating the corrosion of steel in concrete, ranging from 5 to $10\%$ within the steel surface. Moreover, the high level of porosity at the ITZ was observed, accounting for $30\%$, which may reduce the buffering capacity of cement hydration products against a local fall in the pH. These findings may imply that the mole of ($Cl^-$) :($OH^-$) in pore solution as chloride threshold level lead to wrong judgement or to a wide range of values.