• Title/Summary/Keyword: Buffer-Function

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In situ Photoacoustic Study of Water Gas Shift Reaction over Magnetite/Chromium Oxide and Copper/Zinc Oxide Catalysts

  • Byun, In-Sik;Choi, Ok-Lim;Choi, Joong-Gill;Lee, Sung-Han
    • Bulletin of the Korean Chemical Society
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    • v.23 no.11
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    • pp.1513-1518
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    • 2002
  • Kinetic studies on the water-gas shift reaction catalyzed by magnetite/chromium oxide and copper/zinc oxide were carried out by using an in situ photoacoustic spectroscopic technique. The reactions were performed in a closed-circulation reactor system using a differential photoacoustic cell at total pressure of 40 Torr in the temperature range of 100 to $350^{\circ}C.$ The CO2 photoacoustic signal varying with the concentration of CO2 during the catalytic reaction was recorded as a function of time. The time-resolved photoacoustic spectra obtained for the initial reaction stage provided precise data of CO2 formation rate. The apparent activation energies determined from the initial rates were 74.7 kJ/mol for the magnetite/chromium oxide catalyst and 50.9 kJ/mol for the copper/zinc oxide catalyst. To determine the reaction orders, partial pressures of CO(g) and H2O(g) in the reaction mixture were varied at a constant total pressure of 40 Torr with N2 buffer gas. For the magnetite/chromium oxide catalyst, the reaction orders with respect to CO and H2O were determined to be 0.93 and 0.18, respectively. For the copper/zinc oxide catalyst, the reaction orders with respect to CO and H2O were determined to be 0.79 and 0, respectively.

Double-walled carbon nanotubes: synthesis, structural characterization, and application

  • Kim, Yoong Ahm;Yang, Kap-Seung;Muramatsu, Hiroyuki;Hayashi, Takuya;Endo, Morinobu;Terrones, Mauricio;Dresselhaus, Mildred S.
    • Carbon letters
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    • v.15 no.2
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    • pp.77-88
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    • 2014
  • Double walled carbon nanotubes (DWCNTs) are considered an ideal model for studying the coupling interactions between different concentric shells in multi-walled CNTs. Due to their intrinsic coaxial structures they are mechanically, thermally, and structurally more stable than single walled CNTs. Geometrically, owing to the buffer-like function of the outer tubes in DWCNTs, the inner tubes exhibit exciting transport and optical properties that lend them promise in the fabrication of field-effect transistors, stable field emitters, and lithium ion batteries. In addition, by utilizing the outer tube chemistry, DWCNTs can be useful for anchoring semiconducting quantum dots and also as effective multifunctional fillers in producing tough, conductive transparent polymer films. The inner tubes meanwhile preserve their excitonic transitions. This article reviews the synthesis of DWCNTs, their electronic structure, transport, and mechanical properties, and their potential uses.

Performance Analysis of Traffic Shaper for an MPEG Video Source (MPEG 비디오원을 대상으로 한 트래픽 쉐이퍼의 성능 분석)

  • Lee, S.C.;Lee, M.Y.;Hong, J.S.;Lie, C.H.
    • Journal of Korean Institute of Industrial Engineers
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    • v.23 no.1
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    • pp.23-37
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    • 1997
  • In this paper, performance analysis of video traffic shaper for Motion Picture Experts Group (MPEG) video traffic in on ATM network are investigated. Traffic shaping for MPEG video traffic is proposed as a traffic control function in ATM networks. The proposed shaper smoothes video traffics by controling the output rate of the buffer, which is placed in an MPEG source, according to I,B,P frame sequences of MPEG. In performance analysis of an video traffic shaper, a periodic botch arrival model is suggested to describe cell streams in a frame of MPEG video traffic. The queueing model which has periodic independent botch arrival and periodic deterministic service time is used to obtain the cell loss ratio, the mean cell delay, and the measure of smoothing effect. Simulation results are used to validate this queueing model. The cell loss performance of ATM multiplexer is measured by simulation study with real MPEG-1 data. From the viewpoint of traffic load, the cell loss ratio is observed to be considerably high, which is considered to result from the burstiness of MPEG video traffic. As a result, it is shown that the shaping decreases cell loss ratio of multiplexer. The results of this paper can be employed to establish a basic guideline in the implementation of a traffic control scheme and the design of ATM multiplexer for MPEG video traffic.

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An NMR study on the intrinsically disordered core transactivation domain of human glucocorticoid receptor

  • Kim, Do-Hyoung;Wright, Anthony;Han, Kyou-Hoon
    • BMB Reports
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    • v.50 no.10
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    • pp.522-527
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    • 2017
  • A large number of transcriptional activation domains (TADs) are intrinsically unstructured, meaning they are devoid of a three-dimensional structure. The fact that these TADs are transcriptionally active without forming a 3-D structure raises the question of what features in these domains enable them to function. One of two TADs in human glucocorticoid receptor (hGR) is located at its N-terminus and is responsible for ~70% of the transcriptional activity of hGR. This 58-residue intrinsically-disordered TAD, named tau1c in an earlier study, was shown to form three helices under trifluoroethanol, which might be important for its activity. We carried out heteronuclear multi-dimensional NMR experiments on hGR tau1c in a more physiological aqueous buffer solution and found that it forms three helices that are ~30% pre-populated. Since pre-populated helices in several TADs were shown to be key elements for transcriptional activity, the three pre-formed helices in hGR tau1c delineated in this study should be critical determinants of the transcriptional activity of hGR. The presence of pre-structured helices in hGR tau1c strongly suggests that the existence of pre-structured motifs in target-unbound TADs is a very broad phenomenon.

Study on the Design and Fabrication of Traveling-Wave Ti:LiNbO$_3$Phase Optical Modulators (진행파형 Ti:LiNbO$_3$위상 광변조기 설계 및 제작에 관한 연구)

  • 정홍식;서정하;엄진섭
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.19 no.9
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    • pp.1782-1792
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    • 1994
  • Ti : $LiNbO_3$ traveling-wave phase optical modulators at wavelength 1.3㎛ have been designed and fabricated, focusing on the optical waveguide and asymmetric coplanar electrode structure. To improve the phase-mismatch of traveling-wave ACPS electrode, the characteristic impedance, effective microwave index, and electrode loss have been presented as a function of geometric parameters including electrode and buffer layer thickness. Low-loss channel optical waveguides on $LiNbO_3$ were fabricated by the Ti diffusion method with $O_2$ water-vapor environment. $2.5{\mu}m$ thick electrode was successfully fabricated by double-spin image reversal process. Modulation bandwidth was limited by a resonance at 2.9 GHz and modulation bandwidth up to 2.5GHz was approxirnately measured.

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A Comparative study of Assessment Techniques for Soil Ecosystem Health: Focusing on Assessment Factors of Soil Health (토양생태계 건강성 평가기법 비교연구: 토양건강성 평가항목을 중심으로)

  • Chae, Yooeun;Kim, Shin Woong;Kwak, Jin Il;Yoon, Youngdae;Jeong, Seung-Woo;An, Youn-Joo
    • Journal of Soil and Groundwater Environment
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    • v.20 no.3
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    • pp.15-24
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    • 2015
  • The soil ecosystem is a complex system performing particularly complicated and varied functions, such as providing a habitat for organisms, acting as a medium for plant cultivation and growth, and functioning as a buffer against external materials in the environment. To assess whether these important functions of the soil ecosystem are executed appropriately, the concept of soil ecosystem health has been introduced, which is defined as the ability to perform the specific functions of the soil ecosystem. Understanding soil properties and soil indicators related to soil functions is essential to assess the soil health. In this study, systems, the indicators, and evaluation factors for assessing soil ecosystem health employed in a number of countries were investigated and discussed. In particular, it is necessary to introduce a technique for the evaluation of soil ecosystem health in Korea and to develop techniques and indicators appropriate to the soil ecosystem and status in Korea.

Analysis of Urban Green Areas using NDVI and Development of a Model to Analyze Bird Diversity in Urban Parks (NDVI를 활용한 도시 녹지 분석 및 도시공원 조류 종다양성 분석 모형 개발)

  • Song, Won-Kyong
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.21 no.1
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    • pp.73-82
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    • 2018
  • Urban parks are important bird habitat in cities. Various studies have evaluated the habitat function of urban parks focused on field surveys. In this study, we performed applicability of NDVI obtained from Landsat 8 OLI image as a factor for spatial planning considered bird diversity. This study was classified with green boundary into three groups using NDVI's value. Environmental variables were calculated by the green area ratio of the surrounding area from 100m to 500m at each groups. The 20 environmental variables such as park area, park shape index, canopy of tree, etc. were derived, the regression analysis was performed as a dependent variable for the bird diversity of urban parks. As a result, the park area and the green area ratio of Group 3, classified high NDVI, within the 100m buffer were adopted as the variables in the regression model. In other words, it was confirmed that as the park becomes larger, the distribution of key green areas within a radius of 100m of the parks becomes higher, the diversity of bird species has increased. It was appropriate to use satellite image, NDVI to analyze species diversity in urban area.

Effect of thermo-mechanical treatment on fabrication of Ag tapes for YBCO coated conductor (차세대 선재 기판용 Ag 테이프의 제조공정에서 가공 열처리가 집합조직에 미치는 영향)

  • Lee, N.J.;Oh, S.S.;Park, C.;Song, K.J.;Ha, D.W.;Kwon, Y.K.;Ryu, K.S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.04a
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    • pp.46-49
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    • 2002
  • The aim of this paper is to investigate the influence of various deformation ratio on texture of Ag tapes that can be used as a RE-$Ba_2Cu_3O_{7-{\delta}}$ coated conductor tapes without any buffer layer. We fabricated as-rolled Ag substrate with various deformation ratio per step. Thickness and total deformation ratio of Ag tapes were $100{\mu}m$ and >98%, respectively. And as-rolled Ag substrate was annealed at $750^{\circ}C$ for 30min. The as-rolled and recrystallization textures were measured using x-ray pole figures and orientation distribution function (ODF) analysis. With the increase of rolling ratio from 5 to 20%, deformation texture are changed from {1l0}<311> to {1l0}<112>, {032}<100>, {051}<211>. After recrystallization by annealing, main texture was observed to {013}<100> under present condition.

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Myocardial Protection of Contractile Function After Global Ischemia by Compound K in the Isolated Heart

  • Kim, Jong-Hoon
    • Journal of Ginseng Research
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    • v.33 no.4
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    • pp.268-277
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    • 2009
  • Ginsenosides are among the most well-known traditional herbal medicines frequently used for the treatment of cardiovascular symptoms in South Korea. The anti-ischemic effects of compound K (CK), a metabolite of ginsenoside Rb1, on ischemia-induced isolated rat hearts were investigated through the analyses of the changes in the hemodynamics (blood pressure, aortic flow, coronary flow, and cardiac output) and the measurement of the infarct region. The subjects in this study were divided into four groups: the normal control, the CK-alone group, the ischemia-induced group without any treatment, and the ischemia-induced group treated with CK. No significant differences in perfusion pressure, aortic flow, coronary flow, and cardiac output were found between the groups before ischemia was induced. The oxygen and buffer supply was stopped for 30 min to induce ischemia 60 min after reperfusion in the isolated rat hearts, and the CK was administered 5 min before ischemia induction. The CK treatment significantly prevented decreases in perfusion pressure, aortic flow, coronary flow, and cardiac output under ischemic conditions. In addition, the hemodynamics (except for the heart rate) of the group treated with CK significantly recovered 60 min after reperfusion, unlike in the control group. CK significantly limited the infarct. These results suggest that CK treatment has distinct anti-ischemic effects in an exvivo model of an ischemia-reperfusion-induced rat heart.

VLSI Implementation of Forward Error Control Technique for ATM Networks

  • Padmavathi, G.;Amutha, R.;Srivatsa, S.K.
    • ETRI Journal
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    • v.27 no.6
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    • pp.691-696
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    • 2005
  • In asynchronous transfer mode (ATM) networks, fixed length cells of 53 bytes are transmitted. A cell may be discarded during transmission due to buffer overflow or a detection of errors. Cell discarding seriously degrades transmission quality. The quality degradation can be reduced by employing efficient forward error control (FEC) to recover discarded cells. In this paper, we present the design and implementation of decoding equipment for FEC in ATM networks based on a single parity check (SPC) product code using very-large-scale integration (VLSI) technology. FEC allows the destination to reconstruct missing data cells by using redundant parity cells that the source adds to each block of data cells. The functionality of the design has been tested using the Model Sim 5.7cXE Simulation Package. The design has been implemented for a $5{\times}5$ matrix of data cells in a Virtex-E XCV 3200E FG1156 device. The simulation and synthesis results show that the decoding function can be completed in 81 clock cycles with an optimum clock of 56.8 MHz. A test bench was written to study the performance of the decoder, and the results are presented.

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