• Title/Summary/Keyword: Borate

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Effects of Texture on the Electrochemical Properties of Single Grains in Polycrystalline Zinc

  • Park, Chan-Jin;Lohrengel, Manuel M.;Hamelmann, Tobias;Pllaski, Milan;Kwon, Hyuk-Sang
    • Corrosion Science and Technology
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    • v.3 no.2
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    • pp.54-58
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    • 2004
  • Effects of texture on the electrochemical behaviors of single grains in polycrystalline zinc were investigated using a capillary-based micro-droplet cell. Pontiodynamic sweeps and capacity measurements were carried out in pH 9 borate buffer solution. The cyclic voltammograms and the capacity measurements on single grains with different crystallographic orientations in polycrystalline Zn showed a strong dependence of oxide growth on crystallographic grain orientation. The total charge consumed for oxide formation and the inverse capacity increased with an increase of surface packing density of grain. suggesting the oxide formation was greater on grains with higher surface packing density.

Afterglow Properties of LLBO Scintillation Crystal (리튬 루테튬 보레이트 섬광단결정의 잔광 특성)

  • Kim, Sunghwan
    • Journal of Sensor Science and Technology
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    • v.23 no.6
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    • pp.416-419
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    • 2014
  • We grew a $Li_6Lu(BO_3)_3:Ce^{3+}$ single crystal as a new scintillator. And, the scintillation and thermoluminescence properties of the scintillator were determined. The emission spectrum of $Li_6Lu(BO_3)_3:Ce^{3+}$ is located in the range of 370~530 nm, peaking at 416 nm and 439 nm, due to the $5d{\rightarrow}4f$ transition of $Ce^{3+}$ ions. The fluorescence decay time of the crystal is composed two components. The fast component is 34 ns (84%) and the slow component is 125 ns (16%) of the crystal. The afterglow is caused by the electron and hole traps in the crystal lattice. We determined physical parameters of the traps in the crystal. The thermoluminescence trap are composed a trap. The determined activation energy (E) and frequency factor (s) of the TL trap are 1.05 eV and $4.4{\times}10^{10}s^{-1}$, respectively.

Halomonas sp. ES-10균주가 생산하는 효소세제용 알칼리성 Protease

  • 김찬조;이재숙;최성현;오만진
    • Microbiology and Biotechnology Letters
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    • v.25 no.1
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    • pp.51-55
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    • 1997
  • To utilize the alkaline protease produced by Halomonas sp. ES-10 as an enzyme detergent, the crude enzyme was obtained by methanol precipitation and lyophilization. And it was processed to coated enzyme.The best mixing ratio of components such as coated enzyme, builders, actives, fillers and adjuvants on detergency was examined, and temperature and pH influencing detergency were also tested. Detergency test 0.15% detergent solution was carried out on EMPA test cloth #116 with shaking(90 rpm) for 10 min after 30 min of pretreatment. The detergent which contained coated-enzyme 1%, Zeolite 4A 20%, Tween 80 1. 5%, sodium borate 30%, sodium meta silicate 7.5% and water 40% showed about 90% of washing efficiency at 40$\circ $C and pH 10.0.

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Manufacture and Mechanical Properties of $ABO_w/AC4CH$ Composite Material ($ABO_w/AC4CH$복합재료의 제조 및 기계적 특성)

  • 허선철;박원조;허정원
    • Transactions of the Korean Society of Automotive Engineers
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    • v.9 no.5
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    • pp.188-194
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    • 2001
  • Metal matrix composites with whisker reinforcements have significant potential for demanding mechanical applications including defense, aerospace, and automotive industries. Especially, metal matrix composites, which are reinforced with aluminum borate whisker, have been used for the part of piston head in automobile because of good specific strength and wear resistance. Aluminum alloy-based metal matrix composites with whisker reinforcements have been produced using squeeze casting method, which is kind of an infiltration method. In this study, AC4CH-based metal matrix composites with $Al_{18}B$_4$O_{33}$ reinforcement have been produced using squeeze casting method, after T6 heat treatment, we evaluated mechanical properties of matrix and MMC composite were evaluated.

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The Electrochemical Properties of Supercapacitor for Smart Grid Energy Storage System with Variation of MWCNT/Super P Content (스마트 그리드 에너지 저장시스템 슈퍼커패시터의 MWCNT/Super P 함량에 따른 전기 화학적 특성)

  • Lee, Du-Hee;Lee, Kyoung-Min;Yoon, Jung-Rag
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.11
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    • pp.843-847
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    • 2010
  • This paper in concerned with the electrochemical properties for supercapacitor of composition with variation of super P/MWCNTs(multi-walled carbon nanotubes) contents. Electrochemical properties of the super P/MWCNTs were measured by cyclic voltammetry at the scan rates of 0.5 mV/s is $TEABF_4$(tetra-ethyl-ammonium-tetra-fluoro-borate) as electrolytes. As a result, the composition for 6 wt% content of MWCNTs led to an increase of capacitance, but DC resistance were decreased. It was found that the content and dispersion appearance of MWCNTs was attributed to the increase in capacitance and lower DC resistance.

VUV luminescence properties of a novel green-emitting $(Y,Gd)Ga_3(BO_3)_4$:Tb phosphor

  • Moon, Young-Min;Choi, Sung-Ho;Lim, Sang-Ho;Jung, Ha-Kyun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1561-1564
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    • 2007
  • $Tb^{3+}-activated$ green-emitting $(Y,Gd)Ga_3(BO_3)_4$ phosphor has been investigated. The main absorption was in the $120{\sim}238$ nm and exhibited a green emission with the 545 nm and several peaks due to inner shell transition of $Tb^{3+}$ ion. With the optimized $Tb^{3+}$ concentrations, the maximum emission brightness was 90% of the $Zn_2SiO_4$:Mn phosphor.

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Design of Single Ion Conductive Solid Polymer Electrolytes Utilizing the Characteristics of the Boron Atom

  • Matsumi, Noriyoshi;Ohno, Hiroyuki
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.275-275
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    • 2006
  • A series of organoboron polymer electrolytes were prepared and their ion conductive characteristics was investigated in detail. Alkylborane type polymer electrolytes prepared by hydroboration polymerization exhibited improve lithium transference number due to efficient anion trapping of alkylborane unit. A lithium borate type polymer/salt hybrid was also successfully prepared by dehydrocoupling polymerization of lithium mesitylhydrorate. Ionic conductivity of single ion conductive polymer/salt hybrid was further improved in the case of comb like polymer/boron stabilized imido anion hybrid prepared via polymer reaction of poly(organoboron halide) with hexylamine and PEO monomethylether and subsequent neutralization with lithium hydride.

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Potentiometric Sensor for the Determination of Dibucaine in Pharmaceutical Preparations and Electrochemical Study of the Drug with BSA

  • Ensafi, Ali A.;Allafchian, A.R.
    • Bulletin of the Korean Chemical Society
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    • v.32 no.8
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    • pp.2722-2726
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    • 2011
  • Plasticized poly(vinyl chloride), PVCs, with different membrane compositions tested for use in the construction of an ion-selective sensor for the determination dibucaine. A prepared membrane with dioctyl phthalate-PVC and ion-pair of N-(1-naphthyl)ethylenediamine dihydrochloride-tetraphenyl borate had a good potential to acts as a potentiometric sensor for the analysis of dibucaine. A linear relationship was obtained between potential and logC varying between $1.0{\times}10^{-6}$ and $1.0{\times}10^{-2}$ M dibucaine with a good repeatability and reproducibility. The sensor was applied for the determination of the drug in pharmaceuticals and biological fluids such as plasma and urine samples with satisfactory results. The drug electrode has also been used to study the interaction of bovine serum albumin (BSA) with dibucaine. The saturated quantities of dibucaine binding were 13.04, 5.30 and 9.70 mol/mol in 0.01, 0.02 and 0.1% of protein, respectively.

The Study on Chemical Durable Zinc-phosphate Glasses with $B_2$$O_3$Addition ($B_2$$O_3$첨가에 따른 Zinc Phosphate Glasses의 화학적 안정화)

  • 류봉기;이병철;이성욱;황차원;이종성
    • Journal of the Korean Ceramic Society
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    • v.38 no.6
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    • pp.593-595
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    • 2001
  • Zinc-phosphate glasses에 B$_2$O$_3$를 도입하여 borate, phosphate, boro-phosphate networks가 혼재되어 있는 highly cross-linked structures를 형성시켜 Phosphate glasses의 화학적 안정화를 검토하였다. Raman 측정 결과 B$_2$O$_3$와 P$_2$O$_{5}$는 잘 혼화된 polynary networks를 이루고 있으며, 이렇게 하여 증진된 구조적 cross-linking에 의하여 xB$_2$O$_3$.(1-x)Zn$_2$P$_2$O$_{7}$ glasses의 T$_{g}$, T$_{d}$는 증가하였고 동시에 CTE는 감소하는 결과를 가져왔다.

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The Polarographic Wave of Co (III)-Triethanolamine Complex (코발트(III)-Triethanolamine 錯鹽의 폴라로그라프波에 對하여)

  • Hwang Am Kim
    • Journal of the Korean Chemical Society
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    • v.7 no.1
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    • pp.34-37
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    • 1963
  • Cobalt(Ⅲ) ion gives two step waves with $E_{1/2}$-0.1V(?)(vs.S.C.E.) and $E_{1/2}$-1.37V(vs. S.C.E.) from a base electrolyte consisting of 0.1 M TEA+sodium borate+0.0002% gelatin. The first wave results from the reduction Co(Ⅲ) to Co(Ⅱ). The second wave corresponding to the reduction Co(Ⅱ) to Co(0) and this wave is diffusion controlled. The diffusion current constant of the second wave is 2.7. Under these-conditions, diffusion current of the second wave is proportional to the concentration of Co (Ⅱ) in the range of $10^{-3}{\sim}10^{-4}$ M.

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