• Journal of the Korean Chemical Society
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• v.53 no.5
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• pp.491-498
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• 2009

The critical micelle concentration (CMC) and the counter ion binding constant (B) for the mixed micellizations of DBS (sodium dodecylbenzenesulfonate) with Brij 30 (polyoxyethylene(4) lauryl ether) and Brij 35 (polyoxyethylene (23) lauryl ehter) at 25 ${^{\circ}C}$ in pure water and in aqueous solutions of n-butanol were determined as a function of $\alpha$1 (the overall mole fraction of DBS) by the use of electric conductivity method. Various thermodynamic parameters (Xi, $\gamma$i, Ci, aiM, $\beta$, and ${\Delta}H_{mix}$) were calculated and compared for each mixed surfactant system by means of the equations derived from the nonideal mixed micellar model. There sults show that the molecules of DBS interact more strongly with Brij 35 than Brij 30 and that the DBS/Brij35 mixed system has greater negative deviation from the ideal mixed micellar model than the DBS/Brij 30mixed system.

• Journal of the Korean Chemical Society
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• v.50 no.5
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• pp.355-361
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• 2006

The critical micelle concentration (CMC) and the counterion binding constant (B) in a mixed micellar state of the sodium dodecylbenzenesulfonate (DBS) with the polyoxyethylene(23) lauryl ether (Brij 35) at 25oC in water and aqueous solutions of n-butanol (0.1M, 0.2M, and 0.3M) were determined as a function of a1 (the overall mole fraction of DBS) by the use of electric conductivity method and surface tensiometer method. Various thermodynamic parameters (Xi, i, Ci, aiM, , and Hmix) were calculated by means of the equations derived from the nonideal mixed micellar model. The effect of n-butanol on the micellization of the DBS/Brij 35 mixtures has been also studied by analyzing the measured and calculated thermodynamic parameters.

• Journal of the Korean Chemical Society
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• v.51 no.2
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• pp.129-135
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• 2007

The critical micelle concentrations (CMC) and the counter ion binding constants (B) in a micellar state of the mixed surfactant systems of Tetradecyltrimethylammonium bromide (TTAB) with Polyoxyethylene(23) lauryl ether (Brij 35) in water were determined as a function of α1 (the overall mole fraction of TTAB) by the use of electric conductivity method and surface tensiometer method from 15 oC to 35 oC. Values of thermodynamic parameters (ΔGom, ΔHom, and ΔSom) for the micellization of TTAB/Brij 35 mixtures were calculated and analyzed from the temperature dependence of CMC values. The results say that the measured values of ΔGom are all negative at the whole measured condition but the values of ΔSom and ΔHom are positive or negative, depending on the measured temperature and α1.

• Applied Chemistry for Engineering
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• v.18 no.3
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• pp.267-272
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• 2007

The critical micelle concentration (CMC) and the counterion binding constant (B) in a mixed micellar state of the trimethyltetradecylammonium bromide (TTAB) with the polyoxyethylene (23) lauryl ether (Brij 35) at $25^{\circ}C$ in water and in aqueous solutions of n-butanol (0.1 M, 0.2 M, and 0.3 M) were determined as a function of ${\alpha}_1$ (the overall mole fraction of TTAB) by the use of electric conductivity method and surface tensiometer method. Various thermodynamic parameters ($X_i$, ${\gamma}_i$, $C_i$, ${a_i}^M$, ${\beta}$, and ${\Delta}H_{mix}$) were calculated by means of the equations derived from the nonideal mixed micellar model. The effects of n-butanol on the micellization of TTAB/Brij 35 mixtures have been also studied by analyzing the measured and calculated thermodynamic parameters.

• Journal of the Korean Chemical Society
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• v.52 no.5
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• pp.461-467
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• 2008

• Journal of the Korean Chemical Society
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• v.52 no.2
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• pp.111-117
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• 2008

critical micelle concentration (CMC) and the counter ion binding constant (B) in a mixed micellar state of the trimethyltetradecylammonium bromide (TTAB) with the polyoxyethylene (23) lauryl ether (Brij 35) at 25oC in water and in aqueous solutions of butanol isomers were determined as a function of 1 (the overall mole fraction of TTAB) by the use of electric conductivity method and surface tensiometer method. Various thermodynamic parameters (Xi, i, Ci, aiM, and Hmix) were calculated by means of the equations derived from the nonideal mixed micellar model. The results say that the effects of butanol isomers on the micellization of TTAB/Brij 35 mixtures have been in the order of n-butanol>iso-butanol>t-butanol> water.

• Journal of the Korean Chemical Society
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• v.53 no.2
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• pp.118-124
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• 2009

The values of critical micelle concentration (CMC) and counter ion binding constants (B) in a micellar state of CPC (1-hexadecylpyridinium chloride) with Brij 35 (polyoxyethylene(23) lauryl ether) in water were determined as a function of ${\alpha}_1$ (the overall mole fraction of CPC) by the use of electric conductivity method. Various thermodynamic parameters ($X_i,\;{\gamma}_i,\;C_i,\;a_{i}^{M},\;\beta,\;and\;{\Delta}H_{mix}$) were calculated and analyzed by means of the equations derived from the non-ideal mixed micellar model. And thermodynamic parameters (${\Delta}{G^o}_m,\;{\Delta}{H^o}_m,\;and\;{\Delta}{S^o}_m$) for the micellization of CPC/Brij 35 mixtures were also calculated from the temperature dependence of the CMC values. The values of ${\Delta}{G^o}_m$ are all negative, but the values of ${\Delta}{S^o}_m$ and ${\Delta}{H^o}_m$ are positive or negative, depending on the measured temperature and ${\alpha}_1$.

• Applied Chemistry for Engineering
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• v.30 no.2
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• pp.241-246
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• 2019

In this paper, reactive surfactants were synthesized by using acrylic acid or 3-butenoic acid as nonionic surfactants, polyoxyethylene(23) lauryl ether (Brij 35) and polyoxyethylene(20) stearyl ether (Brij S20). The synthesis of surfactants was confirmed by FT-IR and $^1H$-NMR. The surface tension, emulsifying property, and foam power and stability were also measured. The surface tension value was 35~41 dyne/cm at an critical micelle concentration (cmc) which was measured as $1.0{\times}10^{-4}{\sim}9.7{\times}10^{-5}mol/L$ using a surface tension method. The emulsifying power of synthesized surfactant was measured with benzene, soybean oil and monomer. Also, the initial height of the bubbles and the height after 5 minutes were measured and the values were compared with each other.

• Membrane Journal
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• v.16 no.4
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• pp.294-302
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• 2006

Silver polymer electrolytes are very promising membrane materials for the separation of olefin/paraffn mixtures. Olefin molecules are known to be transported through reversible complex formation with silver ions entrapped iii polymer matrix. However, they have poor long-term stability, which is very important fur the industrial application; the selectivity through the membrane decreases gradually with time mostly due to the reduction of silver ions ($Ag^+$) into silver nanoparticles ($Ag^0$). In this study, the stability of silver polymer electrolyte was investigated for poly(vinyl pyrrolidone) (PVP) and $AgBF_4$ system containing a surfactant, i.e. $C_{18}H_{35}(OCH_2CH_2)_{20}OH$ (Brij98) as a stabilizer. The reduction behavior of silver ions to silver nanoparticles in PVP was also investigated by atomic force microscopy (AFM) and UV-visible spectroscopy. It was found that the growth of silver nanoparticles was slower and selectivity of polymer electrolyte for propylene in propylene/propane was maintained longer time when Brij98 was added as a stabilizer.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2006.04a
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• pp.153-156
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• 2006

유류오염토양의 자연복원 시 생물이용도(bioavailability)를 높이기 위해 사용되는 계면활성제의 영향을 살펴보고자 제지 폐수로부터 분리한 미생물과 5가지 계면활성제를 사용하였다. 계면활성제로는 Brij 35, Brij 30, Triton X-100, Tween 40, Tween 80을 사용하였으며 유류오염물질로는 PAHs를 사용하여 계면활성제 별 미생물의 성장률 및 PAHs 분해율을 살펴보았다. 그 결과 각각의 계면활성제에 따라 서로 다른 미생물 성장 및 PAHs 분해능을 보였다. 계면활성제에 따른 미생물 성장은 Tween 계열에서 뚜렷했으며 이들 중 Tween 40에서는 PAHs의 분해능 또한 가장 활발하였다.