• Bulletin of the Korean Chemical Society
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• v.7 no.5
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• pp.395-399
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• 1986

Intramolecular proton transfer equilibria of acetamide and methyl carbamate have been studied theoretically by MNDO MO method. For both substrates, carbonyl-O protonated tautomer was found to be the most stable form, the next most stable one being N-protonated form. Gas phase proton transfers take place by the 1,3-proton rearrangement process and in all cases have prohibitively high activation barriers. When however one solvate water molecule participates in the process, the barriers are lowered substantially and the process proceeds in an intermolecular manner through the intermediacy of the water molecule via a triple-well type potential energy surface; three wells correspond to reactant(RC), intermediate(IC) and product complex(PC) of proton donor-acceptor pairs whereas two transition states(TS) have proton-bridge structure. General scheme of the process can be represented for a substrate with two basic centers(heteroatoms) of A and B as, $$ABH\limits^+\;+\;H_2O\;{\to}\;ABH\limits^+{\cdots}{\limits_{RC}}OH_2\;{\to}\;AB{\cdots}H\limits_{TS}^+{\cdots}{\limits_{1}}OH_2\;{\to}\;AB{\cdots}{\limits_{IC}}H\limits^+OH_2\;{\to}\;BA{\cdots}H\limits_{TS}^+{\cdots}{\limits_{2}}OH_2\;{\to}\;BA H\limits^+{\cdots}{\limits_{PC}}OH_2\;{\to}\;BAH\limits^+\;+\;H_2O$$ Involvement of a second solvate water had negligible effect on the relative stabilities of the tautomers but lowered barrier heights by 5∼6 Kcal/mol. It was calculated that the abundance of the methoxy-O protonated tautomer of the methyl carbamate will be negligible, since the tautomer is unfavorable thermodynamically as well as kinetically. Fully optimized stationary points are reported.

• Smart Structures and Systems
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• v.24 no.5
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• pp.567-585
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• 2019

In the past two decades, structural health monitoring (SHM) systems have been widely installed on various civil infrastructures for the tracking of the state of their structural health and the detection of structural damage or abnormality, through long-term monitoring of environmental conditions as well as structural loadings and responses. In an SHM system, there are plenty of sensors to acquire a huge number of monitoring data, which can factually reflect the in-service condition of the target structure. In order to bridge the gap between SHM and structural maintenance and management (SMM), it is necessary to employ advanced data processing methods to convert the original multi-source heterogeneous field monitoring data into different types of specific physical indicators in order to make effective decisions regarding inspection, maintenance and management. Conventional approaches to data analysis are confronted with challenges from environmental noise, the volume of measurement data, the complexity of computation, etc., and they severely constrain the pervasive application of SHM technology. In recent years, with the rapid progress of computing hardware and image acquisition equipment, the deep learning-based data processing approach offers a new channel for excavating the massive data from an SHM system, towards autonomous, accurate and robust processing of the monitoring data. Many researchers from the SHM community have made efforts to explore the applications of deep learning-based approaches for structural damage detection and structural condition assessment. This paper gives a review on the deep learning-based SHM of civil infrastructures with the main content, including a brief summary of the history of the development of deep learning, the applications of deep learning-based data processing approaches in the SHM of many kinds of civil infrastructures, and the key challenges and future trends of the strategy of deep learning-based SHM.

• Journal of the Korean Society of Hazard Mitigation
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• v.11 no.1
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• pp.15-22
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• 2011

In this research, static load test is performed to verify the arch effect and structural performance of CFTA(Concrete-Filled and Tied steel tubular Arch) girder, and FE(Finite Element) analysis is performed to investigate validity of the test result. CFTA girder is designed to maximize the benefit of each material, such as steel plate, filled concrete and PS tendon. Static load test is performed based on the frame-analysis result of 12m sample miniature model. The result of static load test is that structural performance and safety of CFTA girder are confirmed and there is different deflection mode with other structural form result from arch effect. FE analysis with ABAQUS is also performed to show the validity of the truck collision safety and static load test.

• Smart Structures and Systems
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• v.24 no.1
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• pp.83-94
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• 2019

Passive negative stiffness dampers (NSDs) that possess superior energy dissipation abilities, have been proved to be more efficient than commonly adopted passive viscous dampers in controlling stay cable vibrations. Recently, inertial mass dampers (IMDs) have attracted extensive attentions since their properties are similar to NSDs. It has been theoretically predicted that superior supplemental damping can be generated for a taut cable with an IMD. This paper aims to theoretically investigate the impact of the cable sag on the efficiency of an IMD in controlling stay cable vibrations, and experimentally validate superior vibration mitigation performance of the IMD. Both the numerical and asymptotic solutions were obtained for an inclined sag cable with an IMD installed close to the cable end. Based on the asymptotic solution, the cable attainable maximum modal damping ratio and the corresponding optimal damping coefficient of the IMD were derived for a given inertial mass. An electromagnetic IMD (EIMD) with adjustable inertial mass was developed to investigate the effects of inertial mass and cable sag on the vibration mitigation performance of two model cables with different sags through series of first modal free vibration tests. The results show that the sag generally reduces the attainable first modal damping ratio of the cable with a passive viscous damper, while tends to increase the cable maximum attainable modal damping ratio provided by the IMD. The cable sag also decreases the optimum damping coefficient of the IMD when the inertial mass is less than its optimal value. The theoretically predicted first modal damping ratio of the cable with an IMD, taking into account the sag generally, agrees well with that identified from experimental results, while it will be significantly overestimated with a taut-cable model, especially for the cable with large sag.

• Korean Chemical Engineering Research
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• v.56 no.6
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• pp.811-818
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• 2018

A fire and explosion accident caused by a liquefied petroleum gas (LPG) welding and cutting torch gas leak occurred 10 m underground at the site of reinforcement work for bridge columns, killing four people and seriously injuring ten. We conducted a comprehensive investigation into the accident to identify the fundamental causes of the explosion by analyzing the structure of the construction site and the properties of propane, which was the main component of LPG welding and cutting work used at the site. The range between the lower and upper explosion limits of leaking LPG for welding and cutting work was examined using Le Chatelier's formula; the behavior of LPG concentration change, which included dispersion and concentration change, was analyzed using the fire dynamic simulator (FDS). We concluded that the primary cause of the accident was combustible LPG that leaked from a welding and cutting torch and formed a explosion range between the lower and upper limits. When the LPG contacted the flame of the welding and cutting torch, LPG explosion occurred. The LPG explosion power calculation was verified by the blast effect computation program developed by the Department of Defense Explosive Safety Board (DDESB). According to the fire simulation results, we concluded that the welding and cutting torch LPG leak caused the gas explosion. This study is useful for safety management to prevent accidents caused by LPG welding and cutting work at construction sites.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.32 no.5
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• pp.323-331
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• 2019

In this study, a computational model approach for the modeling of hydrodynamic pressures acting on radial gates during strong earthquakes is proposed. The use of the dynamic layering method with the Arbitrary Lagrangian Eulerian (ALE) algorithm and the SIMPLE method for simulating free reservoir surface flow in addition to moving boundary interfaces between the fluid domain and a structure due to earthquake excitation are suggested. The verification and validation of the proposed approach are realized by comparisons performed using the renowned formulation derived by the experimental results for vertical and inclined dam surfaces subjected to earthquake excitation. A parameter study for the truncated lengths of the two-dimensional fluid domain demonstrates that twice the water level leads to efficient and converged computational results. Finally, numerical simulations for large radial gates with different curvatures subjected to two strong earthquakes are successfully performed using the suggested computational model.

• Journal of the Architectural Institute of Korea Structure & Construction
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• v.35 no.6
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• pp.153-164
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• 2019

The presence of thermal bridges in a building envelope cause additional heat loss which increases the heating energy. Given that a higher building insulation performance is required in these cases, the heat loss via thermal bridges is a high proportion of the total heat energy consumption of a building. For the dry exterior insulation system that uses mullions and transoms to fix insulation and exterior materials such as stone and metal sheet, the occurrence of thermal bridges at mullions and transoms is one of the main reasons for heat loss. In this study, a dry exterior insulation system using the truss insulation frame (TIF) was proposed as an alternative to metal mullions. To evaluate the building envelope performance, structural, air-leakage, water-leakage, fire-resistance, thermal, and condensation risk tests were conducted. In addition, the annual energy consumption associated with heating and cooling was calculated, including the linear thermal transmittance of the thermal bridges. As a result, the dry exterior insulation system using TIF achieved the allowable value for all tests. It was also determined that the annual heating load of a building was reduced by 36.7 % when the TIF dry exterior insulation system was used, relative to the dry exterior insulation system using steel pipes without additional insulations.

• Ecology and Resilient Infrastructure
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• v.7 no.4
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• pp.353-365
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• 2020

In this study, the characteristics of bed elevation changes of the Nakdong River when weir gates are opened were analyzed using the Hydrologic Engineering Center-River Analysis System (HEC-RAS). The study area was 292.37 km downstream of the Gudam Bridge to the Nakdong estuary of the Nakdong River. The HEC-RAS program, which is a 1D numerical analysis model, was used to simulate bed elevation changes. Simulations were conducted under two scenarios from 2017 to 2019. Scenarios 1 and 2 were devised under the conditions of a fully opened gate and during gate installation, respectively. Results confirmed that, under the conditions of Scenario 1, deposition occurred in most sections from the Hapcheon-Changnyeong weir to the Changnyeong-Haman weir (a distance of approximately 40 km). In addition, it was predicted that the flow that included sediments in the main stream of the Nakdong River was not interrupted by the weir structure and regularly produced changes in the river bed.

• The Transactions of the Korean Institute of Power Electronics
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• v.26 no.3
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• pp.214-221
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• 2021

SiC MOSFETs require a faster and more reliable short-circuit protection circuit than conventional methods due to narrow short-circuit withstand times. Therefore, this research proposes a short-circuit protection circuit using a current-sensing circuit based on Rogowski coil. The method of designing the current-sensing circuit, which is a component of the proposed circuit, is presented first. The integrator and input/output filter that compose the current-sensing circuit are designed to have a wide bandwidth for accurately measuring short-circuit currents with high di/dt. The precision of the designed sensing circuit is verified on a double pulse test (DPT). In addition, the sensing accuracy according to the bandwidth of the filters and the number of turns of the Rogowski coil is analyzed. Next, the entire short-circuit protection circuit with the current-sensing circuit is designed in consideration of the fast short-circuit shutdown time. To verify the performance of this circuit, a short-circuit test is conducted for two cases of short-circuit conditions that can occur in the half-bridge structure. Finally, the short-circuit shutdown time is measured to confirm the suitability of the proposed protection circuit for the SiC MOSFET short-circuit protection.

• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.6
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• pp.102-112
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• 2020

In this study, in order to design a wedge-type anchor that can hold an wide carbon plate with a width of 100 mm or more that can be used in a bridge structure, the mechanical behaviors are evaluated based on the main design variables such as the angle of the wedge and the coefficient of friction between the guide and the wedge. The stress state of the carbon plate was calculated by numerical analysis method for each design variable, and the performance of the anchor in the critical state was evaluated according to the failure criteria for composite material, and the optimal design specifications of the anchor were determined based on numerical results. The performance of the optimally designed anchor was verified through actual experiments, and the results of this study are considered to be useful for the optimal design of the CFRP plate anchor to reinforce large structures.